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ABSTRACT:-
INTRODUCTION:-
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An alternative process is to produce a film, cut the film into strips and then
fibrillate the individual strips before winding onto a package. Recently a new
family of catalysts to make polypropylene has been developed called
metallocene catalysts. It is claimed that the polymers made from these catalysts
can be spun to finer counts and drawn to give higher tenacities than existing
polymers.
PROPERTIRS:-
Both polyolefin fibres have a density less than 1.0 and therefore, at
a given decitex, are thicker than other man-made fibres and give more cover.
They do not absorb moisture, which is an advantage in many end-uses, but
without modification, they cannot be dyed. Their melting points are around 130
°C for polyethylene and 160 °C for polypropylene. They have a high resistance to
chemical attack and modern polypropylene fibres have a high resistance to UV
degradation
What is coating ?
• Coatings have also facilitated the development of entirely new products and
have led to innovations in the area of "Smart" materials. Coating and lamination
cuts across virtually every product group in the textile industry, including
composites, where the potential is especially broad.
• Coatings enable significant cost savings when compared with solid materials of
like composition.
• Approximately 100 material types of various grades and strengths are used as
core materials (substrates) for coated fabrics: silk, cotton, polyamide, polyester,
polyaramid, glass fabric, carbon fabric and metal.
• The most frequently used method is coating by means of knife blade coating.
An air knife is used to metre the coating compound above the freely spread fabric
web. This method is used for fine coatings and primer coatings at 5 to 50 g per
metre (g/m). Air knives may be used over a roller to metre the coating compound
at application rates of 30 to 500 g/m. The coat thickness depends on the distance
of the air knife from the substrate surface. For very heavy thickness, air knife is
used over a rubber cloth or table to metre the coating compound.
Besides the classic knife application
methods, there are also numerous other methods:
• The TPO and PP are basically inert towards chemical and microorganism
attack. The finished products have good resistance towards oxygen and ozone
and are flexible at very low temperature i.e. -60ºC. The products are odourless
and do not give out toxic gases on burning.
• The product are lighter than PU or PVC or rubber coated fabrics since
polyolefin are lower in density than PU, PVC or rubbers formulations. The coating
as well as fabric are homologous polymers hence are melt recyclable, which is
not possible in the case of conventional polymer coated fabrics.
• The coated fabrics are available in variety of colors. The dope dyed PP yarn
can be produced in excellent uniform bright colors, which are UV stable. TPO
coating contains light stable pigments. The properties can be custom designed
by altering thickness, strength, flexibility, colors and grain design. In few special
cases fire retardancy can also be archived.
•The fabrics are available in both side as well as one side coated versions,
weldable by thermo fusion welding machine. The fabrics are suitable in a number
of applications. To name a few there are:
BENEFITS OF TPOs:-
In general, TPO membranes are being marketed as a
product that combines the properties of EPDM and PVC, without the associated
drawbacks that the latter two materials have. In other words, they are supposed
to be as UV-resistant and as heat-resistant as EPDM, and as heat-weldable as
PVC.
The following benefits and characteristics have been reported for TPOs
environmentally friendly and recyclable
seams can be heat welded
available in many colours
resistant to heat and UV degradation
resistant to many chemicals
good cold-temperature flexibility
no external plasticizers added.
PERFORMANCE OF TPOs:-
PROCESSING:-
In principle it is basically
a continuous extrusion unit consisting of different arrangement of rollers
adjustable to a fixed nip opening. The coated fabric is produced by “in situ”
pressure laminating the calendered sheet. In this process the care is taken to
avoid thermal shocks to the sensitive materials to avoid deterioration of
mechanical properties. It is worth mentioning here that the whole system is olefin
polymer based and sensitive to the processing temperature. A PP fabric if
processed under warp tension at temperature above its Tm the tenacity is greatly
affected. Calendering processes have advantage in terms of uniformity and
flawlessness of coating however the initial investment cost is high. Following are
description ofcommon calendering process used for TPO coating.
Inverted L calendar:–
• The calender equipments producing coated fabrics are further equipped with
Auxiliary equipments which impart processing ease for further handling of
material. The auxiliaries are very important for processing of TPO coated PP
fabrics.
The outside color of fabric is light and the inside is made dark to avoid excessive
summer heat absorption that could kill anaerobic bacteria. The fabric has all
possibilities and flexibility of fabrication like other coated fabrics and also the
required maintenance possibilities. The choice of strength, weight and colors
remains with the end user requirement as Entremonde has earned expertise in
the custom designing of a product.
ROOFING MEMBRANES:-
In typical low slope roofing systems thermal insulation barrier and water proofing
membrane determines comfort of home. The traditional membranes consist of
PVC or EPDM coated polyester or polyamide fabric. But as discussed earlier
PVC and EPDM materials have their own draw back. New concept of TPO
coated fabric came out with all possible solution to prevailing drawbacks of
conventional materials. Thanks to the developments in multifilament PP yarns, a
sufficiently high tensile strength textile can be manufactured for this application.
The conventional welding equipment can be used for on the spot welding
operations.
FLEXIBLE LIQUID STORAGE TANKS:-
• At present, PVC is dominantly used in many of the auto interior applications for
door panels, roofing upholstery etc. There are certain reasons why PVC is not
the preferred interior material abroad any more.
2. The light weightness of TPO coated fabric is remarkable. This is primarily due
to sp.gravity differences.
3. There is absolutely no smell in the coated fabric unlike in the case of PVC
Coated fabrics.
5. The oil and chemical resistance are superior to those of PVC Coated fabrics.
The interiors made of TPO coated fabrics have distinct advantage of recycling,
as they are same family of materials used in structure and skins etc. Though not
a major critical requirement for Indian market but under the globalization norms,
this is an implied need of auto interiors.
GROUND SHEET:-
Ground Sheet is an essential item used by all soldiers in ground forces. This is
an item of their personal kit. The Ground Sheet are used as sleeping mat,
temporary shelters, to collect water from stream in remote area or as a
hammock. The conventional products are rubber, canvas or cotton based, and
have inherent problems since natural products are susceptible to degradation in
many ways. Cotton fabric being a natural fiber has many disadvantages, like
rough use and daily use makes it very vulnerable to microbial attack, when it is
wet it does not dry up as quickly as polypropylene. The rubber compound
degrades because of unsaturated sites available in its structure. The problem of
oozing is quite common in rubber-coated fabrics. Therefore in older version of
ground sheets, which is a composite of rubber and cotton, there were many
problems, like weathering, UV resistance, and chemical and microbiological
resistance and heaviness due to high-density of materials. Entremonde
Polyecoaters has invented patented1 technology to manufacture PP- TPO
Ground Sheet composite product to over come the above problem faced in
conventional product. These Ground Sheets are successfully introduced in our
Defence forces.
CONCLUSION:-
RERERENCES:-
1.www.fibre2fashion.com
2.www.alcochemical.com
3.www.thomasnet.com
4.m.khandwe, a.k. mody indian patent 211228
5.www.textileworld.com
6.www.omnova.com
7.www.eatp.org
8.www.milliken.com