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Co-Ordination Chemistry and organometallics Assignment

1. The proper name for K 2 [PtCl]6 is (a) Potassium platinum hexachloride (c) Potassium hexachloro platinate IV 2. Pick the correct name of [Co ( NH 3 ) 5 Cl ]Cl 2 (a) Chloropentammine cobalt (III) (c) Chloropentammine cobalt (III) chloride 3. The I.U.P.A.C. name of K 3 [ Ir(C 2 O 4 ) 3 ] is (a) Potassium tri oxalato iridium (III) (c) Potassium tris (oxalato) iridium (III) 4. IUPAC name of [Co (ONO )( NH 3 )5 Cl 2 ] is (a) Pentaammine nitro cobalt (III) chloride (c) Pentaammine nitroso cobalt (III) chloride 5. (a) [Co ( NH 3 ) 3 (H 2 O) 3 ]Cl 2 (c) [CoCl ( NH 3 ) 3 (H 2 O) 2 ]Cl 3 6. (a) Sodium pentacyanonitrosyl ferrate (III) (c) Sodium nitroferrocyanide 7. The correct name of [Pt( NH 3 )4 Cl 2 ] [PtCl 4 ] is (a) Tetra ammine dichloro platinum (iv) tetra chloro platinate (ii) (b) Dichloro tetra ammine platinium (iv) tetrachloro platinate (ii) (c) Tetrachloro platinum (ii) tetra ammine platinate (iv) (d) Tetra chloro platinum (ii) dichloro tetra ammine platinate (iv) 8. 9. 10. 11. 12. Which of the following compounds exhibits linkage isomerism (a) [Co (en ) 3 ]Cl 3 (b) [Co ( NH 3 )6 [Cr (CN )6 ] (c) [Co (en ) 2 NO 2 Cl ]Br (c) Coordination isomerism (c) [Co ( NH 3 )5 NO 2 ]Cl 2 (d) [Co ( NH 3 ) 5 Cl ]Br2 (d) Ionisation isomerism (d) [Pt( NH 3 ) 2 Cl 2 ] (d) Polymerisation The complexes [Co ( NH 3 ) 6 ] [Cr (C 2 O 4 ) 3 ] and [Cr ( NH 3 )6 ] [Co (C 2 O 4 )3 ] (a) Linkage isomerism (b) Geometrical isomerism Which one of the following will not show geometrical isomerism (a) [Cr ( NH 3 ) 4 Cl 2 ]Cl (b) [Co (en ) 2 Cl 2 ]Cl (b) Pentaammine nitrito cobalt (III) chloride (d) Pentaammine oxo-nitro cobalt (III) chloride (b) [Co ( NH 2 ) 3 (H 2 O) 2 ]Cl 2 (d) [CoCl ( NH 3 ) 3 (H 2 O ) 2 ]Cl 2 (b) Sodium nitroferricyanide (d) Sodium pentacyanonitrosyl ferrate (II) (b) Potassium tri oxalato iridate (III) (d) Potassium tris (oxalato) iridate (III) (b) Pentammine cobalt (III) chloride (d) Chloropentammine cobalt (II) chloride (b) Potassium hexachloro platinum IV (d) Potassium hexachloro platinum

The complex chlorocompound diaquatriammine cobalt (III) chloride is represented as

According to IUPAC nomenclature sodium nitroprussied is named is

The type of isomerism present in nitropentamine chromium (III) chloride is (a) Optical (b) Linkage (c) Ionization Coordination isomerism is caused by the interchange of ligands between the

13.

(a) Cis and Trans structure (b) Complex cation and complex anion (c) Inner sphere and outer sphere (d) Low oxidation and higher oxidation states Which one of the following octahedral complexes will not show geometric isomerism (A and B are monodentate ligands) (a) [MA 5 B] (b) [MA 2 B 4 ]
+

(c) [MA 3 B 3 ]

(d) [MA 4 B 2 ]

14.

The possible number of optical isomers in [Co (en ) 2 Cl 2 ] are (a) 2 (b) 3 (c) 4 (d) 6

15.

What is true for [Fe(CN )6 ] 3 and [FeF6 ] 3 (a) Both are paramagnetic (c) Only [FeF6 ] 3 is paramagnetic (d) (b) Only [Fe(CN )6 ]3 is paramagnetic Both are diamagnetic
3

16.

What type of hybridization is involved in [Fe(CN )6 ] (a) d 2 sp 3 (b) dsp 2 (b)

2 Zn( NH 3 )4 +

(c) (c)

sp 3 d 2 Ni(CN ) 2 4

(d) dsp 3 (d) Cu ( NH 3 ) 2 + 4

17.

Which one is an example of octahedral complex (a)

FeF63

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18. 19. 20. 21. What is the shape of Fe(CO )5 (a) Linear (b) Tetrahedral (c) Square planar (c) Tetrahedral (c) [ Ni( NH 3 )6 ]Cl 2 (d) Trigonal bipyramidal (d) Square (d) [Cu ( NH 3 ) 4 ]Cl 2 In the complex [SbF 5 ] 2 , sp 3 d hydridisation is present. Geometry of the complex is (a) Square phyramidal (b) Square bipyramidal Which one has the highest paramagnetism (a) Ni(CO ) 4 (b) [ Ni( NH 3 ) 4 ]Cl 2 The colour of CoCl 3 . 5 NH 3 . H 2 O is (a) Orange yellow (e) Pink 22. (b) Orange (c) Green (d) Violet

[Ti(H 2 O)6 ]+3 is paramagnetic in nature due to

(a) One unpaired e (b) Two unpaired e The most stable complex among the following is (a)
K 3 [ Al(C 2 O 4 )3 ]

(c) Three unpaired e (c)

Ag ( NH 3 ) 2 Cl

(d) No unpaired e (d)

K 2 ( Ni( EDTA )]

23. 24.

(b) [Pt(en ) 2 ]Cl 2 (b) [Fe(Cl )6 ]3

The most stable ion is (a) [Fe(OH ) 3 ] 3 (c) [Fe(CN )6 ] 3 (d) [Fe(H 2 O)6 ]3 +

25.

One mole of the complex compound Co ( NH 3 )5 Cl 3 , gives 3 moles of ions on dissolution in water. One mole of the same complex reacts with two moles of AgNO 3 solution to yield two moles of AgCl (s) . The structure of the complex is (a) [Co ( NH 3 )5 Cl ] Cl 2 (c) [Co ( NH 3 ) 4 Cl 2 ] Cl . NH 3 (b) [Co ( NH 3 )3 Cl 3 ]. 2 NH 3 (d) [Co ( NH 3 ) 4 Cl ] Cl 2 . NH 3

26. 27.

The number of unpaired electrons in the complex ion [CoF 6 ]3 is (Atomic no. Co = 27 ) (a) Zero (b) 2 (c) 3 Pick out the complex compound in which the central metal atom obeys EAN rule strictly (a)
K 4 [ Fe(CN ) 6 ]

(d) 4 (d) [Cu ( NH 3 ) 4 ] SO 4

(b)
2+

K 3 [ Fe(CN )6 ]

(c) [Cr (H 2 O )6 ] Cl 3

28.

Magnetic moment of [Cu ( NH 3 ) 4 ] (a) 1.414

ion is (c) 2.23 (d) 2.38

(b) 1.73

29.

In [NiCl 4 ] 2 , the number of unpaired electron is (a) 4.5 (b) 2 (c) 3

2

(d) 4

30.

The correct order of hybridisations of central atom in NH 3 , [ PtCl 4 ] , PCl 5 and BCl 3 is (a) dsp 2 , dsp 3 , sp 2 and sp 3 (c)
dsp 2 , sp 2 , sp 3 and dsp 3

(b)

sp 3 , sp 3 , sp 3 d and sp 2

(d) dsp 2 , sp 3 , sp 2 and dsp 3

31. 32.

The effective atomic number of cobalt in the complex [Co ( NH 3 )6 ] 3 + is (a) 36 (b) 33 (c) 24 Which of the following is formed when n-butyl lithium reacts with tin (II) chloride (a) (d) 30 (d) (C 2 H 5 ) 4 Pb (d)
Fe(CO )6

LiBr

(b)

Et 4 Pb Fe 2 (CO )9

(c) (C 4 H 9 )4 Sn (c)
Fe 2 (CO )12

33.

Finely divided iron combines with CO to give (a)

Fe(CO )5

(b)

34.

Complex salt can be made by the combination of [Co III ( NH 3 )5 Cl ] X with (a)
3 PO 4

(b) Cl

(c)

2Cl

(d)

2K +

35.

Ammonia forms the complex ion [Cu ( NH 3 ) 4 ] 2 + with copper ions in alkaline solutions but not in acidic solution. What is the reason for it (a) In acidic solutions hydration protects copper ions
+ (b) In acidic solutions protons coordinate with ammonia molecules forming NH 4 ions and NH 3 molecules are not

available (c) In alkaline solutions insoluble Cu (OH ) 2 is precipitated which is soluble in excess of any alkali 36. (d) Copper hydroxide is an amphoteric substance The complex used as an anticancer agent is (a) trans [Co ( NH 3 ) 3 Cl 3 ] (b) cis [PtCl 2 ( NH 3 ) 2 ]

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(c) cis K 2 [PtCl 2 Br2 ] 37. In the process of extraction of gold,
O2 Roasted gold ore + CN + H 2 O [ X ] + OH

(d)

Na 2 CO 3

[ X ] + Zn [Y ] + Au

Identify the complexes [X] and [Y] (a) (c) 38.

X = [ Au (CN ) 2 ] , Y = [ Zn(CN ) 4 ] 2 X = [ Au (CN ) 2 ] , Y = Zn(CN ) 6 ] 4

(b) (d)

X = [ Au (CN ) 4 ] 3 , Y = [ Zn(CN ) 4 ] 2 X = [ Au (CN ) 4 ] , Y = [ Zn(CN ) 4 ] 2

(Me )2 SiCl 2 on hydrolysis will produce

(a) (Me ) 2 Si (OH ) 2 (c)
[O (Me ) 2 Si O ]n

(b) (Me ) 2 Si = O (d)

Me 2 SiCl (OH )

39.

Mixture X = 0 . 02 mol of [Co ( NH 3 )5 SO 4 ] Br and 0.02 mol of [Co ( NH 3 )5 Br ]SO 4 was prepared in 2 litre of solution 1 litre of mixture X + excess AgNO 3 Y . 1 litre of mixture X + excess BaCl 2 Z Number of moles of Y and Z are (a) 0.01, 0.01 (b) 0.02, 0.01 (b) [Fe(n 5 C 5 H 5 ) 2 ] (b) (b)
K[PtCl 3 ( 2 C 2 H 4 )]
RSiCl 3

(c) 0.01, 0.02 (c) [Co (CO )5 NH 3 ] 2 + (c) (c) (c)

Fe( 5 C 5 H 5 ) 2
SiCl 4
d 6 (low spin)

(d) 0.02, 0.02

K[PtCl 3 (n 2 C 2 H 4 )]

40.

Which of the following organometallic compound is and bonded (a)

Fe(CH 3 )3

(d)

41.

Among the following, which is not the -bonded organometallic compound (a) (CH 3 ) 4 Sn (d) Cr ( 6 C 6 H 6 ) 2 (d)
R 2 SiCl 2

42. 43. 44. 45. 46.

Which of the following organo-silicon compound on hydrolysis will give a three dimensional silicone (a)
R 3 SiCl

Which of the following shall form an octahedral complex (a) d 4 (low spin) (b) d 8 (high spin) (d) None of these The oxidation number of Pt in [Pt(C 2 H 4 )Cl 3 ] is (a) +1 (b) +2 Oxidation state of nitrogen is incorrectly given for (a) [Co ( NH 3 ) 5 Cl ]Cl 2 ; 0 (a)
H 2O

(c)

+3

(d) (d)

+4
Mg 3 N 2 ; 3

(b)

NH 2 OH ; 1

(c) ( N 2 H 5 ) 2 SO 4 ; +2 (c)

Which of the following represents a chelating ligand (b) OH

DMG

(d) Cl

47. 48. 49.

How many ions are produced in aqueous solution of [Co (H 2 O )6 ] Cl 2 (a) 2 (b) 3 (c) 4 The number of ions per mole of a complex [CoCl 2 . 5 NH 3 ]Cl 2 in aqueous solution will be (a) Nine (b) Four According to Lewis the ligands are (a) Acidic in nature (c) Neither acidic nor basic Which of the following is wrong statement (a)
Ni(CO ) 4 has oxidation number + 4 for Ni

(d) 6 (d) Two

(c) Three

(b) Basic in nature (d) Some are acidic and others are basic (b)
Ni(CO ) 4 has zero oxidation number for Ni

50.

(c) Ni is metal

(d) CO is gas

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