We have from First Law

d U = dQ + dW ……………… eqn. 1

At constant volume, no work is done so d U = dQ  or
dU dQ
Divide both the sides by dT dT = dT
By definition heat capacity is the quantity of heat per unit degree
of temperature, therefore
dQ
=Cv
dT

Or
dU
=Cv
dT

dU = Cv dT (const V)
Integration yields:

Or from equation 1
At constant pressure, part of the heat is used to do some work
and part of heat is used to rise the temperature, and at constant
pressure this heat will be equal to enthalpy.
Q= H = U + PV

Or in differential form Q =d H = dU + PdV

But dU = Cv dT
Therefore d H = Cv dT + PdV
Divide both the sides by dT
dH
dT
= Cv + P dV
dT

dH dV
dT
=C p and P dT =R so C p=C v + R

Therefore for very small amount of change of temperature the

above equation is written as

Integration yields:

For a mechanically reversible, constant-P process,