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Chemistry 201
Second Hour Exam
October 15,2004

Name: &3&V2, (~GL~C\&\

Read each question carefully. Show all work.

(5 pts.) 1. An ion is formed

a) by adding or subtracting protons from an atom.

@ by adding or subtracting electrons from an atom.
c) by adding or subtracting neutrons from an atom.
d) all of the above are correct.
e) none of the above are correct.

(5 pts.)2. Which islare not the correct chemical formula(s) for the compound named?

@ potassium sulfite K ~ S O ~
b) cesium chloride CsCl
c) ammonium sulfide (NH4)2S
d) magnesium oxide MgO
@ calcium nitrate Ca(NO2)2
(8 pts.)3. An element's most stable ion forms an ionic compound having the formula XF2. If the
mass number of the ion is 137 and it has 54 electrons, what is the element and how many
neutrons does it have?

a) Xe, 83 neutrons c) Te, 85 neutrons e) Rb, 82 neutrons

b) Xe, 85 neutrons
0 d) Ba, 81 neutrons

(10 pts.)4. Identify each of the following:

a) The noble gas in the third period kc.

b) The transition metal that has 25 electrons as a 2+ cation
G"
c) The halogen in the second period F .
d) The alkali metal that has 18 electrons as a stable ion @.
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ex
e) The chalcogen in the second period 0 .
(6 pts.)5. The atomic mass of rhenium is 186.2. Given that 62.9% of natural rhenium is
rhenium -1 87, what is the other isotope?

(10 pts.)6. A metal forms an oxide MO containing 77.4% metal by mass. Calculate the atomic
mass of the metal.

(10 pts.)7. TNT consists of carbon, nitrogen, oxygen and hydrogen. It is 37.02% carbon by mass,
18.49% nitrogen by mass, and 42.27% oxygen by mass. The molar mass of TNT is
between 2 10 g mol-' and 245 g mol-'. What is the molecular formula for TNT?

a) CsHl2N304 b) CaH4N3Oa @ C7HsN306

d) C4H7N606 e) none of these. '-8 &\/\

%
,, \t = -b?. . Q Z7'
- -- z,b% ,+G- a- 19.4 9
--.------- - '-
3 = Z'L.
'=--'?i
--'
I+.L!?
a -\-'

(8 pts.)8. Consider the following unbalanced chemical equation: KC103 -+ KC1 + 0 2 . When
balanced, for every mole of KC103 I. S mole of 0 2 is produced.

5 b) 1.0 c) 2.0 d) 2.5 e) 0.5

(6 pts.)9. Mixing 30.0 mL of 5.00 M sugar solution with 20.0 mL of 3.00 M sugar solution results
in 50.0 mL of a sugar solution with a concentration of

a) 2.00M b) 3.80M @]4.20M d) 3.00M e)5.00M

< ~ Q . Q,"")(-~.ca{-\ + (-.ib\~)\ - -

3-OM\ .
-- 4.z*
4 5 Cd :_.*t

(8 pts.) 10. Lead (11) nitrate reacts with magnesium bromide in aqueous solution to form a
precipitate. Write the complete molecular, complete ionic, and net ionic equations for
this reaction.

(6 pts.)ll. For which of the following acid solutions will 25.0 mL neutralize 25.0 rnL of a
0.10 M Ca(0H)Z solution?
2
a) 0.10 M HC1 b) 0.20 M H2SO3 C) 0.20 M H2SO4 d) 0.30 M HBr
 (8 pts.)l2. Identify the oxidizing agent (OA) and reducing agent (RA) in each of the following
reactions.

1
I
Reaction OA RA

(10 pts.)l3. Complete and balance the following redox reaction in acidic aqueous solution using
the half-reaction method.