INSTITUTE OF COMMERCE EDUCATION

DEPARTMENT OF SCIENCE
Class: XI (Science) St# 7, G-Road, Behar Colony, Karachi
Time: 2½
Paper: Chemistry PRELIUM EXAMINATION Marks:
68
SECTION ‘B’
Q.2: Answer any TEN of the following.
i) Differentiate:
I- Reversible and Irreversible Reaction
II- Ideal and Real Gas III- Hydration and Hydrolysis
IV- Sigma and Pi Bond V- Valance Bond and Molecular
Orbital Theory
ii) Give the name of following crystal system:
I- a = b= c, α = β = γ ≠ 90° II- a = b =c, α = β = 90°
III- a ≠ b ≠ c, α = β = γ = 90° IV- a ≠ b ≠ c, α = γ = 90°, β ≠ 90°
iii) Define following:
a) Stoichometry b) Atomic Radius
c) Velocity d) Latent heat of fusion
iv) Give the proof of Pauli’s principle.
Give the experimental proof of small nucleus which have positive charge and
have most of the mass.
What do you mean by Kc & Kp give their relationship.
Write a short note on any 2 of the following:
a) Buffer b) Ph c) Ionic character of covalent Bond
d) Energy of Activation e) Bond Energy.
14gm of a gas at 27 C and 1440 torr occupies a volume f 0.815dm3 calculate
o

the molecular mass of the gas.

Define rate of reaction also list the affecting factors on it.
Explain ionization theory in short.
2 Na2 S + Na2CO3 + 4 SO2 → 3Na2 S2 O3 + CO2
Which is limiting reactant?
Calculate the volume of CO2 produced when 100gm of each reactant is reacted.
Which stoichometric relationship is used in above calculation?
1gm of Butane, is burnt 3.03gm of CO2, 1.55gm H2O is released, find molecular
formula, if molecular mass is 58
Define heat of formation also calculate the heat of formation of following.
2C + 3H 2 + 1 O2 → C2 H5 OH ∆H = ?
2
C + O2 → CO2 ∆H = −393.5 KJ
H 2 + 1 O2 → H 2 O ∆H = −286 KJ
2
C2 H 2OH + 3O2 → 2CO2 + 3H2 O ∆H = −1369.4 KJ
xiv) Predict whether there will be any precipitate formation by mixing
30cm3 of 0.01M NaCl with 60cm3 of 0.01M AgNO3 solution. (Ksp=1.5 x
10–10)
xv) Define hybridization and briefly define it’s type.

SECTION ‘C’
NOTE: Attempt any two question from this section
Q.3: (a) Derive the expression of wave number of Bohr’s Atom.
Calculate the volume of N gas at S.T.P
Derive the expression of equilibrium constant for following reaction.
aA + bB → cC + dD
Q.4: (a) For a given chemical reaction. C + D → CD
Calculate:
i) Rate constant when initial concentration of C is 0.4 & D is 0.02
and rate of reaction is 1.05x10–4 moles/dm3
ii) Prove that rate constant do not depend on concentration.
Derive Molar gas equation and also calculate the volume of R in both system of
units
Write the electronic configuration of the following.
~ Cl– (Cl=17), O–2 (O=8) ~ Na+ (Na=11), C (C=6)
Q.5: (a) 30dm3 of hydrogen gas was collected over water at831 torr and 23oC
what would be the volume of dry hydrogen gas at S.T.P
State LE-Chatlier’’s principal along with it’s industrial application.
4.6gm Alcohol and 6gm of acid reacted and 22gm acid left at equilibrium
calculate Kc
CH 3COOH + C2 H5 OH ˆˆ†
ˆ CH2 COOC2 H5 + H2 O .
‡

~ WISH YOU ALL BEST OF LUCK ~

Prepared By:
Engr. Adil