NAMA TIARA ANDINI

NPM 1515041005

UTS TERMODINAMIKA 1

3.33 Calculate Z and V for ethane at 323.15 K (50 OC) and 15 bar by the followig equations :
a The truncated virial equation [Eq.(3.39)] with the following experimental values of virial coefficien
B = -156.7 cm3mol-1 C = 9.650 cm6mol-2
b The truncated virial equation [Eq(3.37)], with a value of B from the generalized Pitzer correlation [
c The Redlich/Kwong equation
d The Soave/Redlich/Kwong equation
e The Peng/Robinson equation

3.34 Calculate Z and V for sulfur hexafluoride at 75 OC and 15 bar by the following equations :
a The truncated virial equation [Eq.(3.39)] with the following experimental values of virial coefficien
B = -194 cm3mol-1 C = 15.300 cm6mol-2
b The truncated virial equation [Eq(3.37)], with a value of B from the generalized Pitzer correlation [
c The Redlich/Kwong equation
d The Soave/Redlich/Kwong equation
e The Peng/Robinson equation

3.35 Determine Z and V for steam at 250 OC and 1.800 kPa by the following :
a The truncated virial equation [Eq.(3.39)] with the following experimental values of virial coefficien
B = -152.5 cm3mol-1 C = -5.800 cm6mol-2
b The truncated virial equation [Eq.(3.37)] with a values B from the generalized Pitzer correlation [E
c The steam tables (App.F)

3.38 Calculate the molar volume of saturated liquid ad the molar volume of saturated vapor by the Redlich/Kwong e
a Propane at 40 OC where Psat = 13.71 bar
b Propane at 50 OC where Psat = 17.16 bar
c Propane at 60 OC where Psat = 21.22 bar
d Propane at 70 OC where Psat = 25.94 bar
e n-Butane at 100 OC where Psat = 15.41 bar
f n-Butane at 110 OC where Psat = 18.66 bar
g n-Butane at 120 OC where Psat = 22.38 bar
h n-Butane at 130 OC where Psat = 26.59 bar
i Isobutane at 90 OC where Psat = 16.54 bar
j Isobutane at 100 OC where Psat = 20.03 bar
k Isobutane at 110 OC where Psat = 24.01 bar
l Isobutane at 120 OC where Psat = 28.53 bar
m Chlorine at 60 OC where Psat = 18.21 bar
n Chlorine at 70 OC where Psat = 22.49 bar
o Chlorine at 80 OC where Psat = 27.43 bar
p Chlorine at 90 OC where Psat = 33.08 bar
q Sulfur dioxide at 80 OC where Psat = 18.66 bar
 r Sulfur dioxide at 90 OC where Psat = 23.31 bar
s Sulfur dioxide at 100 OC where Psat = 28.74 bar
t Sulfur dioxide at 110 OC where Psat = 35.01 bar

3.43 To a good approximation, what is the molar volume of ethanol vapor at 480 OC and 6.000 kPa? How does this re

3.44 A 0.35 m3 vessel is used to store liquid propane at its vapor pressure . Safety considerations dictate that at a tem

3.59 Determine a good estimate for the compressibility factor Z of saturated hydrogen vapor at 25 K and 3.213 bar. F
erimental values of virial coefficients:

the generalized Pitzer correlation [Eq.(3.37)]

erimental values of virial coefficients:

the generalized Pitzer correlation [Eq.(3.37)]

erimental values of virial coefficients:

e generalized Pitzer correlation [Eq.(3.59)]

ted vapor by the Redlich/Kwong equation for one of the following and compare results with values found by suitable generalized corre
C and 6.000 kPa? How does this result compae with ideal-gas value?

considerations dictate that at a temperature of 320 K the liquid must occupy no more than 80% of the total volume of the vessel. For t

ogen vapor at 25 K and 3.213 bar. For comparison, an experimental value is Z = 0.7757
suitable generalized correlations
volume of the vessel. For these conditions, determine the mass of vapor and the mass of liquid i the vessel. At 320 K the vapo pressure
At 320 K the vapo pressure of propane is 16.0 bar.