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two
In silicon dioxide, each silicon atom is bonded with three oxygen atoms.
four
ionic.
metallic.
(2)
(b)
© Oleksiy Mark/iStock
Suggest why.
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(1)
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(c) Nanowires can be made from silicon dioxide.
brittle.
thin.
(1)
(Total 4 marks)
Q2. The picture shows a student filling in a multiple choice answer sheet using a pencil.
© Cihan Ta?k?n/iStock
The pencil contains graphite. Graphite rubs off the pencil onto the paper.
(a) Use the diagrams to help you explain why graphite can rub off the pencil onto the paper.
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(2)
(b) Draw a ring around the type of bond which holds the atoms together in each layer.
(a) Use the Chemistry Data Sheet to help you to answer this question.
In which group of the periodic table are lithium and sodium? Group
(1)
(iii) Use the correct answer from the box to complete the sentence.
3 4 7
(1)
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(c) Sodium reacts with chlorine to produce sodium chloride.
gaining
sharing
(1)
a negative
a positive
(1)
covalent
(iii) The ions in sodium chloride are held together by strong electrostatic forces.
magnetic
(1)
Property Tick ( )
Strong bonds
(2)
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(e) (i) The formula of sodium chloride is NaCl
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(ii) Draw a ring around the correct answer to complete each sentence.
ion
mole
(1)
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(1)
(Total 12 marks)
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Q4. Silicon dioxide is used as a lining for furnaces.
© Oleksiy Mark/iStock
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(Total 4 marks)
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Q5. Oil rigs are used to drill for crude oil.
© Digital Vision/Photodisc
The diagrams show the particles in the alloy and in pure iron.
Use the diagrams to explain why the alloy is harder than pure iron.
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(2)
Reason Tick ( )
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(c) Methane gas is often found where crude oil is found.
The diagram shows how atoms bond in methane.
Only the outer electrons are shown.
(i) Draw a ring around the correct answer to complete the sentence.
a compound.
Methane is an element.
a mixture.
(1)
(ii) Draw a ring around the correct answer to complete each sentence.
C4H4
CH4
(1)
(iii) Name the type of bond between the carbon and hydrogen atoms in methane.
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(1)
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(2)
(Total 9 marks)
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Q6. This question is about the planet Mars.
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giant lattices.
simple molecules.
(1)
(b) Many spacecraft have been sent to Mars. Parts of these spacecraft are made from
polymers.
(i) Polymers that behave like shape memory alloys are used in spacecraft.
The shape memory polymers are cooled and compressed. These polymers are
stored on the spacecraft until needed.
Suggest how the polymers could be made to return to their original shape.
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(1)
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(ii) Thermosetting polymers are used for the tiles on the outside of spacecraft.
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(2)
(c) Instrumental methods such as GC−MS are used to analyse substances found on Mars.
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(1)
(ii) Give two reasons for using instrumental methods for analysis.
1 ...............................................................................................................
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2 ...............................................................................................................
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(2)
(Total 7 marks)
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Q7. Scientists have recently developed a method to produce large sheets of a substance called
graphene.
Graphene is made from carbon and is a single layer of graphite just one atom thick.
• it conducts electricity
Use your knowledge of the bonding in graphite and the photograph of the structure to help you to
explain, as fully as you can:
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(3)
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(ii) why graphene conducts electricity.
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(2)
(b) Suggest why a sheet of graphite which has a large number of carbon layers would not be
suitable for the touchscreen.
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(1)
(Total 6 marks)
Q8. Pure carbon can exist in two forms, diamond and graphite.
(a) Complete the diagram to show the electronic structure of a carbon atom.
(1)
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(b) A drill bit is used to cut holes through materials. The cutting end of this drill bit is covered with very
small diamonds.
(i) What property of diamond makes it suitable for use on the cutting end of a drill bit?
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(1)
(ii) Explain, as fully as you can, why diamond has this property. Use your knowledge of
the structure and bonding of diamond and the information shown opposite to help
you to answer this question.
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(3)
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(c) Explain why graphite is a good conductor of electricity and why diamond does not conduct
electricity.
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(3)
(Total 8 marks)
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Q9. The picture shows a copper kettle being heated on a camping stove.
(a) Explain why copper, like many other metals, has a high melting point.
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(4)
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(b) Aeroplanes contain many miles of electrical wiring made from copper. This adds to the
mass of the aeroplane.
It has been suggested that the electrical wiring made from copper could be replaced by
carbon nanotubes which are less dense than copper.
(i) What does the term ‘nano’ tell you about the carbon nanotubes?
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(1)
(ii) Like graphite, each carbon atom in the carbon nanotube is joined to three other
carbon atoms.
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(2)
(Total 7 marks)
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Q10. Spacecraft have been to the planets Venus and Mars. The spacecraft have sent back
information about the atmosphere of each planet.
© Tristan3D/Shutterstock
Explain why, in terms of structure, carbon dioxide is a gas, even at low temperatures.
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(3)
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(1)
(ii) What information do the molecular ion peaks from the mass spectrometer give about
the substances?
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(1)
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(c) The atmosphere on Venus contains droplets of sulfuric acid solution.
pH = ...........................
(1)
(ii) Name the ion which makes sulfuric acid solution acidic.
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(1)
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(3)
(Total 10 marks)
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Q11. Read the article and then answer the questions.
Nanotennis!
Tennis balls contain air under pressure, which gives them their bounce. Normal
tennis balls are changed at regular intervals during tennis matches because they
slowly lose some of the air. This means that a large number of balls are needed for a
tennis tournament.
© Feng Yu/iStock
‘Nanocoated’ tennis balls have a ‘nanosize’ layer of butyl rubber. This layer slows
down the escape of air so that the ball does not lose its pressure as quickly. The
‘nanocoated’ tennis balls last much longer and do not need to be replaced as often.
Description Tick ( )
(b) Suggest two ways in which using ‘nanocoated’ tennis balls would be good for the
environment.
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(2)
(Total 3 marks)
Page 19 of 36
Q12. Graphite and diamond are different forms of the element carbon.
Graphite and diamond have different properties.
Graphite Diamond
Explain why.
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(4)
Explain why.
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(3)
(Total 7 marks)
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Q13. Read the information
Graphene
Graphene Graphite
Use the information above and your knowledge of graphite to answer the questions.
(iii)
2 3 4
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(b) This part of the question is about graphite.
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(2)
(Total 5 marks)
Describe and explain how the bottles can be changed into new plastic objects.
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(Total 4 marks)
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Q15. Oil rigs are used to drill for crude oil.
© Digital Vision/Photodisc
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(3)
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(4)
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(c) Polymers are produced from crude oil.
Describe the structure and bonding in a thermosoftening polymer and explain why
thermosoftening polymers melt when heated.
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(4)
(Total 11 marks)
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M1. (a) four
1
covalent
1
(c) thin
1
[4]
or
(b) covalent
1
[3]
(ii) neutrons
1
(iii) 7
1
(ii) a positive
1
(iii) electrostatic
1
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(d) high melting points
1
strong bonds
1
(ii) mole
1
1-100nm in size or
Page 26 of 36
diamonds have strong bonds between carbon atoms
1
(ii) CH4
1
(iii) covalent
1
• quick / rapid
• accurate
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M7. (a) (i) ionic / molecules / metallic / (inter)molecular = max 2
because one (delocalised / free) electron per atom linked to first marking point
accept because three electrons per atom used (in bonding)
accept because one electron per atom not used (in bonding)
1
or layers slide
or layers not aligned
ignore thick
1
[6]
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(ii) any three from
max 2 if ionic / metallic / molecule / intermolecular bonds or
incorrect number of bonds
• covalent (bonds)
or
Page 29 of 36
(c) any three from:
max 2 if ionic / ions / metallic / molecule
‘it’ needs to be qualified
graphite
or
or
diamond
or
or
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so a lot of energy is needed to break these bonds / attractions / forces
ignore high temperature
ignore heat
1
or
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(ii) hydrogen
allow H+
ignore H / H2 / H–
1
2
• H has one neutron
1
• H has no neutrons
accept different mass number or different number of neutrons for 1
mark
ignore relative atomic mass
• less energy
• less fuel
• less waste
ignore references to cost / recycling
2
[3]
because the layers (of carbon atoms) in graphite can move / slide
it = graphite
1
this is because there are only weak intermolecular forces or weak forces between layers
accept Van der Waals’ forces allow no covalent bonds between
layers
1
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Diamond:
(ii) carbon
two different answers indicated gains 0 marks
1
(iii) 3
two different answers indicated gains 0 marks
1
Page 33 of 36
M14. heat
1
M15. (a) because atoms / ions / particles in alloy are different (sizes)
do not allow reference to molecules
ignore reference to compounds
1
so layers distorted
(and layers / atoms / ions / particles) don’t slide or slide less easily
accept all marking points in a suitably labelled or annotated
diagram
1
covalent (bonds)
1
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with intermolecular forces or forces between chains
allow bonds for forces accept no cross-links
1
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Page 36 of 36