2

Name ( 1 A student sets up the apparatus as shown. predict the gas that will be collected from
) Class
the set-up and identify a suitable dehydrating agent that can be used_

Clementi Town Secondary School {-l

Preliminary Examination 201 0
Secondary 4 Express Iffit 9as

n
q4t_'l €lcim hydroxide and
ammonium chloride

io
CHEMISTRY 5072t01

t
Paper 1 Multiple Cfroice Duratbn: t hol.. dryrng
heat agent
Addihonal Matenalg: Objective Test Answer Sheet (OIAS)

a€reNn rtuN*@^ffYSl1dar.FNi
wNn
(:r+Nn tu setumy smcrrmm
r@N selromYse(:ffir
a
tuNg@ys@ffi i@*(.mRywGGNnT@il=@ay
rqwv*ooo+wiiqw*oiorii*l{@u*mrms€l:Mv
rmsfumvsl:leiirGrriiotir&-aiioi,ii!'iromnrm*cMy

c
(ffin rtu @Mr
qE'*r r.* *@^Rr scte
wct'*
.t F*Nr, rq s.1my s(rc eecmr iorr *oo*ii
msiraomyGiuaffiili6ili&o6ii'ii !m (..6n m wy
!*.*rM*.*y

name of qas

u
dehydratinq aqent
INSTRUCTIONS TO CANDIDATES A ammonia gas calcium oxide
B ammonia gas silica gel

d
Do not open this booklet until you are told to do so. c hydrogen chloride calcium oxide
D hydroqen chloride silica qel
write your name, class and index number on the answer sheet.in the spaces provided.

E
2 A chromatography experiment was carried out using a drop of solution of an ailoy
There are forty questions in this paper. Answer alr questions. For each question, German silver. The result is shown below.
there are
four possible answers, A, B, C and D.
choose the one you consider correct and record your choice in soft pencir on the separate

l
Answer Sheet.
@ @

a
INFORMATION FOR CANDIDATES
@ @

y
Each correct answer wirr score one mark. A mark will not be deducted
for a wrong answer 6
Any rough working should be done in this booklet.
ee

n
You may use a calculator.
- -* -----*---- -O-- --- x- -- - -x- --- - -x-- --
os[?n *o* silvs ?ilnc nickd aruoinium

a
A copy of the Data Sheet is printed on page 1 5.
What are the metals present in German silver?
A copy of the Periodic Table is printed on page 16.

D
A aluminium, copper and nickel
B aluminium, nickel and silver
C copper, nickel and zinc
D copper, silver and zinc

This paper consists of 16,pages.

ffurn r,r" I

CTS S/Prelim/5072 lO 1 I 2O1 O

 3 4

3 Liquid Z melts at 10 "C and boils at 80 'C. lt does not mix with water. Which apparatus 6 Aqueous sodium chloride (NaCl) and aqueous silver nitrate (AgNO:) can react to
can be used to obtain pure liquid Z from a mixture of liquid Z and waler? produce a white solid of silver chloride. A student carried out an experiment in which he
added sodium chloride and sitver nitrate powder at two ends of a dish containing
A B C D distilled water as shown in the diagram below-

n
\i z/ X'*
sodiurir
:w4

io
L]L

t
l
$ ABCD

a
At which point in the dish will the white precipitate of silver chloriile form?

c
4 Tests on a sample of water polluted by sewage and fertilisers gave the following An element, X, has two isotopes, namely X-16 and X-1 8. lls relative atomic mass is
results. 16.4. What is the proportion of each isotope?

u
reagent added result
A 50%X- 16 and 50 % x-18
B 60%x- 16

d
and 4O o/o X-18
sodium hydroiide and colourless, pungent gas
C 7O o/o X- 16 and 30 % x-18
aluminium foil evolved
D 80%X- 16 and 2O o/o XjlB

E
o The diagrams below show the structures of two atoms of the elements P and Q
aqueous potassium iodide yellow precipitate formed
respectively.
PQ

l
Which compound is present in the water?

A ammonium carbonate

a
B ammonium chloride
C lead nitrate
D

y
lead sulfate

5 ln the cooling curye shown below, at which stage can both solid and liquid exist

n
together?
temperature / oC Calculate the mass of I mole of the compound formed by P and Q.

a
A 11g
B 149
A C 239

D
D 309

B 9 When green copper(ll) carbonate is heated, a black solid X and a coloudess gas Y are
formed. Which one of the following describes X and Y?
C
x
D A element element
B compound element
time /'min
c compound mixture
D compound compound

CTSS/Prelim/5072,O1/20 1O CTSS/Prelim/5072/01/201 0
 5 6

10 which of the following statements explains rivhy magnesium chloride has a very hiqtr 15 Which compound can be formed by reacting a metal with a dilute acid?
melting point?
A calcium carbonate
A MagneSium and chlorine are joined together by very strong covalent bonds. B copper(ll) sulfate
B Magnesiurn and chlorine form ions ioined togeitrer by a cry,stal lattice. C iron(ll)chtoride
C The reacti:n between magnesium and chlorine is highly eiothermrc. D magnesrum hydroxide

n
D The reaclion tretween magnesitrm anl chlorine is fast and vigorous_
16 When calcrum is dropped into dirde sutfuric acad. bubbles of gas evolve at the

io
11 Which diagram represents the structure of an alloy? beginning but eventually stop. What causes the reaction to stop?

ABCD A A byer of rnsorubre c€rcium surfate forms around the metal and prevents any

t
G further reaction.
B A layer of carcium oxide on the surface of the calcium stops the calcium from

a
reacting with the acid.

-8,4
K EJT C Calcium is above hydrogen in the reactivity series and does hot react with dilute
acid.

c
D The sulfuric acid is not concentrated enough for the reaction to proceed-

u
17 A titration method can be used to prepare aqueous potassium chloride from potassium
carbonate and dilute hydrochloric acid.
12 Which of the following contains the same number of atoms as g g of water?

d
Which of the following conclusions from this information is correct?
A 2 g of hydrogen gas
B 8 g of methane gas A Potassium carbonate is insoluble in water.
C

E
14 g of nitrogen gas B Potassium carbonate neutralises hydrochloric acid.
D 22 g of carbon dioxide gas c Potassium carbonate reacts more vigorously than sodium carbonate with dilute
hydrochloric acid.
13 Methane burns completely in oxygen according to the equation: D Potassium chloride is a neutral salt.

l
CHa (g) + 2 O, (g) COz (g) + 2 HzO (9) 18
- During the Haber process, how is the ammonia produced separated from the reaction

a
mixture?
ln an experiment, 40 cm3 of methane-from an impure source of petroleum gas was
reacted with excess oxygen. 38.4 cm3 of carbon dioxide was formed. whaiwas the A by cooling the mixture

y
percentage purity of methane? B by dissolving the other two gases
C by filtering out the other two gases through cotton wool
A o/o
D

n
48 by passing the gases through fused calcium oxide
B 52yo
C 91To 19 Which of thefollowing is not a threat posed by the release of sulfur dioxide into the air?

a
D 96%
A formation of acid rain
14 The pH scale below shows the positions of four aqueous solutions p, e, R and S, of B global warming
C

D
equal concentrations. respiratory problems
PQRS D reduced visibility

17.t4
Which of the following chemicals are most likely to be p, e, R and S?

ethanoic acid sulfuric acid ammonia so

A P a R S
B a P R
c a v S
D S o R P

CTSS/Prelir/5072/01 /2010 CTSS/Prelim/5072/01 /20 1 0

 7 B

20 When heated, nitrogen and hydrogen react according to the equation: 22 caesium is a Group I element in the Periodic Table and its relative atomic mass is
greater than that of potassium- Which of the following statements concerning caesium
' + 3Hz <- is incorrect?
Nz 2NH:
The reaction is not complete. The graph below sfuws the number of moles of ammonia A Caesium is a weaker redtrcing agent than potassium
B

n
pioduced from 'l mole of nitrogen at different temperatures and pressures. Caesium reacts vlotently wtth waler
C Caesium is a soft metal.
rcles o{ ammmia produc€d
D Caesium reacts with oxygen to form an oxide, Cs2O_

io
rc ctalys{ 23 !Vhi{* of the fouowing does not stlow a cotrect use lor the given rrcble gas?
zfi

t
2

noble qas USE

no catalyst A neon advertising lights

a
B argon welding
400.c
1
c krypton electronic valves

c
D helium anaesthetic

24 which of the following correctly relates a metal to its most suitable method of

u
pressure / atm
extraction?
500 1000
Which of the following statement(s) can be deduced from this information?

d
metal extraction
A aluminium reduction with carbon
I At 500 atm pressure, the number of moles of ammonia produced is greater B gold reduction with carbon
at 200 "C than at 400 "C . c magnesium electrolysis

E
ll An increase in pressure increases the number of moles of ammonia D zinc
produced both at 200 "C and at400 oC .
lll At 500 atm pressure and 3O0 "C, the number of moles of ammonia 25 The table gives information on four metals and some of their compounds,

l
produced is likely to be greater than one.
metal G H I J
A only action of dilute sulfuric hydrogen hydrogen

a
hydrogen
B and ll ' acid on metal no reaction
evolved evolved evolved
C and ilt effect of hydrogen on

y
D and I I reduced reduced no reaction no reaction
heated oxide
action of metal on a
21 The diagram below represents a section of a catalytic converter on the exhaust system solution of the sulfate of J no reaction no reaction J formed no reaction

n
. of a car. Harmful gases are converted into carbon dioxide, nitrogen and water vapour.
What is the order of reactivity of these metals?

a
CO Coz
hydrocarbon -------} most reactive -----------> least reactive
-------| HzO
A
NO, Nz H G I J
B

D
H J G I
c I J G H
platinum aid rhodium D l H G J
Which processes take place in this catalytic converter? 26 lron filings are wrapped in a damp cloth and left to rust in the apparatus as shown.
Which letter indicates the water level when rusting has finished?
I carbon monoxide and hydrocarbons react together
ll carbon monoxide and nitrogen oxides react together rusty iron fillings in graduated rusty iron fillings in gGduated
lll platinum and rhodium catalyse redox reactions damp doth tube damp cloth tube

A I only 0 A
B landll B
C I, ll and lll
D lland lll water level at c
start D

CTSS/Prelim/So72lO1/2O,1 O
 I 10

27 The diagram shows the energy.profile for a chemical reaction. 30 The diagram below represents a hydrogen-oxygen fuel cell.
ener9y

prcducts
hydrogtr + t e or/gen

n
E" jH

io
,eadants

t
prmres of rection

€ler tI

a
znC
What is the correct description for the reaction? heat
anode

c
sign of AH ovgrall energy chanqe electrolyte
A negative exothermic
B negative

u
endothermic Which of the following diagrams correctly shows the electron flow in the fuel cefl?
c positive endothermic
D positive exothermic A B

d
e
28 Graph I is obtained by observing the decomposition of 100 cm3 of 1 .00 mol/dm3
aqueous hydrogen peroxide, catalysed by manganese(lV) oxide.
-|

E
volure of oxygeo

l
-------[

a l .l

y
C D
Which alteration to the conditions would produced graph ll?

n
e

A adding some 0.100 mol/dm3 aqueous hydrogen peroxide e-< <- e- a>

a
B lowerin! the temperature
c using a different catalyst
D using less manganese(lV) oxide

D
29 which one of the following reac{ions would not be affected by a change in pressurer
'1j..

A C(s) + HrO(g) CO(g) + H,qg1

B
-
3 Fe (s) + + HzO (9) (s) + 4 (g)
* - 2 SO3 (g)
Fese+ Hz
c. 2 SO, (g) + Oz (g)
D coz(s) + c(s) * 2co(s)

CTSS/Prelim/SO72 lO 1 l20fi CTSS/Prelim/507210 1 1201 0

 11 12

31 ln which of the following substances does carbon have the smallest oxidation numher'? 35 A student is given 5 pieces of unknown metal strips (P, O, R, S and T). He runs a test
on these metals using the apparatus shown below and recorded the results in a table.
A CO
B CO:
C CH.

n
o CaCOs

32 Chlorine reacts wlth cotd dilute aqu€ous sodium hydroxide solution accordang to the

o
following equation.

ti
Cl2(g);2NaOH(aq) . NaCIO(aq) * NaCt (aq) + HrO(l) metal unds kad
test
Which of the following statements is conect?

a
A Chlorine is_oxidised and sodium hydroxide is reduced

c
B Chlorine is reduced and sodium hydroxide is oxidised
C Chlorine is both oxidised and reduced.
D Sodium hydroxide is both oxidised and reduced. metal under test voltaqe

u
P 1.11
33 Four electrolytes were electrolysed using carbon electrodes. Which set of data is o 0.65

d
correct? R -0.50
electrolvte product at anode oroduct at cathode S 0
A CuSOa (aq) oxygen copper T 4.77

E
B NaH (l) sodium hydrogen
C NaCl(aq) chlorine sodium Anange the metals according to their reactivity in decreasing order.
D Pbct, (t) lead chlorine
A P>CI>S>R>T

l
34 ln electroplating a titanium bracelet with silver, which of the following combinations B Q>P>T>S>R
should be used? C R>S>Q>T>P
D T>S>R>Q>P

a
anode cathode electrolyte
A bracelet silver silver nitrate 36 ln the process shown below, which of the following combinations is correct?

y
B silver bracelet silver nitrate
catalyst
c bracelet siIver copper(ll) nitrate CroHzz C6H,o + 2 1

n
D silver bracelet coooer(ll) nitrate heat

a
process identity of X
A fractional distillation an alkane
B fractional distillation an alkene
c

D
cracking an alkane
D crackincr an alkene

CTSS/Prelim/5072,/01 /2010 CTSS/Prelim/5072:/01 /201 0

 13 14

37 The diagr:am shows the fractional distillation of petroleum. 40 A condensation polymer is to be made from the hivo monomers below

i-- -
o o
)
il H
fl
i__. fretion X H- O-C-&-C_O-H /H
_ - _ _-1 and N-CHz-{l-cH2-N

n
L-_
-- "{-- H H

heated
--^__=-....* fractbny
Which diagram shou/s the structure of the polymer?

io
Petroleum "-L__i- i
I

o o o o

t
I lt li !l
A -c--@ -C-N-
Which of the following properties about fractions X and y are correct?

a
I i
H H H
X burns moreGasily than y X has a higher boiling point than Y
oooo

c
A
B
yes
yes
yes
ij llc-N-cH2-:fl-.cHr- u
c
og B -
- c - %A* tt
- N
- C
ri
-.QA.-C -* N.,

u
no no
I
D no yes HH H

d
38 A food chemist wants to create the odour of pineapples in a product. An ester with iiri:, o o oo
odour has the formula C3H7COOC2Hs.
c --
il
c
ll
--tl-c - N -a12--%-CH"-N - ilil
c"-fl-c N-
tt

E
Which pair of reactants would produce this ester?
HH
I

H
A CH3COOH and C3H7OH
B C2HsCOOH and C2HsOH OOHHO o
il ll t t --@-c--

l
C C2H5COOH and C3H7OH il fl
D C3HTCOOH and C2H5OH
D
-c--@-c-c-f,-c-c
II

a
NH, NHz
39 Poly(ethene) can be manufactured by the process below.

y
decane > ethene ------+ poly(ethene)

Which diagram shows the change in molecular size during this process?

n
A molecular size
B molecular size

c
start

mol*ular size
finish

D
D moledlar size
a
start finish

start f nish start finish

CTSS/Prelim/sol2lo 1 /20 1 0 CTSS/Prelim/5072/0 1 /20 1 0

 o
o-
o ='
o e
o
Ie SI
c
o
N. !
(!
:. :
=
e'
g
3
3
o = = o
o o o =
x, 6 6 a o o o
o- I, x. x x a a
o o x, a! x, o
.,1
6 o o o o
o
o
o 3
a og
!
0 o-t
3>
1a

n
o
o
qt
! OI
3m
N
6-
N
o =T
o'

o
o
()
€ {
J
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a
t {
z. o 3', 3' o
5 6 x

ati
o f c(b o o
E d
o
i
o

uc
Ed

DATA SHEET
The PeriodicTable ol the Elements
al

I il lil v ' vr-l vil 0

j

H He
2
ny

7 9 it r2 i; r9 t0
Li Be B c N o F Ne
3 I ,tq- 1oo'*n
24 27 2g 366
NA M9 AI Si P S CI Ar i
n,{{'- i hiln{
I 1t 12 13 1l rt llo 18
a
a g 1S 4a 5t 62 56 59 6S & s 7a 13 &
Da

5S

iq K Ca Sc Ti Cr Mn Fe Co NI Cu Zn Ga Ge Ar So Br Kr
t9 2l 25 29 3t p
3 23 27 2A 30

o
o 85 e8 89 91 s 10r tG 16 l@ I r2 116 I 1i9 t?2 I r1/ l3r
a
N Rb Sr Zt Nb Mo Tc Ru Rh Pd Ag cd In Sn Sb Te I Xe
o
37 3g a0 12 13 {5 4 47 49 49 I
5r I
N
o IT 137 139 t7B r8r r& 1S !s 195 r97 m1 ?u 207

Cs Ba La Hf ta W Re Os It Pt Au Hg TI Pb BI Po At Rn

65 fi 57 12 73 76 t'7 7E n & 81 s2 33 !i !6 !6

224

Fr Ra Ac
87 s & t
l4t t& 152 157 !6?
'r55 175
"58-71 Lanthanoid series Tb Er Yb Lu
Ce Pr Nd Pm Sm Eu Gd Dy Ho Tm
190-1 03 Actinoid series
60 8t e g 65' 85 67 h ?o

238

Key Y x - alomlc rymbol Th Pa U Np Pu Am Cm BK Es Fm Md No Lr

b = p6lon (alomic) oumber I 9r s3 95 66 t7 9E 9-o t@ r0! tq r03

The votume of one mole of any gas js 24 dm3 al room temperature and pressule (r.t.p.).
 2

Nanre ( ) Class Section A

Answer alt the questions in this section in the spaces provided.
Clemdnti'Town Secondary School t::)
Preliminary Examination 201 0 I-EFI The total marks for this section is SO.
IEEffiI
Secondary 4 Express
\4
n
A1 Use the foflowing rist of substances to answer the question. you
may use each
substance once. more than onc€ or not at all.
t4I

io
CHEMISTRY 5072tA2 aluminium chbride ammonium chloride coppe(ll) chloride

t
Pape.r 2 t
Duration: hour 45 rlir, hydrogen chloride silver chloride sodium chloride
Additional Materials: Answer paper Which substance

wNl rwl sE@Noey wdEreNn
eE*Nl TOWI S€@Oey s@ G*Nn
cEENrr rwN SlrcEEI
qE6tl r@N s€ffiDAy
a
r&N s@NoaRy sclto amffir rom *omm s@ qicrn rMsEcdomy
rNN *@OARY $H@ qF. t rM *COOmv slm (::ffm rM $cNNy (a) is a diatomic covalent molecule:
rwNsE@oecvsmaw roareooqvweEffit(MsEcNo€y

c
s@{o& w
(kNrl r@N s€@ilomY G&n rMN s€@NoaRy q@ Gffii rm gc(Mii sffi uremr rm src@oMy
w cGWr rNN *@NoaRy scH@ a*Nn rM *c6rimv sm cmrn ro@ sE@o*y
(b) dissolves in water to give a red colour with methyl
orange;

u
INSTRUCTIONS TO CANDIDATES
(c) decomposes to form an alkaline and an acidic gas;
Do not open this booklet until you are told to do so.

d
(d) forms a deep blue solution with excess aqueous
write your name, class and index number in the spaces at the top of this page and on any ammonia?
separate answer paper used.

E
This question paper consists of 2 sections: Section A and Section B A2 tiotr.t bulb, the tungsten wire may get so hot that
fn.a it merts and breaks. The graph
below shows the heating curve for tunlgsten.

l
Section A (50 marks)
Answer all questions in the spaces provided.

a
Section B (30 marks)
Answer all three questions.

y
Question 811 is in the form of EITHER/OR and only oNE of the alternatives should be
temperature / oC
attempted.
Write your answers on the lined papers provided.

n
At the end of the examination, fasten all answer papers securely together.
Ftand in answer papers and question paper separaiely.

a
INFORMATION FOR CANDIOATES

The number of marks is given in brackets [ ] at the end of each question or part of questii:n

D
A copy of the Data Sheet is printed on page 13.
A copy of the Periodic Table is printed on page 14. time
FOR S USE (a) From the graph, predict the temperature at whicfi the tungsten wire breaks. ti]
l

Section A /50 I

Section B
I
(b) Describe the arrangement and movement of the partacres
in tungsten at 5 000 .c.
12)
TOTAL /8i) t

This question paper consists of 14 printed pages

{Turn ori::r

CTSS/Prelim/5072/02/20 1 0
 3 4

(c) Using the graph. explain whether the wire is made up of purely tungsten or an A4 some research students used a detector to compare the air in the
city centre with air in
alloy containing mainty tungsten t2l
the school playground.

aity centre school playground

n
oc 0
0

io
A3 (a) The diagram below shows ttre arrangement of electrons in the outer shel of an
. alom of element E.

t
It I

a
J

c
The detector measures how much carbon monoxide there is-in
a sampre of air. Each

u
(i) State the group in the Periodic Table to which E belongs. t1l
student took one measurement in each prace. The resurts from
the four-stuoents are
shown in the table below.

d
amount of monoxide in a
(ii) E forms an ion. State the formula of the ion formed by E. t1I student city centre
A 67

E
6'1
B 71 63
C 33 65
(iii) E forms a compound with carbon. Draw a 'dot and cross'diagram to show D 70 62

l
the bonding you would expect to see in this compound. You need to show
electrons.
only the outer shell l2l (a) Which student did not use the meter properly at the city centre?
tll

a
(b)

y
Suggest one source of carbon monoxide in the air
t1l

n
:
(c) what is the general difference in the carbon monoxide lever at the city
centre and

a
at the school playground? suggest a possibre expranation for this
difflrence. l2l
(b) Silicon carbide, SiC, has a very high melting point and has a structure similar to

D
that of diamond. With respect to its strudure, explain why silicon carbide hai a
very high melting point. l?i

(d) How can the emission of carbon monoxide be limited?

t1l

(e) State another air pollutant that could be present and shows a similar difference
between the air samples from the city cenke and the school playground.
t1]

CTS S/Preli,r/5072/02/2O 1 0 CTSS/Prelimi507Z02l20 1 0

 J 6

A5 An alloy which was known to.be a mixture of two metars was divided
into two sampres. (b) Method 2 involves the erectrorysis of copper(il)surfate sorution using graphite
electrodes.
The first sample dissolved completery in an excess of dilute nitric acid to form
a blue
solufion (i) Besides the frequent replacement of the anode, suggest one other reason
why method 2 is favoured over method t.
Tlre se6oad sample was add€d to an excess of dilute sulfunc acid. A recdish tIl
brown

n
solid and a colourress soruticn were formed. Additircn of aqueous ammonia
to this
cokcurless solution gave a white precipilate which was sorubre in
an ex@ss of aqueous
ammonia

io
(a) Name the reddish brown solirJ and th€ blue sotution. (ii) One student suggests that coppe(ll) hydroxide can be used for method 2.

t
Vl
reddish brown sollj:
Comment on the feasibitily of this studenl's suggestion, tll

a
blue solution:

c
(b) Explain why aluminium cannot be present in the alloy
t11
(c) Method 3 is ittustrated by the diagram below.
?!-'':'

u
pure mpp€r
OO impure copper

d
(c) Name the white precipitate and write the equations for the reactions which
lead to
its formation. t3l

E
copper(l I ) sulfate $lution impurities

l
(i) Write the ionic equation for the reaction at the anode.
t1l

a
A6
9oqgg,
has. played a significant part in the history of mankind as it has
excellent (ii) will there be a change in the corour of the erectroryte? Exprain your answer-

y
ductility and electricar conductivity. Throughout the evolution of technology,
various l:21
methods of extracting and refining coppeiwere devised.

n
(a) Method I involves the electrolysis of molten coppe(ll) oxide using graphite
i-. -
;:t electrodes.

a
(i) State the ions present in molten copper(ll) oxide.
tll
A7

D
Petroleum is a complex mixture of hydrocarbons.

(ii) write the ionic equations for the reactions taking prace at the anode and the (a) What is meant by the term hydrocarbon?
cathode. pl t1I

- anode:
(b) The crmponents in petroreum are separated by fractionar distilration: which
cathode: property of the components allows them to be separated by this process?
t1l
(iii) Explain why the anode requires frequent replacement.
l1l

CTSS/Pr€lim/5072 I Ozt 20 1 0 CTSS/Prelim/5072/02201 0

 o

(c) One of the fractions of petroleum, kerosene, is used as a fuel in intercontinental iet A8 Three samples of calcium carbonate are placed in flasks for an investigation_
airliners. The formula of kerosene may be taken 3S C1aH36.
ln flask E is 5 g of large lumps of calcium carbonate.
(i) When kerosene burns in an excess of air, carbon dioxide and steam are ln flask F is 5 g of medium-sized lumps of calcium carbonate.
formed. ln flask G is 5 g of small lumps of calcium carbonate.

n
tsalance the following equation for tfe complete combustion of kerosene. The same volume, an excess, of dilute hydrochloric acid is added to each flask. The
t1j flasks are placed on three electronic balances. The figure below shows the change an

io
+ -. + Hzo mass of the flasks pbned against time.

(ii) --c'.H.,, --coz is approximately 10 7O0 km. A @s/g

t
The flight path from Singapore to London
-o2iet airliner bums 115.56 tonnes of kerosene for the
typical intercontinental
flight. Use your equation in (c[i) to calculate the mass of CO2 produced

a
during this flight.
[1 tonne = 1 000 kS] t2)

u c
(d) Fractional distillation of petroleum does not produce sufFicient quantities of some
fractions to match demand. Cracking is used to convert large hydrocarbon
molecules into smaller molecules that are in greater demand.

E d (a) (i) Why do the three flasks and their contents lose their mass?
time / s

t1l

l
A hydrocarbon of molecular fofirUla C12H26 is cracked. The cracking of Cr:[i:,,

a
produces a gaseous hydrocarbon in which the composition by mass of carbon ,:i
85.7% while that of hydrogen is 14.3olo.
(ii) How do the rates of reaction change with time?

y
t1l
(i) Calculate the empirical formula of the hydrocarbon produced. l2i

a n (b) (i) Skbtch on the same axes the curve you would expect if 10 g of powdered
calcium carbonate is used instead of 5 g of lumps of calcium carbonate.
Label this curveH. tll

D
(ii) Use collision theory to explain why the size of the lumps affects the rate of
thereaction. t2l
{ii) A sample of 0.28 g of this hydrocarbon has a volume of 120 cm3 at r.t.p.
Calculate the relative molecular mass and hence determine the molecular
formula of the hydroc.arbon. t2l
, ala:

CTSS/Prelim/5072/02/201 0 CTSS/Prelim/50721021201 0
 q
10

Section B (i) The mass of the paok increased by 4.80 g. Explain why the mass of the pack
increased. t1l
Answer all three questions from this section.
(ii) How long would the pack be effective as a hand warmer? tll
The last question is in the form of either/or and only one of the atternatives shoutd be
atlempted. (c) Given that the initial mass of the pack is 52.2 g,

n
, The total mark for this seclion is 30. (i) calculate the number of mores of oxygen gas reacted with iron at the end of
hours;

o
40
Write your answers on the separate answer papers. tll

i
(ii) calculate the percentage by mass of iron in the pack. l2l
89

t
walkers and climbers buy'warm packs'. when these packs are being used, the packs
become hot and remain at a temperature of about 40;C for several hlours. A.warm (d) (i) ls the reaction taking place in the'warm pack'exothermic or endothermic?
pack'contains severar chemicals evenry mixed together in a porous bag. The whore

a
t1I
pack is contained in a polythene bag. (ii) Draw an energy profile diagram for the oxidation of iro+. Label on the
diagram the activation energy and the enthalpy change.

c
The label from one'warm pack,is shown below. 121

E}10 lron is made by reducing haematite with coke and limestone in the Blast Fumace.

u
This pack contains
finely powdered iron haematite + coke + limestone

d
water and sodium chloride absorbed on
an inert por/der waste gass waste gases

carbon catalyst
\,

E
total mass of pack = 52.2 g

l
th9 polythene bag is opened, air enters the pack. The iron in the pack rusts
]Vhe1
forming iron(llt) oxide.

a
(a) write an equation, with state symbols, for the rusting of iron to produce iron(|il) hot air att

y
oxide.
I2l molten slag
molten iron
(b) A student investigated the reaction occurring in the pack by placing the opened

n
pack on an electronic balance. The increase in mass of the opened pack was (a) Name the element and lhe compound which react to produce the carbon
recorded at regular intervals over a period of several hours. The results are shown monoxide required to reduce the haematite.in the Blast Fumace. tZl

a
below.'
(b) Construct a chemical equation, including state symbols, for the reduction of
time / hour total mass increase of the pack / qrams haematite by carbon monoxide. pl

D
0 0.00
4 1.30 (c) Explain why waste gases contain sulfur dioxide and oxides of nitrogen. t3I
8 2.60
12 3.80 (d) Slag floats above iron in the Blast Furnace before molten iron is tapped for further
16 4.50 use. lf the tayer of slag was not present, there would be a lower yield of molten
20 4.70 iron collected. Suggest a possible reason for this. tl]
24 4.7s
4.80 (e) Pure iron is not commonly used to manufacture products but their alroys are.
32 4.80
36 4.80
(i) Give one use of an alloy of iron. t1]
40 4.80
(ii) State a reason why pure iron is not suitable for the use named in (e)(i). t1l

[-otal:'101

CTSS/Prelim/5072y02i2O1 0 CTSS/Prelim/5072/02/20 1 0
 11 12

EITHER OR

E]11 An organic compound, Q, shows a number of reactions as indicated in the figure below. 811 When potassium chlorate(V), KClOr, is heated at 600 'C, it decomposes into potassium
chloride and oxygen.
- {w b{ H 2KClo3 *o ,

n
H
2KCt t 3oz

'{.-y-L-
polymer b_LL_" I
fruity sanell
l/ Lt Copper(ll) oxide acts as a catal!6t for lhe reaction. Some information about these

io
etharcl:
Y qcu6td clmpounds are shown in tfle table below.
4fi H--9.: tEat

t
t,
IV 6 il KCI KCtOI CUO
1

a
M9 melting point /'C 772 368 1326
/
compound Q
/'C

c
. ia' boiling point 1407

clz (g);
(a) (i) Suggest why there is no boiling point stated in the table for potassium

u
UV light
chlorate(V). t1]

(ii)

d
ln what physical state will potassium chlorate(V) be when it starts to
(a) Draw the structural formula of the organic product formed in reaction l. t1I decompose? t1l

(b) Reaction ll converts the carbon-carbon double bond into single bonds through the

E
r (iii) Potassium chloride has high melting and boiling points. Explain, with
addition of hydrogen. Suggest the conditions necessary for the reaction to take reference to its chemical bonding, why potassium chloride has high melting
place.
{11 and boiling points. l2l
(c)

l
Draw the structuml formula of an organic product in reaction lll t1I (iv) lf you had a mixture of potassium chloride, copper(U) oxide and potassium
chlorate(V), how would you obtain pure coppe(ll) oxide from the mixture?
(d) (i) Write the balanced chemical equation for reaction lV I1l t3l

a
(ii ) State two observations for reaction tV. l2t (b) (i) What is the oxidation state of chlorine in KCIO:? tll

y
(e) (i) Compound Q undergoes addition polymerisation in reaction V. Draw the (ii) Explain, in terms of oxidation number, why this decomposition reaction is
structural diagram of the polymer formed in reaction V. t1I also a redox reaction. l2l

n
(ii ) The product formed in reaction Y is non-biodegradable. Explain the meaning [-otal: 10]
term'non-biodegradable'.

a
,.tf'- r of the I11

:,,;,: (f) Compound Q is an unsaturated organic compound. Describe a test and state the
positive result to show that compound Q is unsaturated. l2l

D
f['oti'r] i{)l

CTSSlPrelim/5072/02/2O1 0 CTSSlPrelim/5072 lO2l2O 1 0

 Clementl Towrl Secondary School a macromolecular 3lructure rn whrch 4l]-lDljtrlrlls
Prellm Examlnatlon 20'10 are covalentlv bonded togethor
Secondary 4 Exprecs A lot of energy is to overcome tho!e allraclivo forcos
Marklng Scheme
Chemistry 5072 A4 (a) Student

Paper 1 (b) lncomplete combustion of petroloum / fossrl fuels 1

n
1 A 11 B 21 D 31 C (c) The carbon monoxide level at lhe city cenlro rs generally grealel lhan at 1

I 12 D 22 A 32 c the playground.
t D 1a D 23 o aa A Greater vehicle traffic / tratfic congestion at tne city contre coutd have 1

io
4 14 c 24 c 34 B released more carbon monoxide into lhe arr
5 15 c 25 c 35 A I
(d)

t
Fit catalytic converters to vehicles. t1
b b 16 A 26 c 5b D (Accept any other reasonable enswers.)
7 D 17 B 27 c a1 B
(e)

a
8 D 18 A 28 A 38 D Oxides of nitrogen / unburnt hydrocarbon (RoJect sullur dlo{rdo) 1
,to
o D 19 s 29 B o
10 B 20 c 30 B 40 B

c
1

Paoer 2 Coppe(ll) nitrate 1

u
On. Answer Marks (b) Aluminium ions (or Al3') that form a{lor lhn odditron ol sulfurrc acid is 1

A,I (a) hydrogon chloride 1 insoluble in excess aqueous anrmonre

(b)

d
hydrogen chloride 1

(c) ammonium chloride 1 (c) White precipitate: zinc(ll) hydro^rdo 1

(d) coppe(ll)chloride ,1

E
Zn+HzSOr-ZnSOr+Ha 1

(a) 3 400 "C 1

ZnSOo + 2 NH3 + I H2O

- Zn(t)H);, (l',lrt,),SO. 1

(b) Arrangement: particles (or atoms) are close to one another in an

,1
OR

l
irreoular manner zn" (aq1+ oH'(aq)- zn(oH), (s)
Movement: particles (or atoms) rollino over one another. 1 (if students give lonic equation, statr symbol! rnusl bc aivon)

a
(c) The wir€ is pCtCU tungsten. 1 1

The wlre has a flxed rneltlno and boilino ooint (or does not have a range 1 (the first mark is
- Oz (g) . a e

y
of melting and boiling poiht, which are characteristics of pure only awarded if the (ii) anode: 2 O'?' 1aq; 1

substances. reason is correcl) cathode: Cu2' (aq) + 2e -. Cu (l) 1 (inclusive of state

symbols)
(a)

n
(i) Grcup Vll 1

(iii) At high,temperatures, the glylglqlgli|lllod al tho anooo rcacls with 1

(ii)E' 1 the oraohite electrode to producod carbon dloridc. Thl3 reacilon erodes

a
/ uses up the graphite.
(iil)
1: sharing of e', (b) (i) Method 2 does not rBquire hoating to a hrgh lomperature / l! more 1

1: correct no. of e' cost effgctive.

D
1

(ii) Coppe(ll) hydroxide is insoluble in wator, hence method 2 cannot

be used to extract copper from coppe(ll) hydroxide,

(c) (i) Cu (s) - Cu'?- (aq) + 2 e 1 (including state

symbols)
 (ii)
'' No cnange in colour of electrolyte. 1

1 (the first mark is A8 (i) Carbon dioxide lost lo lhe Surroundrnqs. 1

The amount of Cu2' remalns constant throughout the electrolysis
process since the anode oxidises to form Cu" while the Cu'' only awarded if the
ions reduce to copper at the cathode. reason is correct) (ii) The rates of reaction decrease wrtn um0 1

A7 (a) A compound contalning mlY the elements carbon and hydrogen. (b) (i) 1

Note: volumo
(b) Their differences in boiling points. I ri r, i!; i,r
chanqe should lgl
'r, r 0i ijt tl
be twico as rnuch

n
(c) (i) ! CrHso 4tOa - 28 COa + 30 H2O
" 1
rl "i since the mass of
'I f Ci:' the flask is stlll
(ii) M. of CuHm = 198

o
measured.
I
fu6. of c,oH* ('l 15.56 x l oa) / 198 = 0,58363 x 106 moles

i
Ho. or co, i1o.'saeoa xfia) l 2 x 28 = 8.1709 x '100 moles 1 H

t
M. of CO, = 44
Mass of 60, = 8.1709 x 106 x 44 = 359.52 tonnes 1

a
(d) (i)
(b) (ii) Smaller lumps have sma116r oartlclo tllc. 1
H
ihe increase in the surface orea ol lho prrllcl€s lncroasos lhe rate of

c
1
o/o
bY mass 85.7 14.3
12 1
etfective collisions for reaction to proceod,
A,
Mole 7.14 14.3 1
-89

u
4Fe(s) + nced eqn
Divide by smallest number 1 2.00
1: state symbols
SimDlest ratlo 1 2

d
Empirical formula: CHr 1 (b) (i) The relative formula mass of ircn(lll) oriqs is orester than the relativq 1

atomic mass of iron, The formation ol lron(lll) oxlde leads t0 sn

(il) No. of mo16s of hydrocarbon = 0j20 124 = 0.005 increase ln the mass of the Pack,

E
.l 1 OR
M, of hydrocarbon = 0.28 / 0.005 = 56
The increase in mass ls due to l[94a!! of oxvoen that fooctod with
n=56/14=4 iron to form iron (lll) oxide.
molecular formula is CrHr 1 (allow ECF)

l
(li) 28 h 1

(c) (i) No. of moles of oxygen = 4,8 I 132 ' 0.16 moler 1

a
(ii) No, of moles of iron = 0.15/ 3 x 4 t 0 2 molss

y
1 (allow ECF)
Mass of iron = 0,2 moles x 56 1 1.2 0 '

n
o/o
by mass of iron = 11.29I 52,2 g x 1000/o '21.45% I (allow ECF)

a
(d) (i) exothermic 1

ener9y levol
(ii) 1/2: shape of graPlt

D
1 12: la)el reactants
ircn +
and products
1/2: label E"
'1l2: label A
Orld o (round down to
nearest whole
progrctt ol tcactior olal

4
3 I
 :rbz-' (e) (i) 1

810 (a Element'oxyge& 1
H
l.{
Cornpound: carbon dioxide 1
I I

(b) 3 CO (s) + FezO: (s) -. 2 Fe (l) + 3 CO2 (g) 1: balanced eqn

1:state symbols
C- c
t
H
(c) The gullcf-plese0uAltre-mileta.ls mined from the eanh reacts with 1
I
clHc c00 fr n

n
oxygen ln the furnace to form sulfur dioxide.
The hioh temperature generated by the combustion of coke causes the 1

nltrooen frorn the air to break its bonds and react with oxygen, hence (ii) Non-biodegradable is a term used to doscribs compounds lhal 1

io
1

formin0 oxide of nitrogen. cannot be decomposed by bacleria in tho goil

(d) (f)

t
ln the absence of slag, the molten iron reacts with the oivoen from the I Test: Add aoueous bromine 1

air and forms iron(lll)oxide again, reducing the yield 0f iron. Result: The reddish brown aqueou3 bronrne decolourlses 1

a
(e) (i) Construction of buildings / bridges / medical equipment / cutlery 1 Potassium chlorate decomposes bef0rn rl borls 1

(accept any other reasonable answers) 811

c
(ii) liquid 1

(ii) Pure lron is too soft as the regular layered structure alloys the atoms 1

to slide over one another. (iii) Potassium chloride is an ionrc compound wrth 3trong eloctrostatic 1
I

u
OR forces of attraction between th6 potas3ium ,nd chloflde iont i

Pure lron is more susceptible to rusting than it's alloys, A lot of energy is required to ovorcomo th6ro lorco! of attrncrron. 1 I

(Answer must match the use in part (l).)

d
(iv) - Add water to the mixlur€ nnd lu lo d'rrolyG polossiLim chlodde 1

(a ) and potassium chlorate.

811 o |l'H
1

- Filter the mixture to obtain th6 coppc(lr) oxldc as the !qlg!!. 1

E
tl I
- Wash the coppe(ll) oxide wlth dl3tillod walcr and press (lry
Cs!{,'-c-0-f!-u
1

between filter papers.

ll H (b) (l) +5 (posltlvo sign must bo lncludcd) 1

l
(ii) The oxidatlon number of clrlorlne has Doon rcduccd fronr 114 1

(b) NicKel catalyst & 200 "C 1 KCIO3 to -1 in KCl.

a
The oxidation number of oxygon has rncroa3od lrom jlt&tlQl2l t0 0.i! 1

Llr.
r!trll(ll t{ l.l it

y
(c) 1 (any hydrogen Since oxidation and reduction nas occuroo 8t th6 same tinlo. tnrs rs a

atom connected to redox reaction.

CL-C-c-c-c=C-H a carbon atom can
rlt

n
be replaced)
HHC:O

a
I

o
I

D
H
(d) (i) 2 CsHrCOoH + M9 - (CsHsCOO)aMg + Hz 1

(ll) Effervescence forfi s; 112 fiark per poinu

Ma0nesiurh dissolves; round down to
I Colourtess, odourless gas; nearest who!e no.
I

i
extldguishes lighted splint with a'pop' sri,nd. ffotal 2]
I
-1--

! 6