Overview of the Kemper County IGCC Project Using Transport Integrated Gasification (TRIGTM)

Coal Loading Hoppers Process Air Compressors Control/Admin Bldg Emergency Crushed Coal Stack Gasifiers, Syngas Coolers, PCDs Coal Preparation Coal Barn

Flare Derricks

Water Treatment Bldg Combined Cycle CO2/Sulfur Removal Area

Sulfuric Acid Production Cooling Towers

RECS Program at the NCCC June 09, 2011

Kemper County IGCC Project Overview

2x1 Integrated Gasification Combined Cycle (IGCC)

2 TRansport Integrated Gasifiers (TRIG) 2 Siemens SGT6 - 5000F CTs 1 Toshiba Steam Turbine (Tandem Compound Double Flow) 582 MW peak and 524 MW on syngas Heat Rate 11,708 Btu/kWh (29.5% HHV Efficiency w/ CO2 control and 40+% moisture coal) Selexol for H2S and CO2 removal 65+% CO2 capture (~800 lb/mWh emission rate) Mine Mouth Lignite

Plant Site

Owner & Operator: Mississippi Power Over $2 billion capital investment Commercial Operating Date: May 2014 Use treated effluent from Meridian as makeup water By-Products (TPY)

~3,000,000 - Carbon dioxide used for EOR ~135,000 - Sulfuric acid ~20,000 - Ammonia
Kemper Lignite Composition
Heat Content Moisture Ash Sulfur btu/lb % % % Average 5,290 45.5 12.0 1.0 Min 4,765 42 8.6 0.35 Max 5,870 50 17 1.7

Kemper County IGCC Project Map

Meridian

Plant Site

~ 70 miles transmission ~ 60 miles CO2 pipeline (for EOR) ~5 miles natural gas pipeline ~31,000 acre mine site ~2,900 acres plant site ~ 30 miles treated effluent line
New CO2 Pipeline

Visual Comparison of Main Gasifier Types

(Not to Scale)

GE

Conoco Shell Siemens

Syngas

MHI

TRIGTM
Syngas

Coal

Coal

Coal Air

Oxygen

Oxygen-blown Oxygen-blown Burner- type, slagging Burner- type, slagging

Air- or -blown O2 -blown

No-burner No-burner Non-slagging Non-slagging

Development of the TRIG for Power and Chemical Production

TRIGTM Leverages Long History of KBR Fluid Catalytic Cracking (FCC) Expertise
First Commercial FCC Unit for Exxon Orthoflow A Design Orthoflow C Design Resid FCCs

Late 30's 1942

1951

Early 1960's 1976 1980's

Design Based on FCC Technology

Orthoflow F Design

1990
Pilot Plant Tech Center

1996
Grand Forks, ND 2,600 Hours Test Run

1996
PSDF at Wilsonville, AL. >14,600 hrs in gasification >2,200 hrs on Mississippi Lignite thru Dec 09

China 2011 USA 2014

TRIGTM In Kemper County, MS, USA & Dong Guan, China

TRIGTM Attributes / Advantages

Presalter Cyclone

syngas
Standpipe Cyclone

Simple, well established design

Based on technology in use for 70 years Air for power Oxygen for liquid fuels and chemicals Non-slagging design:
Provides 10-20 year refractory life, Eliminates black water system Provides non-fouling syngas cooler operation

Either Air- or Oxygen-blown High Reliability Design

Riser

No burners to fail and be replaced Dry dust removal eliminates gray water system Coarse, dry coal feed allows:
Fewer, lower power pulverizers, and Less drying than other dry-feed gasifiers

Mixing Zone Startup Burner

coal

Seal Leg

Lower Fuel Costs

air/O2 steam
J-leg

Standpipe

Cost-effective using high moisture, high-ash, low rank coals (PRB and lignite). Lower water use compared to pulverized coal (PC) Excellent emissions performance Easier to permit compared to PC Lower cost carbon capture compared to PC

sy
ash

Excellent Environmental Performance

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Kemper CO2 Capture Scheme

Refrig.

Two Stages WGS Selexol Physical Solvent Refrigerated to 40F Carbon Capture: 65+% CO2 Emissions: 800 lb CO2/MWh Yield: >3 MM Tons/yr CO2

Refrig. CO2 Absorbers Product CO2

CO2 Compression And Drying CO2 Flash Tanks To Sulfuric Acid CW

Water Gas Shift Reactors

H2S Absorber

Steam Cond Cond H2S Stripper

Recycle Gas Compressor Acid Gas Concentrator Sour Syngas From Gasifier Steam

Syngas To Turbine

To Gasifier

Kemper County TRIGTM 3-D Perspective

HRSGs Gas Turbines Steam Turbine Air Compressors HP Coal Feeders

CO2 and H2S Removal

Gasifiers (2)

Fluid Bed Dryer System Sulfuric Acid Production

Kemper County TRIGTM 3-D Perspective

Flare Derricks Sour Water/NH3 Recovery System H2S Absorbers (2) Dry Ash Filters (4)
Particulate Collection Device (PCD)

Crushed Coal Silos

Gasifiers (2)

CO2 Compressors

AGR Regenerators

HP Coal Feeders (12) Main Syngas Coolers (4)

CO2 Flash Drums (8)

Mercury Adsorbers

CO2 Absorbers (6)

NH3 Removal Coal Mills (6) Back-pulse Surge Drums Admin. Bldg. Steam Turbine WGS Reactors Warehouse Process Air Compressors Syngas Humidifiers COS Hydrolysis

Kemper County TRIGTM

(A Sense of Scale)
Water Gas Shift (WGS) Reactors (12) WGS Reactor Isolation Valves Syngas Saturator/Scrubber Recuperator (2) WGS Recuperator (2) High Temp Syngas Recuperator (2)

6 Person

Kemper County IGCC Timeline & Milestones

2009
3rd 4th 1st

2010
2nd 3rd 4th 1st

2011
2nd 3rd 4th 1st

2012
2nd 3rd 4th 1st

2013
2nd 3rd 4th 1st

2014
2nd 3rd

Detail Design Long Lead Procurement Engineer Procured Sitework & U/G
Piling/Caissons

Foundations GI General Contractor CC General Contractor Startup

COD 5/1/2014

Kemper County IGCC Construction Update

3rd Quarter 2010 Site Preparation and Mass Earthwork

Water Reservoir Area

Site Aerial Photo

Retention Ponds

Kemper County IGCC Construction Update

1st Quarter 2011 Began Installation of Underground Electrical and Mechanical Systems

Storm Drains

Electrical Duct Banks

Fire Protection Piping

Kemper County IGCC Construction Update

2nd Quarter 2011 Deep Foundations/ Major Equipment Foundation Installation/U/G Utilities

130/230 Sumps

Steam Turbine Columns

96 Circ. Water Pipe

Kemper County IGCC Construction Update

Kemper County IGCC Construction Update

TRIGTM Attributes / Advantages

Presalter Cyclone

syngas
Standpipe Cyclone

Simple, well established design

Based on technology in use for 70 years Air for power Oxygen for liquid fuels and chemicals Non-slagging design:
Provides 10-20 year refractory life, Eliminates black water system Provides non-fouling syngas cooler operation

Either Air- or Oxygen-blown High Reliability Design

Riser

No burners to fail and be replaced Dry dust removal eliminates gray water system Coarse, dry coal feed allows:
Fewer, lower power pulverizers, and Less drying than other dry-feed gasifiers

Mixing Zone Startup Burner

coal

Seal Leg

Lower Fuel Costs

air/O2 steam
J-leg

Standpipe

Cost-effective using high moisture, high-ash, low rank coals (PRB and lignite). Lower water use compared to pulverized coal (PC) Excellent emissions performance Easier to permit compared to PC Lower cost carbon capture compared to PC

sy
ash

Excellent Environmental Performance

ng as