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International Journal of Advanced Engineering Research and Science (IJAERS) [Vol-7, Issue-11, Nov-2020]

https://dx.doi.org/10.22161/ijaers.711.14 ISSN: 2349-6495(P) | 2456-1908(O)

Comparative Study and Sensitivity Analysis


in Simulation of Non-Darcy Flow in Shale
Gas Reservoirs
Marcelo Luiz de Oliveira Pessanha1 , Rebeca Costa Dias do Rosário1 ,
Grazione de Souza1 and Helio Pedro Amaral Souto1
1
Departamento de Modelagem Computacional, Universidade do Estado do Rio de Janeiro, Rua Bonfim, 25, Vila Amélia,
28625-570 - Nova Friburgo, RJ, Brazil
Emails: mar.oliveirabreder@gmail.com, rebecacostadias@gmail.com, gsouza@iprj.uerj.br, helio@iprj.uerj.br

Received: 14 Oct 2020; Received in revised form: 10 Nov 2020; Accepted: 12 Nov 2020; Available online: 16 Nov 2020

Abstract — In this work, we perform a comparative study of flow models and a sensitivity analysis con-
cerning some parameters, considering the effects of slipping and gas adsorption in shale gas reservoirs,
using numerical simulation. We use the Finite Difference Method, a linearization based on the Picard
method, and the Conjugate Gradient method to obtain the reservoir and production well pressures. The
results obtained demonstrate the importance of the effects of slipping and adsorption in the variation of
pressure in a single-phase isothermal gas flow. Mainly because some parameters in the flow models,
depending on their values, can act favoring (or disfavoring) the pressure drop.
Keywords — Adsorption. Finite Difference Method. Natural gas. Reservoir simulation. Slipping
flow.

I. INTRODUCTION face conditions), for example, when composed essen-


For decades, the oil industry has followed a stan- tially of methane. Generally, natural gas (depend-
dard strategy in the context of hydrocarbon explo- ing on the reservoir and its characteristics) contains
ration/exploitation: the search for rock formations of methane, ethane, propane, butane, pentane, and hex-
interest, the location of the reservoir rocks, the identi- ane, but we can also find other heavier components in
fication of the mechanisms of imprisonment, and well it. The non-hydrocarbon parcels, considered as impu-
drilling. These procedures had been used by geol- rities, include carbon dioxide, hydrogen sulfide, and
ogists, geophysicists, and engineers, aiming mainly nitrogen. The primary component is always methane,
at the production of hydrocarbons via vertical wells in which may represent 70 to 98% of the total, followed
reservoirs formed, for example, by sandstones or car- by ethane (which may reach 10%).
bonates.
Natural gas is the cleanest and richest source
However, in the past two decades, new concepts
of hydrogen among hydrocarbons and has high effi-
of exploitation have emerged. Rock formations that
ciency in energy conversion. The current trend is for
were previously less important, to the point of not
natural gas to become one of the most important fu-
being considered economically viable, are currently
els in the global economy [12] due to economic and
seen as potential reservoirs. Among unconventional
environmental reasons [29, 31]. See Fig. 1 for the
sources, shale gas reservoirs are gaining more and
breakdown of the internal energy supply in Brazil for
more relevance on the world stage [8].
the year 2019 [13].
1.1. Natural gas In terms of its use, natural gas can provide heat-
Natural gas is a homogeneous fluid with low vis- ing, generate electricity, and we can use it as fuel for
cosity and density. In a reservoir, natural gas can motor vehicles or in the production of hydrogen [12].
be classified as dry (it does not contain molecules According to Economides and Wood [12], the world
heavy enough to form a liquid hydrocarbon under sur- reserves of natural gas have been increasing at an an-

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International Journal of Advanced Engineering Research and Science (IJAERS) [Vol-7, Issue-11, Nov-2020]
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nual rate of about 5% since the seventies. The num- the pores, dissolved in liquids, or adsorbed on solids.
ber of countries with known natural gas reserves has We find the gas adsorbed on carbon-rich compounds,
grown from 40, in 1960, to 85 in 2005. such as kerogen. According to Ali [1], Wang [27] and
Berawala [3], gas in an adsorbed state represents a
1.2. Shale gas fraction ranging from 20 to 80 % of the total gas re-
Non-conventional reservoirs differ from conven- serves in shales. As the pressure decreases, as a
tional ones, for example, in that they have a very result of continuous production, the gas adsorbed de-
low permeability. Among the non-conventional reser- taches from the solid and becomes part of the free
voirs, we can mention the tight-gas sands (low per- phase, contributing to flow and production. Therefore,
meability reservoirs), the coal bed methane (in which by neglecting the effects of adsorption, we can under-
there is gas adhered to coal veins), and the shale gas estimate the potential of a shale reservoir [30].
(gas in shale-like rocks). The latter, the focus of this About two decades ago, we considered gas re-
work, typically have extremely low permeabilities, in covery in shale reservoirs as economically and tech-
the range of 10−6 to 10−9 Darcy, low porosity, gas nically nonviable. However, with the emergence of
adsorbed on the solid, and the gas slips on the pore new technologies, especially the drilling of horizontal
surfaces of the reservoir. Its formations are composed wells and hydraulic fracturing, their exploitation has
of sedimentary rocks, consisting of clay minerals such become possible and economically viable. In 2015,
as illite, smectite, and kaolinite [8]. about three-quarters of natural gas production in the
United States originated from these reservoirs, with
Energy Matrix 2020 the expectation of continued growth over the next two
decades [28]. The great success in North America
has led to unconventional sources gaining more at-
tention on the world stage, including the countries of
7.6%
South America, such as Argentina and Brazil.

34.4% 18% II. NATURAL GAS FLOW IN POROUS


MEDIA
Typically, the classical Darcy law [7] is used in en-
8.7%
gineering to describe low-speed flows in porous me-
12.2% 12.4% dia. For non-Darcy flows, it is modified and expressed
5.3% 1.4%
in the form:

ka
0% v=− (∇p − ρg∇D) , (1)
µ

where v is the surface velocity of the fluid, ka is the


Petroleum Natural coal apparent permeability tensor, µ is the viscosity, p is
the pressure, ρ is the density, g is the magnitude of
Natural gas Metallurgical coal
the acceleration due to gravity, and D is the depth.
Among the non-Darcy effects, which we can incorpo-
Uranium U308 Firewood rate into the apparent permeability, we have:

Hydraulic energy Sugarcane products • the inertial and turbulent effects,

Other primary energy • the non-Newtonian flow,

• the slipping and adsorption of the gas on the


Fig. 1: Supply by energy source in Brazil in 2019.
pore surface,

In them, the gas is present as a free phase in in addition to others that also cause non-linearity [2].

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2.1. The gas slippage phenomenon of the porous medium, Z is the compressibility fac-
Florence et al. [15] reported that the phenomenon tor, T is the temperature, R is the universal constant
of gas slipping occurs when the mean free path of the for gases, M is the molecular mass of the gas, and
fluid molecules is of the order of the characteristic hy- γ = M/Mair is the relative density of the gas and
draulic radius of the pores. We know that gas flows Mair the molecular mass of air [8]. The slip regime
in the porous medium differently from a liquid for two exists for the 10−3 < Kn < 0.1 range [4].
reasons: its high compressibility and the Klinkenberg
effect [2]. We use Klinkenberg’s correction to take into 2.2. The adsorption phenomenon
account the effects of gas slippage, which can be veri- Adsorption occurs when the gas molecules attach
fied when carrying out permeability measurements on to the solid surface of the pores, and the volume of
rock samples [14] gas adsorbed depends on the pressure of the gas
phase. Here, we consider the Langmuir isotherm
  model:
b
ka = 1+ k (2)
p
pVL
Vads = , (7)
where b is the Klinkenberg parameter and k the abso- p + pL
lute permeability tensor [19]. For example, gas slip- where Vads is the volume of adsorbed gas, VL is the
page can occur in shale gas and tight gas sand reser- maximum volume adsorbed (Langmuir volume), and
voirs. pL is the pressure corresponding to half of the max-
As an alternative to Klinkenberg’s correction, we imum adsorption capacity (Langmuir pressure). Ac-
can also account for this effect through a more general cording to Jiang and Younis [18], we can also incor-
expression for the determination of apparent perme- porate the effects of adsorption into the calculation of
ability, which we can calculate as a function of Knud- apparent permeability
sen number [18],
  p 4
dm 
 
4Kn pL
ka = f (Kn)k = (1 + αk Kn) 1 + k, (3) k0a = 1 −  k (8)
 
1 + Kn Rh 1 + p

pL
where k is the absolute permeability tensor, and αk
where dm is the diameter of the gas molecule adhered
is the rarefaction parameter [18], whereas for the slip
to the surface. Therefore, we can combine the contri-
regime, αk = 0. The Knudsen number, Kn, is defined
butions due to gas slippage and adsorption in deter-
by
mining the apparent permeability in the form:

λ
Kn = , (4) ka = f (Kn0 )k0 a (9)
Rh
where λ is the average free path of the molecules and where
Rh the characteristic hydraulic radius [15]
1 + 4Kn0
 
0 0
f (Kn ) = (1 + αk Kn ) (10)

s 1 + Kn0
k
Rh = 2 2τ (5) and the modified Knudsen number is set to
φ

and λ
Kn0 = , (11)
Ref f
r
µ πZRT where
λ= , (6)
p 2M
 p 
where τ is the tortuosity of the porous medium, k is
pL
the geometric mean representing the absolute perme- Ref f = Rh − dm  (12)
 
p 
ability of the porous medium, φ the effective porosity 1+
pL

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International Journal of Advanced Engineering Research and Science (IJAERS) [Vol-7, Issue-11, Nov-2020]
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is the effective hydraulic radius. being that we used the term source to represent the
well flow through an internal boundary condition for
2.3. Governing equation the well-reservoir coupling:
According to Li et al. [21], the mass conservation
equation, incorporating the effects of adsorption, is qsc = −Jw (p − pwf ) , (18)
given by
where Jw is the productivity index, and pwf is the pres-
    sure in the well [14]. In this work, we employ a pre-
∂ ρsc φ ∂ ρs ρsc Vads ρ v
sc
+ +∇· scribed production flow condition.
∂t B ∂t B B
We know that Eq. (15) is a partial nonlinear
parabolic differential equation that we use to deter-
qsc ρsc
− = 0, (13) mine the gas pressure. As an initial condition, we
Vb
consider
where qsc is a source term, ρs is the density of the
rock, B = ρsc /ρ is the volume formation factor, Vb
p(x, y, t = 0) = pini (x, y), (19)
is the total volume of the volume control (rock plus
pores), and the subscript sc indicates the standard where pini is the initial pressure before the reservoir
conditions, is disturbed by production/injection.
On the other hand, the external boundary condi-
tions are those of null flow at the borders
φ = φ0 1 + cφ p − p0 ,
 
(14)
   
∂p ∂p
where the superscript 0 indicates the reference con- = = 0, (20)
∂x x=0,Lx ∂y y=0,Ly
ditions, and cφ is the compressibility coefficient of the
rock. We consider here small and constant rock com- where Lx and Ly are the respective lengths of the
pressibility. reservoir in the x- and y- directions.
Substituting Eq. (1) in Eq. (13) and considering
that: ρsc and ρs are constant, we neglect the gravi- III. NUMERICAL METHODOLOGY
tational effects, the flow is two-dimensional, and the In this work, we use the Finite Difference Method
apparent permeability tensor is diagonal, (FDM) and a computational mesh of centered blocks
[2, 14], together with a well-reservoir coupling tech-
    nique [10], to determine the pressures in the reservoir
∂ kax ∂p ∂ kay ∂p Jw
+ − (p − pwf ) and the producing well.
∂x µB ∂x ∂y µB ∂y Vb
3.1. Discretization of the governing equation
 ∂p We provide a schematic representation of a dis-
= Γ0p + Γ0s (15)
∂t cretized two-dimensional domain is provided consid-
ering a single cell in the direction of the z-axis (high-
where for a non-isothermal flow and considering the
lighted in Fig. 2). We obtain the numerical solution at
previous expressions of Vads and B
the nodes of the computational mesh, located in the
centers of the cells. nx and ny represent the number
cφ φ0
 
d 1 of cells in the x- and y- directions, respectively. The
Γ0p = +φ (16)
B dp B integer indexes i and j represent the numbering of the
cell nodes in the respective x- and y- directions, and
and the fractional indexes i ± 1/2 and j ± 1/2 their inter-
faces.

1 dVads d

1
 Therefore, by writing the governing equation as
Γ0s = ρs + Vads , (17) being evaluated in cell node i, j, and at time level n+1:
B dp dp B

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     n+1
∂ ∂p ∂ ∂p #n+1
T0x T0y n+1 "
dx + dy ∂

∂p 1 ∂p

∂x ∂x ∂y ∂y i,j T0x ∼
= T0x
∂x ∂x i,j ∆xi,j ∂x i+ 1 ,j
2

 n+1
∂p
= (Γp + Γs ) + qsc , (21) "  #n+1
∂t 1 ∂p
i,j
− T0x . (25)
∆xi,j ∂x i− 21 ,j
where, as Vb = dxdyLz , we used

Spatial derivatives, evaluated on the faces of cells,


(Vb )i,j = (∆x∆y)i,j Lz (22) are also discretized by centered differences,

and we introduced the variables

pn+1 n+1
n+1
i+1,j − pi,j

∂p ∼
Ax ka,x = (26)
T0x ≡ (23) ∂x i+ 21 ,j ∆xi+ 21 ,j
µB
and and

Ay ka,y
T0y ≡ , (24)
µB n+1
pn+1 n+1
i,j − pi−1,j

∂p ∼
= (27)
with Ax = ∆yLz and Ay = ∆xLz . ∆xi,j and ∆yi,j ∂x i− 21 ,j ∆xi− 21 ,j
are, respectively, the mesh spacing in the x- and y-
directions in the cell (i, j), and Lz the length of the where ∆xi±1/2,j is the distance between the centers
rock formation in the z-direction. of cells (i, j) and (i ± 1, j). We can obtain the approx-
imations for derivatives in the y-direction in an analo-
gous way.
We also introduced transmissibilities in the x- and
y- directions:

 n+1
Ax ka,x
Tn+1
x,i± 21 ,j
= (28)
µB∆x i± 12 ,j

and

 n+1
Ay ka,y
Tn+1
y,i,j± 12
= (29)
µB∆y i,j± 21

where a harmonic mean is used to determine the val-


ues of areas and permeabilities in positions (i±1/2, j)
Fig. 2: Example of some cells of the discretized and (i, j ± 1/2), from the values known in neighboring
domain. nodes. With regard to the properties of the fluid, we
applied an arithmetic mean [14].
Then, we employ a centered difference type Thus, using an Euler approximation for the time
scheme to approximate the spatial derivative in the derivative and a fully implicit formulation in time, it is
x-direction [2, 14], possible to obtain the final discretized form of Eq. (21),

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3.3. Linearization
n+1 n+1 Equation (30) forms a system of nonlinear alge-
pn+1 − pn+1 pn+1 n+1
 
− i,j − pi−1,j

Tx i+1,j i,j Tx braic equations [17]. From Eq. (33), for the particular
i+1/2,j i−1/2,j
case of the two-dimensional problem, we can isolate
n+1 n+1 the pressure of the vertical well once we know the flow
pn+1 n+1
pn+1 n+1
 
+Ty − p − i,j − pi,j−1 and the pressure of the reservoir at the end of each

i,j+1 i,j Ty
i,j+1/2 i,j−1/2
time step.
 n+1 To achieve the linearization of Eq. (30), we
Γp + Γ s n+1 adopted the well-known method of Picard [22]. There-
pn+1 n

= i,j − pi,j + (qsc )i,j (30)
∆t i,j fore, after its linearization, we get the following equa-
tion
where n indicates the time level at which we know the
pressure, and we used a conservative expansion for v,n+1 v,n+1
the accumulation term [14]: pv+1,n+1 + Tx pv+1,n+1

Ty i,j−1 i−1,j
i,j−1/2 i−1/2,j

cφ φ 0
  
d 1
Γn+1 + φn+1
v,n+1 v,n+1
= Vbi,j (31)
p
Bn dp B +Tx pv+1,n+1 + Ty pv+1,n+1

i,j i+1,j i,j+1
i+1/2,j i,j+1/2

and
"  v,n+1 #
v,n+1 v,n+1 Γp + Γ s
− Ty + Tx + pv+1,n+1

i,j

d

1

ρs dVads
 i,j−1/2 i−1/2,j ∆t i,j
Γn+1
s = Vbi,j n
ρs Vads + n+1 . (32)
dp B B dp i,j
 v,n+1 
v,n+1 v+1,n+1
− Tx + Ty pi,j

3.2. Well-reservoir coupling i+1/2,j i,j+1/2
We proceed with the process of discretization and
n+1
the source term (qsc )i,j takes the discrete form  v,n+1
v,n+1 Γp + Γ s
= (qsc )i,j − pni,j (36)
h i ∆t i,j
n+1 n+1 n+1
(qsc )i,j = − (Jw )i,j pn+1
i,j − (pwf ) i,j , (33)
and transmissibilities, Γp , Γs , and qsc are evaluated at
and the productivity index is expressed by [24] the iterative level v.
Then, we utilize the values determined at the iter-
 n+1 ative level v to calculate the pressure at v + 1, n + 1.
p Therefore, we obtain the pressure from two inter-
n+1  2πLz ka,x ka,y 
(Jw )i,j =    (34) nal and external iterative processes for a given time
 req  step [8].
Bµ ln
rw i,j We choose the method of the Conjugate Gradient
where rw is the radius of the well and the equivalent (CG) to solve the algebraic system of Eq. (36) [16, 25].
radius, req , is given by [24] We can find in Fig. 3 the flowchart of the numerical
scheme of the resolution algorithm for a single time
vs  step calculation. To verify whether we achieve the
convergence of the internal and external iterations, we
u s
u ka,y ka,x
0, 28 t ∆x2 + ∆y 2  use tolerance values equal to tol1 and tol2 , respec-
ka,x ka,y
req i,j = s s ! i,j
(35) tively.
ka,y ka,x
4
+ 4
ka,x ka,y IV. RESULTS
i,j
In this section, we present our numerical results.
and we already rewrote the equivalent radius for its Initially, we introduce the standard case and some in-
use with the apparent permeability. formation about the data used in the simulations, in-

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International Journal of Advanced Engineering Research and Science (IJAERS) [Vol-7, Issue-11, Nov-2020]
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Fig. 3: Flowchart for a single time step.

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cluding rock and fluid properties, simulation parame- of [21], [18] and [9]. We adopt the same tolerance
ters, and geometric data. value for the internal (tol1 ) and external (tol2 ) iterative
Next, we do a numerical verification study, includ- procedures.
ing the refinement of the computational mesh. Finally,
we carry out a sensitivity study of parameters and Table 1: Parameters for the default case.
compare the different models employed. Here, the
standard model is that incorporating the effects of gas
Parameter Value Unit
slippage and adsorption in the modified Darcy’s law,
cφ 1.0×10−6 psi−1
as discussed in Jiang and Younis [18].
dm 2.3×10−10 ft
We show the results using specialized plots, com-
kx = ky 5.0×10−6 Darcy
monly employed in the area of well pressure test anal-
Lx = Ly 4,000 ft
ysis [5].
Lz 40.0 ft
We consider six models according to how we cal-
Lwf 40.0 ft
culate the apparent permeability values (ka ) in Eq. (1)
nx = ny 321 –
and the Γs coefficient in Eq. (15):
psc 14.65 psi
• Model 1 [14], which represents the classic case pL 1,100 psi
of Darcy’s law, without the effects of slippage pini = p0 6,000 psi
and adsorption; Qsc -5.0×104 scf/day
rw 0.25 ft
• Model 2 [15], the apparent permeability is calcu- R 10.73 ft3 psi/R lbm-mol
lated as a function of the Knudsen number (slip- tmax 365 day
page effect); tol1 = tol2 1.0×10−4 psi
• Model 3 [3], without slippage effect and with an T 609.67 R
accumulation term for the inclusion of adsorp- Tsc 519.67 R
tion; VL 0.0005 ft3 /lbm
γ 0.6 psi
• Model 4 [21], apparent permeability corrected δ∆t 1.05 –
as a function of the Knudsen number (slippage ∆tini 0.01 day
effect) and insertion of adsorption through the ∆tmax 10.0 day
source term in Eq. (15); ρs 200.0 lbm/ft3
τ 1.41 –
• Model 5, we modify the apparent permeability
φini = φ0 0.12 –
taking into account adsorption and, also, we in-
troduce its effects via the accumulation term in
Eq. (15); We use the relative density of the gas, together
with the pressure and temperature values, to deter-
• Model 6 [18], we change the value of ka to take mine the other properties of the gas [8, 20, 26].
into account the combined effects of slippage
and adsorption, and we also include the term
4.1. Mesh refinement
Γs 6= 0 in Eq. (15).
Table 2 shows the numbers of cells used in the
We modify the initial time step (∆tini ) according to generation of the different computational meshes ap-
the growth rate (δ∆t ) to obtain the next time step. This plied in the study of refinement of the computational
procedure is interrupted when we reach the specified mesh.
final time step (∆tmax ). We employ this strategy to As the production time increases, we can see
achieve greater accuracy in the initial stages of pro- (Fig. 4) that the pressure curves of the well approach
duction. each other. However, for the initial instants of time,
We can find the default values used in the simula- there is no overlap of values due to the increased ef-
tions in Table 1. They are defined based on the works fect of the well known numeric artifact [10, 11].

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The numerical artifact appears as a consequence Fig. 5 that for the highest values of absolute perme-
of the well-reservoir coupling technique, that assumes ability, there are the smallest pressure variations in
a steady-state flow regime near the well [23, 24]. Nev- the well. In the graphs, the sloping lines are charac-
ertheless, its effects do not compromise the results teristic of the transient regime in a porous medium.
for the advanced time instants. So, having verified In Fig. 6, again, for the highest permeabilities, there
the numerical convergence, Mesh 5 was chosen as is the smallest pressure variation in the well. We
the standard, given the significant reduction of the nu- also observed the occurrence of the transient regime.
merical artifact for times higher than one day of pro- However, compared with Fig. 5, it appears that the
duction. results for Model 6 show a lower pressure drop than
those for Model 1, for the same absolute permeabil-
Table 2: Meshes.
ity, as a result of higher apparent permeability. It also
Mesh nx ny leads to a shorter duration and magnitude of the nu-
merical artifact. Besides that, we should note that a
1 21 21
lower absolute permeability leads to a higher Kn [8],
2 41 41
thus leading to a lower pressure drop, in contrast to
3 81 81
the effect of the absolute permeability in the modified
4 161 161
Darcy’s law.
5 321 321
6 641 641 5 000

We emphasize that de Souza [9] validated the sim- 4 000

ulator used in the present work by comparing its re-


pwf (psi)

3 000
sults with those of the commercial simulator IMEX [6]
for Model 1. 2 000

5 800 k = 4.5 10−6 D


Mesh 1 1 000
k = 5.0 10−6 D
Mesh 2
Mesh 3 k = 5.5 10−6 D
5 600 0
Mesh 4
10−2 10−1 100 101 102 103 104
Mesh 5
pwf (psi)

5 400 Mesh 6 t (days)

5 200 Fig. 5: Permeability variation for Model 1.

5 000
5 800
−2 −1 0 1 2 3 4
10 10 10 10 10 10 10
5 600
t (days)

5 400
pwf (psi)

Fig. 4: Results for mesh refinement.


5 200
4.2. Sensitivity analysis and model comparison
5 000 k = 4.5 10−6 D
After conducting the mesh refinement study, we
k = 5.0 10−6 D
performed a sensitivity analysis considering the dif- 4 800 k = 5.5 10−6 D
ferent models for the single-phase flow of natural gas, 10−2 10−1 100 101 102 103 104
incorporating (or not) the slippage and gas adsorption t (days)
phenomena. We must remark that for all the studied
cases, the Kn remained within the validity range of Fig. 6: Permeability variation for Model 6.
the slip flow regime [4].
Initially, we compare the results obtained with About temperature variation for Model 6, see
Models 1 (Fig. 5) and 6 (Fig. 6) in simulations by Fig. 7, its increase leads to an augmentation in the
varying the absolute permeability. We can see in Knudsen number (via λ) and, consequently, to a

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International Journal of Advanced Engineering Research and Science (IJAERS) [Vol-7, Issue-11, Nov-2020]
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growth in the permeability apparent (facilitating the In the last case studied, we compare the six flow
flow), which contributes to a lower pressure drop. models, and we show the results in Fig. 9. Indeed,
However, the viscosity of the gas rises with tempera- we should point out that we have not found Model 5,
ture too. Thus, it also causes an increase in pressure ka = k0 a and Γs 6= 0, in the literature. Nevertheless,
drop due to the higher resistance to flow. Therefore, it could be used, for example, in reservoir simulations
there is a contraposition of effects that leads to dif- where the effects of adsorption are considerable, al-
ferent trends about pressure variation, with growth in though we can neglect those of slippage.
pressure drop for increasing temperature being preva- When comparing Models 1 and 2, we observe
lent in the tested cases. that the incorporation of the slippage effect leads to
We can see in Fig. 8 the influence that VL has on a lower pressure drop due to the higher values of ap-
the term source (due to adsorption) and the apparent parent permeability. The curves start from different
permeability. We noticed that the curves are close in points and have different slopes, in the region of the
the initial moments and that at a later time, there is a transient flow, due to the difference in apparent per-
gap between them. For the higher volume of Lang- meabilities. In the specific case of Models 1 and 3,
muir, there is a higher amount of adsorbed gas that the curves begin close with each other, as the appar-
can be released, favoring the maintenance of produc- ent permeabilities are the same (the absolute). Fur-
tion (less pressure drop). We know that the increase ther, we observe that the slopes are similar in the re-
of VL causes a reduction in the apparent permeability. gion of the transient regime (except for the effects of
However, with the release of the adsorbed gas, the non-linearities) due to the properties of the fluid, with
effect of VL on k0 a decreases. a lower pressure drop for the case where adsorption
supplements production.

6 000
5 600
5 000
5 400
pwf (psi)

4 000
pwf (psi)

5 200 3 000 Model 1


Model 2
5 000 T=559.67 R 2 000 Model 3
T=609.67 R Model 4
T=659.67 R Model 5
1 000
Model 6
10−2 10−1 100 101 102 103 104
t (days) 10−2 10−1 100 101 102 103 104
t (days)
Fig. 7: Temperature variation for Model 6.
Fig. 9: Comparison between different models.

For Models 1 and 4, we perceive that adsorption


and slippage effects favor the maintenance of pres-
5 600
sure. Because of the slippage effect, we must correct
the permeability apparent. As a consequence, the
5 400
pwf (psi)

slope of these curves is not similar to those of Mod-


5 200
els 1 and 3. Indeed, they are closer to that of Model
2. However, the overlapping effects of slippage and
VL =2.5 10−4 ft3 /lbm
5 000 VL =5.0 10−4 ft3 /lbm adsorption did not lead to values of pressure higher
VL =7.5 10−4 ft3 /lbm than those obtained in Model 2. We can explain this
10−2 10−1 100 101 102 103 104 behavior by the fact that Kn depends on pressure so
t (days) that for higher pressure values, there is a decrease
in Kn and a higher resistance to flow. In the case of
Fig. 8: Variation of VL for Model 6. Model 3, the overlapping effects lead to higher pres-

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International Journal of Advanced Engineering Research and Science (IJAERS) [Vol-7, Issue-11, Nov-2020]
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sure values after about 20 days of production. we have seen, this can happen if we do not consider
As the apparent permeability in Model 5 is lower these two effects. Further, we could perform simula-
than the absolute permeability, at least at the be- tions resulting in production flows closer to real con-
ginning of production, the numerical artifact appears ditions if we take into account both slippage and ad-
more strongly. In the beginning, the production poten- sorption phenomena.
tial is lower, but over time the increase in Langmuir In the case of shale gas reservoirs, due to their
volume results in a higher amount of adsorbed gas characteristics, we must not forget that their feasibil-
that can be released, favoring the maintenance of pro- ity is possible through the use of horizontal producing
duction (less pressure drop). Even so, this situation is wells and hydraulic fracturing.
transient, and Model 1 has a lower pressure drop over
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