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First Step for JEE (Main & Advanced)-2022

E-CAPS-05 : CHEMISTRY
(Engineering-Classroom Assessment Practice Sheet)
Topics covered : Equivalent mass : Equivalent mass and gram equivalent, Normality,
Relation between molarity and normality, Stoichiometry - Application of gram equivalent
concept and percentage of free SO3 in oleum

Choose the correct answer: 7. Calculate the maximum normality of a solution

1. For which of the following aqueous solution the containing 13.4 g of sodium oxalate in 100 mL
normality and molarity are not same? solution.

(1) CH3CO2H (2) H3PO2 (1) 2 N (2) 4 N

(3) H3PO3 (4) HNO3 (3) 1 N (4) 2.5 N
2. Equivalent weight of carbon in CO and CO 2 8. The minimum mass of oxalic acid crystals
respectively are in the ratio of (H2C2O4 . 2H2O) required to prepare 50 mL of a
(1) 1 : 1 (2) 1 : 2 0.2 N solution is
(3) 2 : 1 (4) 1 : 4 (1) 4.5 g (2) 6.3 g
3. In the following reaction : (3) 0.63 g (4) 0.45 g
3Fe + 4H 2O  Fe 3O 4 + 4H 2 , if the atomic 9. Strength of oleum is 104.5%. Then mass
weight of iron is 56, then its equivalent weight will percentage of free SO3 in this sample is
be
(1) 20% (2) 40%
(1) 42 g/geq (2) 21 g/geq
(3) 80% (4) 10%
(3) 63 g/geq (4) 84 g/geq
10. Which among the following has maximum normality?
4. If 25 mL of a H2SO4 solution reacts completely
with 1.06 g of pure Na2CO3, what is the normality (1) 1.6 g of KOH per 100 ml of solution
of this acid solution?
(2) 0.4 molar sulphuric acid
(1) 1 N (2) 0.5 N
(3) 8 g of NaOH per 100 ml of solution
(3) 1.8 N (4) 0.8 N
(4) 4.9 g of sulphuric acid per 100 ml of solution
5. A certain weight of pure CaCO3 is made to react
completely with 200 mL of a HCl solution to give 11. 5 g of a metal when combines with oxygen forms
224 mL of CO2 gas at STP. The normality of the 7 g of metal oxide. The equivalent weight of metal
HCl solution is is
(1) 0.05 N (2) 0.1 N (1) 5 (2) 10
(3) 1.0 N (4) 0.2 N (3) 20 (4) 40
6. What volume of 0.05 M Ca(OH) 2 solution is 12. Which of the following percentage labelling of
needed for complete conversion of 10 mL of 0.1 M
oleum is not possible?
H3PO4 into Ca(H2PO4)2?
(1) 109% (2) 118%
(1) 10 mL (2) 5 mL
(3) 20 mL (4) 40 mL (3) 100.1% (4) 127%

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E-CAPS : 05 (Chemistry)
Numerical Value Questions:
13. 10 mL of 0.1 M NaOH solution is completely neu-
tralized by 25 mL of 1.8 g of dibasic acid in one
litre solution. The molecular weight of acid is
14. Container A = 100 g of 109% oleum
Container B = 100 g of 118% oleum
Ratio of % of free SO2 in container A and B is
 
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First Step for JEE (Main & Advanced)-2022
15. 100 ml solution of NaOH (containing 4 g NaOH per
litre) and 50 ml of HCl (containing 7.3 g HCl per li-
tre) react as
NaOH (aq) + HCl (aq)  NaCl (aq) + H2O (l)
at any instant 0.5 g of NaCl is formed. The mass of
unreacted NaOH is (Given atomic mass of Na = 23
u, O = 16 u, Cl = 35.5 u)

 FS

First Step for JEE (Main & Advanced)-2022

E-CAPS-05 : CHEMISTRY
(Engineering-Classroom Assessment Practice Sheet)
Topics covered : Equivalent mass : Equivalent mass and gram equivalent, Normality,
Relation between molarity and normality,
Stoichiometry - Application of gram equivalent concept and percentage of free SO3 in oleum

ANSWERS

1. (3) 2. (3) 3. (2) 4. (4) 5. (2)

6. (1) 7. (1) 8. (3) 9. (1) 10. (3)
11. (3) 12. (4) 13 (90) 14 (0.50) 15 (0.60)

HINTS & SOLUTIONS

7. Answer (1) 12. Answer (4)

wt. in g / eq.wt % labelling of oleum sample lies between 100 to

Normality = 122.5 (both excluded)
vol. of solution in litre
13. Answer (90)
134
Here, eq. wt. of Na2C2O4 = 1.8
2 10 × 0.1 = 25  2
M
= 67 M = 90
13.4 / 67 15. Answer (0.06)
So, N =
100 / 1000
Milli moles of NaOH is sol = 10
=2N
Milli moles of HCl is sol = 10
11. Answer (3) At any instant millimoles of NaCl formed
∵ 2 g of oxygen combines with 5 g metal 0.5
=  103  8.5
5 58.5
 8 g of oxygen combines with  8 metal
2  Amount of NaOH left = 0.4 – (0.0085 × 40)
 Equivalent weight of metal = 20 = 0.06 g

  

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