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Raspite

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Photos of Raspite (169)
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Raspite

Broken Hill Proprietary Mine, Broken Hill, Broken Hill district, Yancowinna Co.,
New South Wales, Australia
09083890014948298259962.jpg
Raspite, etc.

Le Mazet vein, �chassi�res, Vichy, Allier, Auvergne-Rh�ne-Alpes, France


01323100014977627755112.jpg
Raspite, etc.

Les Montmins Mine, �chassi�res, Vichy, Allier, Auvergne-Rh�ne-Alpes, France


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About RaspiteHide
04030750014946990611220.jpg
Charles Rasp
Formula:Pb(WO4)Colour:Pale yellow, yellowish brown, gray,
colorlessLustre:AdamantineHardness:2� - 3Specific Gravity:8.46Crystal
System:MonoclinicMember of:Scheelite GroupName:Named after Mr. Charles Rasp (1846-
1907), German-Australian prospector, and discoverer of the Broken Hill deposit.Type
Locality:? Broken Hill Proprietary Mine (Proprietary Mine; BHP Mine), Broken Hill,
Broken Hill district, Yancowinna Co., New South Wales, AustraliaDimorph of:Stolzite
The monoclinic dimorph of stolzite. Heating of raspite to 395(5)�C leads to a
transformation into stolzite.

A rare secondary mineral occurring in the oxidized zones of tungsten-bearing


hydrothermal base metal deposits.

An unusual Te-rich variety is described by Andrade et al. (2014).

Classification of RaspiteHide
IMA status:Approved, 'Grandfathered' (first described prior to 1959)
Strunz 8th ed.:6/G.01-50
Nickel-Strunz 10th (pending) ed.:4.DG.20

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites,


sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
G : With large (+- medium-sized) cations; chains of edge-sharing octahedra
Dana 8th ed.:48.1.4.1

48 : ANHYDROUS MOLYBDATES AND TUNGSTATES


1 : AXO4
Hey's CIM Ref.:27.4.9

27 : Sulphites, Chromates, Molybdates and Tungstates


4 : Tungstates
Physical Properties of RaspiteHide
Lustre:Adamantine
Transparency:Transparent
Colour:Pale yellow, yellowish brown, gray, colorless
Hardness:2� - 3 on Mohs scale
Cleavage:Perfect
Perfect {100}
Density:8.46 g/cm3 (Measured) 8.45 g/cm3 (Calculated)
Optical Data of RaspiteHide
Type:Biaxial (+)
RI values:na = 2.270 n� = 2.270 n? = 2.300
Max Birefringence:
d = 0.030
Image shows birefringence interference colour range (at 30�m thickness)
and does not take into account mineral colouration.
Surface Relief:Very High
Dispersion:relatively strong
Chemical Properties of RaspiteHide
Formula:Pb(WO4)
Elements listed:O, Pb, W - search for minerals with similar chemistry
Crystallography of RaspiteHide
Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:P21/b
Setting:P21/a
Cell Parameters:a = 13.555 �, b = 4.976 �, c = 5.561 �
� = 107.63�
Ratio:a:b:c = 2.724 : 1 : 1.118
Unit Cell V:357.47 ų (Calculated from Unit Cell)
Z:4
Morphology:Crystals typically tabular, flattened on {100}, which is striated
parallel [010], and somewhat elongated parallel [010]; also elongated [100] or thin
tabular {101}.
Twinning:Common on {100}; also on {102}.
Crystallographic forms of RaspiteHide
Crystal Atlas:
Click on an icon to view

Raspite no.1 - Goldschmidt (1913-1926)

Raspite no.2 - Goldschmidt (1913-1926)

Raspite no.4 - Goldschmidt (1913-1926)


{100}, {001}, {011}, modified
Locality: Broken Hill, New South Wales, Australia
Hlawatsch, 1897. In: V.M. Goldschmidt, Atlas der Krystallformen, 1913-1923.

3D model ID: 24453d models and HTML5 code kindly provided by www.smorf.nl.

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Crystal StructureHide
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an
AMCSD ID to view structure
ID Species Reference Link Year Locality Pressure (GPa) Temp (K)
0009580 Raspite Fujita T, Kawada I, Kato K (1977) Raspite from Broken Hill
Acta Crystallographica B33 162-164 1977 Broken Hill NSW, Australia 0
293
X-Ray Powder DiffractionHide
Powder Diffraction Data:
d-spacing Intensity
3.619 � (55)
3.593 � (20)
3.478 � (20)
3.224 � (100)
2.760 � (60)
2.705 � (55)
1.812 � (25)
Geological EnvironmentHide
Geological Setting:Secondary oxidation zone of tungsten containing ores.
Type Occurrence of RaspiteHide
Type Locality:? Broken Hill Proprietary Mine (Proprietary Mine; BHP Mine), Broken
Hill, Broken Hill district, Yancowinna Co., New South Wales, Australia
Place of Conservation of Type Material:
Natural History Museum, Vienna, Austria: #G6263.
Other Language Names for RaspiteHide
German:Raspit
Russian:??????
Simplified Chinese:????
Spanish:Raspita
Relationship of Raspite to other SpeciesHide
Member of:Scheelite Group
Other Members of this group:
Powellite Ca(MoO4) Tet. 4/m : I41/a
Scheelite Ca(WO4) Tet. 4/m : I41/a
Stolzite Pb(WO4) Tet. 4/m : I41/a
Wulfenite Pb(MoO4) Tet. 4/m : I41/a
Common AssociatesHide
Cuprotungstite Cu2(WO4)(OH)2
Hydrokenoelsmoreite ?2W2O6(H2O)
Stolzite Pb(WO4)
Yttrotungstite-(Y) YW2O6(OH)3
Associated Minerals Based on Photo Data:
51 photos of Raspite associated with Stolzite Pb(WO4)
19 photos of Raspite associated with Alunite Supergroup AD3(XO4)2(OH)6
7 photos of Raspite associated with Copper-bearing Scheelite (Ca,Cu)WO4
4 photos of Raspite associated with Carminite PbFe3+2(AsO4)2(OH)2
3 photos of Raspite associated with Strengite FePO4 � 2H2O
3 photos of Raspite associated with Mimetite-Pyromorphite Series
2 photos of Raspite associated with Cuprotungstite Cu2(WO4)(OH)2
2 photos of Raspite associated with Limonite (Fe,O,OH,H2O)
2 photos of Raspite associated with Goethite a-Fe3+O(OH)
2 photos of Raspite associated with Pyromorphite Pb5(PO4)3Cl
Related Minerals - Nickel-Strunz GroupingHide
4.DG.05 Euxenite-(Y) (Y,Ca,Ce,U,Th)(Nb,Ta,Ti)2O6 Orth. mmm (2/m 2/m 2/m)
4.DG.05 Fersmite (Ca,Ce,Na)(Nb,Ta,Ti)2(O,OH,F)6 Orth. mmm (2/m 2/m
2/m) : Pbcn
4.DG.05 Kobeite-(Y) (REE,Fe,U)3 Zr(Ti,Nb)3 O12 Iso.
4.DG.05 Loranskite-(Y) (Y,Ce,Ca)ZrTaO6 (?)
4.DG.05 Polycrase-(Y) Y(Ti,Nb)2(O,OH)6 Orth. mmm (2/m 2/m 2/m)
4.DG.05 Tanteuxenite-(Y) Y(Ta,Nb,Ti)2(O,OH)6 Orth. mmm (2/m 2/m 2/m) :
Pbcn
4.DG.05 Uranopolycrase (U4+,Y)(Ti,Nb)2O6 Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DG.05 Yttrocrasite-(Y) (Y,Th,Ca,U)(Ti,Fe)2(O,OH)6 Amor.
4.DG.10 Fergusonite-(Y)-� YNbO4 Mon. 2/m
4.DG.10 Fergusonite-(Nd)-� (Nd,Ce)NbO4
4.DG.10 Fergusonite-(Ce)-� CeNbO4
4.DG.10 Yttrotantalite-(Y) (Y,U4+,Fe2+)(Ta,Nb)(O,OH)4 Orth.
4.DG.10 Beta-Fergusonite-(Nd) (Nd,Ce)NbO4
4.DG.15 Foordite Sn2+(Nb,Ta)2O6 Mon. 2/m : B2/b
4.DG.15 Thoreaulite (Sn2+,Pb)(Ta,Nb)2O6 Mon.
Related Minerals - Hey's Chemical Index of Minerals GroupingHide
27.4.1 Cuprotungstite Cu2(WO4)(OH)2 Tet. 4 2 2 : P41 21 2
27.4.2 Scheelite Ca(WO4) Tet. 4/m : I41/a
27.4.4 Anthoinite AlWO3(OH)3 Tric. 1
27.4.5 Mpororoite WAlO3(OH)3 � 2(H2O) Tric.
27.4.6 Yttrotungstite-(Y) YW2O6(OH)3 Mon. 2/m : P21/m
27.4.7 Yttrotungstite-(Ce) (Ce,Nd,Y)W2O6(OH)3 Mon. 2 : P21
27.4.8 Stolzite Pb(WO4) Tet. 4/m : I41/a
27.4.10 Russellite Bi2WO6 Orth.
27.4.11 Pinalite Pb3WO5Cl2 Orth.
27.4.12 Uranotungstite (Fe2+,Ba,Pb)(UO2)2(WO4)(OH)4 � 12H2O Orth.
27.4.13 H�bnerite MnWO4 Mon. 2/m : P2/b
27.4.14 Ferberite FeWO4 Mon. 2/m : P2/b
27.4.15 Wolframite (Fe2+)WO4to (Mn2+)WO4 Mon. 2/m : P2/b
27.4.16 Ferritungstite Iso. m3m (4/m 3 2/m) : Fd3m
27.4.17 Phyllotungstite (H2O,M)x(W,Fe)(O,OH)3 � yH2O (M = Ca, Cs, Pb or K)
Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
27.4.18 Qitianlingite (Fe,Mn)2(Nb,Ta)2WO10 Orth.
Other InformationHide
Thermal Behaviour:Inverts to Stolzite above 410�C.
Notes:Decomposed by HCl with separation of yellow tungstic acid.
Health Risks:No information on health risks for this material has been entered into
the database. You should always treat mineral specimens with care.
References for RaspiteHide
Reference List:Sort by Year (asc) | by Year (desc) | by Author (A-Z) | by Author
(Z-A)
Hlawatsch, C. (1897): Ueber den Stolzit und ein neues Mineral �Raspit von
Brokenhill. Annalen des kaiserlich-k�niglichen naturhistorischen Hofmuseums 12, 33-
41. [http://www.landesmuseum.at/pdf_frei_remote/ANNA_12_0033-0041.pdf]
Hlawatsch (1898) Zeitschrift f�r Kristallographie, Mineralogie und Petrographie,
Leipzig: 29: 137.
Hlawatsch (1899) Zeitschrift f�r Kristallographie, Mineralogie und Petrographie,
Leipzig: 31: 8.
Hussak (1903) Centralblatt f�r Mineralogie, Geologie und Paleontologie, Stuttgart:
723.
Hlawatsch (1905) Centralblatt f�r Mineralogie, Geologie und Paleontologie,
Stuttgart: 423.
Hlawatsch (1907) Zeitschrift f�r Kristallographie, Mineralogie und Petrographie,
Leipzig: 42: 587.
Jaeger and Germs (1921) Zeitschrift f�r anorganische und allgemeine Chemie,
Hamburg, Leipzig: 119: 145.
Larsen, E.S. (1921) The Microscopic Determination of the Nonopaque Minerals, First
edition, USGS Bulletin 679: 125.
Jung (1931) Jb. Min., Beil.-Bd.: 64A: 197.
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James
Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John
Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 1089-
1090.
Fujita, T., I. Kawada, and K. Kato (1977) Raspite from Broken Hill. Acta
Crystallographica: B33, 162�164.
Andrade, M.B., Yang, H., Downs, R.T., Jenkins, R.A., Fay, I. (2014): Te-rich
raspite, Pb(W0.56Te0.44)O4, from Tombstone, Arizona, USA: the first natural example
of Te6+ substitution for W6+. American Mineralogist, 99, 1507�1510. [includes
crystal-structure refinement of also a pure raspite]
Zeitschrift f�r Kristallographie: 29: 137.
Internet Links for RaspiteHide
mindat.org URL:https://www.mindat.org/min-3368.html
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Raman and XRD data at RRUFF project
References and PDF downloads at RRUFF project
American Mineralogist Crystal Structure Database
Handbook of Mineralogy page PDF
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