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Dr. A. K. Mullick
Former Director General, Durability Provisions in
NCBM, New Delhi,
IRC: 112
E-maiI – ajoy_mullick@rediffmail.com
IABSE Workshop on
IRC: 112,
MMRDA Auditorium,
Mumbai,
19 November 2016
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Corrosion of Reinforcement
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Effect of carbonation
• Atmospheric CO2 is converted to carbonic acid (H2CO3) in the Quick test for depth
presence of moisture,
of carbonated
• H2CO3 attacks Ca(OH)2 in hydrated cement paste; this is concrete using solution
called carbonation.
of phenolphthalein
H2CO3 + Ca(OH)2 = CaCO3 + 2H2O in dilute alcohol;
• Because of consumption of Ca(OH)2, carbonation lowers the
pH value of concrete and reduces the protection to steel by Carbonated portion
the alkalinity of the surrounding medium.
turns colourless, i.e.
• If carbonation is very high, the pH can be as low as 8.
natural colour.
• Carbonation is not significant when the pores of concrete are
saturated, because of slow rate of diffusion of CO2 in water
compared to that in air. On the other hand, if there is Carbonated portion will
insufficient water in the pores, CO2 remains in gaseous form have magenta colour.
and does not react with the hydrated cement.
• The highest rate of carbonation occurs at a relative humidity
of 50 to 70 percent.
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Effect of silica
D at 28 days vrs. w/b
fume
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Tests on concrete
[Cl. 18.5.4(1)]
• Samples from fresh concrete shall be taken as per IS
1199 and tested for workability.
• Cubes shall be made, cured and tested for
compressive strength at 28 days in accordance with
IS 516.
• Tests for compressive strength at earlier ages when
required.
• Other tests like density, chloride content, flexural
strength or tests for durability (RCPT), as specified in
QA plan.
Thank
Thank
You
you
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