For TOR Expansion Case.

1. Basic Information of the Project:

i Name & address of the project site KOHINOOR COLOURS PVT.

(Complete details with plot no. /Survey no., LTD.
Landmark etc.) Plot No. 7204&7205, GIDC,
Ankleshwar, Dist.: Bharuch.
ii Name of the applicant Mr. Hasmukh Dudhat
iii Address of correspondence KOHINOOR COLOURS PVT.
LTD.
Plot No. 7204&7205, GIDC,
Ankleshwar, Dist.: Bharuch.
iv Contact no. and e-mail ID of the Applicant Mo. No.:9327787799
Email: alpesh@kgimail.com
v Aerial distance of nearest Habitat (KM)
vi Longitude & latitude of the Project Site: Latitude: 21.616633
(4 corners of the site) Longitude: 73.040045
vii Category as per the Schedule to the EIA 5(f)
Notification 2006 i.e. 1 (d), 2(b), 5(f) etc.
viii Application of General Condition of EIA No
Notification 2006: i.e.
Ensure that
(1) Protected areas notified under the
wildlife (Protection) Act, 1972;
(2) CEPI areas
(3) Eco-sensitive areas and,
(4) Inter-state boundaries and International
Boundaries; are not located within 5 Km
or 10 Km (as the case may be) area
from the boundary of the proposed site.

2. Online application proposal no.:

3. Date of application for TOR:
4. Project status: Expansion
5. Product profile:

Sr. Name of the CAS no. Quantity End-use of

no. Products MT/MT product
Existing Proposed Total

1. Diethyl Meta Amino 91-68-9 8.0 50 58 Use as

Phenol Dyes
intermediat
e
2. N,N, Diethyl 97-20-1 0.0 20 20 Use as
Metanilic Acid Dyes
intermediat
e
3. Meta Amino 594-27-5 0.0 20 20 Use as
Phenol Dyes
intermediat
e
4. Rhodamine Liquid 64-19-7 0.0 50.0 50.0 Use as
(Minimum 10% To Dyes in
40% Maximum) Paper, ink
and/or etc.
Auramine O Liquid 2465-27-2 0.0 50.0 50.0 Use as
(Minimum 20% To Dyes in
50% Maximum) Paper, ink
etc.
5. Drying Of Wet --- 0.0 5.0 5.0 Use as
Cake Of Dyes dyes in
paper, Jute,
ink etc
6. Liquid Dyes From --- 0.0 20.0 20.0 Use as
Wet cake Of Dyes dyes in
paper, Jute,
ink etc
7. Repacking Of Dyes --- 0.0 10.0 10.0 Use as
And/or Pigments dyes in
plastic, ink
etc

The project falls under Category B project activity 5(f) as per the schedule of EIA Notification
2006.

6. Product wise Raw material consumption:

Sr. Name of the Name of the Raw CAS no. Quantity

no. Products Materials of the raw MT/Month
materials. Existing Proposed Total
1 DIETHYL
META AMINO
PHENOL
Metanilic Acid 121-47-1 12.00 75.00 87.00
Ethyl Chloride 75-00-3 12.00 75.00 87.00
Caustic Lye 1310-73-2 12.00 75.00 87.00
Potassium Hydroxide 1310-58-3 10.96 68.50 79.46
ICE 7732-18-5 39.20 245.00 284.20
Water 7732-18-5 54.88 343.00 397.88
M.L.Recovered Use --- 11.68 73.00 84.68
Hydrochloric Acid 7647-01-0 18.03 112.70 130.73
(HCL30%)

2 N,N, DIETHYL
METANILIC
ACID
Metanilic Acid 121-47-1 0.00 14.00 14.00
Ethyl Chloride 75-00-3 0.00 10.00 10.00
Caustic Lye 1310-73-2 0.00 10.00 10.00
Water 7732-18-5 0.00 13.00 13.00
3 META AMINO
PHENOL
Metanilic Acid 121-47-1 0.00 32.00 32.00
Caustic Lye 1310-73-2 0.00 15.00 15.00
Hydrochloric Acid 7647-01-0 0.00 7.00 7.00
ICE 7732-18-5 0.00 3.00 3.00
Water 7732-18-5 0.00 3.00 3.00
4 RHODAMINE
LIQUID
(MINIMUM
10% TO 40%
MAXIMUM)
Rhodamine 81-88- 0.00 5.00 to 5.00 to
B/Rhodamine Base 9/509-34- 20.00 20.00
2
Diethylene Glycol 111-46-6 0.00 0.00 to 0.00 to
37.25 37.25
Diethylene Glycol 111-90-0 0.00 0.00 to 0.00 to
Mono Ethyl Ether 7.50 7.50
Stabilizer --- 0.00 0.25 0.25
Acetic Acid/Methanol 64-19- 0.00 0.00 to 0.00 to
7/67-56-1 29.75 29.75
5 AURAMINE O
LIQUID
(MINIMUM
20% TO 50%
MAXIMUM)
Auramine O 2465-27-2 0.00 10.00 to 10.00 to
25.00 25.00
Stabilizer --- 0.00 0.25 0.25
Acetic Acid 64-19-7 0.00 24.75 to 24.75 to
39.75 39.75
6 DRYING OF
WETCAKE OF
DYES
Dye Wet Cake --- 0.00 5.75 5.75
7 LIQUID DYES
FROM
WETCAKE OF
DYES
Dye Wet Cake --- 0.00 8.10 8.10
Stabilizer --- 0.00 0.10 0.10
Acetic Acid 64-19-7 0.00 11.80 11.80
8 REPACKING
OF DYES
AND/OR
PIGMENTS
[ LIQUID /
DRY ]
Different types of --- 0.00 10.00 10.00
Dyes and/or Pigments

7. Compliance Status of the existing project:

Sr. Particulars Brief Information/ Details Remarks
No.
1  Earlier EC details Not applicable
 In case of EC not obtained,
Copy of CTE & CCA
obtained before 14.09.2006,
2 Compliance of EC Not applicable
3 Status of inspection by RO- Not applicable
MOEFCC, Bhopal.
4 Status of submission of half yearly Not applicable
 return to concern authorities
5 Compliance of existing CC &A Compliance report is attached
as Annexure-A.
6 Legal action/ Closure direction/SCN Three SCN Issued by the
etc. issued by GPCB Boardand compliance has
been done.
7 Any Public complaints No
8. Is there any litigation pending before No
any court of law against the Project?

8. Water, Air and Hazardous waste management:

Sr. Particulars Details

No.
A Total cost of Proposed Project Existing:157 Lacs
(Rs. In Crores): Proposed: 300 Lacs
Total: 457Lacs
(1) Capital cost for EMS (Environmental management System): 0.6Crores
Recurring cost towards the Environmental protection measures: 0.3Crores per annum.
B Total Plot area Existing:2000 sq. meter
(sq. meter) Proposed: NIL
Total: 2000 sq. meter
Green belt area, / Tree plantation area Existing: -35.sq. meter
(sq. meter) Proposed: 570 sq. meter
Total:- 605sq. meter
C Employment generatio
1. Direct Existing:15
Proposed:35
Total:50
2. Indirect Existing: 3
Proposed:6
Total:9
D Water
i Source of Water Supply GIDC
(GIDC, Bore Well, Surface water etc…)
Status of permission from the concern authority. GIDC permission letter is attachedas
Annexure – B.
ii Water consumption (KL/Day)
Sr. PURPOSE Consumption, KL/day
no.
Existing Proposed Total After Proposed expansion
1. Domestic 1.0 3.0 4.0
2. Industrial
a. Process 1.0 7.0 8.0
b. Boiler make 1.0 5.0 6.0
up
c. Cooling 0.0 1.0 1.0
make up
d. Washing 4.0 24.0 28.0
water
e. Any other – 0.0 2.0 2.0
Gardening
TOTAL [2] 6.0 39.0 45.0
 TOTAL 7.0 42.0 49.0
[1+2]
Note:**The total water consumption is included the condensate recovery quantity. The
condensate recovery will be done from the MEE system and the same will be utilised within the
plant premises.

iii Waste water generated (KL/Day)

Sr. PURPOSE Generation, KL/day

no. Existing Proposed Total after proposed expansion
1. Domestic 0.8 3.0 3.8
2. Industrial
a. Process 0.5 4.0 4.5
b. Boiler blow 0.0 0.5 0.5
down
c. Cooling 0.0 0.1 0.1
bleed off
d. Washing 4.0 23.0 27.0
water
e. Any other 0.0 0.0 0.0
scrubbing
TOTAL [2] 4.5 27.6 32.1
TOTAL 5.3 30.6 35.9
[1+2]

iv Treatment facility with ETP and/or MEE (Multi Effect Evaporator)

Capacity
(ETP, CETP, MEE, STP
etc.).
v Mode of Disposal & final Domestic :- Disposal through septic/soak pit system
meeting point Industrial: -[Existing]
For the existing production capacity, the generated waste water is
collected, treated into ETP, and then discharge to G.I.D.C. underground
drainage system and conveyed to FETP which ultimately leads to deep
sea for final disposal through BEAIL pipeline.
[Proposed]
For proposed expansion, there will be increase in the waste water
generation from the process and utility, washing sections and this
 generated waste water will be treated into ETP and then sent to Multi
Effect Evaporator, condensate water will be reuse within the plant
premises.Hence, for the proposed expansion, the generated additional
waste water will have zero discharge and there will not be any
increase in the consented discharge quantity.
Also, At present, unit has planned to install MEE for proposed
Expansion, However, in future as and when function of CETP in this
area will improved/installed and if GPCB will grant permission to
discharge effluent into CETP (ETL or Ankleshwar Waste Management
Limited or any other Common effluent treatment plant), mode of
disposal will be of CETP after getting its permission and Total
Quantity after proposed expansion will be 35.9 KL/Day.
vi Reuse/ Recycle details --------------
(KL/Day)
vii Details of rain water Not provided
harvesting
E Air (Existing and
Proposed)
i. Flue gas emission details Boiler and G.G.Set
No. of Boilers/TFHF/
Furnace/ DG sets etc.
with capacity viz. TPH,
Kcal/hr., KVA etc.

Sr. Source of Stack Name of Quantity of Types of APCM Emission

No. emission with Height the fuel fuel MT/hr. emission Standards
capacity e.g. (meter) & MT/day i.e. Air
Boiler Pollution
(8TPH)

Existing
1. Boiler 10 m Natural [90m3/day] PM < 150mg/Nm3
Gas
SO2 < 100 ppm
NO2 -- < 50 ppm

Proposed
1. Boiler [600 10 m Natural [400 PM Cyclone < 150mg/Nm3
Kg/Hr][2 Nos.] each Gas m3/Day.] Separator
SO2 < 100 ppm
and/or and/or +
Bio-coal [1.4MT/Day] NO2 Water < 50 ppm
Scrubber

2. G.G.Set (63KVA) 2m Natural [80 m3/Day] PM ------ < 150mg/Nm3

(Stand By) Gas
SO2 < 100 ppm
NO2 < 50 ppm

ii. Process gas i.e. Type of Pollution gases (SO2, HCl, NH3, Cl2, NOx etc.)
 (Existing and Proposed)

Sr. No. Source of Types of Stack/ APCM NAAQS (National Ambient Air
emission emission Vent Quality standards)
Height
(meter)
Existing
1. There shall be no any process gas emission from existing products.
Proposed
1. Blender 3m Bag filter PM < 150 mg/Nm3
Dryer 6m Bag filter PM < 150 mg/Nm3

iii. Fugitive emission details with its mitigation measures.

(Existing and Proposed)-Not applicable
F Hazardous Waste
(As per the Hazardous and other Wastes (Management and Transboundary Movement)
Rule 2016.
(Existing and Proposed)
i Sr. Name of Category Generation Per year Remarks
No. Hazardous as per
Waste HWM,2016
Consented Additional Total
1. Used Oil 5.1 0.0001 0.024 0.0241 Collection,
MT/year MT/year MT/year Storage,
Transportation
and sold to
authorized
Recyclers.
2. Discarded 33.1 0.8MT/year 2.4MT/year 3.2MT/year Collection,
containers Storage,
Decontamination
or sold to
authorized
recycler.
3. ETP 26.2 4.80 1200 1204.8 Collection,
Waste/MEE MT/year MT/year MT/year Storage,
solid waste Transportation
(Potassium and sent TSDF
Sulphate & site.
Sodium
Sulphate)
4. Fly Ash -- -- 50.0 50.0 Collection,
MT/year MT/year Storage,
Transportation &
Disposal by
selling to
Cement / Brick
Manufacturing
unit /Low lying
area.
Quantity of Discarded containers must be in MT/Annum.
ii Membership details of CETP, TSDF, CHWIF, Common Member of NCTL.
MEE etc. Member of BEIL-TSDF-Ankleshwar.
 Certificate attached as Annexure-C.
iii Details of Non-Hazardous waste & its disposal Fly Ash – 50 MT/year. Disposal by
(MSW and others) selling to Brick/Cement Manufacturing
unit or Send to Low lying area.
G Solvent management (If any) Not applicable.
i Details of Solvent recovery (as per respectively ToR)
ii VOC emission source and its mitigation measures
9. Details of Environment Consultants: Project Proponent
Sr. No. Particulars Details
i Name of the Consultant
Ii Contact no. and E-mail ID of the Applicant.
iii Accreditation for the categories
iv Any other details
Name &designation of the Applicant: Mr. Hasmukh Dudhat

Stamp & Signature of the Applicant:

Date:
 ANNEXURE-A

Compliance of Consolidated Consent and Authorization,

Consent Order No. AWH-64584

Condition Description Remarks

No.
1. Consent vide No.AWH-64584, date of issue 09/08/2017 Noted
2. The consent under water Act-1974 for conveying the industrial Noted and
effluent to the CETP of M/s. ETL for treatment and disposal of Complied
trade effluent & The consent under Air Act-1981 and Authorization with.
under Environment (Protection)Act,1986 shall be valid up to
13/05/2019,to operate industrial plant for manufacture of the
following products:
The list of proposed products to be manufactured shall be follows:

Sr. Name of the Product Capacity

No. [ MT/month ]
1. Di Ethyl Meta Amino Phenol 8

3 CONDITION UNDER THE WATER ACT 1974:

3.1 The quantity of total water consumption shall not exceed 7.0 Noted
KL/Day.[Break up as below]
a) Domestic : 1.0 KL/Day
b) Industrial : 6.0 KL/Day

3.2 The quantity of total wastewater generation shall not exceed 5.3 Noted
KL/Day.[Break up as below]
c) Domestic : 0.8 KL/Day
d) Industrial : 4.5 KL/Day
3.3 Sewage shall be disposed through septic/soak pit system. Noted

3.4 The unit shall affix of water meters as per section 4(1) of the Noted
Water (Prevention and Control of pollution) Cess Act -1977 for
the purpose of measuring and recording the quantity of water
consumption at such places as may be required, within 15 days
and it shall be presumed that the quantity indicated by the meter
has been consumed by the industry unit the contrary is proved.
3.5 TRADE EFFLUENT: Noted
3.5.1 The effluent conforming to the above standards shall be Noted
discharged in to GIDC underground drainage system and
conveyed to FETP which ultimately leads to deep sea for final
disposal through BEAIL pipeline.

Sr. Parameters Permissible Limit

No.
1. pH 6.5 to8.5
2. Temperature 40°C
3. Colour (pt.co.scale.) 100 units
4. Total suspended Solids (TSS) 150 mg/l
5. Total Dissolved Solids (TDS) 10000 mg/l
6. Biochemical oxygen demand 200 mg/ l
(BOD)
7. Chemical Oxygen Demand (COD) 1000 mg/ l
8. Oil Grease (O & G) 10 mg/ l
9. Phenolic Compound (as C6H5OH) 5 mg/ l
10. Sulphide (as S) 5 mg/ l
11. Ammoniacal Nitrogen (as N) 50 mg/ l
12. Total Kjeldahl Nitrogen (as N) 50 mg/ l
13. Phosphate (as P) 5 mg/ l
14. Chlorides (as Cl) 1000 mg/ l
15. Sulphate(as SO4) 1000 mg/ l
16. Cyanide (as CN) 0.2 mg/ l
17. Fluoride (as F) 15 mg/ l
18. Hexavalent Chromium (as Cr + 6) 0.1 mg/ l
19. Total Chromium (as Cr) 2 mg/ l
20. Copper (as Cu) 3 mg/ l
21. Nickel (as Ni) 3 mg/ l
22. Zinc (as Zn) 15 mg/ l
23. Iron (as Fe) 3 mg/ l
24. Manganese (as Mn) 2 mg/ l
25. Mercury (as Hg) 0.01 mg/ l
26. Lead (as Pb) 0.1 mg/ l
27. Arsenic (as As) 0.2 mg/ l
28. Venedium (as V) 0.2 mg/ l
29. Cadmium (as Cd) 0.05 mg/ l
30. Selenium (as Se) 0.05 mg/ l
31. Bio-assay test 90 % survival of
fish after 96 hr.in
100% effluent
32. Insecticides /Pesticides Absent
3.5.2 The applicant shall have to make a storage facilities to store the
effluent for at least 48 hr. in an impervious acid proof bricks lining
tank/HDPE tanks.
3.5.3 The applicant shall keep accurate records of quantity of Noted
production of each product, quantity of water consumption,
quantity of effluent generated and consumption of electricity on
day to day basis and required to submit the complied record of
one month to GPCB &ETL on day or before fifth day of the
succeeding month.
4 CONDITION UNDER THE AIR ACT 1981:
4.1 The following shall be used as fuel in Boiler. Noted and
Complied
Sr. No. Name of fuel QUANTITY with.
1. Natural Gas 90 m3/day

4.2 The applicant shall install & operate a comprehensive adequate Noted
air pollution control system in order to achieve prescribed norms
so as to achieve standards.
4.3 The flue gas emission through stack attached to Boiler/ furnace Noted and
shall conform to the following standards. Complied
with.
Stack Stack Stack Parameter Permissible
No. Attached Height Limit
To in Meter
1. Boiler 10 SPM 150 mg/NM3
SO2 100 ppm
NOX 50 ppm

4.4 There shall be no Process Emission from the manufacturing Noted and
process as well as any other ancillary operation. Complied
with.
4.5 The concentration of the following parameters in the ambient air Noted and
within the premises of the industry shall not exceed the limits Complied
specified here under. with.

Sr. Parameters Permissible

No. limit
1. PM10 100Microgram/M3
2. PM2.5 60Microgram/M3
3. SOx 80Microgram/M3
4. NOx 80Microgram/M3

4.6 The application shall operate industrial plant/ air pollution control Noted
equipment very efficiently and continuously so that the gaseous
 emission always conforms to the standards specified in condition
no.4.3 & 4.4 above.
4.7 The consent to operate the industrial plant shall lapse if at any Noted
time parameters of the gaseous emission are not within the
tolerance limits specified in the condition no 4.3 &4.5 above.
4.8 The application shall provide portholes, Ladder, platform etc. at Noted and
chimney(s) for monitoring the air emissions and the same shall Complied
be open for inspection to /and for use of Board’s staff. The with.
chimney(s) vents attached to various sources of emission shall be
designed by numbers such as S-1.S-2 etc. and these shall be
painted /displayed to facilitate identification.
4.9 The application shall take adequate measures for control of noise Noted and
levels from its own sources within the premises so as to maintain Complied
ambient air standards in respect of noise to less than 75dB(a) with.
during day time and 70Db(a) during night time. Daytime
reckoned in between 6a.m. and 10p.m. and night-time is
reckoned between 10 p.m. and 6 a.m.
5. GENREAL COBNDIRTIONS:-
5.1 Any change in personnel, equipment or working condition as Noted
mentioned in the consents form/order should immediately be
intimated this Board.
6. AUTHORISATION FOR THE MANAGEMENT &HANDLING OF
HAZARDOUS WASTES Fom-2(see rule 3(c) &(5))
6.1 Number of authorization: AWH-64584, date of ISSUE Noted
09/08/2017.
6.1.1 M/s. Kohinoor Colours Pvt. Ltd, is hereby granted an Noted and
authorization to operate facility for following hazardous wastes on Complied
the premises situated at PLOT NO:7204/7205, GIDC ESTATE with.
ANKLESHWAR, DIST:BHARUCH.

Sr. Name of Category Quantity Mode of

No. Hazardous / year Disposal
Waste
1. ETP Waste 26.2 4.8 MT Collection,
Storage,
Transportation
Disposal at TSDF-
BEIL
2. Used Oil 5.1 0.0001MT Collection,
Storage,
Transportation,
Disposal by selling
to registered
recycler.
 2. Discarded 33.3 300 Nos. Collection,
Drums Bags Storage,
Transportation,
Decontamination.

6.2 The authorization is granted to operate a facility for as above. Noted

6.3 The authorization shall be in force for a period up to Five years Noted
from the date of application.
6.4 The authorization is subjected to conditions stated below and such Noted
other conditions as may be specified in the rules from time to time
under the Environment (protection) Act-1986.
7 TERMS AND CONDITIONS OF AUTHORISATION:
7.1 The applicant shall comply with the provision of the Environment Noted
(Prevention) Act -1986 and the rules made there under.
7.2 The authorization shall be produced for inspection at the request Noted
of officer authorized by the Gujarat Pollution Control Board.
7.3 The persons authorized shall not rent, lend, and transfer of Noted
otherwise transport the hazardous wastes without obtaining prior
permission of the Gujarat Pollution Control Board.
7.4 Any unauthorized change in personnel, equipment or working Noted
condition as mentioned in the authorization order by the persons
authorized shall constitute a breach of this authorization.
7.5 It is the duty of the authorized person to take prior permission of Noted
the Gujarat Pollution Control Board to close down the facility.
7.6 An application for the renewal of an authorization shall be made Noted
as laid down in rule 5(6) (ii).
7.7 Industrial shall have to display the relevant information with Noted
regard to hazardous waste as indicated in the Court’s order in
W.P. No. 657 of 1995 dated 14th October 2003.
7.8 Industrial shall have to display on-line handled in the main factory Noted
gate with regard to and nature of hazardous chemicals being
handled in the plant, including waste water and air emission and
solid hazardous waste generated within the factory premises.
7.9 Industry shall submit annual report within 15 days and Noted
subsequently 31st January every year.
7.10 Industry shall have to manage waste oil; discarded containers Noted
etc., process waste as per Amended Rules-2003 and shall apply
Authorization for applicable waste as per Amended Rules-2003.
 r6a
/!}Et.
(C
Srt
rJl BHARUGH ENVIRO INFRASTRUCTURE LIMITED
.&
g!

Ref. BEIL/ANK/2017
1 August, 2OL7

To,
Kohinoor Colours Pvt. Ltd.
Plot No.7204 & 7205,
GIDC Estate,
Ankleshwar,

Sub: NOC for receivinq Landfill waste.

Dear Sir,

We are in receipt of your letter dtd.28-Jul-17. You are planning to

expand capacity. Due to this, additional Qty.22OO.O8 MT/Year
Waste will be generating.

We would like to inform you that we have no objection in accepting

your additional waste quantity, We shall be accepting your Landfill
waste subject to verification of quality and it should be as per GPCB
authorisation. You will also be required to increase your
booking quantity and necessary fees paid'

Thanking you,

Yours faithfully,
For, BHARUCH ENVIRO INFRASTRUCTURE LTD.

fVkJ*'l
AUTHORISED SIGNATORY

CIN No.: U45300GJl 997PLC032696

Works Office : Plot No. 9701 -16 GIDC Estate, Post Box No. 82, Ankleshwar 393 002, Dist. : Bharuch (Gujarat)
Phones (02646) 253135,225228. Fax: (026461222849. E-mail: panjwania@uniphos.com
Regd. Office : Plot No. 117-1'18, GIDG Estate, Ankleshwar 393 002,Dlst.: Bharuch. (Gujarat)
 Gujarat Pollution Control Board
SHOW CAUSE NOTICE Paryavaran Bhavan, Sector-10/A,
Gandhinagar - 382010
PCB ID : 15286 23222756

Legal ID : 22060

ACT : Air , Water , Hazardous Show Cause Notice DATE : 01/03/2016

WHEREAS, the Officials of the Gujarat Pollution Control Board (hereinafter referred to as the Board, in short),
conducted inspection on 10/12/2015 in order to verify the statements made by you in your application for Consent to
Operate under the Air , Water , Hazardous Act / to ascertain the Compliances of Conditions specified in Consent
Order.
WHEREAS during the inspection it was observed that:-
Reason :
Natural gas consumed in Sep-15= 5064 SCM, Oct-15= 4649 SCM, Nov-15= 4337 SCM which is more than
consented quantity i.e. 2700 SCM/Month.
1 This indicates that you have failed to fulfill the conditions mentioned in the Consent Order. Consequently , you have
rendered yourself liable to be prosecuted under the provisions of the above mentioned Sections-Acts.

NOW THEREFORE, in exercise of the powers vested with this Board

Under Section 33(A) read with section 25/26 of the Water(Prevention and Control of Pollution) Act, 1974
Under section 31(A) read with section 21 of the Air (Prevention and Control of Pollution) Act, 1981
Under Hazardous Waste (Management, Handling & Transboundary Movement) Rules 2008
notice is hereby served on you, to show cause within 15 days from the date of receipt of this show cause notice in
view of the non compliance observed above and why legal action should not be initiated as per the provision of the
Acts which may include rejection of your application and suspension/ closure of your unit.
For and on behalf of
Gujarat Pollution Control Board

D. M. Thaker, Unit Head

NO : SCN-347040 , 01/03/2016
Kohinoor Colours Pvt. Ltd.,,
7204/7205,, B/h., Lyka Labs,
Ankleshwar,
Dist : Ankleshwar, Tal : Ankleshwar, SIDC : Ankleshwar
Phone : 000

COPY TO :-
The RO Head(P.C.B.), Ankleshwar
With a request to carryout monitoring and send the detailed I.R. & A.R. for the sample collected to this office
immediately.

Printed On : 01/03/2016 1 - Through XGN N I C

 GPCB ID: 15286, Unit: Ankleshwar
To, 12th April, 2016
Gujarat Pollution Control Board
Sector – 10 A, Paryavaran Bhavan,
Gandhinagar – 382 010.
: Mr. D. M. Thaker (Unit Head)
Kind Attn.
Subject : Reply to your Show Cause Notice
Reference : Your Letter No. SCN-347040 dated 01/03/2016

Dear Sir,

We are in receipt of your above mentioned letter bearing Show Cause Notice, with
reference to Board officials’ visit and inspection of our plant on 10/12/2015, by stating
specific reason that consumption of natural gas is higher than the consent limit.
In this regards, we would to inform you that we are involved in the manufacturing of Di
Ethyl Meta Amino Phenol (Powder & Fused Form).

We are using natural gas in the fusion and distillation process to manufacture DEMAP
Powder and DEMAP Fused respectively. DEMAP Fused Form is made from DEMAP
powder by distillation & condensation process (to remove water content from DEMAP
powder).

Now, market demand for DEMAP Fused form is more, which leads to higher
consumption of natural gas. It is to be noted that we never exceed production consented
quantity, though there is increase in natural gas (Fuel) consumption.

Sir, looking to the above clarification, we request you not to take any further action on us
and close the showcase notice issued on us and request you to inform us in case of any
further details or clarifications.

Thanking you and looking forward to your kind consideration.

Sincerely Yours,
For, Kohinoor Colours Pvt. Ltd.,

Authorized Signatory

CC TO,
Regional Office,
Gujarat Pollution Control Board.
Cleaner Technology Development Centre Building (ARAIL),
1st Floor, Plot No: 1501, GIDC Estate, Ankleshwar - 393 002, Dist: Bharuch.
 Gujarat Pollution Control Board
SHOW CAUSE NOTICE Paryavaran Bhavan, Sector-10/A,
Gandhinagar - 382010
PCB ID : 15286 23222756

Legal ID : 30311

ACT : Air , Water , Hazardous Show Cause Notice DATE : 06/06/2017

WHEREAS, the Officials of the Gujarat Pollution Control Board (hereinafter referred to as the Board, in short),
conducted inspection on 21/04/2017 in order to verify the statements made by you in your application for Consent to
Operate under the Air , Water , Hazardous Act / to ascertain the Compliances of Conditions specified in Consent
Order.
WHEREAS during the inspection it was observed that:-
Reason :
1) Except collection tank, all other ETP unit was found filed with plain water. 2) The unit also manufacture and sells
the extra production quantity of intermediate product of DEMAP named as NND without obtaining CTE/CCA of the
Board. 3) As per documents furnished, The unit is involving in selling of various other products namely Rhodamine,
Solvent Blue, Victoria Blue, Acid Blue liquid, Kohinoor Red 555 L etc., which they do not manufacture in their unit
and purchase directly from outside units.
1 This indicates that you have failed to fulfill the conditions mentioned in the Consent Order. Consequently , you have
rendered yourself liable to be prosecuted under the provisions of the above mentioned Sections-Acts.

NOW THEREFORE, in exercise of the powers vested with this Board

Under Section 33(A) read with section 25/26 of the Water(Prevention and Control of Pollution) Act, 1974
Under section 31(A) read with section 21 of the Air (Prevention and Control of Pollution) Act, 1981
Under Hazardous Waste (Management, Handling & Transboundary Movement) Rules 2008
notice is hereby served on you, to show cause within 15 days from the date of receipt of this show cause notice in
view of the non compliance observed above and why legal action should not be initiated as per the provision of the
Acts which may include rejection of your application and suspension/ closure of your unit.
For and on behalf of
Gujarat Pollution Control Board

D. M. Thaker, Unit Head

NO : SCN-414233 , 06/06/2017
Kohinoor Colours Pvt. Ltd.,,
7204/7205,, B/h., Lyka Labs,
Ankleshwar,
Dist : Ankleshwar, Tal : Ankleshwar, SIDC : Ankleshwar
Phone : 000

COPY TO :-
The RO Head(P.C.B.), Ankleshwar
With a request to carryout monitoring and send the detailed I.R. & A.R. for the sample collected to this office
immediately.

Printed On : 06/06/2017 1 - Through XGN N I C

 KOHINOOR COLOURS PVT. LTD. GEN/F/02

PLOT NO. 7204, 7205, GIDC ESTATE, Rev.0.0

ANKLESHWAR - 393002, GUJARAT, INDIA
TEL: +91-2646-653301 ~ 4 * E-FAX: +91-8860075622
E-Mail @ : rajesh@kgimail.com

PCB ID: 15286

Date: 12/06/2017

TO,
The Unit Head-Ankleshwar,
Gujarat Pollution Control Board,
Paryavaran Bhavan, Sector- 10/A,
Gandhinagar- 382010.

Sub. : Show Cause Notice.

Ref.: Your office letter no. SCN- 414233 dtd. 06/06/2017

Dear Sir,

We are the unit namely M/s. Kohinoor Colours Pvt.Ltd., located at Plot
No7204/7205, B/H., Lyka Labs, Ankleshwar, Dist. Bharuch.

The above mentioned notice has been issued to us based on the Board’s
officials visit to our unit on21/04/2017. The copy of SCN is attached here as
Annexure-A.

The reply for the reason stated in the notice is as follows:

1. Except collection tank, all other ETP unit found filled with plain water.
The Effluent Treatment Plant has been already provided to treat the
generated waste water from the plant. The generated waste water is treated
in the provided ETP and disposed to NCTL after meeting with the inlet norms.
We would like to state that the generated waste water is treated within
the plant premises batch wise after having sufficient quantity of waste water.
The observed waste water in the other ETP units was treated and also
settled down. On other hand, the observed waste water was in the collection
tank was untreated. Because of this reason, the observed waste water in
other units except collection tank might be apparently different. So, we assure
you that the observed waste water in other units was not the plain water.
 KOHINOOR COLOURS PVT. LTD. GEN/F/02

PLOT NO. 7204, 7205, GIDC ESTATE, Rev.0.0

ANKLESHWAR - 393002, GUJARAT, INDIA
TEL: +91-2646-653301 ~ 4 * E-FAX: +91-8860075622
E-Mail @ : rajesh@kgimail.com

Therefore, at the time of Board’s officials visit to our unit, the generated
waste water has been filled in the ETP units and this waste water is treated
batch wise.

2. The unit also manufacture and sells the extra production quantity of
intermediate product of DEMAP named as NND without obtaining
CTE/CCA of the Board.

We would like to state that the NND is the intermediate product of

manufacturing DEMAP product. The intermediate product – NND has been
sold out to the actual users on trial basis.

We assure you to sell any other products except consented products

only after obtaining necessary permission of the Board.

3. As per documents furnished, the unit is involving in selling of various

other products namely Rhodamine, Solvent Blue, Victoria Blue, Acid
Blue liquid, Kohinoor Red 555 etc., which they donot manufacture in
their unit and purchase directly from outside units.

We would like to state that we are doing the trading activity of the
products namely Rhodamine, Solvent Blue, Victoria Blue, Acid Blue liquid,
Kohinoor Red 555 etc., as documents submitted to your office. We do this
trading activity to sustain in the market and also assure you that the
mentioned products are not manufactured in our plant premises.

Based on above we request you not to take any legal action as

mentioned in the notice and oblige.

Thanking You,
Yours Faithfully,

For, .Kohinoor Colours Pvt.Ltd

Encl.: Annexure A: The copy of SCN

 Annexures to Form – 1 &Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by M/s
Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District:Bharuch,Gujarat

ANNEXURE - A

DETAILS OF PRODUCTS

SR. NAME OF PRODUCTS QUANTITY (MT/MONTH)

NO.
EXISTING PROPOSED TOTAL

1. Diethyl Meta Amino Phenol 8.00 50.00 58.00

(DEMAP)

2. N,N, Diethyl Metanilic Acid -- 20.00 20.00

3. Meta Amino Phenol -- 20.00 20.00

4. Liquid Basic Dyes -- 50.00 50.00

Rhodamine Liquid (Minimum 10% to

40% Maximum)

AND / OR

Auramine O Liquid (Minimum 20%

to 50% Maximum)

5. Drying of Wet Cake of Dyes -- 5.00 5.00

6. Liquid Dyes from Wet Cake of Dyes -- 20.00 20.00

7. Repacking of Dyes and Pigments -- 10.0 10.0

[ Liquid / Powder ]

TOTAL 8.00 175.00 183.00

 Annexures to Form – 1 &Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by M/s
Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar, District:
Bharuch, Gujarat

ANNEXURE – B

DETAILS OF RAW MATERIALS CONSUMPTION

Sr. Name of Raw Material Consumption [ MT/month]

No.
Existing Additional Total
1. DIETHYL META AMINO
PHENOL
1 Metanilic Acid Powder/Liquid 12.00 73.00 85.00
(On Dry Basis)
2 Ethyl Chloride 12.00 73.00 85.00
3 Caustic Lye 12.00 73.00 85.00
4 Potassium Hydroxide 11.00 69.00 80.00
5 ICE 44.00 273.00 317.00
6 Water 35.00 455.00 490.00
7 Hydrochloric Acid (HCL30%) 18.00 113.00 131.00
2. N,N, DIETHYL METANILIC
ACID
1 Metanilic Acid Powder/Liquid 0 7.00 7.00
(On Dry Basis)
2 Ethyl Chloride 0 7.00 7.00
3 Caustic Lye 0 7.00 7.00
3. META AMINO PHENOL
1 Metanilic Acid Powder/Liquid 0 13.00 13.00
(On Dry Basis)
2 Caustic Lye 0 13.00 13.00
3 Hydrochloric Acid (HCL30%) 0 7.00 7.00
4 ICE 0 5.00 5.00
5 Water 0 5.00 5.00
4. Liquid Basic Dyes
RHODAMINE LIQUID Minimum Maximum Minimum Maximum
(MINIMUM 10% TO 40% 10% 40 % 10% 40 %
MAXIMUM)
1 Rhodamine B/Rhodamine 0.0 5.00 20.00 5.00 20.00
Base
2 Diethylene Glycol 0.0 37.25 0.00 37.25 0.00
3 Diethylene Glycol Mono Ethyl 0.0 7.50 0.00 7.50 0.00
Ether
 Annexures to Form – 1 &Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by M/s
Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar, District:
Bharuch, Gujarat

4 Stabilizer 0.0 0.25 0.25 0.25 0.25

5 Acetic Acid/Methanol 0.0 0.00 29.75 0.00 29.75
AURAMINE O LIQUID
(MINIMUM 20% TO 50%
MAXIMUM)
Minimum Maximum Minimum Maximum
20% 50 % 20% 50 %
1 Auramine O 0.0 10.00 25.00 10.00 25.00
2 Stabilizer 0.0 0.25 0.25 0.25 0.25
3 Acetic Acid 0.0 39.75 24.75 39.75 24.75
5. DRYING OF WETCAKE OF Existing Additional Total
DYES
1 Dye Wet Cake 0.0 5.75 5.75
6. LIQUID DYES FROM
WETCAKE OF DYES
1 Dye Wet Cake 0.0 8.1 8.1
2 Stabilizer 0.0 0.10 0.10
3 Acetic Acid 0.0 11.80 11.80
7. REPACKING OF DYES
AND/OR PIGMENTS
[ LIQUID / DRY ]
1 Different types of Dyes and/or 0.0 10.0 10.0
Pigments
 Annexures to Form – 1 & Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by
M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District: Bharuch,Gujarat

ANNEXURE – C

MANUFACTURING PROCESS DESCRIPTION

Existing Product& Proposed Products:

1.] Diethyl Meta Amino Phenol (DEMAP)

Process Description:

1. Pressure vessel:
Charge in pressure vessel caustic lye/flakes. Metanilic acid powder/liquid and
prepare slurry and then charge ethyl chloride under string after complete reaction
dump reaction mass to Dumping vessel.

2. Dumping vessel:
Dumped materials in dumping vessel & string up to complete crystallization
material then transfer to Filter press.

3. Filterpress:
Do filtration of material by filter press and after filtration transfer to Fusion vessel
.
4. Fusion:
Take material from Filter press add caustic potassium hydroxideand heat up to
2500 c to 2700 c under string and after complete fusion reaction, charge water
and make slurry of fusionmass and transfer to isolation vessel.

5. Isolation:
Take slurry in isolation vessel and isolate material with Ice and slowly add
Hydrochloric acid in it to isolate material, after complete isolation do centrifuge
and then transfer for Drying or Dehydration.

6. Drying OR Dehydration:
Take Centrifuge wet cake for Drying or Do Dehydration by distillation. After
selected operation, DEMAP is ready.
 Annexures to Form – 1 & Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by
M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District: Bharuch,Gujarat

Chemical Reaction of DEMAP:

 Annexures to Form – 1 & Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by
M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District: Bharuch,Gujarat

Mass Balance of DEMAP:

Sr. Input Quantity Output Quantity
No. [kg] [kg]
1 Metanilic Acid Powder/Liquid 87.00 Diethyl Meta Amino 58.00
(On Dry Basis) Phenol
2 Ethyl Chloride 87.00 Waste Water 1077.87
3 Caustic Lye/Flakes 87.00 M.L.Recovered for
use in Next batch 84.68
4 Potassium Hydroxide 79.46 Distilled water
recovered use in
next batch 17.4
5 ICE 284.20
6 Water 397.88
7 M.L. Recovered use 84.68
8 Hydrochloric Acid (HCL30%) 130.73
Total 1237.95 Total 1237.95

Flow Chart Diethyl Meta Amino Phenol (DEMAP)

Metanilic Acid Powder/Liquid

Ethyl Chloride Pressure Reactor
Caustic Lye

Caustic Lye Dumping Vessel

Filtration M.L. Reuse

in next batch

Potassium Hydroxide Fusion

Water
Isolation ICE
HCL

Water Filtration Waste Water to

ETP
Centrifuge Waste Water to
ETP
Dryer OR Dehydration Water reuse

Final Product
(DEMAP)
 Annexures to Form – 1 & Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by
M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District: Bharuch,Gujarat

2.] N,N, Diethyl Metanilic Acid

Process Description:

Charge in pressure vessel caustic lye/flakes, Metanilic acid Powder/Liquid and

prepare slurry and then charge ethyl chloride under string after complete reaction
dump reaction mass to Dumping vessel & string up to complete crystallization
material then transfer to Filter press and collect Filter cake, dry it and pack.
Generated waste water as M.L. will transfer to ETP for treatment.

Chemical Reaction of N, N, Diethyl Metanilic Acid:

 Annexures to Form – 1 & Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by
M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District: Bharuch,Gujarat

Mass Balance of N, N, Diethyl Metanilic Acid:

Sr. Input Quantity Output Quantity
No. [kg] [kg]
1 Metanilic Acid Powder/Liquid 14.0 N,N,DiethylMetanilic 20.0
(On Dry Basis) Acid
2 Ethyl Chloride 10.0 Waste Water 27.0
3 Caustic Lye/Flakes 10.0
4 Water 13.0
Total 47 Total 47

Flow ChartN,N, Diethyl Metanilic Acid

Metanilic Acid Powder/Liquid

Ethyl Chloride Pressure Reactor
Caustic Lye

Caustic Lye Dumping Vessel

Filtration Waste water

transfer to ETP

Drying

N,N, Diethyl
Metanilic Acid
 Annexures to Form – 1 & Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by
M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District: Bharuch,Gujarat

3.] Meta Amino Phenol

Process Description:

Charge in vessel caustic lye/flakes, Metanilic acid Powder/Liquid and heat up to

2500 c to 2600 c under string and after complete reaction, charge water and
make slurry of reaction mass and transfer to isolation vessel.
Take slurry in isolation vessel and isolate material with Ice and slowly add
Hydrochloric acid in it to isolate material, after complete isolation do centrifuge
and then transfer for Drying. Take Centrifuge wet cake for Drying and pack Meta
Amino Phenol. Generated waste water from centrifuge will transfer to ETP for
treatment.

Chemical Reaction of Meta Amino Phenol:

 Annexures to Form – 1 & Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by
M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District: Bharuch,Gujarat

Mass Balance of Meta Amino Phenol:

Sr. Input Quantity Output Quantity
No. [kg] [kg]
1 Metanilic Acid Powder/Liquid 32.0 Meta Amino Phenol 20.0
(On Dry Basis)
2 Caustic Lye/Flakes 15.0 Waste Water 40.0
3 Hydrochloric Acid (HCL30%) 7.0
4 ICE 3.0
5 Water 3.0
Total 60 Total 60

Flow Chart Meta Amino Phenol

Metanilic Acid Powder/Liquid

Caustic Lye Reaction Vessel

Water
Isolation Vessel HCl
ICE

Centrifuge Waste water

transfer to ETP

Drying

Meta Amino Phenol

 Annexures to Form – 1 & Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by
M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District: Bharuch,Gujarat

4.] Rhodamine Liquid(Minimum 10% to 40% Maximum)

Under stirring charge Diethylene Glycol or Acetic acid or Methanol and stabilizer
then heat the mixture up to 60 °C now slowly charge Rhodamine B & Rhodamine
Base and dissolve it under stirring for 2 to 3 hours. Do in process test and once QC
department approve quality of product cool down to room temperature and do
filtration and packing, finished product isRhodamine Liquid.

Mass Balance of Rhodamine Liquid 10% Minimum:

Sr. Input Quantity[Kg] Output Quantity
No. [kg]
1 Rhodamine 100 Rhodamine Liquid 10% 1000
B/Rhodamine Base Minimum

2 Diethylene Glycol 745

3 Diethylene Glycol 150
Mono Ethyl Ether
4 Stabilizer 5
5 Acetic Acid/Methanol 0.00
Total 1000 Total 1000

Mass Balance of Rhodamine Liquid 40% Maximum:

Sr. Input Quantity Output Quantity
No.
1 Rhodamine 400 Rhodamine Liquid 40% 1000
B/Rhodamine Base Maximum

2 Diethylene Glycol 0.00

3 Diethylene Glycol Mono 0.00
Ethyl Ether
4 Stabilizer 5
5 Acetic Acid/Methanol 595
Total 1000 Total 1000
 Annexures to Form – 1 & Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by
M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District: Bharuch,Gujarat

PROCESS FLOW DIAGRAM:

Rhodamine Liquid (Minimum 10% to 40% Maximum)

Rhodamine B / Reactor Stabilizer

Rhodamine Base (Heat to 60 °C) Diethylene Glycol
OR
Acetic Acid OR
Filtration Diethylene Glycol
Mono ethyl ether

Finished Product
(Rhodamine Liquid
10% Minimum to 40%
Maximum)

AuramineO Liquid (Minimum 20% to 50% Maximum)

Under stirring charge Acetic acid and stabilizer then heat the mixture up to 60 °C
now slowly charge Auramine O and dissolve it under stirring for 2 to 3 hours. Do in
process test and once QC department approve quality of product, cool down to room
temperature and do filtration and packing, finished product isAuramine O Liquid.

PROCESS FLOW DIAGRAM:

Auramine Liquid (Minimum 20% to 50% Maximum)

Reactor Stabilizer
Auramine O Acetic Acid
(Heat to 60 °C)

Filtration

Finished Product
(Auramine Liquid
20% Minimum to 50%
Maximum)
 Annexures to Form – 1 & Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by
M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District: Bharuch,Gujarat

Mass Balance of Auramine Liquid 20% Minimum:

Sr. Input Quantity Output Quantity
No. [kg] [kg]
1 Auramine O 200 Auramine Liquid 20% 1000
Minimum
2 Stabilizer 5.0
3 Acetic Acid/Methanol 795
Total 1000 Total 1000

Mass Balance of Auramine Liquid 50% Maximum:

Sr. Input Quantity Output Quantity
No.
1 Auramine O 500 Auramine Liquid 50% 1000
Minimum
2 Stabilizer 5.0
3 Acetic Acid/Methanol 495
Total 1000 Total 1000

5.] Drying of Wet Cake of Dyes:

Take Dye wet cake and dry it at 105°C in tray dryer or other suitable dryer. After 4 to
5 hours of drying, Do in process test and once QC department approve quality of
product, do packing, finished product isDye Powder.

Mass Balance of Drying of wet cake of Dyes:

Sr. Input Quantity[Kg] Output Quantity
No. [kg]
1 Dye wet cake 5.750 Dye Powder 5.00
Evaporation loss 0.750

Total 5.750 Total 5.750

 Annexures to Form – 1 & Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by
M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District: Bharuch,Gujarat

PROCESS FLOW DIAGRAM:

Dye Wet Cake Drying

Dye Wet Cake Dryer Evaporation

Packing

Dye Powder

6.] Liquid Dye from Wet Cake of Dyes:

Under stirring charge Acetic acid and stabilizer then heat the mixture up to 60 °C
now slowly charge Wet Cake Dye and dissolve it under stirring for 2 to 3 hours. Do in
process test and once QC department approve quality of product, cool down to room
temperature and do filtration and packing, finished product isLiquid Dye.

Mass Balance of Liquid dye from wet cake:

Sr. Input Quantity Output Quantity
No. [kg] [kg]
1 Dye wet cake 40.0 Liquid dye 100
2 Stabilizer 1.0
3 Acetic Acid/Methanol 59
Total 100 Total 100

PROCESS FLOW DIAGRAM:

Liquid Dye fromWet Cake:

Reactor Stabilizer
Wet Cake of Dye (Heat to 60 °C) Acetic Acid

Filtration

Finished Product
(Liquid Dye)
 Annexures to Form – 1 & Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by
M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar,
District: Bharuch,Gujarat

7.] Repacking of Dyes and/or Pigments [Liquid / Dry]:

 The Dyes or pigments in Liquid / dry form, will be mixed and blended as per
requirement
 And packed in the bags / drums packing as per client requirement.
 Also, the dyes / pigment in liquid / dry form will be repacked in the small
packings as per client requirement.

Different types of Mixing / blending

dyes / pigments

Packing as per
desired quantity

Sold to the
customers
 Annexures to Form – 1 &Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by M/s
Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar, District:
Bharuch, Gujarat.

ANNEXURE– D

DETAILS OF WATER CONSUMPTION AND WASTE WATER GENERATION

 DETAILS OF WATER CONSUMPTION :

Sr. PURPOSE Consumption, KL/day

no.
Existing Proposed Total After
Proposed expansion
1. Domestic 1.0 3.0 4.0
2. Industrial
a. Process 1.0 7.0 8.0
b. Boiler make up 1.0 5.0 6.0
c. Cooling make up 0.0 1.0 1.0
d. Washing water 4.0 24.0 28.0
e. Any other – 0.0 2.0 2.0
Gardening
TOTAL [2] 6.0 39.0 45.0
TOTAL [1+2] 7.0 42.0 49.0

Note:**The total water consumption is included the condensate recovery quantity. The
condensate recovery will be done from the MEE system and the same will be utilised
within the plant premises.
 Annexures to Form – 1 &Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by M/s
Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar, District:
Bharuch, Gujarat.

 DETAILS OF WASTE WATER GENERATION :

Sr. PURPOSE Generation, KL/day

no.
Existing Proposed Total after proposed
expansion
1. Domestic 0.8 3.0 3.8
2. Industrial
a. Process 0.5 4.0 4.5
b. Boiler blow down 0.0 0.5 0.5
c. Cooling bleed off 0.0 0.1 0.1
d. Washing water 4.0 23.0 27.0
e. Any other – 0.0 0.0 0.0
scrubbing
TOTAL [2] 4.5 27.6 32.1
TOTAL [1+2] 5.3 30.6 35.9

Note: [Existing]

For the existing production capacity, the generated waste water is collected, treated
into ETP, and then discharge to G.I.D.C. underground drainage system and conveyed to
FETP which ultimately leads to deep sea for final disposal through BEAIL pipeline.

[Proposed]

For proposed expansion, there will be increase in the waste water generation from
the process and utility, washing sections and this generated waste water will be treated into
ETP and then sent to Multi Effect Evaporator, condensate water will be reuse within the plant
premises.Hence, for the proposed expansion, the generated additional waste water will
have zero discharge and there will not be any increase in the consented discharge
quantity.

Also, At present, unit has planned to install MEE for proposed Expansion,
However, in future as and when function of CETP in this area will improved/installed
and if GPCB will grant permission to discharge effluent into CETP (ETL or Ankleshwar
Waste Management Limited or any other Common effluent treatment plant), mode of
 Annexures to Form – 1 &Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by M/s
Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar, District:
Bharuch, Gujarat.

disposal will be of CETP after getting its permission and Total Quantity after proposed
expansion will be 35.9 KL/Day.

Effluent treatment Plant-Existing

Details of Effluent Treatment Scheme:-

 The effluent coming out from plant is passed through Collection cum
Equalization Tank to equalize the effluent. Equalized Effluent is then pumped to
chemical Dosing Tank where required chemicals are added in required proportion for
precipitation and make the final pH neutral.
 Neutralized effluent is then pumped to Filter press and Nutch Filter for further
treatment.
 Effluent coming out from Nutch Filter is then pumped to Primary Clarifier, where
settable solids are settled at the bottom of the tank and this sludge is forwarded to
sludge Drying Bed within Industry premises.
 The clear supernatant is sent to Aeration Tank for biological treatment using
acclimatized micro-organisms. The overflow of Aeration Tank is entered into
Secondary Clarifier where sludge is settled at the bottom of the tank and is recycled
back to Aeration tank with the help of Recycle Pump and excess quantity of sludge,
if any is forwarded to sludge Drying Bed within Industry premises.
 The clear supernatant is collected in treated effluent collection tank and is passed
through Pressure sand filter, Carbon Filter and Filter Tower and final treated effluent
is collected in Final discharge tank. The final treated effluent complying with the
norms is discharged into underground drainage system and then conveyed to FETP
for further treatment and ultimately discharged into deep sea through BEAIL pipeline.

Flow Diagram of ETP:

 Annexures to Form – 1 &Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by M/s
Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar, District:
Bharuch, Gujarat.

1 Collection cum Equalization Tank

2 Chemical Dosing tank (Neutralization)
with precipitation
3 Filter Press
4 Nutch Filter
5 Primary Clarifier
6 Aeration Tank
7 Secondary Clarifier
8 Collection Tank
9 Sludge Drying Bed
10 Sand Filter Tower
11 Carbon Filter Tower
12 Filter Tower
13 Final Discharge Tank
Transfer Pump
Flow Meter

Effluent treatment Plant-Proposed

1
2 3 4

1 Collection cum Equalization Tank

2 Neutralization tank
3 Filtration
4 Multi Effect Evaporator
5 Sludge Drying Bed
 Annexures to Form – 1 & Pre Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by M/s Kohinoor
Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar, District:Bharuch,Gujarat

ANNEXURE – E

DETAILS OF HAZARDOUS WASTE GENERATION AND ITS DISPOSAL

Sr. Name of Category Generation Per year Remarks

No. Hazardous as per
Waste HWM,2016
Consented Additional Total
1. Used Oil 5.1 0.0001 0.024 0.0241 Collection, Storage,
MT/year MT/year KL/year Transportation and
sold to authorized
Recyclers.

2. Discarded 33.1 0.8 MT/year 2.4 3.2 Collection, Storage,

containers MT/year MT/year Decontamination or
sold to authorized
recycler.

3. ETP 26.2 4.80 1200 1204.8 Collection, Storage,

Waste/MEE MT/year MT/year MT/year Transportation and
solid waste sent TSDF site.
(Potassium
Sulphate&
Sodium
Sulphate)
4. Fly Ash -- -- 50.0 50.0 Collection, Storage,
MT/year MT/year Transportation &
Disposal by selling to
Cement / Brick
Manufacturing unit
/Low lying area.
 Annexures to Form – 1 &Pre-Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by M/s
Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C Estate, Ankleshwar, District:
Bharuch, Gujarat

ANNEXURE – F

DETAILS OF AIR POLLUTION CONTROL MEASURES

 DETAILS OF FLUE GAS EMISSION

Sr. Stack Name of fuel & its Stack Air Parameters

No. Attached to consumption Heightpollution
Control
System
For Consented Production Capacity
1. Boiler Natural Gas 10 m ---- PM < 150 mg/Nm3
@ 90 m3/day SO2< 100 ppm
NOx< 50 ppm

For Proposed additional production capacity

1. Boiler Natural Gas 10 m Cyclone PM < 150 mg/Nm3
(600Kg/Hr)[2 @ 400m3/day each Separator SO2< 100 ppm
Nos] AND/OR Bio-coal – 1.4 +Water NOx< 50 ppm
MT/Day Scrubber
2. G.G.Set Natural Gas 2m ---- SPM < 150 mg/Nm3
(63KVA) @ 80 m3/day SO2< 100 ppm
(Stand By) NOx< 50 ppm

DETAILS OF PROCESS GAS EMISSION:

Sr. Stack Stack Height Air pollution Parameters

No. Attached to Control System
For Proposed additional production capacity
1. Blender 3m Bag filter PM < 150 mg/Nm3
2. Dryer 6m Bag filter PM < 150 mg/Nm3
 Annexures to Form – 1 &Pre Feasibility Report
Proposed Expansion Project for manufacturing of Synthetic Organic Chemicals by M/s Kohinoor Colours Pvt Ltd, Plot No. 7204, 7205, G.I.D.C
Estate, Ankleshwar, District:Bharuch,Gujarat

ANNEXURE – GPLANT LAY OUT

 r6a
/!}Et.
(C
Srt
rJl BHARUGH ENVIRO INFRASTRUCTURE LIMITED
.&
g!

Ref. BEIL/ANK/2017
1 August, 2OL7

To,
Kohinoor Colours Pvt. Ltd.
Plot No.7204 & 7205,
GIDC Estate,
Ankleshwar,

Sub: NOC for receivinq Landfill waste.

Dear Sir,

We are in receipt of your letter dtd.28-Jul-17. You are planning to

expand capacity. Due to this, additional Qty.22OO.O8 MT/Year
Waste will be generating.

We would like to inform you that we have no objection in accepting

your additional waste quantity, We shall be accepting your Landfill
waste subject to verification of quality and it should be as per GPCB
authorisation. You will also be required to increase your
booking quantity and necessary fees paid'

Thanking you,

Yours faithfully,
For, BHARUCH ENVIRO INFRASTRUCTURE LTD.

fVkJ*'l
AUTHORISED SIGNATORY

CIN No.: U45300GJl 997PLC032696

Works Office : Plot No. 9701 -16 GIDC Estate, Post Box No. 82, Ankleshwar 393 002, Dist. : Bharuch (Gujarat)
Phones (02646) 253135,225228. Fax: (026461222849. E-mail: panjwania@uniphos.com
Regd. Office : Plot No. 117-1'18, GIDG Estate, Ankleshwar 393 002,Dlst.: Bharuch. (Gujarat)