Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
CHAPTER
Atoms
Law of conservation of mass was given by
Lavoisier in 1774. According to the law of
Symbols of elements conservation of mass : Matter is neither
created nor destroyed in a chemical reaction.
Atomic mass The substances which combine together in a
chemical reaction are known as ‘reactants’
Molecules whereas the new substances formed as a
result of chemical reaction are called
Ions ‘products’. The law of conservation of mass
means that in a chemical reaction, the total
Valency mass of products is equal to the total mass of
reactants. There is no change in mass during a
Chemical formulae chemical reaction.
Neon Ne c
Monoatomi
There are two types of molecules.
Hydrogen H2 cDiatomic
Molecules of elements
The molecule of an element contains two (or Chlorine Cl2 Diatomic
more) similar atoms chemically combined Nitrogen N2 Diatomic
together. Oxygen O2 Diatomic
Ex. A molecule of hydrogen element contains 2 Phosphor P4 Tetratomic
hydrogen atoms combined together, and it is us
Sulphur S8 Polyatomic
written as H2.
Metals Sodium Na Monoatomi
Molecules of compounds
Iron Fe c
Monoatomi
The molecule of a compound contains two cMonoatomi
(or more) different types of atoms chemically Aluminiu Al
combined together m
Copper Cu c
Monoatomi
Ex. Hydrogen chloride is a compound. The c
molecule of hydrogen chloride (HCl) contains Ions
two different types of atom. Hydrogen(H) and
chlorine atom (Cl) An ion is a positively or negatively charged
atom (or group of atoms). An ion is formed
Molecules of some compounds by the loss or gain of electrons by an atom, so
Compound Combining Formula Ratio by it contains an unequal number of electrons
elements mass and protons.
Water Hydrogen H2 O 1:8 Ex. Sodium ion Na+, magnesium ion Mg2+,
and chloride ion Cl–, and oxide ion O2–.
oxygen There are two types of ions : cations and
Ammonia Nitrogen NH3 14:3 anions.
and
Hydrogen Cation
Carbon Carbon CO2 3:8 A positively charged ion is known as cation.
dioxide and A cation is formed by the loss of one or more
Oxygen electrons by an atom.
Atomicity Ex. Sodium atom loses 1 electron to form a
The number of atoms present in one molecule sodium ion, Na+, which is cation :
of an element is called its atomicity.
Na Na
1 electron
Ex. Noble gases (helium, neon, argon, krypton, Sodium ion
Sodium
etc.) have one atom each in their molecules (A cation )
such as He, Ne, Ar and Kr. So, the atomicity
of noble gases is 1. The ions of all the metal elements are cations.
2+ – 2–
Cobalt Co Chlorate ClO3 Zincate ZnO2
2+ – 2–
Tin [II] Sn Hypochlorite ClO Thiosulphate S2 O3
–
Cadmium 2+ Nitrite NO2
Cd
–
2+ Nitrate NO3
Lead [II] Pb
–
2+
Permanganate MnO4
Copper [II] Cu
Trivalent Tetravalent
Trivalent Tetravalent
Name Formula Name Formula
Name Formula Name Formula
3+ 4+
Aluminium Al Manganese [II] Mn 3– 4–
Nitride N Ferrocyanide Fe(CN) 6
3+ 4+
Chromium Cr Tin [IV] Sn 3–
Phosphate PO4
3+ 4+
Iron [III] Fe Lead [IV] Pb Ferricyanide Fe(CN)6
3–
3+ 4+
Gold Au Platinum Pt Phosphide P
3–
Pt
4+
Variable valency in one molecule. One molecule of hydrogen
element contains two atoms of hydrogen,
There are certain elements that exhibit more
therefore, the formula of hydrogen is H2.
than one valencies in their ions (or
Ex. The formula H2 indicates that one molecule
compounds).
of hydrogen element contains 2 atoms of
Ex. Iron can exist as Fe2+ or Fe3+ in its hydrogen. 2 H represents 2 separate atoms of
compounds. In such cases the name of the ion hydrogen; H2 represents 1 molecule of
with lower valency ends with a suffix ‘ous’ hydrogen and 2H2 represents 2 molecules of
while that with higher valency ends with a hydrogen.
suffix ‘ic’. Formulae of compounds
Some basic ions exhibiting variable valency The chemical formula of a compound is a
statement of its composition in which the
Name of Formula
chemical symbols tell us which elements are
ions +
Cuprous Cu present and the subscripts tell us how many
2+
Cupric Cu atoms of each element are present in one
Mercurous Hg2
2+ molecule of the compound.
Mercuric Hg
2+ Ex. Water is a compound whose molecule
2+ contains 2 atoms of hydrogen and 1 atom of
Ferrous Fe
3+ oxygen. So, the formula of water is H2O.
Ferric Fe
2+ Rules for writing a chemical formula
Plumbous Pb
4+ We first write the symbols of the elements
plumbic Pb
2+ which form the compound
Stannous Sn
4+ Below the symbol of each element, we write
Stannic Sn down its valency.
+
Aurous Au Finally, we cross-over the valencies of the
3+
Auric Au combining atoms. That is, with first atom we
write the valency of second atom (as a
Chemical formulae subscript); and with the second atom we write
A compound is represented in the abbreviated the valency of first atom (as subscript).
form by chemical formula. Ex.
The chemical formula of a compound Element C C
l
represents the composition of a molecule of Formula C1Cl4 or CCl4
the compound in terms of the symbols of the
elements present in it. Valency 4 1
Ex. Water is a compound made up of 2 atoms of Ex.
hydrogen element and 1 atom of oxygen Element H C
element, so the formula of water is written as l
H2O. In the formula H2O, the subscript 2 Valency 1 1
indicates 2 atoms of hydrogen. In the formula Formula HCl
of water, oxygen O is written without a
Ex.
subscript and it indicates 1 atoms of oxygen.
Element H O
Formulae of elements
The chemical formula of an element is a Valency 1 2
statement of the composition of its molecule
Formula H2O
in which symbol tells us the element and the
subscript tells us how many atoms are present
Ex. Thus, the formula of barium nitrate is
Element H S Ba(NO3)2
Valency 1 2
Significance of the formula of a substance
Formula H2S
Formula represents the name of the substance
Ex.
Formula represents one molecule of the
Element N H substance
Formula also represents one mole of
Valency 3 1 molecules of the substance. That is, formula
Formula NH3 also represents 6.022 × 1023 molecules of the
substance.
Writing the formula of a compound Formula gives the name of all the elements
present in the molecule.
Step-1 :
Formula gives the number of atoms of each
Write the symbols of formulae of the ions of element present in one molecule.
the compound side by side with positive ion
on the left hand side and negative ion on right Formula represents a definite mass of the
hand side. substance
Ex. On heating a sample of CaCO3, volume of Ex. Calculate mass of hydrazine N2H4 obtained
CO2 evolved at NTP is 112 cc. Calculate when 1.12 litre of N2 taken at NTP reacts
with H2 according to N2 + 2H2 N2H4.
(i) Weight of CO2 produced
1.12 1
(ii) Weight of CaCO3 taken Sol. Moles of N2 taken = =
22.4 20
(iii) Weight of CaO remaining
N2 + 2H2 N2H4
112 1
Sol. (i) Mole of CO2 produced = mole (1/20 mole) (1/20 mole)
22400 200
1 1
mass of CO2 = × 44 = 0.22 gm mass of N2H4 = × 32 = 1.6 gm
200 20
(ii) CaCO3 CaO + CO2 Ex. Calculate mass of Na2SO4 obtained when
(1/200 mole) 100 ml of 0.2 M H2SO4 is completely
1 neutralised by NaOH.
mole of CaCO3 = mole
200 Sol. Mole of H2SO4 taken =
1 100
mass of CaCO3 = × 100 = 0.5 gm Molarity × Vol. (lit) = 0.2 × = 0.02
200 1000
1
(iii) mole of CaO produced = mole
200 H2SO4 + 2NaOH Na2SO4 + 2H2O
1 0.02 mole 0.02 mole
mass of CaO = × 56 = 0.28 gm
200
Mole of Na2SO4 obtained = 0.02
* Interesting by we can apply
mass of Na2SO4 = 0.02 × 142 = 2.84 gm
Conversation of mass or wt. of CaO
= wt. of CaCO3 taken – wt. of CO2 produced
= 0.5 – 0.22 = 0.28 gm
EXERCISE- 1
A. Very Short Answer Type Questions Q.19 “If 100 grams of calcium carbonate are
Q.1 Name of the building block of all matter. decomposed completely, then 56 grams of
calcium oxide and 44 grams of carbon
Q.2 What are the symbols of copper and cobalt? dioxide are obtained” Which law of chemical
combination is illustrated by this statement?
Q.3 Name two elements whose symbols are
derived from Latin names. Give their Q.20 Name the scientist who gave law of
symbols. conservation of mass
Q.17 What is the molar mass of sulphur molecule Q.31 Explain the difference between 2N and N 2.
(S8)? Q.32 What do the symbols, H2, S and O4 mean in
Q.18 “If 100 grams of pure water taken from the formula H2SO4?
different sources is decomposed by passing
electricity, 11 grams of hydrogen and 89
grams of oxygen are always obtained”.
Which chemical law is illustrated by this
statement?
EXERCISE- 2
Q.11 What weight of oxygen gas will contain the
A. Long Answer Type Questions same number of molecules as 56 g of nitrogen
(More than 47–60 words) gas? (O = 16 u ; N = 14 u)
Q.2 What is Dalton’s atomic theory? Give its Q.13 ................ is a pure substance which is made
main postulates. Which postulate of Dalton’s up of only one kind of atoms.
atomic theory explain the law of conservation
of mass. Q.14 The atomicity of ozone is ..............
Q.3 Calculate the following : Q.15 1 mole of oxygen atoms = ............... oxygen
atoms.
(i) Number of S atoms in 3.2 g of S8.
(ii) Number of molecules of CH4 in 80.0 g of it Q.16 The ratio by mass of S and O in SO2
(iii) The mass of 1 molecule of NH3. is..............
(iv) The mass of 0.25 moles of calcium
(v) Number of bromide ion in 0.2 mole of C. True /False Type Questions
MgBr2.
Q.17 Two elements sometimes form more than one
Q.4 What is the significance of the symbol of an compounds.
element? Explain with the help of an
example. Q.18 The smallest particle of a compound is
element.
Q.5 What is meant by saying that ‘the atomic
mass of oxygen is 16” ? Q.19 Mass of 6.022 atoms of an element is called
atomic mass.
Q.6 Calculate the molecular masses of the
following compounds : Q.20 One mole of every substance has same mass.
(i) Methanol, CH3OH (ii) Ethanol, C2H5OH
Q.21 One mole of CO2 and SO2 contains same
Q.7 What is the significance of the formula of a number of oxygen atoms.
substance?
Q.22 Mass of 1 mole of CO2 is 44 g.
Q.8 The mass of one atom of an element X is
2.0 × 10–23 g. Q.23 The mass of a hydrogen atom is th the mass
of a carbon atom.
(i) Calculate the atomic mass of element X.
(ii) What could element X be?
Q.9 The mass of one molecule of a substance is
4.65 × 10–23 g. What is its molecular mass?
What could this substance be?
EXERCISE-2
12. 1 : 8 13. Element 14. 3 15. 6.022 × 1023 16. 1 : 1
17. True 18. False 19. False 20. False 21. True
22. True 23. False