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CHEMISTRY
ASSIGNMENT. 02
Introduction
In cellulosic fibres, there are many methods
used in dyeing process. When dyeing a fabric from cellulose or any other fibre
type, dyestuff should be strictly attached to fibre, to have good fastness property.
These dye stuffs make some kind of bonds to get stuck with fibres. Hydrogen
bonds, van der walls bonds, and covalent bonds are some of them. To make this
type of bonds, first of all dye stuffs should be solubilized in water solution.
In dyeing of textile materials, every used dyes are not soluble in
aqueous medium. There’re some water insoluble dyes also used in textile dyeing
industry. After having some chemical treatments, they take from their water
soluble form for further processing.
We discus here how to make a dyed fabric
from water insoluble colourants, and the reactions involved in that process and
their qualities.
Vat dyes are insoluble in water and they can not be used
directly for dyeing fabrics. Vat dyes are only possible in dyeing, when they are in
their reduced form, which is known as leuco form. For the reduction, it is used
sodium hydrosulphite with caustic soda.
When this compound reduced from sodium dithionite, it can be applied to cellulose
fibres. But when we look at the indigo’s soluble form (leucoindigo), it’s containing
negative charge. The fibres of fabric, we’re going to dye, also contain negative charge.
So this dyeing process is not possible under those conditions. There should be a way
carry out the dye ions to fibre by reducing the repulsion between dye ion and cellulose
molecule. For this purpose we add some sodium salt to the dye bath. Negatively
charged dye ions gather around these sodium ions and it makes an affinity to fibre
from dye ion.
After dye molecules are deposited in fibres, once again they are oxidized to
make them water insoluble. Oxidizing reaction is done by oxygen in air.
After the dyeing process is end, the dyed materials are rinsed
away, then it’s treated with acid, rinsed again, and then it’s soaped at the boiling
temperature for the final product.
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The conditions of dyeing process.
Reduction of insoluble dye molecule is done at room temperature.
During the dyeing process temperature is gradually raised about to
o
80 C.
o
The time for dyeing,o depend on the temperature, 45mnts for 60 C
and 20mnts for 100 C.
Salt are added to improve absorption of dye molecules.
02.Sulphur dyes
Sulfur dyes are primarily used for dark colors such as blacks, browns, and
dark blues.
Same as we discussed in vat dyeing process, in normal state of sulfur
dyes are not in water soluble form. It should be converted into reduced form
(leuco form), after having a reducing reaction from sodium sulphide or sodium
hydrosulphite, to make it water soluble.
03.Disperse dyes.
Azo disperse dye is a one of disperse dye, characterized by
their presence of one or more azo groups (–N=N–). These azo groups make the
linkage of molecule, between two or more aromatic rings.
To prepare an azo dye, a primary
aromatic amine should be converted in to a diazonium compound. Then
prepared diazonium compound should be coupled with phenols, naphthols, or
other aromatic amine.
Coupling with those products should be carried out in acidic or basic
medium, as they required. Diazotization reactions should be carried out in
temperature, 0 C – 5 C, as those compounds are very unstable.
o o
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and it’s none ionic in charge. Shape of these dyes makes it easier to slide
between tightly packed polymer chains.
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04.Coupling dyes.
Naphthol dyes and azoic dyes are used dyes in coupling dyes.
This type is difference than other dyes, because of its dyeing mechanism. It
makes insoluble large molecule, using a two reactive organic component, with in
a fibre. The two components used is a diazonium and a naphthol.
The dyes which have coupling reaction with in a fibre have good fastness
property to washing and rubbing. The final dye molecule come after
coupling reaction, is bigger than other types of dyestuffs. So the coupled
dyestuff entangle with cellulose polymer. Then it difficult to remove either
washing or rubbing.
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05.Pigments.
Pigments are not dyes but used in textile industry as a colourant,
for dyeing and printing. In this dyeing method there’s no actual chemical
reaction involved between dye and fabric. In briefly pigments are applied as a
layer on fibre, and then they’re bonded to the fibre surface by using with the
help of “binders”.
These pigments are insoluble in water and they don’t have an
affinity to fibres. (But the affinity is not important character.) Insoluble
pigments take as dispersion, they attached to the fibre in this state.
Pigments are maintained as a stable dispersion in
aqueous medium, by anionic surfactants. This type of pigment is known as
pigment resin color (PRC). These pigments are used in printing.
In pigment dyeing, attachment of a cationic polymer to
fibre may cause to pigments absorption to the fibre surface. This attachment
of cationic polymer is done in pre-processing stage. But this absorption is not
a strong one, because bonding occurs between cationic surface of the pre-
processing agent and anionic surfactant of the pigment surface.
The main disadvantage of pigment is hardening of
hand. The chemicals used to bind the pigments to fibre are the reason for this
fault.
06.Reactive dyes.
Reactive dyes react with cellulose fibre and they
make covalent bond between fibre and dye molecule. Therefore reactive dyes
are extremely washing fast.
A dye like a direct dye reacts with a trichlorotriazine
molecule to form this kind of dyes.
The -NH2 group of dye ion react with the –Cl of
trichlorotriazine. Then it releases a HCl as a byproduct.
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During the dyeing process, the
Cl atom of dye molecule reacts with a primary alcohol group, which attached to
the cellulose polymer. Then it combines a dyestuff and cellulose polymer.
There is some repulsion between dye ion and cellulosic fibre, which
have (-) zeta potential.
If this repulsion is lower than attraction between and dyestuff,
dyestuffs can migrate to the fibre.
In reactive dyeing, it uses salts to improve this.
Dye molecules diffuse from the fibre surface to the interior of fibre.
Diffusion will continue until they come to an equilibrium of dye concentration in
fibre and in dye.
Increasing the dyeing temperature can enlarge the diffusion of dye molecules in
the interior of fibre. It results to increases the dyeing rate.
When dyeing with reactive dyes, dyestuffs react with fibres during
the diffusion.