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FINAL REPORT
Vapor Pressure
Vapor pressure typically rises with the addition of ethanol to gasoline. The
increase is greatest at 10% by volume. At higher concentrations, the
vapor pressure of the blend decreases.
The magnitude of the vapor pressure increase associated with ethanol
addition becomes greater as the base fuel vapor pressure decreases. For
all ethanol levels, it rises steeply for blends produced using base gasoline
fuels with vapor pressures below about 9.5-10.5 psi. Above this level, the
vapor pressure of the base gasoline has minimal impact on the magnitude
of vapor pressure increase from ethanol addition.
Distillation
All levels of ethanol addition tend to lower the boiling temperatures in the
mid-range and back-end of the distillation curve.
1
At a given mid-range temperature (e.g., 200oF), the percent of fuel
evaporated generally increases in proportion to the amount of ethanol
added to the base fuel.
Vapor-Liquid Ratio
The addition of ethanol to gasoline at a concentration of 10% by volume
significantly depresses the temperature for a vapor-liquid ratio of 20
(TV/L=20). Additions of higher levels of ethanol generally result in either no
change or a slight increase in the TV/L=20.
Octane Number
Addition of ethanol to gasoline increases the octane number of the blend.
The rate of increase in octane number is:
o Lower for premium unleaded base gasoline samples than for
regular unleaded base gasoline samples;
o Relatively constant for ethanol blend concentrations ranging from
zero up to about 20% by volume but may decline slightly at higher
levels.
2
BACKGROUND
1
Numbers in parentheses denote references listed at the end of this report.
3
TEST PLAN
As described in detail below, the study test plan entailed: (a) collecting
samples of motor gasoline for use as base stocks for ethanol blending, (b) splash
blending the base stocks to specified concentrations of denatured ethanol, and
(c) analyzing the resultant blends for specific fuel property measurements.
Table 1 shows the distribution of the base stocks collected and used in
this study. Ranges of selected volatility characteristics of the base stocks also
are shown in the table. Inspections of the vapor pressure, distillation and vapor-
lock properties of the retail base stocks in Table 1 indicates that they essentially
complied with the relevant geographic and seasonal ASTM D4814 gasoline
volatility specifications (summarized in Tables 2 and 3).3
2
Six of the base stocks collected at retail were later determined to contain ethanol. These
samples have been excluded from the data shown in Table 1 and from the results discussed later
in this report.
3
The one exception was an ASTM Class B base stock which fell slightly below the minimum
TV/L=20 specifications
4
Table 1: Base Stock Sample Distribution and Range of Volatility Properties
Vapor
a/ b/ T10 T50 T90 TV/L=20
States RUL PUL Total Pressure
(F) (F) (F) (F)
(psi)
ASTM TX, PA,
5 6 11 6.4 – 7.6 130 – 156 213 – 231 306 – 347 147 – 170
Class AA UT, TN
TX, WV,
ASTM Class A 5 5 10 7.5 – 8.2 124 – 146 202 – 240 312 – 332 141 – 160
AR, SD
NE, SD,
ASTM Class B 4 3 7 8.9 – 11.0 119 – 134 194 – 222 29 – 333 128 – 153
UT
TX, AL,
ASTM Class C 3 4 7 8.3 – 12.3 110 – 132 200 – 230 320 – 351 126 – 147
LA, OK
TX, AL,
ASTM Class D 4 4 8 11.0 – 13.2 105 – 116 191 – 229 315 – 338 123 – 130
NC
AK, SD,
ASTM Class E WV, UT, 6 6 12 11.0 – 13.8 100 – 125 176 – 228 262 – 317 110 – 134
WA, IA
Refiner-
TX, NJ,
supplied 3 7 10 4.8 – 7.0 139 – 163 197 – 235 310 – 335 156 – 173
IL, CA
Summer BOBs
Refiner-
supplied Winter TX, IL 1 2 3 10.9 – 11.7 109 – 120 193 – 229 296 – 346 120 – 134
BOBs
CRC Fuels 3 0 3 13.9 – 14.7 93 – 96 143 – 171 269 – 279 104 – 109
TOTALS 34 37 71
a/
RUL = Regular unleaded gasoline
b/
PUL = Premium unleaded gasoline
5
Table 3: ASTM D4814-09b Vapor Lock
Protection Class Requirements
Vapor Lock
Minimum Temperature (oF) for a
Protection
Vapor-Liquid (V/L) Ratio of 20a/
Class
1 129
2 122
3 116
4 116
5 105
6 95
a/
Except for the high altitude region defined as “Area V” in ASTM D4814-09b (6)
Denatured ethanol
6
The denatured fuel ethanol (and all of the base stock samples) were
logged into the SwRI laboratory information system then immediately stored in a
cold box kept at 34-40°F.
Ethanol Blends
Each of the base stocks was splash-blended with denatured fuel ethanol
(in 2-liter blended sample quantities) to the following final blend concentrations
by volume: 0%, 10%, 12.5%, 15%, 20% and 30%.4 All of the ethanol blends
were prepared (and subsequently stored) in the cold box kept at 34-40°F.
Each of the ethanol-free (E0) base stock samples was analyzed for
detailed hydrocarbon species using the ASTM D6729-04 test method.
4
For ease of reference, these ethanol concentrations are denoted in this report using the
following terminology: E0, E10, E12.5, E15, E20 and E30.
7
Table 5: Distribution of Base Stock Samples
Measured For Octane
Premium Regular
Total
Unleaded Unleaded
ASTM Class AA 2 3 5
ASTM Class A 3 2 5
ASTM Class C - 1 1
ASTM Class D - - -
ASTM Class E 1 1 2
Refiner-supplied
1 3 4
Summer BOBs
Refiner-supplied
1 1 2
Winter BOBs
TOTALS 8 11 19
8
RESULTS AND DISCUSSION
Volatility Measurements
As illustrated in the figure, vapor pressure typically rises with the addition
of ethanol over the range of ethanol concentrations measured in this study. For
the ethanol blend levels tested, the vapor pressure is greatest when the
concentration of ethanol in gasoline is 10% by volume.6 At higher
concentrations, the vapor pressure of the blend decreases. This non-linear trend
is consistent with that which has been observed in the literature and has been
attributed to the non-ideal mixture behavior of the highly polar ethanol molecule
which – as a pure compound – has a vapor pressure of 2.3 psi. (1)
Figure 2 shows that the vapor pressure effect associated with the addition
of ethanol for each level of ethanol examined in this study. Each chart illustrates
that this vapor pressure effect is less in gasolines of higher vapor pressure than it
is for gasolines of lower vapor pressure. As described in the literature, this
phenomenon results from the fact that the partial pressure fraction generated by
the ethanol mole fraction is constant for a given temperature, regardless of how
much partial pressure is contributed by the gasoline. (1)
The trend lines drawn in each chart in Figure 2 represent a 2-piece linear
fit of the data at each level of ethanol addition (10, 12.5, 15, 20 and 30% by
volume, respectively). The chart at the bottom right of Figure 2 displays these
5
This classification scheme is used for all of the figures presented in this section (except where
specifically noted otherwise).
6
The present study did not evaluate the volatility effects associated with the addition of ethanol at
concentrations between 0 and 10% by volume. Other studies in the literature have shown that
the maximum increase in vapor pressure with ethanol addition actually occurs in the
neighborhood of 2-5% ethanol by volume, and the magnitude of the effect is a function of the
vapor pressure of the underlying hydrocarbon base fuel. (1,3,4)
9
Figure 1
Effect of Ethanol Addition on Vapor Pressure
10
Figure 1 (cont’d)
Effect of Ethanol Addition on Vapor Pressure
11
Figure 2
Change in Vapor Pressure with Ethanol Addition
As a Function of Base Gasoline Vapor Pressure
12
trend lines on a single plot without the individual data points for ease of viewing.
The magnitude of the vapor pressure increase associated with ethanol addition
becomes greater as the base fuel vapor pressure decreases. For all ethanol
levels it rises steeply for blends produced with base gasoline fuels having vapor
pressures below about 9.5-10.5 psi. Above this level, the vapor pressure of the
base gasoline has minimal impact on the magnitude of vapor pressure increase
from ethanol addition.
For the low T50 base gasoline, the largest depression in the distillation
curve occurs roughly between the 62% and 85% evaporated points, depending
upon the amount of ethanol in the blend. For the high T 50 fuel, the largest
temperature depression occurs between the 45% and 70% evaporated points,
again depending upon the amount of ethanol in the blend. Stated in other terms,
at a given mid-range temperature (e.g., 200oF), the percent of fuel evaporated
13
Figure 3
Effect of Ethanol Addition on D86 Distillation Temperature
For a Retail Base Gasoline with Low T50
14
Figure 4
Effect of Ethanol Addition on D86 Distillation Temperature
For a Retail Base Gasoline with High T50
15
Figure 5
Effect of Ethanol Addition on D86 Distillation Temperature
For a CRC Base Gasoline with a T50 of 143oF
16
Figure 6
Effect of Ethanol Addition on D86 Distillation Temperature
For a CRC Base Gasoline with a T50 of 148oF
17
generally increases in proportion to the amount of ethanol added to the base
fuel.7
7
This observation is not necessarily surprising as ethanol has a constant boiling temperature of
o o o
172 F whereas gasoline typically boils over a range of 80 F to 437 F. (1)
18
Figure 7
Effect of Ethanol Addition on T50
19
Figure 7 (cont’d)
Effect of Ethanol Addition on T50
20
Table 6: Distribution of Samples Failing to Meet the ASTM D4814
Minimum T50 Specification of 170oF for ASTM Volatility
Classes AA, A, B and C
Range of
Nominal Ethanol # of Samples Total
Measured T50 o
(Volume %) with T50<170 F Samples
(oF)
0 193 – 240 0 48
10 153 – 226 18 48
20 157 – 167 47 47
30 159 – 168 48 48
21
differences among the hydrocarbon compositions of the base gasoline samples.
At high levels of ethanol addition, the sensitivities tend to converge. This simply
reflects the effect of a greater concentration of a relatively high octane number
blending value single component molecule in the fuel mixture. Stated in other
words, as sensitivity increases, the boost provided by the addition of ethanol
decreases.
22
Figure 8
Effect of Ethanol Addition on Temperature for V/L=20
23
Figure 8 (cont’d)
Effect of Ethanol Addition on Temperature for V/L=20
24
Figure 9
Effect of Ethanol Addition on Octane Number
25
Figure 10
Increase in Octane Number with Ethanol Addition
26
Figure 11
Effect of Ethanol Addition on Sensitivity
27
SUMMARY
Vapor Pressure
Vapor pressure typically rises with the addition of ethanol to gasoline. The
increase is greatest at 10% by volume. At higher concentrations, the
vapor pressure of the blend decreases.
The magnitude of the vapor pressure increase associated with ethanol
addition becomes greater as the base fuel vapor pressure decreases. For
all ethanol levels, it rises steeply for blends produced with base gasoline
fuels having vapor pressures below about 9.5-10.5 psi. Above this level,
the vapor pressure of the base gasoline has minimal impact on the
magnitude of vapor pressure increase from ethanol addition.
Distillation
All levels of ethanol addition tend to lower the boiling temperatures in the
mid-range and back-end of the distillation curve.
At a given mid-range temperature (e.g., 200oF), the percent of fuel
evaporated generally increases in proportion to the amount of ethanol
added to the base fuel.
Vapor-Liquid Ratio
The addition of ethanol to gasoline at a concentration of 10% by volume
significantly depresses the temperature for a vapor-liquid ratio of 20
(TV/L=20). Additions of higher levels of ethanol generally result in either no
change or a slight increase in the TV/L=20.
Octane Number
Addition of ethanol to gasoline increases the octane number of the blend.
The rate of increase in octane number is:
o Lower for premium unleaded base gasoline samples than for
regular unleaded base gasoline samples;
28
o Relatively constant for ethanol blend concentrations ranging from
zero up to about 20% by volume but may decline slightly at higher
levels.
..
29
REFERENCES
30
(This page is intentionally blank.)
31
Determination of the Potential Property Ranges of
Mid-Level Ethanol Blends
APPENDIX A
A-1
ASTM Class AA AA AA AA AA AA AA AA AA AA AA AA
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839055 839199 839200 839201 839202 839203 839054 839194 839195 839196 839197 839198
Date 9/25/08 10/1/08 10/1/08 10/1/08 10/1/08 10/1/08 9/25/08 10/1/08 10/1/08 10/1/08 10/1/08 10/1/08
TV/L=20 (oF) 169.6 139.1 139.1 139.7 138.9 140.5 149.8 131.7 131.6 131.5 132.3 133.3
RON
MON
(R+M)/2
A-2
ASTM Class AA AA AA AA AA AA AA AA AA AA AA AA
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839057 839209 839210 839211 839212 839213 839056 839204 839205 839206 839207 839208
Date 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08 9/25/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08
A-3
ASTM Class AA AA AA AA AA AA AA AA AA AA AA AA
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839057 839209 839210 839211 839212 839213 839056 839204 839205 839206 839207 839208
Date 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08 9/25/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08
TV/L=20 (oF) 167.2 138.9 140.4 139.9 139.6 140.6 147.1 128.2 128.3 128.4 129.2 130.5
A-4
ASTM Class AA AA AA AA AA AA AA AA AA AA AA AA
State UT UT UT UT UT UT UT UT UT UT UT UT
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839061 839229 839230 839231 839232 839233 839060 839224 839225 839226 839227 839228
Date 9/25/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08 9/25/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08
A-5
ASTM Class AA AA AA AA AA AA AA AA AA AA AA AA
State UT UT UT UT UT UT UT UT UT UT UT UT
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839061 839229 839230 839231 839232 839233 839060 839224 839225 839226 839227 839228
Date 9/25/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08 9/25/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08
TV/L=20 (oF) 162.5 137.9 137.8 137.7 138.4 140.2 157.2 134.7 134.4 134.5 134.7 137.7
A-6
ASTM Class AA AA AA AA AA AA AA AA AA AA AA AA
State PA PA PA PA PA PA PA PA PA PA PA PA
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839062 839234 839235 839236 839237 839238 839064 839244 839245 839246 839247 839248
Date 9/25/08 10/1/08 10/1/08 10/1/08 10/1/08 10/1/08 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08
A-7
ASTM Class AA AA AA AA AA AA AA AA AA AA AA AA
State PA PA PA PA PA PA PA PA PA PA PA PA
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839062 839234 839235 839236 839237 839238 839064 839244 839245 839246 839247 839248
Date 9/25/08 10/1/08 10/1/08 10/1/08 10/1/08 10/1/08 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08
TV/L=20 (oF) 152.0 133.4 133.0 133.3 133.0 134.3 155.5 136.5 137.0 137.1 136.7 137.8
RON 92.5 95.9 96.7 96.6 98.6 100.5 98.8 100.7 101.1 101.4 101.5 101.8
MON 82.9 84.6 85.1 85.1 85.7 88.1 87.5 88.8 88.6 89.0 88.8 89.4
(R+M)/2 87.7 90.3 90.9 90.9 92.1 94.3 93.2 94.8 94.9 95.2 95.2 95.6
A-8
ASTM Class AA AA AA AA AA AA AA AA AA AA AA AA
State PA PA PA PA PA PA TN TN TN TN TN TN
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839063 839239 839240 839241 839242 839243 839059 839219 839220 839221 839222 839223
Date 9/25/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08 9/25/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08
A-9
ASTM Class AA AA AA AA AA AA AA AA AA AA AA AA
State PA PA PA PA PA PA TN TN TN TN TN TN
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839063 839239 839240 839241 839242 839243 839059 839219 839220 839221 839222 839223
Date 9/25/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08 9/25/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08
TV/L=20 (oF) 154.0 132.2 131.6 131.8 132.4 133.6 164.8 140.2 139.7 139.8 139.9 141.2
RON
MON
(R+M)/2
A-10
ASTM Class AA AA AA AA AA AA A A A A A A
State TN TN TN TN TN TN SD SD SD SD SD SD
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839058 839214 839215 839216 839217 839218 839066 839256 839257 839258 839259 839260
Date 9/25/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08 9/25/08 10/1/08 10/1/08 10/1/08 10/1/08 10/1/08
A-11
ASTM Class AA AA AA AA AA AA A A A A A A
State TN TN TN TN TN TN SD SD SD SD SD SD
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839058 839214 839215 839216 839217 839218 839066 839256 839257 839258 839259 839260
Date 9/25/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08 9/25/08 10/1/08 10/1/08 10/1/08 10/1/08 10/1/08
TV/L=20 (oF) 152.9 134.4 134.6 133.3 134.0 135.0 151.3 133.1 132.7 133.2 133.1 134.8
RON 92.0 95.6 96.4 97.2 98.4 100.0 94.4 98.4 99.0 99.6 101.0 101.8
MON 82.8 84.2 84.7 85.4 87.1 87.7 86.7 89.1 89.5 89.4 90.2 90.4
(R+M)/2 87.4 89.9 90.6 91.3 92.8 93.9 90.6 93.8 94.3 94.5 95.6 96.1
A-12
ASTM Class A A A A A A A A A A A A
State SD SD SD SD SD SD SD SD SD SD SD SD
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839065 839251 839252 839253 839254 839255 839068 839344 839345 839346 839347 839348
Date 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08
A-13
ASTM Class A A A A A A A A A A A A
State SD SD SD SD SD SD SD SD SD SD SD SD
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839065 839251 839252 839253 839254 839255 839068 839344 839345 839346 839347 839348
Date 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08
TV/L=20 (oF) 147.3 129.0 130.1 129.3 129.9 131.8 150.3 132.6 132.5 133.1 133.2 134.5
RON
MON
(R+M)/2
A-14
ASTM Class A A A A A A A A A A A A
State SD SD SD SD SD SD TX TX TX TX TX TX
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839067 839339 839340 839341 839342 839343 839070 839354 839355 839356 839357 839358
Date 9/25/08 10/1/08 10/1/08 10/1/08 10/1/08 10/1/08 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08
A-15
ASTM Class A A A A A A A A A A A A
State SD SD SD SD SD SD TX TX TX TX TX TX
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839067 839339 839340 839341 839342 839343 839070 839354 839355 839356 839357 839358
Date 9/25/08 10/1/08 10/1/08 10/1/08 10/1/08 10/1/08 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08
TV/L=20 (oF) 147.4 128.8 128.1 128.9 129.3 130.2 148.9 129.7 130.2 130.5 130.3 131.6
RON 89.0 93.4 94.7 95.7 97.3 99.9 94.5 97.7 98.3 98.9 99.6 101.4
MON 81.5 83.8 84.2 84.6 85.6 88.1 83.9 86.6 86.6 86.8 87.1 88.7
(R+M)/2 85.3 88.6 89.5 90.1 91.5 94.0 89.2 92.1 92.4 92.9 93.4 95.1
A-16
ASTM Class A A A A A A A A A A A A
State TX TX TX TX TX TX AR AR AR AR AR AR
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839069 839349 839350 839351 839352 839353 839072 839364 839365 839366 839367 839368
Date 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08
A-17
ASTM Class A A A A A A A A A A A A
State TX TX TX TX TX TX AR AR AR AR AR AR
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839069 839349 839350 839351 839352 839353 839072 839364 839365 839366 839367 839368
Date 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08
TV/L=20 (oF) 149.8 129.0 129.3 129.2 129.1 130.7 150.6 130.3 131.0 129.9 130.7 132.4
RON
MON
(R+M)/2
A-18
ASTM Class A A A A A A A A A A A A
State AR AR AR AR AR AR WV WV WV WV WV WV
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839071 839359 839360 839361 839362 839363 839074 839374 839375 839376 839377 839378
Date 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08 11/4/08 11/21/08 11/21/08 11/21/08 11/21/08 11/21/08
A-19
ASTM Class A A A A A A A A A A A A
State AR AR AR AR AR AR WV WV WV WV WV WV
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839071 839359 839360 839361 839362 839363 839074 839374 839375 839376 839377 839378
Date 9/25/08 10/3/08 10/3/08 10/3/08 10/3/08 10/3/08 11/4/08 11/21/08 11/21/08 11/21/08 11/21/08 11/21/08
TV/L=20 (oF) 141.0 125.3 126.0 126.1 126.3 127.9 160.2 134.9 135.3 136.1 136.5 138.4
RON 91.4 95.6 96.2 96.8 98.3 100.2 97.0 100.7 101.4 102.0 101.9 102.1
MON 82.1 84.4 84.8 85.2 85.7 87.2 91.3 91.0 91.8 92.1 92.3 91.8
(R+M)/2 86.8 90.0 90.5 91.0 92.0 93.7 94.2 95.9 96.6 97.1 97.1 97.0
A-20
ASTM Class A A A A A A B B B B B B
State WV WV WV WV WV WV NE NE NE NE NE NE
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839073 839369 839370 839371 839372 839373 895211 895212 895213 895214 895215 895216
Date 11/4/08 11/21/08 11/21/08 11/21/08 11/21/08 11/21/08 10/21/09 11/5/09 11/5/09 11/5/09 11/5/09 11/5/09
A-21
ASTM Class A A A A A A B B B B B B
State WV WV WV WV WV WV NE NE NE NE NE NE
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839073 839369 839370 839371 839372 839373 895211 895212 895213 895214 895215 895216
Date 11/4/08 11/21/08 11/21/08 11/21/08 11/21/08 11/21/08 10/21/09 11/5/09 11/5/09 11/5/09 11/5/09 11/5/09
TV/L=20 (oF) 144.6 126.8 126.4 127.2 128.0 129.8 142.50 126.40 128.90 126.70 130.20 131.70
RON
MON
(R+M)/2
A-22
ASTM Class B B B B B B B B B B B B
State NE NE NE NE NE NE SD SD SD SD SD SD
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 895205 895206 895207 895208 895209 895210 895229 895230 895231 895232 895233 895234
Date 10/21/09 11/5/09 11/5/09 11/5/09 11/5/09 11/5/09 10/21/09 11/5/09 11/5/09 11/5/09 11/5/09 11/5/09
A-23
ASTM Class B B B B B B B B B B B B
State NE NE NE NE NE NE SD SD SD SD SD SD
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 895205 895206 895207 895208 895209 895210 895229 895230 895231 895232 895233 895234
Date 10/21/09 11/5/09 11/5/09 11/5/09 11/5/09 11/5/09 10/21/09 11/5/09 11/5/09 11/5/09 11/5/09 11/5/09
TV/L=20 (oF) 139.90 125.20 123.50 125.80 124.60 129.10 152.90 131.40 135.00 133.20 132.00 137.40
RON
MON
(R+M)/2
A-24
ASTM Class B B B B B B B B B B B B
State SD SD SD SD SD SD UT UT UT UT UT UT
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 895223 895224 895225 895226 895227 895228 895235 895236 895237 895239 n/a 893886
Date 10/21/09 11/5/09 11/5/09 11/5/09 11/5/09 11/5/09 11/9/09 12/2/09 12/2/09 12/2/09 12/2/09 12/2/09
A-25
ASTM Class B B B B B B B B B B B B
State SD SD SD SD SD SD UT UT UT UT UT UT
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 895223 895224 895225 895226 895227 895228 895235 895236 895237 895239 n/a 893886
Date 10/21/09 11/5/09 11/5/09 11/5/09 11/5/09 11/5/09 11/9/09 12/2/09 12/2/09 12/2/09 12/2/09 12/2/09
TV/L=20 (oF) 140.90 124.90 127.70 127.80 128.30 128.10 141.00 128.30 126.10 129.10 n/a 130.95
RON
MON
(R+M)/2
A-26
ASTM Class B B B B B B B B B B B B
State UT UT UT UT UT UT UT UT UT UT UT UT
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 895247 895248 895249 895250 895251 895252 895241 893887 n/a 895244 895245 895246
Date 10/21/09 11/5/09 11/5/09 11/5/09 11/5/09 11/5/09 11/9/09 12/2/09 12/2/09 12/2/09 12/2/09 12/2/09
A-27
ASTM Class B B B B B B B B B B B B
State UT UT UT UT UT UT UT UT UT UT UT UT
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 895247 895248 895249 895250 895251 895252 895241 893887 n/a 895244 895245 895246
Date 10/21/09 11/5/09 11/5/09 11/5/09 11/5/09 11/5/09 11/9/09 12/2/09 12/2/09 12/2/09 12/2/09 12/2/09
TV/L=20 (oF) 151.20 129.70 132.90 130.30 130.80 136.00 127.90 119.50 n/a 121.40 122.40 122.60
RON
MON
(R+M)/2
A-28
ASTM Class C C C C C C C C C C C C
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 865541 865542 865543 865544 865545 865546 865535 865536 865537 865538 865539 865540
Date 4/14/09 4/29/09 4/29/09 4/29/09 4/29/09 4/29/09 4/14/09 4/28/09 4/28/09 4/28/09 4/28/09 4/28/09
A-29
ASTM Class C C C C C C C C C C C C
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 865541 865542 865543 865544 865545 865546 865535 865536 865537 865538 865539 865540
Date 4/14/09 4/29/09 4/29/09 4/29/09 4/29/09 4/29/09 4/14/09 4/28/09 4/28/09 4/28/09 4/28/09 4/28/09
TV/L=20 (oF) 137.8 123.8 124.1 124.4 125.6 128.8 126.2 116.7 116.6 118.1 118.1 120.9
A-30
ASTM Class C C C C C C C C C C C C
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 865515 865548 865549 865550 865551 871059 865589 865590 865591 865592 865593 865594
Date 4/6/09 4/28/09 4/28/09 4/28/09 4/28/09 5/8/09 4/14/09 4/29/09 4/29/09 4/29/09 4/29/09 4/29/09
A-31
ASTM Class C C C C C C C C C C C C
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 865515 865548 865549 865550 865551 871059 865589 865590 865591 865592 865593 865594
Date 4/6/09 4/28/09 4/28/09 4/28/09 4/28/09 5/8/09 4/14/09 4/29/09 4/29/09 4/29/09 4/29/09 4/29/09
TV/L=20 (oF) 117.97 120.0 120.3 120.7 121.8 126.4 140.8 125.8 125.7 126.2 128.4 128.8
RON
MON
(R+M)/2
A-32
ASTM Class C C C C C C C C C C C C
State TX TX TX TX TX TX LA LA LA LA LA LA
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 865583 865584 865585 865586 865587 865588 865601 865602 865603 865604 865605 865606
Date 4/14/09 4/29/09 4/29/09 4/29/09 4/29/09 4/29/09 4/14/09 4/29/09 4/29/09 4/29/09 4/29/09 4/29/09
A-33
ASTM Class C C C C C C C C C C C C
State TX TX TX TX TX TX LA LA LA LA LA LA
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 865583 865584 865585 865586 865587 865588 865601 865602 865603 865604 865605 865606
Date 4/14/09 4/29/09 4/29/09 4/29/09 4/29/09 4/29/09 4/14/09 4/29/09 4/29/09 4/29/09 4/29/09 4/29/09
TV/L=20 (oF) 144.3 129.4 130.6 130.7 131.5 131.4 147.2 128.0 129.8 129.7 129.7 133.3
RON
MON
(R+M)/2
A-34
ASTM Class C C C C C C
State LA LA LA LA LA LA
Grade RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 865595 865596 865597 865598 865599 865600
Date 4/14/09 4/28/09 4/28/09 4/28/09 4/28/09 4/28/09
A-35
ASTM Class C C C C C C
State LA LA LA LA LA LA
Grade RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 865595 865596 865597 865598 865599 865600
Date 4/14/09 4/28/09 4/28/09 4/28/09 4/28/09 4/28/09
RON
MON
(R+M)/2
A-36
ASTM Class D D D D D D D D D D D D
State NC NC NC NC NC NC NC NC NC NC NC NC
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 861975 861976 861977 861978 861979 861980 861969 861970 861971 861972 861973 861974
Date 3/13/09 3/20/09 3/20/09 3/20/09 3/20/09 3/20/09 3/13/09 3/20/09 3/20/09 3/20/09 3/20/09 3/20/09
A-37
ASTM Class D D D D D D D D D D D D
State NC NC NC NC NC NC NC NC NC NC NC NC
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 861975 861976 861977 861978 861979 861980 861969 861970 861971 861972 861973 861974
Date 3/13/09 3/20/09 3/20/09 3/20/09 3/20/09 3/20/09 3/13/09 3/20/09 3/20/09 3/20/09 3/20/09 3/20/09
TV/L=20 (oF) 124.9 113.9 115.3 115.6 115.6 119.8 123.8 113.5 114.7 113.5 115.6 118.2
RON
MON
(R+M)/2
A-38
ASTM Class D D D D D D D D D D D D
State NC NC NC NC NC NC NC NC NC NC NC NC
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 861987 861988 861989 861990 861991 861992 861981 861982 861983 861984 861985 861986
Date 3/13/09 3/20/09 3/20/09 3/20/09 3/20/09 3/20/09 3/13/09 3/20/09 3/20/09 3/20/09 3/20/09 3/20/09
A-39
ASTM Class D D D D D D D D D D D D
State NC NC NC NC NC NC NC NC NC NC NC NC
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 861987 861988 861989 861990 861991 861992 861981 861982 861983 861984 861985 861986
Date 3/13/09 3/20/09 3/20/09 3/20/09 3/20/09 3/20/09 3/13/09 3/20/09 3/20/09 3/20/09 3/20/09 3/20/09
TV/L=20 (oF) 130.1 115.1 116.7 116.3 118.6 122.1 126.5 114.0 115.4 114.5 117.1 120.0
RON
MON
(R+M)/2
A-40
ASTM Class D D D D D D D D D D D D
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856521 856522 856523 856524 856525 856526 856515 856516 856517 856518 856519 856520
Date 2/12/09 3/4/09 3/4/09 3/4/09 3/4/09 3/4/09 2/12/09 3/4/09 3/4/09 3/4/09 3/4/09 3/4/09
A-41
ASTM Class D D D D D D D D D D D D
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856521 856522 856523 856524 856525 856526 856515 856516 856517 856518 856519 856520
Date 2/12/09 3/4/09 3/4/09 3/4/09 3/4/09 3/4/09 2/12/09 3/4/09 3/4/09 3/4/09 3/4/09 3/4/09
TV/L=20 (oF) 125.8 116.6 117.0 117.7 119.3 122.9 116.2 109.4 109.8 110.3 111.7 115.0
RON
MON
(R+M)/2
A-42
ASTM Class D D D D D D D D D D D D
State AL AL AL AL AL AL AL AL AL AL AL AL
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856545 856546 856547 856548 856549 856550 856539 856540 856541 856542 856543 856544
Date 2/12/09 3/4/09 3/4/09 3/4/09 3/4/09 3/4/09 2/12/09 3/4/09 3/4/09 3/4/09 3/4/09 3/4/09
A-43
ASTM Class D D D D D D D D D D D D
State AL AL AL AL AL AL AL AL AL AL AL AL
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856545 856546 856547 856548 856549 856550 856539 856540 856541 856542 856543 856544
Date 2/12/09 3/4/09 3/4/09 3/4/09 3/4/09 3/4/09 2/12/09 3/4/09 3/4/09 3/4/09 3/4/09 3/4/09
TV/L=20 (oF) 128.4 118.5 118.5 119.4 120.3 123.2 123.3 114.6 115.3 115.6 116.4 119.0
RON
MON
(R+M)/2
A-44
ASTM Class E E E E E E E E E E E E
State SD SD SD SD SD SD SD SD SD SD SD SD
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856589 856590 856591 856592 856593 856594 856583 856584 856585 856586 856587 856588
Date 2/13/09 3/12/09 3/12/09 3/12/09 3/12/09 3/12/09 2/13/09 3/13/09 3/13/09 3/13/09 3/13/09 3/13/09
A-45
ASTM Class E E E E E E E E E E E E
State SD SD SD SD SD SD SD SD SD SD SD SD
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856589 856590 856591 856592 856593 856594 856583 856584 856585 856586 856587 856588
Date 2/13/09 3/12/09 3/12/09 3/12/09 3/12/09 3/12/09 2/13/09 3/13/09 3/13/09 3/13/09 3/13/09 3/13/09
TV/L=20 (oF) 134.3 121.4 121.6 122.1 122.9 129.5 122.6 113.8 115.0 114.4 116.4 119.2
RON
MON
(R+M)/2
A-46
ASTM Class E E E E E E E E E E E E
State AK AK AK AK AK AK AK AK AK AK AK AK
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856601 856602 856603 856604 856605 856606 856595 856596 856597 856598 856599 856600
Date 2/13/09 3/13/09 3/13/09 3/13/09 3/13/09 3/13/09 2/13/09 3/12/09 3/12/09 3/12/09 3/12/09 3/12/09
A-47
ASTM Class E E E E E E E E E E E E
State AK AK AK AK AK AK AK AK AK AK AK AK
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856601 856602 856603 856604 856605 856606 856595 856596 856597 856598 856599 856600
Date 2/13/09 3/13/09 3/13/09 3/13/09 3/13/09 3/13/09 2/13/09 3/12/09 3/12/09 3/12/09 3/12/09 3/12/09
TV/L=20 (oF) 112.9 107.6 108.0 107.8 109.3 112.2 109.7 104.4 104.7 104.9 106.8 107.5
A-48
ASTM Class E E E E E E E E E E E E
State UT UT UT UT UT UT UT UT UT UT UT UT
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856613 856614 856615 856616 856617 856618 856607 856608 856609 856610 856611 856612
Date 2/13/09 3/4/09 3/4/09 3/4/09 3/4/09 3/4/09 2/13/09 3/12/09 3/12/09 3/12/09 3/12/09 3/12/09
A-49
ASTM Class E E E E E E E E E E E E
State UT UT UT UT UT UT UT UT UT UT UT UT
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856613 856614 856615 856616 856617 856618 856607 856608 856609 856610 856611 856612
Date 2/13/09 3/4/09 3/4/09 3/4/09 3/4/09 3/4/09 2/13/09 3/12/09 3/12/09 3/12/09 3/12/09 3/12/09
TV/L=20 (oF) 126.1 117.3 118.0 118.2 119.8 123.8 120.9 115.0 114.2 115.4 116.7 118.2
A-50
ASTM Class E E E E E E E E E E E E
State WV WV WV WV WV WV WV WV WV WV WV WV
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856625 856626 856627 856628 856629 856630 856619 856620 856621 856622 856623 856624
Date 2/13/09 3/12/09 3/12/09 3/12/09 3/12/09 3/12/09 2/13/09 3/12/09 3/12/09 3/12/09 3/12/09 3/12/09
A-51
ASTM Class E E E E E E E E E E E E
State WV WV WV WV WV WV WV WV WV WV WV WV
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856625 856626 856627 856628 856629 856630 856619 856620 856621 856622 856623 856624
Date 2/13/09 3/12/09 3/12/09 3/12/09 3/12/09 3/12/09 2/13/09 3/12/09 3/12/09 3/12/09 3/12/09 3/12/09
TV/L=20 (oF) 121.1 112.8 112.5 115.2 116.5 119.1 120.2 112.9 112.0 113.5 114.0 119.7
RON
MON
(R+M)/2
A-52
ASTM Class E E E E E E E E E E E E
State IA IA IA IA IA IA IA IA IA IA IA IA
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856637 856638 856639 856640 856641 856642 856631 856632 856633 856634 856635 856636
Date 2/13/09 3/13/09 3/13/09 3/13/09 3/13/09 3/13/09 2/13/09 3/13/09 3/13/09 3/13/09 3/13/09 3/13/09
A-53
ASTM Class E E E E E E E E E E E E
State IA IA IA IA IA IA IA IA IA IA IA IA
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856637 856638 856639 856640 856641 856642 856631 856632 856633 856634 856635 856636
Date 2/13/09 3/13/09 3/13/09 3/13/09 3/13/09 3/13/09 2/13/09 3/13/09 3/13/09 3/13/09 3/13/09 3/13/09
TV/L=20 (oF) 119.5 110.6 112.2 112.0 114.1 115.7 114.7 108.9 110.0 110.6 110.7 114.2
RON
MON
(R+M)/2
A-54
ASTM Class E E E E E E E E E E E E
State WA WA WA WA WA WA WA WA WA WA WA WA
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856649 856650 856651 856652 856653 856654 856643 856644 856645 856646 856647 856648
Date 2/13/09 3/12/09 3/12/09 3/12/09 3/12/09 3/12/09 2/13/09 3/13/09 3/13/09 3/13/09 3/13/09 3/13/09
A-55
ASTM Class E E E E E E E E E E E E
State WA WA WA WA WA WA WA WA WA WA WA WA
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 856649 856650 856651 856652 856653 856654 856643 856644 856645 856646 856647 856648
Date 2/13/09 3/12/09 3/12/09 3/12/09 3/12/09 3/12/09 2/13/09 3/13/09 3/13/09 3/13/09 3/13/09 3/13/09
TV/L=20 (oF) 112.6 107.8 107.9 109.0 110.8 113.2 110.8 106.0 106.4 107.1 108.3 110.7
RON
MON
(R+M)/2
A-56
Refiner BOB Winter Winter Winter Winter Winter Winter Winter Winter Winter Winter Winter Winter
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 859062 864721 864722 864723 864724 864725 859063 864726 864727 864728 864729 864730
Date 2/19/09 4/2/09 4/2/09 4/2/09 4/2/09 4/2/09 2/19/09 4/2/09 4/2/09 4/2/09 4/2/09 4/2/09
A-57
Refiner BOB Winter Winter Winter Winter Winter Winter Winter Winter Winter Winter Winter Winter
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 859062 864721 864722 864723 864724 864725 859063 864726 864727 864728 864729 864730
Date 2/19/09 4/2/09 4/2/09 4/2/09 4/2/09 4/2/09 2/19/09 4/2/09 4/2/09 4/2/09 4/2/09 4/2/09
TV/L=20 (oF) 120.3 114.1 113.5 114.9 115.4 119.2 134.3 121.8 121.9 124.0 125.2 128.0
A-58
Refiner BOB Winter Winter Winter Winter Winter Winter SBOB Summer Summer Summer Summer Summer
State IL IL IL IL IL IL IL IL IL IL IL IL
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839043 839399 839400 839401 839402 839403 831491 831999 832000 832001 832002 832003
Date 9/23/08 9/30/08 9/30/08 9/30/08 9/30/08 9/30/08 8/6/08 10/7/08 10/7/08 10/7/08 10/7/08 10/7/08
A-59
Refiner BOB Winter Winter Winter Winter Winter Winter SBOB Summer Summer Summer Summer Summer
State IL IL IL IL IL IL IL IL IL IL IL IL
Grade PU PU PU PU PU PU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 839043 839399 839400 839401 839402 839403 831491 831999 832000 832001 832002 832003
Date 9/23/08 9/30/08 9/30/08 9/30/08 9/30/08 9/30/08 8/6/08 10/7/08 10/7/08 10/7/08 10/7/08 10/7/08
TV/L=20 (oF) 126.9 112.6 113.4 114.2 115.4 116.1 159.0 137.8 137.7 137.5 138.3 139.2
RON 93.9 98.6 99.4 100.4 101.7 102.2 84.0 90.9 91.9 93.0 95.9 99.9
MON 88.1 90.2 90.3 90.8 91.0 91.3 80.3 83.8 84.4 86.9 87.7 89.0
(R+M)/2 91.0 94.4 94.9 95.6 96.4 96.8 82.2 87.4 88.2 90.0 91.8 94.5
A-60
Refiner BOB Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer
State NJ NJ NJ NJ NJ NJ NJ NJ NJ NJ NJ NJ
Grade RU RU RU RU RU RU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 836082 836230 836231 836232 836233 836234 836083 836225 836226 836227 836228 836229
Date 9/10/08 10/7/08 10/7/08 10/7/08 10/7/08 10/7/08 9/10/08 10/7/08 10/7/08 10/7/08 10/7/08 10/7/08
A-61
Refiner BOB Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer
State NJ NJ NJ NJ NJ NJ NJ NJ NJ NJ NJ NJ
Grade RU RU RU RU RU RU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 836082 836230 836231 836232 836233 836234 836083 836225 836226 836227 836228 836229
Date 9/10/08 10/7/08 10/7/08 10/7/08 10/7/08 10/7/08 9/10/08 10/7/08 10/7/08 10/7/08 10/7/08 10/7/08
TV/L=20 (oF) 169.3 141.7 141.4 141.6 141.5 142.3 141.9 141.7 141.6 141.7 142.4
RON
MON
(R+M)/2
A-62
Refiner BOB Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer
State CA CA CA CA CA CA CA CA CA CA CA CA
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 836035 839379 839380 839381 839382 839383 836036 839384 839385 839386 839387 839388
Date 9/3/08 10/7/08 10/7/08 10/7/08 10/7/08 10/7/08 9/3/08 10/7/08 10/7/08 10/7/08 10/7/08 10/7/08
A-63
Refiner BOB Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer
State CA CA CA CA CA CA CA CA CA CA CA CA
Grade RU RU RU RU RU RU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 836035 839379 839380 839381 839382 839383 836036 839384 839385 839386 839387 839388
Date 9/3/08 10/7/08 10/7/08 10/7/08 10/7/08 10/7/08 9/3/08 10/7/08 10/7/08 10/7/08 10/7/08 10/7/08
TV/L=20 (oF) 166.3 140.6 139.8 139.8 140.0 141.4 165.0 139.7 139.9 139.6 139.8 141.0
A-64
Refiner BOB Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer
State TX TX TX TX TX TX IL IL IL IL IL IL
Grade RU RU RU RU RU RU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 836037 839389 839390 839391 839392 839393 838796 839394 839395 839396 839397 839398
Date 9/4/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08 9/23/08 9/30/08 9/30/08 9/30/08 9/30/08 9/30/08
A-65
Refiner BOB Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer
State TX TX TX TX TX TX IL IL IL IL IL IL
Grade RU RU RU RU RU RU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 836037 839389 839390 839391 839392 839393 838796 839394 839395 839396 839397 839398
Date 9/4/08 10/2/08 10/2/08 10/2/08 10/2/08 10/2/08 9/23/08 9/30/08 9/30/08 9/30/08 9/30/08 9/30/08
TV/L=20 (oF) 157.8 134.1 134.0 134.0 134.4 135.9 165.2 136.9 136.7 136.9 137.0 138.2
A-66
Refiner BOB Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade PU PU PU PU PU PU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 844187 845575 845576 845577 845578 845579 844188 845580 845581 845582 845583 845584
Date 11/10/08 11/21/08 11/21/08 11/21/08 11/21/08 11/21/08 11/10/08 11/21/08 11/21/08 11/21/08 11/21/08 11/21/08
A-67
Refiner BOB Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer Summer
State TX TX TX TX TX TX TX TX TX TX TX TX
Grade PU PU PU PU PU PU PU PU PU PU PU PU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 844187 845575 845576 845577 845578 845579 844188 845580 845581 845582 845583 845584
Date 11/10/08 11/21/08 11/21/08 11/21/08 11/21/08 11/21/08 11/10/08 11/21/08 11/21/08 11/21/08 11/21/08 11/21/08
TV/L=20 (oF) 145.8 145.2 144.9 144.7 145.3 172.9 145.7 144.9 144.8 144.5 145.3
RON 98.1 99.9 100.6 101.0 101.7 101.6 97.9 99.1 99.6 100.0 100.8 101.6
MON 86.4 87.6 88.3 88.4 88.9 89.5 86.0 86.9 88.0 88.3 88.3 88.1
(R+M)/2 92.3 93.8 94.5 94.7 95.3 95.6 92.0 93.0 93.8 94.2 94.6 94.8
A-68
Refiner BOB Summer Summer Summer Summer Summer Summer
State TX TX TX TX TX TX
Grade RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 844189 845585 845586 845587 845588 845589
Date 11/10/08 11/21/08 11/21/08 11/21/08 11/21/08 11/21/08
A-69
Refiner BOB Summer Summer Summer Summer Summer Summer
State TX TX TX TX TX TX
Grade RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 844189 845585 845586 845587 845588 845589
Date 11/10/08 11/21/08 11/21/08 11/21/08 11/21/08 11/21/08
A-70
CRC Fuel 11 11 11 11 11 11 12 12 12 12 12 12
State MI MI MI MI MI MI MI MI MI MI MI MI
Grade RU RU RU RU RU RU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 893880 893881 893882 893883 893884 893885 893868 893869 893870 893871 893872 893873
Date 10/5/09 10/15/09 10/15/09 10/15/09 10/15/09 10/15/09 10/5/09 10/15/09 10/15/09 10/15/09 10/15/09 10/15/09
A-71
CRC Fuel 11 11 11 11 11 11 12 12 12 12 12 12
State MI MI MI MI MI MI MI MI MI MI MI MI
Grade RU RU RU RU RU RU RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0% 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 893880 893881 893882 893883 893884 893885 893868 893869 893870 893871 893872 893873
Date 10/5/09 10/15/09 10/15/09 10/15/09 10/15/09 10/15/09 10/5/09 10/15/09 10/15/09 10/15/09 10/15/09 10/15/09
TV/L=20 (oF) 105.70 101.60 102.50 101.60 104.00 104.70 104.40 99.90 101.10 100.30 103.30 105.90
RON
MON
(R+M)/2
A-72
CRC Fuel 8 8 8 8 8 8
State MI MI MI MI MI MI
Grade RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 893874 893875 893876 893877 893878 893879
Date 10/5/09 10/15/09 10/15/09 10/15/09 10/15/09 10/15/09
A-73
CRC Fuel 8 8 8 8 8 8
State MI MI MI MI MI MI
Grade RU RU RU RU RU RU
Nominal Ethanol
Concentration (vol%) 0.0% 10.0% 12.5% 15.0% 20.0% 30.0%
Sample Id 893874 893875 893876 893877 893878 893879
Date 10/5/09 10/15/09 10/15/09 10/15/09 10/15/09 10/15/09
RON
MON
(R+M)/2
A-74