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1. Which ion with a +2 charge has the electron configuration 1s2 2s2 2p6 3s2 3p6 3d10?
__ A. K
__ B. Si
X_ C. Zn
__ D. Ca
__ E. Ge
2. Which of the following elements has the lowest first ionization energy?
__ A. Be
__ B. Mg
X _ C. Ca
__ D. S
__ E. Si
3. Order the ions Na+1, Mg+2, and Al+3 in terms of increasing ionic radii.
__ A. Na+1, Mg+2, Al+3
__ B. Mg+2, Al+3, Na+1
__ C. Al+3, Na+1, Mg+2
X _ D. Al+3, Mg+2, Na+1
__ E. Na+1, Al+3, Mg+2
__ A. KCl
__ B. LiCl
__ C. KI
__ D. NaI
X _ E. LiF
CH141 – Fall 2016 – Exam 3 Page 2 of 5
Part II. Short Answers: You must show your work for full credit!
7. In one or two sentences, clearly explain why the 2s and 2p orbitals are the same energy in a
hydrogen atom, but different energies in a sodium atom.
In single electron systems (hydrogen), there is no shielding and the 2s and 2p are the same
energy.
In multi-electron systems (sodium), there is shielding and the 2s becomes lower energy than
the 2p.
8. Give the electron configuration for the following atoms and ions (condensed notation is OK).
10. a) In the space below, draw a Lewis structure for the nitrate ion (NO3-1) and assign formal
charges to all the atoms.
–1 –1
O +1 O
N
O
CH141 – Fall 2016 – Exam 3 Page 3 of 5
g) In the space below, draw all additional resonance structures for the nitrate ion.
–1 –1
O +1 O O O O O
N N N
O O O
i) Is nitrate polar? Why or why not? Clearly but briefly explain your answer. You may use words
and drawings.
No, nitrate is nonpolar. The ion has polar bonds but the bond dipoles cancel.
O O
N
O
CH141 – Fall 2016 – Exam 3 Page 4 of 5
F
H P H
Cl F
H
F
Molecular Geometry: (words only, you do not Molecular Geometry: (words only, you do not
have to draw the molecule in three dimensions) have to draw the molecule in three dimensions)
Idealized Bond Angle for H–P–H Idealized Bond Angle for F–Cl–F
109.5° 90°
12. a) Draw a molecular orbital (MO) diagram for H2–1 and include the number of electrons and their
spins in each MO (In other words, identify the MOs in the first quantum shell and the electrons in each of
these MOs). You do not have to draw pictures of the MOs.
σ∗ H–H
H1s H1s
σ H–H
b) Circle each of the following compounds that is stable (has a bond order greater than zero). Hint: use an
MO analysis like you did in part (a).
13. The reaction of ethylene (C2H4) with diazene (H2N2) affords ethane (C2H6) and nitrogen gas.
C 2H 4 + H 2N 2 à C 2H 6 + N2
H H H H H H
C C N N H C C H N N
H H H H
c) Using the bond enthalpies in the table below, calculate the enthalpy change (ΔHrxn°) for the reaction
above (assume the reaction is run at standard state).