Product:

SafetyDataSheet

TOTALISOLECKL23

Issue:1

Page:1/6
Date:2008-07-18
Invalidatesandreplacestheissueof:2008-07-18

PRODUCTLABELS

LABELLING(standardorEU):

Notapplicable

TRANSPORTLABELLING:

Notapplicable

1.Productandcompanyidentification

Commercialname:

TOTALISOLECKL23

Productapplication:Insulatingoil
Companyname:

S-OIL TOTAL LUBRICANTS CO., LTD.

Address:

1F,YTNTower61Namdaemunno5ga,JungGu,
SEOUL, KOREA

Emergencynumberofthecompany:

82(2)63865151

Fax:82(2)63865103

2.Composition/informationoningredients
PREPARATION:
Chemicalnature:ALKYLBENZENE

CASnumberandcontent:[67774747],100%

3.Hazardidentification

Adversehumanhealtheffects:

Undernormalconditionsofuse,theproductholdsnodangerofintoxication

Environmentaleffects:

Dontrejectthisproductintotheenvironment

Physicalandchemicalhazards:

Nospecificriskoffireorexplosionundernormalconditionsofuse

4.Firstaidmeasures
INCASEOFSERIOUSMANIFESTATIONS,CALLINADOCTOROREMERGENCYMEDICALCARE
Routeofexposure:
Inhalation:

Inhalationofheavyconcentrationsofvapour,fumesorspray,maycausemildirritationofthe
throat.
Transportthepersonintofreshair,keepwarmandallowtorest

Contactwiththeskin:

Iftheskinisexposedtohighpressurespray,theproductmayenterthehumanorganism.Inall
suchcasestheaffectedpersonmustbetakentohospital,evenifnosignofinjurycanbe
detected
Immediatelyremoveallsoiledorstainedclothing
Washtheaffectedareaimmediatelyandrepeatedlywithsoapandwater.

SOILTOTALLUBRICANTSCO.,LTD.1F,YTNTower,61Namdaemunno5ga,Junggu,SEOUL,KOREA


Product:

SafetyDataSheet

TOTALISOLECKL23

Issue:1

Page:2/6
Date:2008-07-18
Invalidatesandreplacestheissueof:2008-07-18

Contactwiththeeyes:Keepeyesopenandrinseimmediatelyandrepeatedlywithwaterforatleast15minutes
Ingestion:Possibleriskofvomitinganddiarrhea
Donotinducevomitingtoavoidtheriskofaspirationintotherespiratorytract
Givenothingtodrink
Aspiration:Iftheproductisbelievedtohaveenteredthelungs(incaseofvomiting,forexample),takethe
persontohospitalforimmediatecare
5.Firefightingmeasures
Flashpoint:Seeheading9
Fireextinguishers:
suitable:Foam,carbondioxide(CO2),powder
notsuitable:donotusewaterjets(stickjets)forextinguishingfiresincetheycouldhelptospreadtheflames.
Specifichazards:IncompletecombustionandthermolysisproducetoxicgasessuchasCO,CO2,various
hydrocarbons,aldehydesandsoot.Thesearehighlydangerousifinhaled
Firefighterprotection:Aninsulatedbreathingapparatusmustbeworninconfinedpremiseswithheavyconcentrationsof
fumesandgases

6.Accidentalreleasemeasures

Seealsoheading8and13:
Afterspillage/leakage:
onsoil:Surfacesonwhichtheproducthasbeenspilledmaybecomeslippery
Avoiddischargeofthematerialinastreamorasewerorcausegroundcontamination.
recoverybyphysicalmeans
Containandcollectthespilledproductwithsandoranyotherinertmaterial.
Intheeventofamajorspill,informthecompetentauthoritiesifthesituationcannotbebrought
undercontrolrapidlyandefficiently
onwater:Usefloatingabsorbentmaterialtoberemovedmechanically
Ifthematerialhasbeendischargedintoastreamorasewer,informtheauthoritiesofthepossible
presenceoffloatingmaterials
Ifthematerialhasbeendischargedintoastreamorasewer,informtheauthorities
7.Handlingandstorage
HANDLING:
Technicalmeasures:
.preventionofuserexposure:Provideadequateventilationincaseofthepotentialformationofvapour,fumes,mistorspray
Takeallmeasurestoreducetheriskofexposure,inparticulartousedorwasteproduct
Keepawayfromflammablematerial;keepawayfromfoodandbeverages
.Preventionoffireandexplosion:Emptycontainersmaycontainflammableorexplosivevapours
Thereisafirehazardassociatedwithrags,paperoranyothermaterialusedtoremovespillswhich
becomesoakedwithproduct
Avoidaccumulateofthese:theyaretobedisposedoffsafelyafteruse

SOILTOTALLUBRICANTSCO.,LTD.1F,YTNTower,61Namdaemunno5ga,Junggu,SEOUL,KOREA


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SafetyDataSheet

TOTALISOLECKL23
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Date:2008-07-18
Invalidatesandreplacestheissueof:2008-07-18

Precautions:Avoidstaticelectricitybuildupwithconnectiontoearth.
Setupmachineryandequipmentsoastoavoidtheriskofaccidentalspillsorsplashesontohot
machinepartsandelectricalcontacts(onjointfailure,forexample)
Preventoilleaksinpressurecircuitsresultinginafineinflammablespray(theflammabilitylimit
foroilmistisdepressedwhenconcentrationsofabout45g/m3arereached)
Safehandlingadvice:Avoidcontactwithstrongoxidizingagents
Useonlyhydrocarbonresistantcontainers,joints,pipesetc...
STORAGE:
Technicalmeasures:Makethenecessaryarrangementsandtakeallmeasurestopreventwaterandgroundpollution
Storageconditions:
.Suitable:Storeatroomtemperature,protectedagainstcontactwithwaterandmoisture,andawayfromany
sourceofignition
Keepcontainersclosedwhennotinuse
.Tobeavoided:Donotstoreexposedtotheelements
Incompatibleproducts:Dangerousreactionwithstrongoxidizingagents
Packagingmaterials:
.Recommended:Useonlyhydrocarbonresistantcontainers,joints,pipes,etc.
Keepinoriginalcontainerifpossible
Otherwise,transferallindicationsontheregulatorylabeltothenewcontainer
8.Exposurecontrols/personalprotection

Engineeringmeasures:Usetheproductinwellventilatedpremises
Whenworkingonenclosedplace(tanks,reservoirs...),makesurethatatmosphereisnot
suffocatingand/orwearrecommendequipment
Controlparameters:

.Occupationalexposurelimit:.oilmist:10mg/m3,for15minutes
.oilmist:5mg/m3,for8hours
Personalprotectiveequipment:

Handprotection:Impermeablehydrocarbonproofgloves
recommendedmaterial:nitrile,neoprene

Eyeprotection:Goggles,incaseofsplashing
Skinandbodydifferenthandprotection:Asrequired,wearafacemask,hydrocarbonproofclothing,andsafetyboots(whenhandling
drums)
Dontwearring,watchorsimilarthingwhichwillbeabletoholdtheproductandmaygiveriseto
someskindiseases
Industrialhygiene:Avoidprolongedandrepeatedcontactwiththeskin,especiallywithusedorwasteproduct
Immediatelyremoveallsoiledorstainedclothing.
Iftheproductcomesintocontactwiththeskin,washtheaffectedareaimmediatelyandrepeatedly
withsoapandwater
Usenoabrasives,solventsorpetroleumspirit
Donotuseclothsstainedwiththeproducttodryhands
Dontputtheproductsoakedragsinthepocketsofworkingclothes
9.Physicalandchemicalproperties

Appearance:

SOILTOTALLUBRICANTSCO.,LTD.1F,YTNTower,61Namdaemunno5ga,Junggu,SEOUL,KOREA


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SafetyDataSheet
TOTALISOLECKL23

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Physicalstate:Liquid
Colour:Yellowtoamber
Odour:Characteristicodourofoil
pH:Notapplicable
Specifictemperaturesofchangeinstate
Flashpoint:142(ASTMD93)
Autoignitiontemperature:>250(ASTME659)
Thistemperaturemaybesignificantlylowerunderparticularconditions(oxidationonhighsurface
areas)
Explosionlimits:Notapplicable
Density:About861kg/m3at15
Solubility:
inwater:Insolubleandimmiscible
inorganicsolvents:Solubleinmanycommonsolvents
Viscosity:Kinematicviscosityat40:about4.3mm2/s

10.Stabilityandreactivity

Stability:Theproductisstableundernormaltemperaturesofstorage,handlinganduse
Dangerousreactions:Notdangerousreactionknownundernormalconditionsofuse,torefertothetechnicalnotice
Conditionstoavoid:Heat(temperaturesaboveflashpoint),sparks,ignitionpoints,flames,staticelectricity
Materialstoavoid:Avoidcontactwithstrongoxidizing
Dangerousdecompositionproducts:IncompletecombustionandthermolysisproducemoreorlesstoxicgasessuchasCO,CO2,various
hydrocarbons,aldehydesandsoot
11.Toxicologicalinformation

ACUTETOXICITY/LOCALEFFECTS:
Inhalation:Riskisimprobableundernormalconditionsofuse
Inhalationofimportantconcentrationofvapouroraerosolsmaycauseirritationoftheupper
respiratorytract.
Contactwiththeskin:Riskisimprobableundernormalconditionsofuse
Iftheskinisexposedtohighpressurespray,theproductmayenterthehumanorganism.Inall
suchcasestheaffectedpersonmustbetakentohospital,evenifnosignofinjurycanbedetected
Ingestion:Incaseofingestionofsmallquantities,noimportanteffectobserved.incaseofingestionoflarger
amounts:abdominalpain,diarrhea,...
SENSITIZATION:Toourknowledge,theproductdontinducesensitization
CHRONICTOXICITYORLONGTERM
TOXICITY:
Contactwiththeskin:Characteristicskinaffections(oilblisters)maydevelopfollowingprolongedandrepeated
exposurethroughcontactwithstainedclothing

SOILTOTALLUBRICANTSCO.,LTD.1F,YTNTower,61Namdaemunno5ga,Junggu,SEOUL,KOREA


Product:

SafetyDataSheet

TOTALISOLECKL23

Issue:1

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Date:2008-07-18
Invalidatesandreplacestheissueof:2008-07-18

Carcinogenecity:Theproductisformulatedfromingredientsconsideredtobenoncarcinogenic

12.Ecologicalinformation

Mobility:

Air:thereisaslowlossbyevaporation.

Ground:Givenitsphysicalandchemicalcharacteristics,theproductgenerallyshowslittlemobilityinthe
ground

Water:Theproductisinsoluble;itspreadsonthesurfaceofthewater

Persistenceanddegradability:Experimentaldataonthefinishedproductarenotavailable
However,themineraloilportionofthevirginproductisintrinsicallybiodegradable.Particular
ingredientsmaynotbebiodegradable

Ecotoxicity:Thevirginproductisconsideredtopresentnodangerforlandgrowingorganisms.
Itisconsideredtopresentalittledangerforaquaticlife.
noinformationavailableforusedproduct
Experimentaldataonthefinishedproductarenotavailable
13.Disposalconsiderations

Wastedisposal:Disposeinasafemannerinaccordancewithlocal/nationalregulations
Ifneedbe,collectionbyanauthorizedwastecontractorandregenerationorincinerationinan
approvedinstallation

Usedpackagingdisposal:Conformtotheregulationineffect

IndustrialwastenumberEU:130899(wastesnototherwisespecified)

14.Transportinformation

UNNumber:unregulated

Road(ADR)/Rail(RID)/River(ADNR):Notrestrictedfortransport.

Marine(IMOIMDG):Notrestrictedfortransport.

Airline(ICAO/IATA):Notrestrictedfortransport
15.Regulatoryinformation

EUROPEANREGULATIONS:

EClabelling:

Symbol(s):None

RPhrase(s):None

SPhrase(s):None
16.Otherinformation
Thisdatasheetconformstostandardsdefinedbydirectives91/155,93/112/EEC&2001/58/ECDatasheetrequiredpursuanttoArt.14ofdirective
1999/45/EC.
Dateofcurrentversion:18/07/2008

SOILTOTALLUBRICANTSCO.,LTD.1F,YTNTower,61Namdaemunno5ga,Junggu,SEOUL,KOREA


Product:

SafetyDataSheet

TOTALISOLECKL23

Issue:1

Page:6/6
Date:2008-07-18
Invalidatesandreplacestheissueof:2008-07-18

SupersedespreviousSafetyDataSheetof:18/07/2008
ThisSafetyDataSheetservestocompletebutnottoreplacethetechnicalproductsheets.Theinformationcontainedhereinisgiveningoodfaith
accuratetothebestofonknowledgeatthedateindicatedhereabove.
Itisunderstoodbytheuserthatanyuseoftheproductforpurposesotherthanthoseforwhichitwasdesignedentailspotentialrisk.
Theinformationgivenhereininnowaydispensestheuserfromknowingandapplyingallprovisionsregulatinghisorheractivity.Theuserbears
liabilityfortheprecautionsrequiredwhenusingtheproduct.
Theregulatorytextsindicatedhereinareintendedtoaidtheusertofulfillhisobligations.Thislistisnottobeconsideredcompleteandexhaustive.
Itistheusersresponsibilitytoensurethatheissubjecttonootherobligationsthanthosementioned.
Endofdocument.
Numberofpage(s):6

SOILTOTALLUBRICANTSCO.,LTD.1F,YTNTower,61Namdaemunno5ga,Junggu,SEOUL,KOREA