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Chemistry

AIEEE 2011

PARTCCHEMISTRY
61. Amongthefollowingthemaximumcovalentcharacterisshownbythecompound :
(1) SnCl2
(2) AlCl3
(3) MgCl2
(4) FeCl2
61. (2) Greaterthenumberofcovalentbond,greateristhecovalency.
62. ThepresenceorabsenceofhydroxygrouponwhichcarbonatomofsugardifferentiatesRNA
andDNA?
(1) 2nd
(2) 3rd
(3) 4th
(4) 1st
62. (1) 2ndcarbon.
63. TrichloroacetaldehydewassubjectedtoCannizzarosreactionbyusing NaOH.Themixtureof
theproductscontainssodiumtrichloroacetateandanothercompound.Theothercompoundis :
(1) Trichloromethanol
(2) 2,2,2Trichloropropanol
(3) Chloroform
(4) 2,2,2Trichloroethanol

63. (4)

Cl O

Cl O
Cl-C-C-H

OH

Cl-C-C-H

Cl3C-C-H

ClO

Cl-C-C-OH+Cl3C-C-H

ClOH

Cl

Cl

64. Sodiumethoxidehasreactedwithethanoylchloride.Thecompoundthatisproducedinthe
abovereactionis :
(1) 2Butanone
(2) Ethylchloride (3) Ethylethanoate (4) Diethylether
O

64. (3)

CH3-C-Cl

EtO-

CH3-C-OEt

65. Thereductionpotentialofhydrogenhalfcellwillbenegativeif :
(1) p(H2)=1atmand[H+]=1.0M
(2) p(H2)=2atmand[H+]=1.0M
+
(3) p(H2)=2atmand[H ]=2.0M
(4) p(H2)=1atmand[H+]=2.0M

.059 H+
log
65. (2) Emf = 0+
P
2
H2

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66. Thestrongestacidamongstthefollowingcompoundsis :
(1) HCOOH
(2) CH3CH2CH(Cl)CO2H
(3) ClCH2CH2CH2COOH
(4) CH3COOH
66. (1) Formicacidisstronger.
67. Thedegreeofdissociation(a)ofaweakelectrolyte, AxByisrelatedtoVantHofffactor(i)bythe
expression :

a=

(1)

i- 1
(2) a = x+ y- 1
x+ y+ 1
i- 1

(3)

a=

x+ y+ 1
i- 1

(4)

a=

i- 1
(x+ y- 1)

67. (4) AxBy xA+ +yB

1a
xa ya
\ i =1+ a (x + y1)
(i1)/( x + y1)= a
68. aandbarevanderWaalsconstantsforgases.Chlorineismoreeasilyliquefiedthanethane
because
(1) a and b for Cl2< a and b for C2H6
(2) a forCl2 < a forC2H6butb forCl2>b for C2H6
(3) a forCl2 > a forC2H6butb forCl2<b for C2H6
(4) a and b for Cl2> a and b for C2H6
68. (3) a forCl2 > a forC2H6butb forCl2<b for C2H6
69. Avesselat1000Kcontains CO2withapressureof0.5atm.Someofthe CO2isconvertedinto
CO ontheadditionofgraphite.Ifthetotalpressureatequilibriumis0.8atm,thevalueof K is :
(1) 3atm
(2)
0.3atm (3) 0.18atm
(4) 1.8atm
69. (4) CO2 +C 2CO
.5p
2p
.5+ p = .8
p =.3
Kp=(.36/.2)=1.8
70. Boroncannotformwhichoneofthefollowinganions?
(1) BH4
(2) B (OH)4
(3) BO2

(4) BF63

70. (4) Itcantgive sp3d2state.

71. Whichofthefollowingfactsaboutthecomplex[Cr(NH3)6]Cl3iswrong?
(1) Thecomplexisparamagnetic
(2) Thecomplexisanouterorbitalcomplex
(3) Thecomplexgiveswhiteprecipitatewithsilvernitratesolution
(4) Thecomplexinvolves d2sp3hybridisationandisoctahedralinshape
71. (2)
Cr+3=[Ar],3d3
(NH3)beingstrongerligandwillform d2sp3

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72. EthyleneglycolisusedasanantifreezeinacoldclimateMassofethyleneglycolwhichshould
beaddedto4kgofwatertopreventitfromfreezingat6Cwillbe :
(Kfforwater=1.86Kkgmol1,andmolarmassofethyleneglycol=62gmol1)
(1) 204.30g
(2) 400.00g
(3) 304.60g
(4) 804.32g
72. (4) 6=(1.86W)/(624)

\ W =800

73. Whichoneofthefollowingorderspresentsthecorrectsequenceoftheincreasingbasicnature
ofthegivenoxides?
(1) MgO<K2O<Al2O3 < Na2O
(2) Na2O<K2O<MgO< Al2O3
(3) K2O< Na2O< Al2O3 < MgO
(4) Al2O3 <MgO<Na2O< K2O
73. (4) Basedonelectropositivecharacterofgivenmetal.
74. Therateofachemicalreactiondoublesforevery10Criseoftemperature.Ifthetemperatureis
raisedby50C,therateofthereactionincreasesbyabout.
(1) 24times
(2) 32times
(C) 64times
(4) 10times
74. (2) (2)5=32
75. Themagneticmoment(spinonly)of[NiCl4]2is :
(1) 5.46BM
(2) 2.82BM
(3) 1.41BM

(4) 1.82BM

75. (2) Ni+2=(Ar)3d8

2 4= 8 = 2.82
76. Thehybridisationoforbitalsof N atomin NO3, NO2+and NH4+arerespectively :
(1) sp2, sp, sp3
(2) sp, sp3, sp2
(3) sp2, sp3, sp
(4) sp, sp2, sp3
76. (1)

O N = Osp2

O = N = O,sp

NH4 = sp3

77. Incontextofthelanthanoids,whichofthefollowingstatementsisnotcorrect?
(1) Allthemembersexhibit+3oxidationstate.
(2) Becauseofsimilarpropertiestheseparationoflanthanoidsisnoteasy.
(3) Availabilityof4felectronsresultsintheformationofcompoundsin+4stateforallthe
membersoftheseries
(4) Thereisagradualdecreaseintheradiiofthememberswithincreasingatomicnumberin
theseries.
77. (3) +4stateisfoundonlyifthereisextrastability1/2filledfsubshell
78. A5.2molalaqueoussolutionofmethylalcohol, CH3OH,issupplied.Whatisthemolefractionof
methylalcoholinthesolution?
(1) 0.190
(2) 0.086
(3) 0.050
(4) 0.100
78. (2)

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5.2
60.7
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79. Whichofthefollowingstatementiswrong?
(1) Nitrogencannotfromdp pp bond.
(2) Single N N bondisweakerthanthesingle P P bond.
(3) N2O4hastworesonancestructures.
(4) Thestabilityofhydridesincreasesfrom NH3to BiH3ingroup15oftheperiodictable.
79. (4) Stabilityofhydridedecreases.
80. Theouterelectronconfigurationof Gd (AtomicNo:64)is :
(1) 4f85d06s2
(2) 4f45d46s2
(3) 4f75d16s2

(4) 4f35d56s2

80. (3) Itshouldbein3rdgroupi.e., d1s2...

81. Whichofthefollowingstatementsregardingsulphurisincorrect?
(1) Thevapourat200 Cconsistsmostlyof S8rings.
(2) At600 Cthegasmainlyconsistsof S2molecules.
(3) Theoxidationstateofsulphurisneverlessthan+4initscompounds.
(4) S2moleculeisparamagnetic.
81. (3) InH2S,Sisin2State
82. Thestructureof IF7is :
(1) Trigonalbipyramid
(3) Pentagonalbipyramid

82. (3)

F
F
I

(2) Octahedral
(4) Squarepyramid

F
F

83. Ozonolysisofanorganiccompoundgivesformaldehydeasoneoftheproducts.Thisconfirms
thepresenceof :
(1) Avinylgroup
(2) Anisopropylgroup
(3) Anacetylenictriplebond
(4) Twoethylenicdoublebonds
O

83. (1) CH2= CH

O3 /Zn

H2O

H C H asoneoftheproduct

84. Agasabsorbsaphotonof355nmandemitsattwowavelengths.Ifoneoftheemissionsisat
680nm,theotherisat :
(1) 325nm
(2) 743nm
(3) 518nm
(4) 1035nm
84. (2)
\

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1
1 1
=
+
355 680 x
1
1
1
=
x 355 680

\ x =743.

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85. SilverMirrortestisgivenbywhichoneofthefollowingcompounds?
(1) Acetone
(2) Formaldehyde (3) Benzophenone (4) Acetaldehyde
85. (4) Aldehydegivessilvermirrortest
86. Whichofthefollowingreagentsmaybeusedtodistinguishbetweenphenolandbenzoicacid?
(1) Tollensreagent
(2) Molischreagent
(3) Neutral FeCl3
(4) Aqueous NaOH
86. (3) Neutral FeCl3+Phenol redcolourcomplex.
87. Phenolisheatedwithasolutionofmixtureof KBr and KBrO3.Themajorproductobtainedinthe
abovereactionis :
(1) 3Bromophenol
(2) 4Bromophenol
(3) 2,4,6Tribromophenol
(4) 2Bromophenol
OH

OH

87. (3)

KBr+KBrO3

Br

Br

Br

88. Inafacecentredcubiclattice,atom A occupiesthecornerpositionsandatom B occupiesthe

facecentrepositions.Ifoneatomof B ismissingfromoneofthefacecentredpoints,theformula
ofthecompoundis :
(1) AB2
(2) A2B3
(3) A2B5
(4) A2B
88. (3) AB2.5 =A2B5
89. Theentropychangeinvolvedintheisothermalreversibleexpansionof2molesofanidealgas
fromavolumeof10dm3toavolumeof100dm3at27 Cis :
(1) 35.8Jmol1K1
(2) 32.3Jmol1K1
1
1
(3) 42.3Jmol K
(4) 38.3Jmol1K1
89. (4)

DS =28.3142.303log10=38.3

90. Identifythecompoundthatexhibitstautomerism.
(1) Lacticacid
(2) 2Pentanone (3) Phenol
O

90. (2)

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(4) 2Butene

OH

CH3 C CH2 CH2 CH3 CH3 C=CH CH 2CH3

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