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SECTION - 10
Process Mathematical Modeling
For almost half a century, numerous design criteria utilizing empirical and rational
parameters based on biological kinetic equations have been developed for suspended-growth
systems. Generally, two types of mixing regimes are of major interest in the activated sludge
process:
1. Conventional plug flow activated sludge process and,
2. Complete mixing activated sludge process.
In conventional plug flow, the regime is characterized by an orderly flow of mixed liquor
through the aeration tank with no element of mixed liquor overtaking or mixing with any
other element. There may be lateral mixing of mixed liquor but there must be no mixing along
the path of flow.
In complete mixing, the contents of the aeration tank (substrate load, MLVSS
concentration, and oxygen demand) are well stirred and uniform throughout. Thus, at steady
state, the effluent from the aeration tank has the same composition as the aeration tank
contents. Relatively simple to operate but to have low organic substrate concentration (i.e low
F/M) that encourage the growth of filamentous bacteria causing sludge bulking.
Table 10.3: Design criteria for conventional plug flow activated sludge process.
Item Basis Range
Volumetric BOD5 loading kg BOD5 applied /(m3.d) 0.3 - 0.6
MLSS mg/L 1500 - 3000
The aeration period ranges (θ) (HRT) hours 4-8
Return activated-sludge flow ratios Qr/Q - 0.25- 0.5
The cell residence time (θc) days 5-15
The F/M ratio Day -1 0.2-0.4
BOD5 removal percent 85 -95
Table 11.2: Design criteria for complete mix flow activated sludge process.
Item Basis Range
Volumetric BOD5 loading kg BOD5 applied /(m3.d) 0.8 - 2.0
MLSS mg/L 3000 - 6000
The aeration period ranges (θ) (HRT) hours 3-5
Return activated-sludge flow ratios Qr/Q - 0.25 - 1.0
The cell residence time (θc) days 5 - 15
The F/M ratio Day -1 0.2-0.6
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Wastewater Engineering Dr. Ali Jalil Chabuk Second Course - Lecture 7
EXAMPLE 10.1:
Determine the aeration basin dimensions for a town of 20000 population for the following
requirements:
• Average BOD contribution of 0.091 kg/(person.d)
• BOD removal in the primary clarifiers is 30%.
• Sludge Volume Index (SVI) = 110 mL/g
• Percentage of solids in the mixed liquor P = 0.26%
• Allowlled loading rate of BOD is 0.48 kg/ (d. m3)
• The allowable an additional return sludge is 40%,
• Mixed liquor suspended solids is 2600 mg/L
• Using two tanks with a water depth of 4.5 m, and the tank width is 7 m.
SOLUTION:
Step 1. Calculate total BOD loading (L) on the aeration basin.
Total BOD load influent into the wastewater treatment plant
= 20000 person x 0.091 kg/(person.d) = 1820 kg/d
The total daily BOD load on aeration basin would be
L = 1820 (kg/d) x (1 - 0.3 (BOD removal)) = 1274 kg/d
𝟏𝟎𝟎
% 𝒓𝒆𝒕𝒖𝒓𝒏 𝒔𝒍𝒖𝒅𝒈𝒆 = = 𝟒𝟎 %
𝟏𝟎𝟎
− 𝟏
𝟏𝟏𝟎 𝒙 𝟎. 𝟐𝟔
Step 3. Determine the total BOD loading in the basin
Assume the BOD concentration for both the RAS and the influent areation basin is the same.
The allowable an additional return sludge is 40%, the total BOD loading will be calculated as
follow:
1274 kg/d x 1.40 = 1784 kg/d
Step 4. Determine the required volume (V) for the aeration tank
𝐓𝐨𝐭𝐚𝐥 𝐁𝐎𝐃 𝐥𝐨𝐚𝐝𝐢𝐧𝐠
𝐕=
𝐀𝐥𝐥𝐨𝐰𝐞𝐝 𝐥𝐨𝐚𝐝𝐢𝐧𝐠 𝐩𝐞𝐫 𝐦𝟑
𝟏𝟕𝟖𝟒 𝐤𝐠/𝐝
𝐕= = 𝟑𝟕𝟏𝟕𝐦𝟑
𝐤𝐠
𝟎. 𝟒𝟖
𝐝. 𝐦𝟑
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Wastewater Engineering Dr. Ali Jalil Chabuk Second Course - Lecture 7
Step 5. Determine the dimensions of the aeration tank
Select two tanks, the water depth of 4.5 m, and add 0.6 m as a freeboard, and width of 7 m.
The length of a tank is calculated as follows:
𝟑𝟕𝟏𝟕/𝟐 𝒎𝟑
𝑳𝒆𝒏𝒈𝒕𝒉 = = 𝟓𝟗 𝒎
𝟒. 𝟓 𝒎 𝒙 𝟕 𝒎
EXAMPLE 10.2:
Determine the aeration tank volume based on 6 hours of aeration period, using the data given
in the above Example (10.1). Assume waste flow for each person is 0.53 m3/(person.d).
SOLUTION:
Step 1. Calculate flow rate Q influent into treatment plant
𝑚3
Q = 0.53 ( ) x 20000 persons
person × d
= 10600 m3/d
Step 2. add 40% of Qr
Q + Qr = Q ×1.4
Q + Qr = 10600 m3/d × 1.4
= 14840 m3/d
Qr = 4240 m3/d
Step 3. Calculate the required volume V of a tank
V=Q×t
𝑚3 1𝑑
V = 14840 ( ) x 6h ( )
𝑑 24ℎ
= 3710 m3
Note: For these two examples, the tank volume determined is based on either organic loading
or hydraulic loading.
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Wastewater Engineering Dr. Ali Jalil Chabuk Second Course - Lecture 7
EXAMPLE 10.3:
Determine the return activated-sludge flow as a percentage of the influent flow 37850 m3/d.
The sludge settling volume after 30 min is 255 mL/L.
SOLUTION:
Step 1. Compute RAS flow Qr in %
𝒎𝑳
𝐐𝐫 𝑺𝑺𝑽𝟑𝟎 𝟐𝟓𝟓 𝑳 𝒙 𝟏𝟎𝟎%
𝐑% = = = = 𝟑𝟒%
𝐐 𝟏𝟎𝟎𝟎 − 𝑺𝑺𝑽𝟑𝟎 𝒎𝑳
𝟏𝟎𝟎𝟎 − 𝟐𝟓𝟓 𝑳
Step 2. Compute RAS flow rate
𝐐𝐫
𝐑=
𝐐
Qr = 0.34 Q = 0.34 x 37850 m3/d = 12869 m3/d.
EXAMPLE 10.4:
The MLSS concentration in the aeration tank is 2800 mg/L. The sludge settlable test
showed that the sludge volume (SSV30) is 285 mL that settled for 30 min in a 1 liter
graduated cylinder. Calculate the sludge volume index (SVI) and estimate the SS
concentration in the RAS and the required return sludge ratio.
SOLUTION:
𝐐𝐫
Step 3. Calculate (R) ( )
𝐐
𝒎𝒈
𝐐𝐫 𝑺𝑺𝑽𝟑𝟎 𝟐𝟖𝟓 𝑳
= = 𝒎𝒈 = 𝟎. 𝟒
𝐐 𝟏𝟎𝟎𝟎 − 𝑺𝑺𝑽𝟑𝟎 (𝟏𝟎𝟎𝟎 − 𝟐𝟖𝟓)
𝑳
𝐐𝐫
= 𝟒𝟎 % 𝐫𝐞𝐭𝐮𝐫𝐧
𝐐
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Wastewater Engineering Dr. Ali Jalil Chabuk Second Course - Lecture 7
EXAMPLE 10.5:
Compute the return activated-sludge flow rate in (m3/d and as a percentage of the influent
flow of 37850 m3/d. The laboratory results show that the SVI is 110 mg/L and the MLVSS is
2500 mg/L.
SOLUTION:
Step 1. Compute the suspended solids in RAS based on the SVI
𝟏𝟎𝟔 𝟏𝟎𝟔 𝐦𝐠/𝐋
𝐗𝐫 = = = 𝟗𝟎𝟗𝟎 𝐦𝐠/𝐋
𝐒𝐕𝐈 𝟏𝟏𝟎
𝐦𝐠
𝐗𝐐 𝟐𝟓𝟎𝟎 𝐋 𝐱 𝟑𝟕𝟖𝟓𝟎 𝐦𝟑 /𝐝
𝟑
𝐐𝐫 = = 𝐦𝐠 𝐦𝐠 = 𝟏𝟒𝟑𝟔𝟎 𝐦 /𝐝
𝐗𝐫 − 𝐗 𝟗𝟎𝟗𝟎 𝐋 − 𝟐𝟓𝟎𝟎 𝐋
EXAMPLE 10.6:
An activated-sludge process has a tank influent BOD concentration of 140 mg/L, influent
flow (Q) of 18900 m3/d and 16100 kg of suspended solids (MLSS) under aeration. Calculate
the F/M ratio.
SOLUTION:
Step 1. Calculate BOD in kg/d
BOD (kg/d) (F) = Q (m3/d) × BOD (mg/L)
103
= 18900 m3/d × 140 mg/L × ( ) = 2646 kg/d
106
Step 2. Calculate the volatile suspended solids (VSS) under aeration (kg)
Assume VSS (MLVSS) is 80% of TSS (MLSS)
MLVSS (M) = 16100 kg x 0.8 = 12880 kg
Step 3. Calculate F/M ratio.
𝐤𝐠 𝐤𝐠
𝐅 𝐁𝐎𝐃, 𝟐𝟔𝟒𝟔
= 𝐝 = 𝐝
𝐌 𝐌𝐋𝐕𝐒𝐒, 𝐤𝐠 𝟏𝟐𝟖𝟖𝟎 𝐤𝐠
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Wastewater Engineering Dr. Ali Jalil Chabuk Second Course - Lecture 7
EXAMPLE 10.7:
Convert the BOD concentration of 160 mg/L in the primary effluent into the BOD loading
rate in terms of kg/m3. If this is used for 24 h high rate aeration, what is the rate for 6 h
aeration?
SOLUTION:
Step 1. Calculate BOD loading in kg/m3
𝟏𝐠
𝐦𝐠 𝟏𝟔𝟎 𝐦𝐠 𝐱 ( 𝟏𝟎𝟎𝟎 𝐦𝐠) 𝐠
𝟏𝟔𝟎 = = 𝟏𝟔𝟎 = 𝟎. 𝟏𝟔 𝐤𝐠/𝐦𝟑
𝐋 𝟏 𝐦𝟑 𝐦𝟑
𝟏 𝐋 𝐱 ( 𝟏𝟎𝟎𝟎 𝐋)
𝟐𝟒 𝒉
0.16 kg/(d . m3) x ( ) = 0.64 kg/(d . m3)
𝟔𝒉
Note: The influent BOD to the conventional activated sludge process is limited to 160 mg/L
for 6-h aeration (Ten States Standards).
EXAMPLE 10.8:
Calculate the amount of microbes (kg) (MLVSS) that need to be added into the aeration basin
of a treatment plant over a day, and calculate the RAS value to achieve the amount of MLVSS
in the areation tank. The plant has a capacity (or flow) (Q) of 5000 m3/day. The BOD (S0) of
the wastewater is 200 mg/L. You want to achieve F/M ratio of 0.5 (1/d).
SOLUTION:
𝐅 𝐐 𝐒𝐨 𝐁𝐎𝐃, 𝐤𝐠/𝐝
= =
𝐌 𝐗𝐕 𝐌𝐋𝐕𝐒𝐒, 𝐤𝐠
1. Concentration of BOD (SO) in (kg/m3) in aeration tank
𝟏𝐠
𝐦𝐠 𝟐𝟎𝟎 𝐦𝐠 𝐱 ( 𝟏𝟎𝟎𝟎 𝐦𝐠) 𝐠
𝟐𝟎𝟎 = 𝟑 = 𝟐𝟎𝟎 𝟑 = 𝟎. 𝟐 𝐤𝐠/𝐦𝟑
𝐋 𝟏𝐦 𝐦
𝟏 𝐋 𝐱 ( 𝟏𝟎𝟎𝟎 𝐋)
𝟏𝟎𝟎𝟎, 𝐤𝐠/𝐝
𝐌𝐋𝐕𝐒𝐒, 𝐤𝐠 = = 𝟐𝟎𝟎𝟎 𝐤𝐠
𝟎. 𝟓 /𝐝
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Wastewater Engineering Dr. Ali Jalil Chabuk Second Course - Lecture 7
So, we will need to add 2000 kg of microbes into the aeration basin per day.
About 2% of RAS is microbes. So, if you have 100 grams of RAS, 2 grams of this is
made up of microbes.
𝟎. 𝟎𝟐 𝐑𝐀𝐒 = 𝟐𝟎𝟎𝟎 𝒌𝒈
𝟐𝟎𝟎𝟎 𝒌𝒈
𝐑𝐀𝐒 = = 𝟏𝟎𝟎𝟎𝟎𝟎 𝒌𝒈
𝟎. 𝟎𝟐
So, we need to feed 100000 kg of returned activated sludge into the aeration basin each
day.
EXAMPLE 10.9:
An activated-sludge system has an influent flow of 22700 m3/d with suspended solids of 120
mg/L. Three aeration tanks hold 1500 m3 each with MLSS of 3250 mg/L with 80 percent
volatile portion are in operation. Calculate the sludge age for the system.
SOLUTION:
11700 𝑘𝑔
𝜃𝑐 = = 5.4 𝑑𝑎𝑦𝑠
2180 𝑘𝑔/𝑑
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Wastewater Engineering Dr. Ali Jalil Chabuk Second Course - Lecture 7
EXAMPLE 10.10:
In an activated-sludge system, the solids under aeration (VSS) are 13000 kg ; the solids added
(VSS) are 2200 kg/d; the return activated-sludge VSS concentration is 6600 mg/L; the desired
sludge age is 5.5 days; and the current waste activated sludge (WAS) is 2100 kg/d. Calculate
the WAS flow rate using the sludge age control technique.
SOLUTION:
1. Calculate the desired MLVSS under aeration for the desired sludge age of 5.5 days
The return activated-sludge VSS concentration = 6600 mg/L = 6.6 kg/m3 (given)
Additional VSS in RAS = 900 kg/d
𝑘𝑔
Additional solids removed VSS
𝑑
Additional WAS flow (q) = 𝑘𝑔
concentration VSS in RAS 3
𝑚
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Wastewater Engineering Dr. Ali Jalil Chabuk Second Course - Lecture 7
EXAMPLE 10.11:
The aeration basin volume is 6600 m3. The influent flow to the basin is 37850 m3/d with
BOD5 of 140 mg/L, and the MLSS is 3200 mg/L with 80 percent volatile portion. The SS
concentration in the return activated sludge is 6600 mg/L. The current waste activated-sludge
flow rate is 340 m3/d. Determine the desired WAS flow rate using the F/M ratio control
technique with a desired F/M ratio of 0.32.
SOLUTION:
1. Calculate BOD5 loading
BOD5 = 140 mg/L = 140 g/m3 = 0.14 kg/m3
BOD5 Loading = BOD5 x flow
= 0.14 kg/m3 x 37,850 m3/d
= 5299 kg/d
SOLUTION:
16896 kg
7.5 day =
kg kg
𝑀𝐿𝑉𝑆𝑆 wasted ( ) + 360 ( )
d d
kg
MLVSS wasted 1893 x 103
Q wr = = d = 358 m3 /𝑑
Xr mg
5280
L
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Wastewater Engineering Dr. Ali Jalil Chabuk Second Course - Lecture 7
EXAMPLE 10.13:
The given operating conditions are the same as in Example 11.11. The desired MLVSS is
16500 kg. The SS concentration in RAS is 6600 mg/L. Using MLVSS as a control technique,
calculate the desired WAS flow rate. The current WAS flow rate is 420 m3/d
SOLUTION:
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Wastewater Engineering Dr. Ali Jalil Chabuk Second Course - Lecture 7
EXAMPLE 10.14:
Design an aeration tank for a complete mixing of activated sludge process to reduce the BOD5
of an municipal wastewater to below 50 mg/L. The BOD5 of the raw wastewater averages
214 mg/L. Primary treatment is expected to remove 30% of the BOD5 (influent BOD5 (S0)
into aeration tank is 214 x 0.7 = 150 mg/L). The average rate of flow is 1000 m3/d,
MLVSS/MLSS = 0.8, BOD5 / BODu = 0.67, and the concentration of solids MLSS in the
recycle is Xr = 10000 mg/L.
The design values for the kinetic constants are as follow:
• k = 12 d−1
• Ks = 100 mg/L BOD
• Y = 0.6
• kd = 0.057 d−1
• θ = HRT = 4 hrs.
• θc = 10 days = Sludge Age
SOLUTION:
1. Estimate the soluble BOD of the treated effluent using the following relationship.
𝑘𝑠 (1 + 𝑘𝑑 𝜃𝑐 )
𝑆=
𝜃𝑐 (𝑌𝑘 − 𝑘𝑑 ) − 1
𝑚𝑔
100 (1 + 0.057 𝑑 −1 𝑥 10 𝑑 ) mg
𝑆= 𝐿 = 2.23
10 𝑑 (0.6 𝑥 12 𝑑 −1 − 0.057 𝑑 −1 ) − 1 L
2. Reactor Volume:
V=Q×θ
= 1000 m3/d × 4/24 = 167 m3
𝑴𝑳𝑽𝑺𝑺
MLSS =
𝟎.𝟖
3790 mg/L
MLSS = = 4737 mg/L
0.8
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Wastewater Engineering Dr. Ali Jalil Chabuk Second Course - Lecture 7
4. Calculate the recycle ratio:
Qr 𝑿
R= =
Q 𝐗𝐫 − 𝑿
𝐐𝐫 𝟑𝟕𝟗𝟎
𝐑= = = 𝟎. 𝟗
𝐐 𝟖𝟎𝟎𝟎 − 𝟑𝟕𝟗𝟎
𝑚𝑔
167 𝑚3 𝑥 3790 𝑥 103 /106
𝑋𝑤 = 𝐿 = 63 kg/d
10 d
6. Calculate the observed yield (Px) and the increase in the mass of MLVSS:
𝑌 0.6
𝑌𝑜𝑏𝑠 = = = 0.356
1 + 𝑘𝑑 𝜃𝑐 1 + 0.057 𝑑 −1 𝑥 12 𝑑
𝑃𝑥 = 𝑌𝑜𝑏𝑠 𝑄 (𝑆𝑜 − 𝑆)
𝑚3
𝑃𝑥 = 0.356 𝑥 1000 (150 − 2.23)𝑚𝑔/𝐿 𝑥 103 /106
𝑑
𝑃𝑥 = 52.6 𝑘𝑔/𝑑
𝑘𝑔 𝑄 (𝑆𝑜 − 𝑆)
𝑂2 𝑟𝑒𝑞𝑢𝑖𝑟𝑒𝑑 ( )= 𝑔 – 1.42 𝑃𝑥
𝑑 𝑓 (1000 )
𝑘𝑔
𝑚3
1000 (150 − 2.23)𝑚𝑔/𝐿 𝑥 103 /106 𝑘𝑔
𝑂2 𝑟𝑒𝑞𝑢𝑖𝑟𝑒𝑑 = 𝑑 – 1.42 (52.6 )
0.67 𝑑
𝑘𝑔
𝑂2 𝑟𝑒𝑞𝑢𝑖𝑟𝑒𝑑 = 146
𝑑
32