EJ-2.

VOLUMEN MOLAR Y
FACTOR DE COMPRESIBILIDAD
EC. REDLICH-KWOMG
Table of Contents
Ecuación de Redlich-Kwong ................................................................................................. 1
a) Calculo de volumen molar (Vm), P=56[atm], T=450[K] ......................................................... 1
b) Calculo de volumen molar (Vm), Pr=[1,2,4,10,20] ................................................................ 1
c) Variación de fact. compresibilidad Z respecto a presiones reducidas ......................................... 2
Conclusiones y comentarios .................................................................................................. 5

GONZALO M. VILLEGAS SALAZAR

Ecuación de Redlich-Kwong
La ec. de Redlich-Kwong presenta la sgte. relación:

Además:

a) Calculo de volumen molar (Vm), P=56[atm],

T=450[K]
R=0.082; %Ctte. Universal de los Gases [L*atm/K*mol]
T=450; P=56; Tc=405.5; Pc=111.3;
a=0.42747*(((R^2)*(Tc^2.5))/Pc);
b=0.08664*((R*Tc)/Pc);
op=optimset('Display','off');
rk=@(Vm) P-((R*T)/(Vm-b))+(a/(Vm*(Vm+b)*sqrt(T)));
Vm=fsolve(rk,0.1,op);
disp(['Vm [L/mol] = ',num2str(Vm)])

Vm [L/mol] = 0.56939

b) Calculo de volumen molar (Vm),

Pr=[1,2,4,10,20]
Pr=[1 2 4 10 20];

1
 EJ-2. VOLUMEN MOLAR Y
FACTOR DE COMPRESIBILI-
DAD EC. REDLICH-KWOMG
P1=Pc*Pr;
frk=@(Vm,P) P-((R*T)./(Vm-b))+(a./(Vm.*(Vm+b).*sqrt(T)));
for k=1:length(Pr)
VM(k)=fsolve(@(Vm)frk(Vm,P1(k)),1,op);
end
Pr=Pr'; Vm=VM';
disp('Volumenes molares[L/mol] respecto a Presiones reducidas:')
table(Pr,Vm)

Volumenes molares[L/mol] respecto a Presiones reducidas:

ans =

Pr Vm
__ ________

1 0.23311
2 0.073661
4 0.050839
10 0.039774
20 0.03481

c) Variación de fact. compresibilidad Z respec-

to a presiones reducidas
Pr=1:1:100;
P1=Pc.*Pr;
frkz=@(Vm,P) P-((R*T)./(Vm-b))+((a*T^-0.5)./(Vm.*(Vm+b)));
for m=1:length(Pr)
fZ(m)=fsolve(@(z)frkz(z,P1(m)),1,op);
end
Pr=Pr'; Z=fZ';
plot(Pr,Z,'b'),grid on
xlabel('Presiones reducidas, Pr'), ylabel('Factor de compresibilidad,
Z')
table(Pr,Z)

ans =

Pr Z
___ ________

1 0.23311
2 0.073661
3 0.056903
4 0.050839
5 0.047351
6 0.044978
7 0.043216
8 0.041836
9 0.040712

2
 EJ-2. VOLUMEN MOLAR Y
FACTOR DE COMPRESIBILI-
DAD EC. REDLICH-KWOMG
10 0.039774
11 0.038974
12 0.03828
13 0.037671
14 0.03713
15 0.036646
16 0.036209
17 0.035813
18 0.03545
19 0.035117
20 0.03481
21 0.034525
22 0.034261
23 0.034014
24 0.033784
25 0.033567
26 0.033364
27 0.033172
28 0.032991
29 0.03282
30 0.032658
31 0.032503
32 0.032357
33 0.032217
34 0.032084
35 0.031957
36 0.031835
37 0.031718
38 0.031607
39 0.0315
40 0.031397
41 0.031298
42 0.031203
43 0.031111
44 0.031023
45 0.030938
46 0.030855
47 0.030776
48 0.030699
49 0.030625
50 0.030553
51 0.030484
52 0.030416
53 0.030351
54 0.030287
55 0.030226
56 0.030166
57 0.030108
58 0.030052
59 0.029997
60 0.029943
61 0.029892
62 0.029841
63 0.029792

3
 EJ-2. VOLUMEN MOLAR Y
FACTOR DE COMPRESIBILI-
DAD EC. REDLICH-KWOMG
64 0.029744
65 0.029697
66 0.029652
67 0.029607
68 0.029564
69 0.029521
70 0.02948
71 0.02944
72 0.0294
73 0.029362
74 0.029324
75 0.029287
76 0.029251
77 0.029216
78 0.029181
79 0.029148
80 0.029115
81 0.029082
82 0.029051
83 0.029019
84 0.028989
85 0.028959
86 0.02893
87 0.028901
88 0.028873
89 0.028845
90 0.028818
91 0.028792
92 0.028766
93 0.02874
94 0.028715
95 0.02869
96 0.028666
97 0.028642
98 0.028619
99 0.028596
100 0.028573

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 EJ-2. VOLUMEN MOLAR Y
FACTOR DE COMPRESIBILI-
DAD EC. REDLICH-KWOMG

Conclusiones y comentarios
La ec. de Redlich-Kwong es una ec. de estado mas rigurosa y precisa para temperaturas y presiones mas
altas, en comparación con la ec de VdW.

Published with MATLAB® R2016a