SAFETY DATA SHEET according to EC directive 93/112/EC

SIGMA C200a COAL TAR EPOXY

Version 1 Print Date Dec 2002

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Product information

Trade name : 3307 SIGMA C200a COAL TAR EPOXY

Company : Sigma Paints Saudi Arabia Ltd.

P.O. Box 7509
Dammam 31472
Telephone : +966 3 847 3100
Telefax : +966 3 847 1734

Emergency telephone number : +966 3 857 2394

2. COMPOSITION/INFORMATION ON INGREDIENTS

Components CAS-No. Symbol(s): R-phrase(s) Concentration

XYLENE 1330-20-7 Xn R10, R20/21, 25.00 - 50.00%

R38
2-METHYLPROPAN-1-OL 78-83-1 Xi R10, R41, R67, 10.00 - 25.00%
R37/38
ETHYL BENZENE 100-41-4 F, Xn R11, R20 10.00 - 25.00%
2,4,6-TRIS-(DIMETHYLAMINOMETHYL)- 90-72-2 Xn R22, R36/38 2.50 - 10.00%
PHENOL
4-NONYLPHENOL, BRANCHED 84852-15-3 Xn, N R22, R38, R41, 2.50 - 10.00%
R50/53

3. HAZARDS IDENTIFICATION

Harmful

Hazardous components :
XYLENE
POLYAMINO IMIDAZOLINE
TRIETHYLENETETRAMINE

R-phrase(s) :
FLAMMABLE.
HARMFUL BY INHALATION AND IN CONTACT WITH SKIN.
IRRITATING TO RESPIRATORY SYSTEM AND SKIN.
RISK OF SERIOUS DAMAGE TO EYES.
MAY CAUSE SENSITIZATION BY SKIN CONTACT.

S-phrase(s) :
Avoid contact with the skin.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Wear suitable protective clothing, gloves and eye/face protection.
In case of insufficient ventilation, wear suitable respiratory equipment.
Do not breathe spray.

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 SAFETY DATA SHEET according to EC directive 93/112/EC
SIGMA C200a COAL TAR EPOXY
Version 1
4. FIRST AID MEASURES
General advice
Eye contact
Skin contact
Inhalation
Ingestion
5. FIRE-FIGHTING MEASURES
Specific hazards during fire
fighting
Special protective equipment
for fire-fighters
Suitable extinguishing media
Extinguishing media
which must not be used for
safety reasons
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Environmental precautions
Methods for cleaning up
Additional advice
7. HANDLING AND STORAGE
Handling
Safe handling advice
Print Date Dec 2002
: When symptoms persist or in all cases of doubt seek medical advice.
Never give anything by mouth to an unconscious person.
: Irrigate copiously with clean, fresh water for at least 10 minutes, holding the
eyelids apart. Remove contact lenses. Seek medical advice.
: Take off all contaminated clothing immediately. Wash skin thoroughly
with soap and water or use recognized skin cleanser. Do NOT use solvents
or thinners.
: Remove to fresh air. Keep patient warm and at rest. If breathing is irregular
or stopped, administer artificial respiration. If unconscious place in
recovery position and seek medical advice.
: If accidently swallowed obtain immediate medical attention. Keep at rest. Do
not induce vomiting.
: As the product contains cumbustible organic components, fire will produce
dense black smoke containing hazardous products of combustion (see section
10). Exposure to decomposition products may be a hazard to health. Cool
closed containers exposed to fire with water spray. Do not allow run-off
from fire fighting to enter drains or water courses.
: In the event of fire, wear self-contained breathing apparatus.
: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Keep containers and surroundings cool with water spray.
: Do NOT use water jet.
: Use personal protective equipment. Ventilate the area. Refer to protective
measures listed in sections 7 and 8. Wear respiratory protection. Beware of
vapours accumulating to form explosive concentrations. Vapours can
accumulate in low areas. Remove all sources of ignition.
: Try to prevent the material from entering drains or water courses. If the
product contaminates rivers and lakes or drains inform respective authorities.
: Clean with detergents. Avoid solvents. Contain and collect spillage with non-
combustible absorbent material, (e.g. sand, earth, diatomaceus earth,
vermiculite) and place in container for disposal according to local / national
regulations (see section 13).
: Refer to section 15 for specific national regulation.
: Avoid exceeding of the given occupational exposure limits (see section 8).
Use only in area provided with appropriate exhaust ventilation. Avoid contact
with skin, eyes and clothing. Smoking, eating and drinking should be
prohibited in the application area. Avoid inhalation of vapour or mist. For
personal protection see section 8.
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