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USES OF SULPHURIC ACID 1. Sulphuric acid is used to produce chemical fertilizer such as ammonium sulphate and potassium sulphate, which are highly soluble in water and can be easily obsorbed by plant. 2. Car batteries contain sulphuric acid which is used as the electrolyte. 3. Sulphuric acid also used in the making of artificial silk-like fibres and rayon. 4. Chemical like paints, dyes and drug use sulphuric acid as one of their component materials.
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STAGE2: Production Of Sulphur Trioxide From Sulphur Dioxide i. The purified sulphur dioxide SO2 and excess air are passed over vanadium(V) oxide V2O5 at controlled optimum condition optimum condition to produce sulphur trioxide SO3. 2SO2(g)+O2(g) 2SO3(g) ii. The optimum used are a) Temperature:450-500C b) Pressure: 2-3 atmospheres c) Catalyst: Vanadium(V) oxide iii. Under controlled optimum conditions, 98% conversion is possible. Sulphur dioxide and oxygen that have not reacted are allowed to flow back again over the catalyst in the converter. STAGE3: Conversion of trioxide to sulphuric acid i. Sulphur trioxide SO2 is dissolved in concentrated sulphuric acid H2SO4 to form oleum H2S2O7 which is then diluted with water to form sulphuric acid H2SO4. SO3(g)+H2SO4(l)H2S2O7(l)
Oleum
H2S2O7(l)+ H2O(l)2H2SO4(aq) ii. The two reactions in stage3 are equivalent to adding sulphur trioxide directly into water. SO3(g)+H2O(l)H2SO4(aq) iii. The addition of sulphur trioxide directly into is not carried out because the reaction is vary vigorous; a lot of heat is given off. As a result, alarge cloud of sulphuric acid fumes is produced, which is corrosive and causes severe air pollution.
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Sulphur
2SO(g) + O2(g) 2SO3(g) Temperature: 450-500C Pressure: 2-3 atmospheres Catalyst: Vanadium(V) oxide
SULPHUR DIOXIDE AND ENVIRONMENTAL POLLUTION 1. Sulphur dioxide is one of the by-product of contact process. It is a colourless and poisonous gas with a vary pungent smell. 2. Sulphur dioxide which escape into the air causes air pollution. 3. Sulphur dioxide is an acidic which dissolves in water to form sulphurous acidic, H2SO3. In the atmosphere, sulphur dioxide dissolve in water droplets to form sulphurous acidic. SO2(g) + H2O(l) H2SO3(aq) 4. Oxidation of sulphur acid by oxygen produce sulphuric acid, H2SO4, which falls to the earth as acid rain. Sulphur trioxide is also easily oxidised in the air to form sulphur trioxide. Sulphur trioxide dissolve in rainwater to produce sulphuric acid. SO3(g) + H2O(l) H2SO4(aq)
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(NH3)
USES OF AMMONIA
1. Ammonia that is produce commercially has many uses. 2. It uses: i. In the manufacture of chemical fertilizers such as ammonium sulphate, ammonia nitric, ammonia phosphate and urea. ii. To manufacture nitric acid and explosive. 6|Page
iii. In the making of synthetic fibre and nylon. iv. As a degreasing agent in aqueous form to remove greasy stains in the kitchen.
b) The presence of hydroxide icon causes the aqueous solution to become alkaline. Thus aqueous ammonia solution: i. Turns red litmus paper blue. ii. Reacts with acid to form only salt and waterin neutralization reaction. NH3(aq) + HCI(aq) NH4CI(aq) 2NH3 + H2SO4(aq) (NH4)2SO4(aq) iii. Reacts with solution of metallic cations to produce precipitates. Fe+(aq) + 2OH(aq) Fe (OH)2(s)
(Form ammonia solution) Dirty green precipitate
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3. The mixture of nitrogen and hydrogen gases is passed over an iron catalyst under controlled optimum condition as below to form ammonia gas. i. Temperature: 450-500C ii. Pressure: 200-500 atmospheres iii. Catalyst used: Iron fillings N2(g) + 3H2(g) 2NH3(g)
4. Under these control optimum condition, only 15% of the gas mixture turn into ammonia gas. The nitrogen and hydrogen that have not reacted are then flow back over the catalyst again in the reactor chamber. 5. The ammonia product is then cooled at a low temperature so that it condenses into a liquid in the cooling chamber.
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Nitrogen
Hydrogen
N2 and H2 are mixed in the proportion of 1:3 In the reactor chamber N2(g) + 3H2(g) 2NHIn cooling chamber (g) Temperature: 450-500C Liquid Pressure: 200-500 atmospheres Catalyst used:ammonia process Iron fillings Outline Of Habert
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AMMONIUM FERTILIZERS
1. 2. 3. 4. Nitrogen is required in large amount by plant to make proteins which are necessary for growth and cell repair. Most plant are not able to get a nitrogen supply directly from the air although it is abundant in the air (78%). Plants can only absorb soluble nitrogen compounds from soil through their roots. The nitrogen compounds are usually soluble nitric salt, ammonia and ammonia salt which are manufacture as chemical fertilizer. Reactions of ammonia with acids produce ammonium fertilizers. NH3(aq) + HNO3(aq) NH4NO3(aq)
Ammonium nitrate
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Force
Force
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Composition 99% iron 1% carbon 80.6% iron 0.4% carbon 18%chromium 1% nickel 70% copper 30% zinc
Properties Uses Strong,hard and high Making of cutting wear resistance tools, hammers and chisels Do not rust and Making of surgical tarnish, strong and instrument, knives durable forks and spoons Hard, do not rust, bright appearance
Brass
Bronze Pewter
Duralumin Cupronickel
Making of ornaments, electrical wiring and plug. 90% copper Hard, do not corrode For casting bells, 10% tin easily and durable medals, swords and statues 90% tin Ductile and Making of 2.5% copper malleable, white ornaments, 0.5% antimony silvery appearance souvenirs and mugs 95% aluminium Light, strong and Making part of 4% copper durable aircrafts and racing 1%magnesium cars 75%copper Attractive, silvery Making of silver 25%nickel appearance, hard and coins tough Composition, properties and uses of alloys
ethylene (CH2-CH2)n CH2=CH2 [CH2CH(CH3)]n (CH2CHCl)n (CH2CCl2)n [CH2CH(C6H5)]n (CH2propylene CH2=CHCH3 vinyl chloride CH2=CHCl vinylidene chloride CH2=CCl2 styrene CH2=CHC6H5 acrylonitrile
atactic: soft, elastic similar to LDPE solid carpet, isotactic: hard, upholstery strong solid strong rigid solid pipes, siding, flooring
dense, high-melting seat covers, films solid hard, rigid, clear solid soluble in organic solvents high-melting solid toys, cabinets packaging (foamed) rugs, blankets 13 | P a g e
CHCN)n
CH2=CHCN
clothing non-stick surfaces electrical insulation lighting covers, signs skylights latex paints, adhesives requires vulcanization for practical use synthetic rubber oil resistant
Polytetrafluoroeth tetrafluoroethyl resistant, smooth ylene (CF2-CF2)n ene solid (PTFE, Teflon) CF2=CF2 Poly(methyl methacrylate) (PMMA, Lucite, Plexiglas) methyl [CH2methacrylate C(CH3)CO2C CH2=C(CH3)C H3]n O2CH3 hard, transparent solid
(CH2vinyl acetate Poly(vinyl acetate) CHOCOCH3) CH2=CHOCOC soft, sticky solid (PVAc) H3 n cis-Polyisoprene natural rubber Polychloroprene (cis + trans) (Neoprene) [CH2isoprene CH=C(CH3)- CH2=CHCH2]n C(CH3)=CH2 [CH2CH=CClCH2]n chloroprene CH2=CHCCl=CH2 soft, sticky solid tough, rubbery solid
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Soda-lime glass
Borosilicate glass
SiO2: 78% B2O3: 12% Na2O: 5% CaO: 3% Al2O3:2% SiO2: 70% Pbo/PbO2:20% Na2O: 10%
Cooking utensils Laboratory glassware such as conical flaks and boiling tube Lenses and prisms Decorative glassware and art object Imation jewellery
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CERAMICS
1. Traditional silicate ceramics are made by heating aluminosilicate clay such as kaolin to a vary high temperature. 2. Ceramics have many special properties that make them one of the most useful materials in our everyday life. That: a. Are hard, strong but brittle b. Have high melting point and remain stable at high temperature c. Are heat and electric instrument d. Are resistant to corrosion and wear e. Are chemically not reactive f. Do not readily deform under stress 3. Ceramic play important role in our daily life. They are uses as a. Construction materials i. Ceramic are strong and hard, uses to make roof tiles, bricks cement, sinks, and toilet bowls. ii. They are also used to make refractory bricks because high resistant to heat. b. Decorative items i. To make pottery, china plates, and porcelain vases since they do not tarnish easily and are durable. ii. They are used to make bathroom fixture such as floor and wall tiles. c. Electrical insulator i. Ceramic are used to make electrical insulator in electrical items such as toasters, fridges and electrical plug. Materials Oxide ceramic Alumina,AL2O3 Beryllia, BeO Zirconia, ZiO Non-oxide ceramics Boron carbide,B4C3 Silicon nitride, Si3, n4 Metals Aluminium Steel Melting point/ C 2054 2574 2710 2350 2830 1900 660 1515 Density/G cm-3 3.97 3.01 5.68 2.50 3.16 3.17 2.70 7.86 Elastic modulus/ GPa 380 370 210 280 400 310 70 205 Hardness/ mohs 9 8 8 9 9 9 3 5
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REINFORCES CONCRETE
1. Concrete is hard, fireproof, waterproof, comparatively cheap and easy to maintain. It is more important construction materials. 2. The reinforces is a combination of concrete and steel.
SUPERCONDUCTOR
1. Metal such as copper and aluminium are good conductor of electricity, but 20% of the electric energy is lost in the form of heat during transmission. 2. Super conductor are materials that have no resistance to the flow of electricity at a particular temperature. Hence, 100% electricity transmission is possible. 3. One of the most dramatic properties of a superconductor is its ability to levitate a magnet. Superconductor are used to build magnetically levitate high-speed train (at about 552 km/h). 4. Superconductor are used to make chips for smaller and faster supercomputer. Superconductor also play an important role in high speed data processing in internet communication.
FIBRE OPTIC
1. Fibre optic is a composite material that in used to transmit signals for light wave. 2. Fibre optic is used in a. Telecommunicate where the telephone substation are liked by fibre optic cables. b. Domestic cable television network c. Closed circuit television security system. 3. Fibre optic also used in medical fields. It is used in a number of instrument which enable the investigation for internal body part without having to perform surgery. 17 | P a g e
FIBRE GLASS
1. Fibre glass is glass in the form of fine threads. Molten gas is dropped onto a refractory rating disc when the glass flies off the disc glass to form fibre. 2. Fibre glass is strong than steel, do not burnt, stretch or rot, resistant to fire and water but is brittle. 3. When fibre glass added to a plastic, a new composite material fibre glass reinforces plastic is formed. 4. Fibre glass reinforces plastic has more superior properties than glass and plastic. It is a. Extremely strong b. Light weigh c. Resistant to fire and water d. Can be molded, shaped and twisted
PHOTOCHROMIC GLASS
1. When 0.01 to 0.1% of silver chloride (a type of photochromic substances) and a small amount of copper (II) chloride are added to molten silicon dioxide, photochromic glass is formed. 2. The photochromic glass has a special properties. It darken when exposed to strong sunlight or ultraviolet. 3. Photochromic glass is suitable for making sunglasses.
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