Section A Basic Constants I

Vc Zc= Cp l DHvb DHvb Vl Cp g Cpl

Formula Name CAS# MW Tfp K Tb,K Tc,K Pc,bar cm3/mol PV /RT w cal/g°C cal/mol° cal/mo cal/g cm3/mol cal/mol° kJ/kmol
26 CH4 methane 74-82-8 16.04 90.69 111.66 190.56 45.99 98.60 0.286 0.011 1953 31.3 34.54 8.530
26 CH4 methane 74-82-8 16.04 90.69 111.66 190.56 45.99 98.60 0.286 0.011 1953 31.3 35.54 8.530
27 CH4O methanol 67-56-1 32.04 175.49 337.69 512.64 80.97 118.00 0.224 0.565 0.605 19.38 8415 262.6 40.73 10.531 81.08

47 C2H2 ethyne (acetylene) 74-86-2 26.038 192.35 188.40 308.30 61.14 112.20 0.268 0.189 14.109

55 C2H4 ethene (ethylene) 74-85-1 28.054 103.99 169.42 282.34 50.41 131.10 0.282 0.087 3234 115.3 10.253

60 C2H4O2 ethanoic acid (acetic acid) 64-19-7 60.053 289.77 391.04 594.45 57.9 171 0.2 0.445 0.490 29.42 5664 94.3 57.53 15.163 123.10

65 C2H6 ethane 74-84-0 30.07 90.35 184.55 305.32 48.72 145.5 0.279 0.099 1.840 55.33 3513 116.8 46.15 12.541 231.50

66 C2H6O ethanol 64-17-5 46.069 159.05 351.8 513.92 61.48 167 0.24 0.649 0.582 26.83 9216 200.0 56.68 15.586 112.25

85 C3H6 propene (propylene) 115-07-1 42.081 87.89 225.46 364.9 46 184.6 0.28 0.142 4402 104.6 15.373

89 C3H6O propanone (acetone) 67-64-1 58.08 178.5 329.22 508.1 47 209 0.233 0.307 0.521 30.26 6955 119.7 73.94 17.811 126.60

95 C3H8 propane 74-98-6 44.097 91.45 231.02 369.83 42.48 200 0.276 0.152 0.650 28.68 4551 103.2 17.591 120.00

96 C3H8O 1-propanol 71-23-8 60.096 147 370.93 536.78 51.75 219 0.254 0.629 0.572 34.35 9904 164.8 20.521 143.73

97 C3H8O 2-propanol 67-63-0 60.096 183.65 355.39 508.3 47.62 220 0.248 0.665 0.614 36.90 9524 158.5 76.92 21.348 154.40

110 C4H6 1,3-butadyene 106-99-0 54.092 164.24 268.62 425 43.2 221 0.27 0.195 0.552 29.88 5370 99.3 19.011 125.00

111 C4H6O3 acetic anhidride 108-24-7 102.09 199 412.69 606 40 0.456 0.291 29.66 23.783 124.10
124 C4H8O2 ethyl ethanoate(acetate) 141-78-6 88.106 189.55 350.21 523.2 38.3 286 0.252 0.361 0.463 40.77 7634 86.6 98.55 27.161 170.60
127 C4H10 butane 106-97-8 58.123 134.79 272.66 425.12 37.96 255 0.274 0.200 0.588 34.15 5363 92.3 100.48 23.540 142.89

128 C4H10 2-methylpropane (isobutane 75-28-5 58.123 113.54 261.34 407.85 36.4 262.7 0.278 0.186 0.586 34.06 5091 87.6 104.36 23.100 142.50

166 C5H12 pentane 109-66-0 72.15 143.43 309.22 469.7 37.7 311 0.268 0.252 0.554 39.96 6164 85.4 115.22 28.690 167.19

167 C5H12 2-metylbutano (isopentano) 78-78-4 72.15 113.26 300.99 460.39 33.81 308.3 0.272 0.229 0.546 39.39 5901 81.8 116.46 28.435 164.80

187 C6H6 benzene 71-43-2 78.114 278.6 353.24 562.05 48.95 256 0.268 0.210 0.416 32.49 7342 94.0 89.41 34.183 135.95

188 C6H6O phenol 108-95-2 94.113 314.05 455.04 694.25 61.3 229 0.243 0.442 1.253 117.96 ### 117.3 87.87 24.670
216 C6H14 hexane 110-54-3 86.177 177.84 341.88 507.6 30.25 368 0.264 0.300 0.542 46.71 6895 80.0 131.59 34.080 195.43

234 C7H8 toluene 108-88-3 92.141 178.16 383.79 591.75 41.08 316 0.264 0.264 0.408 37.59 7930 86.1 106.87 24.797 157.29

259 C7H16 heptane 142-82-5 100.2 182.59 371.57 540.2 27.4 428 0.261 0.350 0.537 53.77 7593 75.8 147.47 39.316 224.98

273 C8H10 ethylbenzene 100-41-4 106.17 178.18 409.36 617.15 36.09 374 0.263 0.304 0.419 44.45 8501 80.1 123.08 30.449 185.96

296 C8H18 octane 111-65-9 114.23 216.39 398.82 568.7 24.9 492 0.259 0.399 0.532 60.74 8224 72.0 163.53 44.880 254.15

334 C9H20 nonane 111-84-2 128.26 219.66 423.97 594.6 22.9 555 0.257 0.445 0.530 67.99 8822 68.8 179.7 50.289 284.45

440 H2O water 7732-18-5 18.015 273.15 373.15 647.14 220.64 55.95 0.229 0.344 0.999 18.00 9718 539.4 18.07 8.026 75.29
455 N2 nitrogeno 7727-13-9 28.014 73.15 77.35 126.2 33.98 90.1 0.289 0.037 1334 47.6 34.84 29.120

460 oxigeno 7782-44-7 31.999 54.36 90.17 154.56 50.43 73.37 0.288 1630 50.9 27.85 29.380
Ecuación # 2 log (Pvp) = A - B/ ( t + C) + 0.43429 x^n + E x^8 + F x^12 donde x =(T- to-273.15)/Tc
Ecuación # 3 ln (Pvp) =ln Pc + (Tc/T)(a tau + b tau^1.5 + c tau^2.5 + d tau^5) donde tau = 1 - T/Tc, para agua c tau^3 + d tau^6
DHvb Cpl
kJ/mol kJ/kg
8.17
8.17
35.21 2.530

0.446

13.53

23.70 2.050

14.70 7.699

38.56 2.437

18.42

29.10 2.180

19.04 2.721

41.44 2.392

39.85 2.569

22.47 2.311

1.216
31.94 1.936
22.44 2.458

21.30 2.452

25.79 2.317

24.69 2.284

30.72 1.740

46.18 5.244
28.85 2.268

33.18 1.707

31.77 2.245

35.57 1.752

34.41 2.225

36.91 2.218

40.66 4.179
###

6.82
 Section D Vapor pressure Correlatio Parameters Hvap con ec. Watson y Riedel Cálculode Pvap y Hvap a t =
cal/mol
Name # A/A/Tc B/B/a C/C/b Tc/c to/d n/Pc E F bar T min,K bar Tmax,K tn t= Pv Hvap
25 methane 1 3.7687 395.744 266.681 0.15 92.64 2 120.59 -161.49 ### 1.0152 1953 1982
3 190.551 -6.02242 1.26652 -0.5707 -1.366 45.992 45.99 190.55 -161.49 ### 1.0135 1973
27 methanol 1 5.20277 1580.0800 239.500 0.02 262.59 2 356 64.54 64.54 1.0135 8415 9132
3 512.64000 -8.6357 1.180 -2.47900 -1.0240 80.92000 80.92 512.64 64.54 64.54 1.0134 8727
47 ethyne 1 3.67374 528.6700 228.790 1.2 191.44 2 201.11 -84.75 -84.75 1.0080 3974
(acetylene) 3 308.35000 -6.8789 1.302 -1.22474 -3.59556 61.39000 61.39 308.35 -84.75 -84.75 1.0130 3896
55 ethene 1 3.91382 596.526 256.37 0.02 123.06 2 181.9 -103.73 ### 1.0134 3234 3239
(ethylene) 2 3.91382 596.53 256.37 282.34 -99 2.79132 9.717 52.77 2.71 188.15 40.99 273.15 -103.73 ### 3194
60 ethanoic acid 1 4.54456 1555.12 224.65 0.02 297.58 2 414.97 117.89 117.89 1.0106 5664 9494
(acetic acid) 3 592.71 -8.2943 0.97928 -0.21745 -5.72367 57.86 57.86 592.71 117.89 117.89 1.0133 9180
65 ethane 1 3.95405 663.72 256.681 0.02 133.8 2 198.16 -88.6 -88.60 1.0121 3513 3534
3 305.33 -6.475 1.41071 -1.144 -1.859 48.71 48.71 305.33 -88.6 -88.60 1.0130 3492
66 ethanol 1 5.33675 1648.22 230.918 0.02 276.5 2 369.54 78.65 78.65 1.0292 9216 9657
3 513.92 -8.68587 1.17831 -4.8762 -1.588 61.32 61.32 513.92 78.65 78.65 1.0131 9030
85 propene 1 3.95606 789.624 247.58 0.02 165.2 2 241.61 -47.69 -47.69 1.0134 4402 4413
(propylene) 2 3.95606 789.62 247.58 365.57 -41 2.67417 22.13 -199 1.74 238.15 44.67 363.15 -47.69 -47.69 4340
89 propanona 1 4.2184 1197.01 228.06 0.02 247.38 2 350.65 56.07 56.07 1.0128 6955 7185
(acetona) 3 508.1 -7.55098 1.60784 -1.9944 -3.2002 47.02 47.02 508.1 56.07 56.07 6990
95 propane 1 3.92828 803.997 247.04 0.02 168.9 2 247.76 -42.13 -42.13 1.0107 4551 4491
3 369.85 -6.76368 1.55481 -1.5872 -2.024 42.48 69.9 369.85 -42.13 -42.13 1.0135 4420
96 1-propanol 1 4.99991 1512.94 205.807 0.02 293.19 2 389.32 97.78 97.78 1.0384 9904 9879
3 536.48 -8.53706 1.96214 -7.6918 -2.945 51.68 51.68 536.78 97.78 97.78 9215
97 2-propanol 1 5.24268 1580.92 219.61 0.02 281.28 2 373.46 82.24 82.24 1.0121 9524 9521
3 508.3 -8.73656 2.1624 -8.70785 4.77927 47.63 47.63 508.3 82.24 82.24 1.0135 8862
### 1,3-butadiene 1 3.9664 927.21 238.63 0.02 198 2 287.49 -4.53 -4.53 1.0131 5370 5385
2 3.9664 927.21 238.63 425 2 2.5146 23.65 1971 2.04 348.15 41.9 343.15 -4.53 -4.53 5293
### acetic anhidride 3 606 -8.35313 1.8905 -2.8357 -5.1156 40 40 606 139.54 139.54 1.0123 9622
### ethyl etenoate(a 1 4.13361 1195.13 212.47 0.02 268.9 2 377.68 77.06 77.06 1.0134 7634
### butane 1 3.93266 935.773 238.789 0.02 200.5 2 292.03 -0.49 -0.49 1.0134 5363 5377
3 425.25 -7.01763 1.6777 -1.9739 -2.172 37.92 37.92 425.25 -0.49 -0.49 1.0131 5271
### 2-methylpropan 1 4.00272 947.54 248.87 0.02 190.4 2 280.25 -11.81 -11.81 1.0131 5091 5061
(isobutane) 2 4.00272 947.54 248.87 408.14 -5 2.6705 -19.6 2792 1.863 278.15 19.87 373.15 -11.81 -11.81 4982
### pentane 1 3.97786 1064.84 232.014 0.02 228.71 2 330.75 36.07 36.07 1.0135 6164 6462
3 469.8 -7.30698 1.75845 -2.1629 -2.913 33.75 33.75 469.8 36.07 36.07 1.0133 6042
### 2methylbutane 1 3.92023 1022.88 233.46 0.02 221.72 2 322.32 27.84 27.84 1.0131 5901 5929
(isopentane) 2 460.43 36 2.14912 -227 19674 1.766 318.15 15.77 413.15 27.84 27.84 5811
### benzene 1 3.98523 1184.24 217.572 0.05 279.64 2 377.06 80.09 80.09 1.0157 7342 7315
3 562.16 -7.01433 1.55256 -1.8479 -3.13 48.98 48.98 562.16 80.09 80.09 1.0199 7142
### phenol 1 4.2696 1523.42 175.4 0.02 353 2 481.62 181.89 181.89 1.0134 ### ###
### hexane 1 4.00139 1170.875 224.317 0.02 254.24 2 365.25 68.73 68.73 1.0136 6895 6931
3 507.9 -7.53998 1.83759 -2.5438 -3.163 30.35 30.35 507.9 68.73 68.73 1.0132 6733
### toluene 1 4.05043 1327.62 217.625 0.02 286.44 2 409.61 110.64 110.64 1.0141 7930 7996
3 591.8 -7.316 1.59425 -1.93165 -3.7222 41.06 41.06 591.8 110.64 110.64 1.0132 7791
### heptane 1 4.02023 1263.909 216.432 0.02 277.71 2 396.53 98.42 98.42 1.0138 7593 7649
3 540.15 -7.77404 1.85614 -2.8298 -3.507 27.35 27.35 540.15 98.42 98.42 1.0133 7386
### ethylbenzene 1 4.06861 1415.77 212.3 0.02 306.32 2 436.63 136.21 136.21 1.0145 8501 8569
3 617.2 -7.53139 1.75439 -2.42012 -3.57146 36 36 617.2 136.21 136.21 1.0132 8318
### octane 1 4.05075 1356.36 209.635 0.02 299.42 2 425.23 125.67 125.67 1.0130 8224 8330
3 568.95 -8.04937 2.03865 -3.312 -3.648 24.9 24.9 568.95 125.67 125.67 1.0133 7991
### nonane 1 4.07356 1438.03 202.694 0.02 319.57 2 451.64 150.82 150.82 1.0133 8822 8980
3 594.9 -8.32886 2.25707 -3.8257 -3.732 22.9 22.9 594.9 150.82 150.82 1.0133 8560
### water 1 5.11564 1687.537 230.17 0.01 273.2 16 473.2 100 100.00 1.0105 9718 ###
3 647.3 -7.77224 1.45684 -2.71942 -1.41336 221 0.01 273.2 221 647.3 100 100.00 1.0121 9921
*

*
*
 Capacidad calorífica estado de gas ideal cal/mol. J.R. Elliot, C.T. Lira revisar Cp
J/molK cal/molK
Name # a b c d Cp m Tb t para Cp DH
25 methane 1 19.250 5.21E-02 1.20E-05 -1.13E-08 7.0876 384.1500 111 386.6202 methane 19.250
3 methanol 21.150
27 methanol 1 21.150 7.09E-02 2.59E-05 -2.85E-08 10.6145 31.3340 (acetylene) 26.820
3 (ethylene) 3.806
47 ethyne 1 26.820 7.58E-02 -5.01E-05 1.41E-08 9.9883 35.9963 (acetic acid) 4.840
(acetylene) 3 ethane 5.409
55 ethene 1 3.806 1.57E-01 -8.35E-05 1.76E-08 8.2450 ethanol 9.014
(ethylene) 2 (propylene) 3.710
60 ethanoic acid 1 4.840 2.55E-01 -1.75E-04 4.95E-08 17.1664 (acetona) 6.301
(acetic acid) 3 propane -4.224
65 ethane 1 5.409 1.78E-01 -6.94E-05 8.71E-09 10.1808 1-propanol 2.470
3 2-propanol 32.430
66 ethanol 1 9.014 2.14E-01 -8.39E-05 1.37E-09 16.1860 1,3-butadiene -1.687
3 butane 9.487
85 propene 1 3.710 2.35E-01 -1.16E-04 2.21E-08 13.2135 (isobutane) -1.390
(propylene) 2 pentane -3.626
89 propanona 1 6.301 2.61E-01 -1.25E-04 2.04E-08 17.6750 (isopentane) -9.525
(acetona) 3 benzene -33.920
95 propane 1 -4.224 3.06E-01 -1.59E-04 3.22E-08 15.1545 hexane -4.413
3 toluene -24.350
96 1-propanol 1 2.470 3.33E-01 -1.86E-04 4.30E-08 21.9001 heptane -5.146
3 ethylbenzene -43.100
97 2-propanol 1 32.430 1.89E-01 6.41E-05 -9.26E-08 22.7316 octane -6.096
3 nonane -8.374
110 1,3-butadiene 1 -1.687 3.42E-01 -2.34E-04 6.34E-08 17.9295 water 32.240
2
111 acetic anhidride 3
124 ethyl etenoate(ac 1
127 butane 1 9.487 3.31E-01 -1.11E-04 -2.82E-09 21.8908
3
128 2-methylpropane 1 -1.390 3.85E-01 -1.85E-04 2.90E-08 21.2203
(isobutane) 2
166 pentane 1 -3.626 4.87E-01 -2.58E-04 5.31E-08 28.1261
3
167 2methylbutane 1 -9.525 5.07E-01 -2.73E-04 5.72E-08 27.4270
(isopentane) 2
187 benzene 1 -33.920 4.74E-01 -3.02E-04 7.13E-08 20.7873
3
188 phenol 1
216 hexane 1 -4.413 5.28E-01 -3.12E-04 6.49E-08 31.1303
3
234 toluene 1 -24.350 5.13E-01 -2.77E-04 4.91E-08 27.6449
3
259 heptane 1 -5.146 6.76E-01 -3.65E-04 7.66E-08 42.3577
3
273 ethylbenzene 1 -43.100 7.07E-01 -4.81E-04 1.30E-07 35.0959 0.0000
3
296 octane 1 -6.096 7.71E-01 -4.20E-04 8.86E-08 49.8527
3
394 nonane 1 -8.374 8.73E-01 -4.82E-04 1.03E-07 57.5869
3
440 water 1 32.240 1.92E-03 1.06E-05 -3.60E-09 8.0899
3
 t
5.21E-02 1.20E-05 -1.13E-08 353.15 3.87E+01
7.09E-02 2.59E-05 -2.85E-08 353.15 4.82E+01
7.58E-02 -5.01E-05 1.41E-08 353.15 4.80E+01
1.57E-01 -8.35E-05 1.76E-08 353.15 4.95E+01
2.55E-01 -1.75E-04 4.95E-08 353.15 7.52E+01
1.78E-01 -6.94E-05 8.71E-09 353.15 6.00E+01
2.14E-01 -8.39E-05 1.37E-09 353.15 7.42E+01
2.35E-01 -1.16E-04 2.21E-08 353.15 7.30E+01
2.61E-01 -1.25E-04 2.04E-08 353.15 8.36E+01
3.06E-01 -1.59E-04 3.22E-08 353.15 8.56E+01
3.33E-01 -1.86E-04 4.30E-08 353.15 9.86E+01
1.89E-01 6.41E-05 -9.26E-08 353.15 1.03E+02
3.42E-01 -2.34E-04 6.34E-08 353.15 9.27E+01
3.31E-01 -1.11E-04 -2.82E-09 353.15 1.13E+02
3.85E-01 -1.85E-04 2.90E-08 353.15 1.13E+02
4.87E-01 -2.58E-04 5.31E-08 353.15 1.39E+02
5.07E-01 -2.73E-04 5.72E-08 353.15 1.38E+02
4.74E-01 -3.02E-04 7.13E-08 353.15 9.90E+01
5.28E-01 -3.12E-04 6.49E-08 353.15 1.46E+02
5.13E-01 -2.77E-04 4.91E-08 353.15 1.24E+02
6.76E-01 -3.65E-04 7.66E-08 353.15 1.91E+02
7.07E-01 -4.81E-04 1.30E-07 353.15 1.52E+02
7.71E-01 -4.20E-04 8.86E-08 353.15 2.18E+02
8.73E-01 -4.82E-04 1.03E-07 353.15 2.44E+02
1.92E-03 1.06E-05 -3.60E-09 353.15 3.41E+01