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MOCK NET – CHEMISTRY

1. No. of P – O bonds in solid phosphorous trioxide
(A) 9 (B) 12 (C) 15 (D) 3

2. Product of the reaction 3NaBH4 + 2BF3 ---

(A) B2H6 + NaBF4 (B) BH2F + H2 (C) B2H6 + H2 (D) H2 + BH3

3. Which of the following is best Fluorinating agent

(A) XeF2 (B) XeF4 (C) XeF6 (D) XeO2F2

4. Perxenate ion can be represented as

(A) [XeO6]–4 (B) [XeO4]–2 (C) [XeO3]–3 (D) [XeOF4]–2

5. The octahedral crystal field splitting energy ( ∆ 0 ) of d orditals of the following metal ions decreases in the order
(A) Co2+ > Co3+ > Rh3+ (B) Rh3+ > Co3+ > Co2+
(C) Rh3+ > Co2+ > Co3+ (D) Co3+ > Co2+ > Rh3+
6. The unit of the wave function ψ of a hydrogen atom is :
(A) L3 (B) L–3 (C) L–3, 2 (D) dimensionless
Here, L represents length.

7. The orbital angular momentum (in units of h/2π; where h is the Planck’s constant) of an electron in the 3d orbital
is
(A) 2 (B) 3 (C) 21/2 (D) 61/2

8. The result of the reduction of either (R) or (S) 2-methylcycyclohexanone, in separate reactions, using LiAlH4 is
that the reduction of
(A) the R enantiomer is stereoselective (B) the R enantiomer is sterespecific
(C) the S enantiomer is stereospecific (D) both the R and S enantiomers is stereoselective

9. Which of the following statement is correct?

(A) In living organism, circulation of 14C from atmosphere is high so that carbon content is constant in organism.
(B) Carbon dating can be made to find out the age of earth curst and rocks.
(C) Radioactive absorption due to cosmic radiation is equal to the rate of radioactive decay, hence the carbon
content remains constant in organism.
(D) Carbon dating can not be used to determine concentration of 14C in dead being.
10. The activity of a radioactive substance is R0 at t = 0; R1 at t = t and R2 at t = 2t. The decay constant of this
species cannot be given by
loge R1 − logR2 loge R0 − loge R1
(A) (B)
t t
loge R2 − loge R1 loge R0 − loge R2
(C) (D)
2t 2t
11. What is left if chloroplast is burnt?
(A) Mg (B) Mn (C) Fe (D) S
12. Mo deficiency causes
(A) Wilting (B) Increase in growth (C) Chlorosis (D) Necrosis and molting

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13. The molecules (s) that exist as meso structure (s)

(K) (L) (M)

is/are
(A) only M (B) both K and L (C) only L (D) only K

14. The compound is known by which of the following names:-

(A) Bicyclo-[2, 2, 2] octane (B) Bicyclo-[2, 2, 1] octane
(C) Bicyclo-[1, 2, 1] octane (D) Bicyclo-[1, 1, 1] octane

15. The number of stereo isomers that are possible for the following compound is
+
H C O O C N –: – – – C -H X
5 2 6 5

(A) 1 (B) 2 (C) 3 (D) 4

16. The hydrogen atoms Ha and Hb in the given allene are

H b
H
––

C = C = C
––

C 3H
H 3 C
(A) Enantiotopic (B) Homotopic (C) Diastereotopic (D) None

17. Huckel’s rule for aromaticity is followed by

(1) C10H10 (2) C12H12 (3) C12H12–2 (D) C12H12+2
(A) 1, 3 (B) 1, 4 (C) 3, 4 (D) 2, 3

18. The aromatic species are

(1) C20H20 (2) C20H20– (3) C20H20–2 (4) C20H20+ (5) C20H20+2
(A) 3, 5 (B) 2, 4 (C) 2, 3, 4 (D) 1, 3, 5

19. Consider the 1H NMR spectrum of the following substance, which set of protons appears farthest downfield
relative to TMS ?

(A) a (B) b (C) c (D) bc

20. Which of the following substance does not give a 1H NMR spectrum consisting of only two peaks?

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(A) (B)

(C) (D) None of these (all satisfy the spectrum)

21. The multiplicity of the protons in the 1H NMR spectrum of the following substance is

(A) Singlet (B) Doublet (C) Triplet (D) Quartet

22. For a free radical polymerisation reaction, the kinetic chain length ‘γ’, is defined as the ratio
propagation rate initiation rate initiation rate propagation rate
(A) initiation rate (B) propagation rate (C) ter mination rate (D) ter mination rate

23. How many signals are expected in the 13C NMR spectrum of the following substance ?

(A) 5 (B) 6 (C) 8 (D) 10

24. The major product formed in the reaction of cyclopentadiene with a mixture of dichloroacetyl chloride and
triethylamine is

(A) (B) (C) (D)

NaNH2
 →
25. lip.NH3 +
The above reaction is an example of
(A) nucleophilic substitution of addition-elimination mechanism
(B) electrophilic substitution by addition-elimination mechanism
(C) radical substitution reaction
(D) nucleophilic substitution involving benzyne intermediate

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26. undergoes electrophilic substitution reaction preferentially

(A) at position 2 (B) at position 3 (C) at position 4 (D) at positions 2 and 4

27. Oxymercuration-demercuration reaction of 1-methylcyclohexene gives

(A) cis-2-methylcyclohexanol (B) trans-2-methylcyclohexanol
(C) 1-methylcyclohexanol (D) mixture of cis and trans-2-methylcyclohexanol

28. Sodium metal crystallizes in the body centered cubic lattice with cell edge a. The radius of the sodium atom is
a a 3 a 3 a
(A) 2 (B) 2 (C) 4 (D) 2 2

29. Which carbons of 1-chloro-4-fluorobenzene are the most shielded ?

(A) C - 1 (B) C - 3 and C - 5 (C) C - 2 and C - 6 (D) C - 4
30. A chlorinated derivative of benzene had only two peaks for aromatic carbons in its 13
C NMR spectrum. Of the
following, which compound can be eliminated on the basis of this information ?
C I
C I C I C I C I

C I C IC I C I C I C I
(A) (B) (C) (D)

31. The 13 C NMR spectrum of a C7H7CIO isomer has peaks for a methyl carbons. Which compound can you
exclude based solely on the number of peaks ?

O C3 H O C 3 CH I O C3 H

C I C I
(A) (B) (C)

32. A compound of molecular formula C6 H9 NO2 had peaks for its benzene ring carbons at δ 113.8, 119.3, 131.6,
and 151.4. No other peaks for benzene ring carbons were present. Which compound is most consistent with this
13
C NMR data?

(A) (B) (C) (D)

33. A compound of molecular formula C8 H2 CIO2 had peaks for its benzene ring carbons at δ 114.3, 125.3, 134.0,
and 165.5. other peaks for benzene ring carbons were present. Which compound is most consistent with the 13C
NMR data ?

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O O O O

C I C O 3 C H C 3 H O C C I C O 3 C H C C I

C I C 3 H O
(A) (B) (C) (D)

34. If the shortest wavelength of H atom in Lyman series is a then longest wavelength in balmer series of He+ is
9 36 a 5a
(A) a (B) a (C) (D)
5 5 4 9
35. Given than
 2 – r  – aor 1
∝ e
a 
ψn, l, m(r, θ, φ) = Rnl (r) Ylm(θ, φ); R20 (r)  0  ; Y0, 0(θ, φ) = 4π
The position of radial node in the 2s orbital is at
a0 a0
(A) r = a 0
(B) r = 2a 0
(C) r = 2 (D) r = 4

36. Which of the following relates to photons both as wave motion and as a stream of particles ?
(A) Interference (B) E = mc2 (C) Diffraction (D) E = hv

37. If the slope and intercept values for a Langmuir absorption process are 0.55 Pa cm–3 and 0.525 × 10–3 cm–1,
respectively, the value of adsorption coefficient (Pa–1) is
(A) 1,904 (B) 1.818 (C) 1 × 10–3 (D) 1.047 × 103
38. The absorption isotherm is defined as the dependence of
(A) surface coverage on the temperature at a fixed pressure
(B) surface coverage on the pressure at a fixed temperature
(C) surface coverage on the oxidation state of the surface material
(D) rate of a surface reaction on the pressure at a fixed temperature
39. Which option represent the general form of an equation of state
(A) P = f(T, V, n) (B) V = f(P, T, n) (C) T = f(P, V, n) (D) n = f(P, V, T)

40. For the reaction PCl3(g) + Cl2(g) → PCl5(g), if Kc at 250ºC is 26, Kp at 250ºC will be –
(A) 0.57 (B) 0.4 6 (C) 0.33 (D) 0.61
41. Steam reacts with iron at high temperature to give hydrogen gas and Fe 3O4(s). The correct expression for the
equilibrium constant is –
PH22 (PH 2 )4 (PH2 )4 [Fe3 O 4 ] [Fe3 O4 ]
(A) 2 (B) 4 (C) 4 (D)
PH2O (PH2 O ) (PH2 O ) [Fe] [Fe]

42. In a reaction A + B ˆˆ ˆˆ ˆˆˆ C + D, , the initial concentrations of A and B were 0.9 mol. dm–3 each. At equilibrium the
concentration of D was found to be 0.6 mol dm–3. What is the value of equilibrium constant for the reaction ?
(A) 8 (B) 4 (C) 9 (D) 3

43. Which of the following option is true about isothermal Joule-Thomson coefficient ?
−1  ∂H   ∂H 
(1) µ T = − CP µ (2) µ T = − CP µ (3) µ T =   (4) µ T =  
 ∂P T  ∂P H
( µ = Joule -momentum coefficient; µ T = Isothermal Joule -Thomson coefficient)

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(A) 1, 3 (B) 2, 4 (C) 1, 4 (D) 2, 3

44. Which of the following options are true about Joule -Thomson coefficient (µ)
(1) Positive value of µ implies that gas cools on expansion
(2) Real gases have non-zero value of µ
(3) Positive value of µ imples that gas heats-up on expansion.
(A) 1, 2 (B) 2, 3 (C) Only 2 (D) Only 1

45. Internal energy and pressure of a gas of unit volume are related as :
2 3 E
(A) P = E (B) P = E (C) P = (D) P = 2E
3 2 2

46. The rate of reaction A + B → Pr oducts is given by the equation r = k[A] [B]. If B is taken in large excess, the
order of the reaction would be
(A) 2 (B) 1 (C) 0 (D) unpredictable
47. For an endothermic reaction where ∆H represents the enthalpy of the reaction in kJ/ mol, the minimum value
for the energy of activation will be
(A) less than ∆H (B) zero (C) more than ∆H (D) equal to ∆H

48. The conductivity of 0.01 mol/dm3 aqueous acetic acid at 300K is 19.5 × 10 -5 ohm-1cm-1 and the limiting molar
conductivity of acetic acid at the same temperature is 390 ohm -1cm2mol-1. The degree of dissociation of acetic
acid
(A) 0.5 (B) 0.05 (C) 5 × 10-3 (D) 5 × 10-7

49. The standard reduction potentials, E0, for the half reactions are
Zn2+ + 2e − → Zn, E 0 = −0.76 V
Fe2 + + 2e − → Fe, E 0 = −0.41 V
The EMF for the cell reaction
Fe2 + + Zn → Zn 2+ + Fe is

(A) – 0.35 V (B) + 0.35 V (C) + 1.17 V (D) – 1.17 V

50. The ionization constant of a weak electrolyte is 25 × 10-6 while the equivalent conductance of its 0.01M solution
is 19.6 S cm2eq-1. The equivalent conductance of the electrolyte at infinite dilution (in S cm2eq-1) will be
(A) 250 (B) 196 (C) 392 (D) 384

Answer key
Question. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Answer. B A C A B C D D C C A D D A B B C A A B
Question. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Answer. A A C A D B C C C D C A A A B D D B A D
Question. 41 42 43 44 45 46 47 48 49 50
Answer. B D D A A B C B B C

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