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Table of Contents....................................................................................................... 2
Introduction ............................................................................................................... 1
Direct Dyes.................................................................................................................1
Structural Requirements.............................................................................................2
Conjugated Double Bonds..........................................................................................2
Linear molecule with co-planarity...............................................................................4
Higher molar mass for better Van der waal forces.....................................................5
Sufficient number of Hydrogen bondable groups.......................................................7
Presence of optimum number of solubilising groups..................................................7
Assignment
What are the essential structural requirement for a colorant to be a direct
dye?
Introduction
• Acid Dyes
• Basic Dyes
• Direct Dyes
• Reactive Dyes
• Vat Dyes
Direct Dyes
The society of Dyers and colourists has divided direct dyes into three classes
according to recommendations. They are as follows,
Structural Requirements
Nitro group
All the direct dyes should have a coplanar structure are a requirement
to bond with the fibre. Direct dyes are combined with the fibre using
hydrogen bonds and van der waal forces. Hydrogen bonds and van der waal
forces are very week attractions. Without co-planarity the hydrogen bonds
and the van der waal forces cannot take place as they cannot come close to
the fibre molecule.
Van der waal forces occur due to the attraction of the masses of the
molecules. That means the strength of the van der waal forces increases
with the increase of the molar mass of the molecules. Therefore to increase
the attraction the dye molecule should have a bigger molar mass. As a result
all the direct dyes have long chain of atoms.
Hydrogen bonds usually have a better strength of bonding than van der waal
force. There fore hydrogen bonds are the main bondable groups in direct
dyes. Due to this reason a sufficient number of hydrogen bond must be
present in the dye to properly combine with the fibre. Just having the
sufficient number of hydrogen bondable groups doesn’t make a hydrogen
bond. The hydrogen bondable groups must have a proper distribution to
coincide with primary OH group of the cellulose chain. Then only a proper
hydrogen bond is formed
Presence of
optimum
number
of
solubilising groups
For example