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T HE increasing demand on low-power, low-voltage elec- programming [14, I]. T. Takeshima et. al. have designed
tronics has accelerated the pace of circuit designers to a 3.3-V single-power-supply 64-Mbit flash memory which
seek a promising candidate for high-density EEPROM’s. This requires 12 V internally to erase and 8 V on the bit line
new generation of EEPROM’s, characterized by high pack- and 5 V on the word line to write The high voltage
ing density, fast programming time, long memory retention, requirement has created a reliability issue, as it has exceeded
and high endurance for programming cycles, would gener- the voltage limit where a normal CMOS device can operate
ate an impact on applications such as semiconductor disks, without dielectric or junction breakdown. Therefore, special
nonvolatile random access memories, and neural networks. attention must be paid to designing high-voltage devices,
Semiconductor disks have shown their attractiveness in the which complicates the processing technology and hinders
replacement of the hard disks in portable computers which yield. Reduction of the programming voltage to 8-9 V with
mandates moderate programming speed and endurance but an extension towards 5 V simplifies the design and process
long retention. In the application of nonvolatile random access technology.
memory (NVRAM), the normal READWRITE operation is In this paper, we describe an alternative EEPROM technol-
undertaken by a SRAM cell that is accompanied in parallel ogy (SONOS) whose dielectric composition and programming
by a nonvolatile memory transistor acting as a shadow RAM voltage can be scaled according to the required application.
[20]. The nonvolatile memory is programmed every minute to First, we demonstrate the implementation of the SONOS
provide nonvolatility. Therefore, the EEPROM’s must possess device in an EEPROM array that can be applied to the semi-
fast programming speed, good endurance, and good retention. conductor disk application. Section 111 outlines the fabrication
On the other hand, for neural network application where the of the n-channel SONOS transistor. Since our main goal is
nonvolatile memory transistor can be used as the electrically to scale the programming voltage, we review the theoretical
reprogrammable synaptic element and is required to be repro- device behavior, including our closed-form transient analysis
Manuscript received March 8, 1994; revised May 12, 1994. This paper was and the basic retention characteristics in Section IV, and
presented at the Nonvolatile Memory Technology Review, Baltimore, MD, discuss how scaling the device affects both the speed and
June 22-24, 1993. This work was funded in part by the National Science retention. We present the measurement results of our devices
Foundation under Contract ECS-9023607 and the Office of Naval Research
under Contract “14-92-J-1672. in Section V and relate these results to the various NVSM ap-
M. L. French is with Elizabethtown College, Department of Computer plications. In particular, our results demonstrate a new scaled
Science, Elizabethtown, PA 17022 USA. SONOS structure (1.8-nm tunnel oxide, 5-nm nitride, and 4-
C.-Y. Chen, H. Sathianathan, and M. H. White are with the Sherman
Fairchild Laboratory, Department of Electrical Engineering and Computer nm blocking oxide) and the advantages and disadvantages of
Science, Lehigh University, Bethlehem, PA USA. scaling the tunnel oxide and blocking oxide.
1070-9886/94$04.00 1994 IEEE
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FRENCH et al.:DESIGN AND SCALING OF A SONOS MULTIDIELECTRIC DEVICE 39
x2
,i:,[[tn[innr,
(a) I
(a)
(b)
Fig. 2. Programming scheme for our SONOS EEPROM. A single program-
ming voltage (Vp)or ground is applied to the select lines (Xl, X2), word
(b) lines (Wl,W2), bit lines (BI, B2), and p-well (PW) or n-well (NW) to erase,
write, read, or inhibit the cell. Also, a sense amplifier (SA) is applied to one
Fig. Proposed (a) n-channel dual-gate SONOS memory cell in a p-well of the bit lines during the read mode.
and (b) p-channel dual-gate SONOS memory cell in an n-well.
TABLE I1
t
DUAL-GATE
MEMORYCELL SONOS DEVICESTRUCTURES
SONOS3
Using a dual-gate SONOS memory cell, previous investiga-
tors have obtained a high-density 1-Mbit SONOS EEPROM
1.1 nm
with n-channel transistors 1181. All the sources and p-wells nitride (XN) 5.0 nm
are tied together to reduce the memory area. Their SONOS 3.3 nm
EEPROM has been designed with a 1.2-pm address gate
length and a 1.5-pm memory gate length, yielding an 18.4
pm2 cell size. N. Ajika et al. have proposed a 16-Mbit floating
except for the formation of the tunnel oxide and the thickness
gate Flash EEPROM with a 3.6 p m 2 cell size given a 0.6-pm
of the blocking oxide. These transistors are formed using a
gate length [14]. We can project a 5.76 p m 2 cell size for the
LOCOS process starting with 2-3 52 cm 100 p-type
SONOS technology given a 0.6-pm design rule which is only
substrates. Fig. 3 illustrates the device cross section and TEM
slightly larger than the floating gate technology.
photomicrograph of the completed device structure. The key
The 1-Mbit SONOS EEPROM designed by Nozaki et al.
steps in the fabrication process involve the triple dielectric
requires both +5 V and -4 V, thus producing an effective 9-
since the electrical properties of the tunnel oxide, nitride, and
V programming voltage We propose a scheme to program
blocking oxide strongly depend on the processing conditions
a SONOS array with a single positive programming voltage
for each of these layers.
using either dual-gate n-channel SONOS transistors in a p-well
First, the tunnel oxide is formed either in situ within the low-
or dual-gate p-channel SONOS transistors in a n-well (Fig.
pressure chemical vapor deposition (LPCVD) silicon nitride
1). When integrating the CMOS and SONOS technologies, the
furnace for an ultra-thin 1.1-nm tunnel oxide or grown at
SONOS devices must have a separate bulk (memory well) than
700°C in a triple wall oxidation furnace to form a 1.8-nm
the CMOS peripheral circuitry. The memory well is employed
layer. The tunnel oxide thickness can be controlled to less than
to apply a positive programming voltage to the bulk to
0.05 nm, which is similar to results obtained by Kamagaki et
erase (write) the n-channel (p-channel) SONOS device while
al. [24]. Superior retention and endurance characteristics are
maintaining the peripheral CMOS substrate at ground. Thus
obtained by using a triple-wall oxidation furnace instead of the
a single power supply (Vp) can be used to accomplish both
conventional single-wall furnace [233. After tunnel oxidation,
the erase and write operations. The proposed programming
the silicon nitride (5 nm) is deposited at 725°C with a 1O:l
scheme is illustrated in Fig. 2.
NH3:SiClZHz ratio and a 300 mtorr pressure. Finally, we form
the blocking oxide by LPCVD (1O:l NzO:SiClZHz, 725°C
DEVICEFABRICATION 800 mtorr) followed by a 900°C steam anneal to densify the
In order to study the scaling of the SONOS device, we oxide. Minami and Kamigaki have demonstrated improved
have fabricated three different n-channel transistors (Table endurance by using this method, instead of the traditional
11). For each device, the processing conditions are the same steam oxidation at high temperatures (900°C to llOO°C),
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392 IEEE TRANSACTIONS ON COMPONENTS, PACKAGING, AND MANUFACTURING TECHNOLOGY-PART A, VOL. 17, NO. 3, SEPTEMBER 1994
p-Si
which they attribute to the sharper potential banier of the In scaling the SONOS device, we must consider each of
CVD oxide 161. the following characteristics: programming voltage, speed,
retention, and endurance. The scaling process is complex
IV. SCALINGTHEORY since varying the thickness of each dielectric layer can in-
fluence both the programming speed and retention. In order
During writing (erasing) of an n-channel SONOS device, an
to investigate the scaling of the SONOS device, we have
electron (hole) tunnels through the tunnel oxide and is trapped
developed a closed-form solution for its transient behavior
in the nitride. The threshold voltage of a SONOS transistor
[3]. Previous models have required numerical simulations [4],
includes information about the amount of charge stored in the
or obtained long analytical solutions where it is difficult
nitride layer and is given by
to determine how the change in threshold voltage depends on
the device parameters [4], [9]. Several of these models also
have required that the nitride thickness be much greater than
the tunnel oxide thickness [9], [8]. As the SONOS device is
scaled, the nitride thickness is reduced such that it no longer
meets the criteria mentioned above. In our analysis, we extend
where +GS is the gate to semiconductor work function; is the Lundstrom and Svensson model [9] to the scaled SONOS
the bulk Fermi potential; N B is the bulk doping; XOT. X N , device. We approximate the tunneling current by a first-order
and XOB are the tunnel oxide, nitride, and blocking oxide binomial expansion to yield a simpler solution, locate the
thicknesses, respectively; cox, en, and are the dielectric nitride traps in the center of the nitride bulk, and allow the
constants for an oxide, nitride, and silicon, respectively; and tunnel oxide thickness to approach the nitride thickness. From
C,ff is the effective capacitance of the triple dielectric. our model we find the change in turn-on voltage (AV,,) as
The charge stored in the nitride layer, Q N , depends on a function of the programming time (t,) is given by
the programming voltage Vp and the programming time t,.
A transistor in a memory cell may be characterized more
accurately by measuring the turn-on voltage corresponding to
the gate-to source voltage (VGS) at a specified current (usually
10 PA) in the constant current regime. For a SONOS transistor
in the constant current regime, the drain to source current can
be approximated by
where
IDS -(vGS VTHl2 (2)
where
Lff(F)Gff. (3)
EOt(0)
VP (EZ)QN(O)
W is the width of the transistor, L is the length of the xeff
1
transistor, and p e p f is the field-dependent effective mobility.
Thus, we find the turn-on voltage can be given by
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FRENCH et al.: DESIGN AND SCALING OF A SONOS MULTIDIELECTRIC DEVICE 393
-
0
3
C O
O
Programming Time, (seconds) Programming Time, (seconds)
Fig. 4. Simulated change in turn-on voltage versus the programming time Fig. 5. Erasdwrite simulation of a 1.8-nm tunnel oxide, 5-nm nitride,
given XOT 1.8 nm, XN 5 nm, XOB 4 nm, E,t(O) 7.46 MV/cm, and 4-nm blocking oxide device given E,t(O) 7.46 MV/cm. When the
and Vp 5 V. We observe that the erasdwrite speed is determined by the programming voltage is reduced from 9 V to 5 V, the turn-on time increases
turn-on time and the slope of the eradwrite curve from to and the erase/write slope decreases from Spl to Sp2. resulting
in an overall slower programming speed.
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394 IEEE TRANSACTIONS ON COMPONENTS, PACKAGING, AND MANUFACTURING TECHNOLOGY-PART A, VOL. 17, NO. 3, SEPTEMBER 1994
$2
-6
I nm tunnel
,I
- 2 2
-2
loo lo2 1 1o -~ 10 10 O
Programming Time, (seconds) Programming Time, (seconds)
Fig. 6. Eradwrite measurement of SONOSl at a 5-V programming voltage. Fig. Eradwrite measurement of two different scaled SONOS transistors
The initial threshold voltage is -1.2 V for the write characteristic and 2.1 V with an 1.8-nm tunnel oxide [9], and a 2-nm tunnel oxide [5] comparing
for the erase characteristic, corresponding to an initial electric field of 7.46 the speed of the devices at f 9 V. By comparing these devices, we see the
MV/cm and -6.4 MV/mc, respectively [9]. importance of controlling the tunnel oxide thickness and the trap density in
the silicon nitride films. The 1.8-nm tunnel oxide device has a faster speed
than the 2-nm tunnel oxide device.
3
f
p
s
cn
c
9K
0 -1
10
Programming Time, (seconds)
Fig. 7. Comparison of the erasdwrite measurement with our analytical model 1 1 1
given the initial electric field is 7.46 MV/cm for the write curve and -6.4
MV/cm for the erase curve (SONOS 1 , L'p 5 V). Our analytical model agrees
with the measured data except for large programming times, when additional Fig. 9. Retention measurement of SONOSl (1.8-nm tunnel oxide, 5-nm
low-field tunneling mechanisms become important [9]. nitride, and 4-nm blocking oxide) demonstratingten-year retention for a 0.1-V
detection window, f 9-V programming voltage, write time, and I-ms
erase time [16].
Given W 140pm, L 100pm, IDS 100 pA, and
pejf 400 cm2 V-ls-l we calculate the initial electric a 50-ps write and a 1-ms erase time to obtain the same 2.5-
field across the tunnel oxide to be 7.15 MVkm for the write V memory window as Nozaki et al. Furthermore, the 1.8-nm
characteristic and -6.56 MVkm for the erase characteristic. tunnel oxide transistor can achieve ten-year retention given
Comparing the measurements from SONOS 1 with our closed- a 0.1-V detection window, f 9 V programming voltage,
form analytical model, we find close agreement except for 100 write, and 1-ms erase time (see Fig. 9). Excellent
large pulse widths when the electric field in the tunnel oxide endurance characteristics (greater than lo6 cycles) for scaled
is less than 6.25 MV/cm (see Fig. 7). This deviation is due SONOS devices have already been demonstrated by previous
to the addition of another tunneling mechanism, trap-assisted investigators [18], [22]. Thus, this scaled device can be used
tunneling, which occurs only at low fields [2], [3], and is in a semiconductor disk, NVRAM, and neural network.
neglected in our closed-form solution. Still, a desire exists to scale the programming voltage
To guarantee reliability, the nonvolatile memory device below 9 V. We have studied two different cases, 1) scaling
must be scaled along with the CMOS peripheral circuitry. the tunnel oxide thickness and 2) scaling the blocking oxide
Nozaki et al. have reported a f 9 V programmable SONOS thickness in order to investigate the limits of scaling SONOS
memory transistor with a 100-ps write time and a 10-ms microstructures. First, we have decreased the tunnel oxide
erase time [18]. Typically, Flash floating gate EEPROM's thickness from 1.8 nm (SONOS1) to 1.1 nm (SONOS2). Fig.
program in lops or less [14], [l]. We have scaled the SONOS 10 illustrates a comparison between the measured erase/write
microstructure from a 2-nm to a 1.8-nm tunnel oxide, and characteristics of SONOSl and SONOS2. From our analysis,
Fig. 8 illustrates the comparison of our device measurements a reduction in the tunnel oxide thickness is manifested in a
with the measurement results published by Nozaki et al. [3], decrease in the tum-on time (see (8)). Examining Fig. 10, we
[13]. Both device structures have a 5-nm silicon nitride storage observe a reduced tum-on time from 71 50 for SONOSl
layer and a 4-nm blocking oxide. We can see the importance to 7 2 10 for SONOS2.
of controlling the tunnel oxide thickness and the trap density Previous MNOSBONOS scaling scenarios keep the
in the silicon nitride film since our devices can operate with electric field across the tunnel oxide or nitride nearly constant
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FRENCH et al.: DESIGN AND SCALING OF A SONOS MULTIDIELECTRIC DEVICE 395
0.4 detection
window
f5
anmtunneloxide
nmtunneloxide
.I nm tunnel oxide 1.8 nm tunnel oxide The retention characteristics of SONOSl and SONOS2 are
programming programming
1 shown in Fig. 12 given a 5-V programming voltage and a 10-s
d
' erase and write time. The major difference between the two
devices is the onset of memory loss at 100 p s for the erase state
of the 1.1-nm tunnel oxide (SONOS2) in contrast with the 10-
ms comer for the 1.8-nm tunnel oxide (SONOSl), resulting
in a difference of two orders of magnitude due to the 0.7-nm
reduction in the tunnel oxide thickness. This difference is due
to an increase in back tunneling for the 1.1-nm tunnel oxide
over the 1.8-nm tunnel oxide. Thus, there is a tradeoff between
-2 the erase/write speed and memory retention in conventional,
scaled SONOS device structures. The reduction in memory
retention is manifested by a decrease in memory "sense"
Fig. Erase/write measurement of the 1.1-nm tunnel oxide device and window for long retention times. Given a 0.4-V detection
the 1.8-nm tunnel oxide device with a constant tunnel oxide electric field. By window, SONOSl retains the memory window for four days
scaling the tunnel oxide thickness 7 nm, we can decrease the programming
voltage from V to 8 V and reduce the erase time from 10 ms to 1 ms while while SONOS2 keeps the window for one hour. The 1.1-nm
maintaining a constant write speed. ultrathin tunnel oxide device (SONOS2) may no longer meet
the stringent retention requirements for the semiconductor
disk application but may be utilized in NVRAM's or neural
while the triple dielectric dimensions are scaled [ l l ] , [171.
networks. Other scaling approaches should be explored for
Therefore, we can compare devices with different tunnel oxide
applications which require extended retention times.
thicknesses using constant tunnel oxide electric field criteria.
Clearly there is room for further improvement in retention.
We have already examined the erase/write characteristics
Various methods of improving the retention characteristics
for a 9-V programming voltage on the 1.8-nm tunnel oxide
in MNOS/SONOS structures have been studied by previous
device in comparison to the SONOS transistors from Nozaki
researchers. Hu and White have used a buried channel structure
et al. (see Fig. 8). Assuming zero stored nitride charge, the
instead of a surface channel structure to eliminate the charge
initial electric field across the tunnel oxide is given by
back tunneling [23]. Severals investigators have examined the
VP possibility of tailoring the nitride traps by using a graded
E,,(O) nitride [15] or an oxynitride [21]. Finally, Maes et al. have
Xeff
incorporated a hydrogen anneal to reduce the interface trap
For the 1.8-nm tunnel oxide device (SONOSl) at a 9-V pro- density and improve the retention [5], [7]. We are in the
gramming voltage, the initial tunnel oxide field is 10.2 MV/cm. process of incorporating several of these methods on our
Thus, the programming voltage for the 1.1-nm tunnel oxide scaled SONOS structures to obtain fast erase/write times, low
device (SONOS2) should be 8 V to maintain a constant electric programming voltages, and improved retention and endurance
field across the tunnel oxide. When comparing the eraselwrite characteristics.
measurements for the two different tunnel oxide thicknesses Another alternative to scaling is to decrease the blocking
with the same tunnel oxide electric field, the speed of SONOS2 oxide thickness. The tum-on time is reduced from 71 10
is slightly faster than SONOSl (see Fig. 11) for a given to 7 2 1 p s by decreasing the blocking oxide thickness from 4
memory window. Thus, we can decrease the programming nm for SONOS2 to 3.3 nm for SONOS3 (see Fig. 13) since the
voltage from 9 V to 8 V and maintain the programming speed initial turn-on time, is smaller for a thinner blocking oxide
by scaling the tunnel oxide thickness 0.7 nm. thickness (see (8)). However, a smaller memory window is
r---
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396 IEEE TRANSACTIONS ON COMPONENTS, PACKAGING, AND MANUFACTURING TECHNOLOGY-PART A, VOL. 17, NO. 3, SEPTEMBER 1994
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FRENCH al.: DESIGN AND SCALING OF A SONOS MULTIDIELECTRIC DEVICE 391
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