JPCRD 36 685

IUPAC-NIST Solubility Data Series. 82.
Alcohols with Water–Revised

and Updated: Part 5. C8 – C17 Alcohols with Water
Andrzej Maczynski, Volume Editora…

Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland
David G. Shaw, Volume Editorb…

University of Alaska, Fairbanks, Alaska
Marian Goral and Barbara Wisniewska-Goclowska, Assistants

Institute of Physical Chemistry, Polish Academy of Sciences, Warsaw, Poland
共Received 8 May 2006; revised manuscript received 7 July 2006; accepted 4 September 2006; published online 6 July 2007兲
The mutual solubilities and related liquid–liquid equilibria of C8 – C17 alcohols with
water are exhaustively and critically reviewed. Reports of experimental determination of
solubility in 21 chemically distinct binary systems that appeared in the primary literature
prior to the end of 2004 are compiled. For 12 systems sufficient data are available to
allow critical evaluation. All data are expressed as mass percent and mole fraction as well
as the originally reported units. In addition to the standard evaluation criteria used
throughout the Solubility Data Series, a new method based on the evaluation of the all
experimental data for a given homologous series of saturated alcohols was used. © 2007
American Institute of Physics. 关DOI: 10.1063/1.2391321兴
Key words: C8–C17 alcohols; critical evaluation; liquid–liquid equilibria; reference data; solubilities; water.
CONTENTS 2.17. 1-Undecanol + Water*. . . . . . . . . . . . . . . . . 722

2.18. 1-Dodecanol ⫹ Water*. . . . . . . . . . . . . . . . . 723
2.19. 1-Tetradecanol + Water*. . . . . . . . . . . . . . . . 726
1. Preface. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 687 2.20. 1-Hexadecanol + Water*. . . . . . . . . . . . . . . 726
1.1. Scope of this Volume. . . . . . . . . . . . . . . . . . 687 2.21. 1-Heptadecanol + Water*. . . . . . . . . . . . . . . 727
1.2. References for the Preface. . . . . . . . . . . . . . 687 3. System Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 728
2. C8 – C17 Alcohols with Water. . . . . . . . . . . . . . . . 688 4. Registry Number Index. . . . . . . . . . . . . . . . . . . . . 729
2.1. ␣-Methylbenzenemethanol ⫹ Water. . . . . . 688 5. Author Index. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 729
2.2. 2-Phenylethanol ⫹ Water. . . . . . . . . . . . . . . 688 6. Cumulative References for the Solubility of
2.3. Cyclooctanol ⫹ Water. . . . . . . . . . . . . . . . . 688 C8 – C17 Alcohols with Water. . . . . . . . . . . . . . . . 730
2.4. 2,6-Dimethylcyclohexanol ⫹ Water. . . . . . . 689
*A Critical Evaluation is prepared for this system.
2.5. 2-Ethyl-1-hexanol ⫹ Water*. . . . . . . . . . . . 689
2.6. 1-Octanol ⫹ Water*. . . . . . . . . . . . . . . . . . . 694
2.7. 2-Octanol + Water*. . . . . . . . . . . . . . . . . . . . 703 List of Tables
2.8. 3-Octanol + Water. . . . . . . . . . . . . . . . . . . . . 707
2.9. 1-Phenyl–1-propanol + Water. . . . . . . . . . . . 707 1. Solubility in the
2.10. 2,6-Dimethyl–4-heptanol ⫹ Water*. . . . . . . 708 ␣-methylbenzenemethanol/water system.14. . . . . 688
2.11. 1-Nonanol + Water*. . . . . . . . . . . . . . . . . . . 710 2. Solubility in the 2-phenylethanol/water
2.12. 2-Nonanol + Water*. . . . . . . . . . . . . . . . . . . 714 system.40. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 688
2.13. 3,3,5-Trimethyl–1-hexanol ⫹ Water. . . . . . . 716 3. Solubility in the cyclooctanol/water system.40... 688
2.14. 3,5,5-Trimethyl-1-hexanol ⫹ Water. . . . . . . 716 4. Solubility in the 2,6-dimethylcyclohexanol/
2.15. cis-3,7-Dimethyl–2,6-octadien–1-ol + water system.40. . . . . . . . . . . . . . . . . . . . . . . . . . . 689
Water. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 717 5. Sources of solubility data for 2-ethyl–
2.16. 1-Decanol ⫹ Water*. . . . . . . . . . . . . . . . . . . 717 1-hexanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . 689
6. Sources of solubility data for water 共2兲 in
a兲 2-ethyl–1-hexanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . 690
Electronic mail: macz@ichf.edu.pl
b兲
Electronic mail: ffdgs@uaf.edu 7. The data categories for solubility of 2-ethyl–
© 2007 American Institute of Physics. 1-hexanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . 691
0047-2689/2007/36„3…/685/47/$42.00 685 J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
Downloaded 09 Jan 2011 to 140.226.6.63. Redistribution subject to AIP license or copyright; see http://jpcrd.aip.org/about/rights_and_permissions
686 A. MACZYNSKI AND D. G. SHAW
8. Experimental values for solubility of 2-ethyl– 43. Solubility in the 1-phenyl–1-propanol/water

1-hexanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . 691 system.40. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 707
9. The data categories for solubility of water 共2兲 44. The data categories for solubility of
in 2-ethyl–1-hexanol 共1兲.. . . . . . . . . . . . . . . . . . . 691 2,6-dimethyl–4-heptanol 共1兲 in water 共2兲.. . . . . . 709
10. Experimental values for solubility of water 共2兲 45. Experimental values for solubility of
in 2-ethyl–1-hexanol 共1兲.. . . . . . . . . . . . . . . . . . . 692 2,6-dimethyl–4-heptanol 共1兲 in water 共2兲.. . . . . . 709
11. Solubility in the 2-ethyl–1-hexanol/water 46. Experimental values for solubility of water 共2兲
system.11. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 692 in 2,6-dimethyl–4-heptanol 共1兲.. . . . . . . . . . . . . . 709
12. Solubility in the 2-ethyl–1-hexanol/water 47. Solubility in the 2,6-dimethyl–4-heptanol/
system.16. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 693 water system.40. . . . . . . . . . . . . . . . . . . . . . . . . . . 709
13. Solubility in the 2-ethyl–1-hexanol/water 48. Sources of solubility data for 1-nonanol 共1兲 in
system.30. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 693 water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 710
14. Solubility in the 2-ethyl–1-hexanol/water 49. Sources of solubility data for water 共2兲 in
system.32. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 693 1-nonanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . 710
15. Solubility in the 2-ethyl–1-hexanol/water 50. The data categories for solubility of 1-nonanol
system.33. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 694 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . 711
16. Solubility in the 2-ethyl–1-hexanol/water 51. Experimental values for solubility of
system.41. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 694 1-nonanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . 711
17. Sources of solubility data for 1-octanol 共1兲 in 52. The data categories for solubility of water 共2兲
water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 695 in 1-nonanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . 712
18. Sources of solubility data for water 共2兲 in 53. Experimental values for solubility of water 共2兲
1-octanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 695 in 1-nonanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . 712
19. The data categories for solubility of 1-octanol 54. Solubility in the 1-nonanol/water system.40. . . . . 713
共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . 697 55. Solubility of 1-nonanol 共1兲 in water 共2兲s.42. . . . . 714
20. Experimental values for solubility of 1-octanol 56. Experimental values for solubility of
共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . 697 2-nonanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . 715
21. The data categories for solubility of water 共2兲 57. Experimental values for solubility of water 共2兲
in 1-octanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . 698 in 2-nonanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . 715
22. Experimental values for solubility of water 共2兲 58. Solubility in the 2-nonanol/water system.40. . . . . 715
in 1-octanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . 699 59. Solubility in the 3,3,5-trimethyl–1-hexanol/
23. Solubility study in the 1-octanol/water water system.40. . . . . . . . . . . . . . . . . . . . . . . . . . . 716
system.6. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 700 60. Solubility in the 3,5,5-trimethyl–1-hexanol/
24. Solubility of water 共2兲 in 1-octanol 共1兲.5. . . . . . . 700 water system.40. . . . . . . . . . . . . . . . . . . . . . . . . . . 716
25. Solubility of water 共2兲 in 1-octanol 共1兲.4. . . . . . . 700 61. Solubility of cis-3,7-dimethyl–2,6-octadien–
26. Solubility in the 1-octanol/water system.9. . . . . . 701 1-ol 共1兲 in water 共2兲.28. . . . . . . . . . . . . . . . . . . . . 717
27. Solubility of water 共2兲 in 1-octanol 共1兲.15. . . . . . 701 62. Sources of dolubility data for 1-decanol 共1兲 in
28. Solubility of 1-octanol 共1兲 in water 共2兲.21. . . . . . 701 water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 717
29. Solubility of water 共2兲 in 1-octanol 共1兲.30. . . . . . 702 63. Sources of solubility data for water 共2兲 in
30. Solubility in the 1-octanol/water system.33. . . . . 702 1-decanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . 718
31. Solubility of 1-octanol 共1兲 in water 共2兲.35. . . . . . 702 64. The data categories for solubility of 1-decanol
32. Solubility in the 1-octanol/water system.41. . . . . 703 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . 719
33. Sources of solubility data for 2-octanol 共1兲 in 65. Experimental values for solubility of 1-decanol
water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 703 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . 719
34. Sources of solubility data for water 共2兲 in 66. The data categories for solubility of water 共2兲
2-octanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 703 in 1-decanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . 720
35. The data categories for solubility of 2-octanol 67. Experimental values for solubility of water 共2兲
共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . 704 in 1-decanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . 720
36. Experimental values for solubility of 2-octanol 68. Solubility of water 共2兲 in 1-decanol 共1兲.15. . . . . . 721
共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . 705 69. Solubility in the 1-decanol/water system.40. . . . . 721
37. The data categories for solubility of water 共2兲 70. Experimental values for solubility of
in 2-octanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . 705 1-undecanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . 722
38. Experimental values for solubility of water 共2兲 71. Experimental values for solubility of water 共2兲
in 2-octanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . 705 in 1-undecanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . 723
39. Solubility in the 2-octanol/water system.7. . . . . . 706 72. Solubility in the 1-undecanol/water system.40. . . 723
40. Solubility of water 共2兲 in 2-octanol 共1兲.30. . . . . . 706 73. The data categories for solubility of
41. Solubility in the 2-octanol/water system.40. . . . . 706 1-dodecanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . 724
42. Solubility in the 3-octanol/water system.40. . . . . 707 74. Experimental values for solubility of
J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007
IUPAC-NIST SOLUBILITY DATA SERIES 687
1-dodecanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . 725 1. Preface

75. The data categories for solubility of water 共2兲
in 1-dodecanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . 725 1.1. Scope of this Volume
76. Experimental values for solubility of water 共2兲 This paper is Part 5 of a revised and updated version of an
in 1-dodecanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . 725 earlier compilation and evaluation of the mutual solubilities
77. Solubilty in the 1-dodecanol/water system.40. . . 725 of water and alcohols containing three or more carbon
78. Experimental values for solubility of
atoms.8 This new work incorporates new compilations based
1-tetradecanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . . 726
on recent and previously overlooked reports in the peer-
79. Experimental values for solubility of
1-hexadecanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . 727 reviewed scientific literature prior to 2004. To facilitate com-
80. Experimental values for solubility of parison of data, all original results are expressed in terms of
1-heptadecanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . 728 mass percent and mole fraction as well as the units reported
81. Experimental values for solubility of water 共2兲 by the original investigators. This revised work also includes
in 1-heptadecanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . 728 all new evaluations for systems where two or more indepen-
82. Solubility in the 1-heptadecanol/water dent measurements of solubility have been reported. In these
system.44. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 728 evaluations reported solubility values are characterized as
Recommended, Tentative, Doubtful, or Rejected, based on
consistency between independently determined experimental
List of Figures values and reference values derived from a newly developed
set of smoothing equations 共see Maczynski and Shaw26 and
1. All the solubility data for 2-ethyl–1-hexanol Goral et al.17兲. Recommended data are supported by two 共or
共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . 690 more兲 independent experimental data and a reference value
2. All the solubility data for water 共2兲 in 2-ethyl– that are all in agreement. Tentative values are supported by
1-hexanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . 690
two 共or more兲 independent values in agreement with each
3. All the solubility data for 1-octanol 共1兲 in
other, but not with the reference value, or one experimental
water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 695
4. All the solubility data for water 共2兲 in value in agreement with the reference value. Doubtful values
1-octanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 696 are those for which a single experimental value differs from
5. All the solubility data for 2-octanol 共1兲 in the reference value. The data, which lack sufficient informa-
water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 704 tion to justify evaluation are Rejected.
6. All the solubility data for water 共2兲 in Detailed introductory material including explanations of
2-octanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 704 the formats of compilation and evaluation, definitions of
7. All the solubility data for 2,6-dimethyl– commonly used measures of solubility, and the scope of the
4-heptanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . . 708 Solubility Data Series can be found in Part 1.25 The deriva-
8. All the solubility data for 1-nonanol 共1兲 in tion of the smoothing equations used for calculate reference
water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 710 values can be found in Part 226 and Goral et al.17
9. All the solubility data for water 共2兲 in
1-nonanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . 711
10. All the solubility data for 2-nonanol 共1兲 in
water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 714
11. All the solubility data for water 共2兲 in 1.2. References for the Preface
2-nonanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . 715
8
12. All the solubility data for 1-decanol 共1兲 in A. F. M. Barton, Editor, IUPAC Solubility Data Series, Vol.
water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 718 15, Alcohol with Water 共Pergamon, New York 1989兲.
13. All the solubility data for water 共2兲 in 17
M. Goral, B. Wisniewska-Goclowska, and A. Maczynski,
1-decanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . 719 “Recommended Liquid-Liquid Equilibrium Data, Part 4:
14. All the solubility data for water 共2兲 in Binary Alkanols - Water Systems,” J. Phys. Chem. Ref.
1-undecanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . 722 Data 35, 1391 共2006兲.
15. All the solubility data for 1-dodecanol 共1兲 in 25
A. Maczynski and D. G. Shaw, Editor, “IUPAC-NIST Solu-
water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 724
bility Data Series. 82. Alcohol with Water–Revised and
16. All the solubility data for water 共2兲 in
Updated. Part 1. C5 alcohols with water,” J. Phys. Chem.
1-dodecanol 共1兲.. . . . . . . . . . . . . . . . . . . . . . . . . . 724
17. All the solubility data for 1-tetradecanol 共1兲 in Ref. Data 36, 59 共2007兲.
26
water 共2兲.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 726 A. Maczynski and D. G. Shaw, Editor, “IUPAC-NIST Solu-
bility Data Series. 82. Alcohol with Water - Revised and
Ref. Data 36, 191 共2007兲.
2. C8 – C17 Alcohols with Water TABLE 2. Solubility in the 2-phenylethanol/water system.40—Continued
2.1. ␣-Methylbenzenemethanol ⴙ Water Solubility of 2-phenylethanol in water
0.0 7.10 0.3410

Components: Original Measurements: 10.0 7.95 0.3694
共1兲 ␣-Methylbenzenemethanol; 14
A. F. Frolov, M. A. Loginova, 19.7 8.06 0.3728
C8H10O; 关98-85-1兴 E. A. Frolova, I. I. 30.5 8.54 0.3877
共2兲 Water; H2O; 关7732-18-5兴 Skorokhodova, and Z. V. 40.0 8.89 0.3982
Krupina, Uch. Zap. Yarosl. 50.0 9.42 0.4136
Tekhnol. Inst. Khim. Khim.
60.3 10.24 0.4362
Tekhnol. 28, 98 共1971兲.
Variables: Prepared by: Auxiliary Information

One temperature: 25 ° C B. Wisniewska-Goclowska
Method/Apparatus/Procedure:
The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought
Experimental Values into equilibrium at a given temperature in a thermostat and samples of
TABLE 1. Solubility in the ␣-methylbenzenemethanol/water system.14 each layer were removed by syringe for analysis. To each sample a higher
boiling organic compound was added as a standard and the ratio of peaks
Solubility of ␣-methylbenzenemethanol in water was measured by gas chromatography 关R. M. Stephenson, J. Stuart, and
M. Tabak, J. Chem. Eng. Data 29, 287 共1984兲兴. Temperature was
t 共°C兲 g共1兲 / 100 g sln x1 共compiler兲
measured by a calibrated thermometer accurate to 0.1 ° C 共see Table 2兲.
t 共°C兲 g共2兲 / 100 g sln x2 共compiler兲
Source and Purity of Materials:
共1兲 Commercial reagent; purity 98 mass %.
Auxiliary Information 共2兲 Not stated.
Method/Apparatus/Procedure: Estimated Error:

The titration method was used. The appearance and disappearance of Temperature: ±0.1 ° C.
cloudness was observed after adding the components at constant Solubility: 共a兲 0.02, 共b兲 0.03 共standard deviation兲.
temperature. No more details were reported in the paper. The results
reported above are part of ternary solubility measurements 共see Table 1兲.

2.3. Cyclooctanol ⴙ Water
共1兲 Source not specified; nD20 = 1.5214, d4 = 1.0153, tb / ° C = 205.0.
共2兲 Not specified.
Components: Original Measurements:
Estimated Error: 共1兲 Cyclooctanol; C8H16O; 40
R. M. Stephenson and J.
Not specified. 关696-71-9兴 Stuart, J. Chem. Eng. Data 31,
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲.
Variables: Prepared by:

2.2. 2-Phenylethanol ⴙ Water Temperature: 10– 90.5 ° C B. Wisniewska-Goclowska
Experimental Values
Components: Original Measurements: TABLE 3. Solubility in the cyclooctanol/water system.40
共1兲 2-Phenylethanol; C8H10O; 40
关60-12-8兴 Stuart, J. Chem. Eng. Data 31, Solubility of cyclooctanol in water
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲.
t共°C兲 g共1兲 / 100 g slna兲 x1共compiler兲
Temperature: 0 – 60.3 ° C B. Wisniewska-Goclowska 20.0 0.69 0.00098
31.0 0.61 0.00086
Experimental Values
40.0 0.60 0.00085
TABLE 2. Solubility in the 2-phenylethanol/water system.40
50.0 0.66 0.00093
60.5 0.61 0.00086
Solubility of 2-phenylethanol in water
70.3 0.61 0.00086
t共°C兲 g共1兲 / 100 g slna兲 x1共compiler兲 80.5 0.66 0.00093
90.5 0.73 0.00103
19.7 2.45 0.00369
30.5 2.32 0.00349 Solubility of water in cyclooctanol
40.0 2.38 0.00358
t共°C兲 g共2兲 / 100 g slnb兲 x2共compiler兲
50.0 2.55 0.00384
60.3 2.67 0.00403 31.0 5.18 0.2800
40.0 5.49 0.2925
Solubility of water in 2-phenylethanol
50.0 5.49 0.2925
t共°C兲 t共°C兲g共2兲 / 100 g slnb兲 x2共compiler兲 60.5 5.83 0.3058
TABLE 3. Solubility in the cyclooctanol/water system.40—Continued TABLE 4. Solubility in the 2,6-dimethylcyclohexanol/water

system.40—Continued
Solubility of cyclooctanol in water
70.3 6.05 0.3143 90.6 0.43 0.00061

80.5 6.33 0.3248 Solubility of water in 2,6-dimethylcyclohexanol
90.5 6.84 0.3432 t共°C兲 g共2兲 / 100 g slnb兲 x2共compiler兲
0.0 2.54 0.1565
9.5 2.86 0.1732
Auxiliary Information
19.7 3.16 0.1885
Method/Apparatus/Procedure: 30.6 3.39 0.1998
The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought 40.0 3.48 0.2042
into equilibrium at a given temperature in a thermostat and samples of 49.9 3.73 0.2161
each layer were removed by syringe for analysis. To each sample a higher 60.5 3.73 0.2161
boiling organic compound was added as a standard and the ratio of peaks 70.6 3.73 0.2161
was measured by gas chromatography 关R. M. Stephenson, J. Stuart, and 80.5 3.82 0.2204
M. Tabak, J. Chem. Eng. Data 29, 287 共1984兲兴. Temperature was 90.6 3.98 0.2278
Source and Purity of Materials: Auxiliary Information

共2兲 Not stated.
Estimated Error: into equilibrium at a given temperature in a thermostat and samples of
Temperature: ±0.1 ° C. each layer were removed by syringe for analysis. To each sample a higher
Solubility: 共a兲 0.01, 共b兲 0.02 共standard deviation兲. boiling organic compound was added as a standard and the ratio of peaks
was measured by gas chromatography关1R. M. Stephenson, J. Stuart, and
2.4. 2,6-Dimethylcyclohexanol ⴙ Water measured by a calibrated thermometer accurate to 0.1 ° C 共see Table 4兲.

Components: Original Measurements: 共1兲 Commercial reagent; purity 99 mass %.
共1兲 2,6-Dimethylcyclohexanol; 40
R. M. Stephenson and J. 共2兲 Not stated.
C8H16O; 关5337-72-4兴 Stuart, J. Chem. Eng. Data 31,
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲. Estimated Error:
Temperature: ±0.1 ° C.
Variables: Prepared by: Solubility: 共a兲 0.03, 共b兲 0.03 共standard deviation兲.
Temperature: 0 – 90.6 ° C B. Wisniewska-Goclowska
Experimental Values
TABLE 4. Solubility in the 2,6-dimethylcyclohexanol/water system.40 2.5. 2-Ethyl-1-hexanol ⴙ Water
Solubility of 2,6-dimethylcyclohexanol in water

Components: Evaluators:
t共°C兲 g共1兲 / 100 g slna兲
x1共compiler兲共1兲 2-Ethyl-1-hexanol; C8H16O; A. Maczynski, M. Goral, and B.
0.0 0.83 0.00117 关104-76-7兴 Wisniewska-Goclowska,
共2兲 Water; H2O; 关7732-18-5兴 Thermodynamics Data Center,
9.5 0.64 0.00090
Warsaw, Poland, March, 2006.
19.7 0.49 0.00069
30.6 0.41 0.00058
40.0 0.36 0.00051 Critical evaluation of the solubility of 2-ethyl–1-
49.9 0.35 0.00049 hexanol (1) in water (2)
60.5 0.42 0.00059 The experimental solubility data for 共1兲 in 共2兲 have been
70.6 0.36 0.00051
investigated by the authors listed in Table 5 together with
80.5 0.36 0.00051
temperature range:
TABLE 5. Sources of solubility data for 2-ethyl–1-hexanol 共1兲 in water 共2兲.
Author 共s兲 T共K兲 Author 共s兲 T共K兲

11 32
Cabezas et al. 298 Ratkovics et al. 293
Ghanadzadeh et al.16 298–313 Ratkovics et al.33 293
McBain and Richards27 298 Stephenson et al.41 283–364
Moriyoshi et al.30 298
FIG. 1. All the solubility data for 2-ethyl–1-hexanol 共1兲 in water 共2兲. FIG. 2. All the solubility data for water 共2兲 in 2-ethyl–1-hexanol 共1兲.
The reference solubility values of 共1兲 in 共2兲 were calcu- TABLE 6. Sources of solubility data for water 共2兲 in 2-ethyl–1-hexanol 共1兲.
lated by the equation:
11 30
Cabezas et al. 298 Moriyoshi et al. 298
Ghanadzadeh et al.16 298–303 Ratkovics et al.32 293
ln x1 = ln x1,min + C1关T1,min/T − 1 − ln共T1,min/T兲兴, 共1兲 Hlavaty and Linek19 298 Ratkovics et al.33 293
McBain and Richards27 273 Stephenson et al.41 283–364
where T1,min = 306.4 K, ln x1,min = −9.24, and C1 = 40.0. The reference solubility values of water 共2兲 in alkanol 共1兲
T1,min, ln x1,min, and C1 were calculated with Eqs. 共7兲, 共9兲, were determined by liquid–liquid equilibrium 共LLE兲 calcula-
and 共10兲, where constants defined by Eqs. 共12兲 were used. In tions described in the Preface to Part 2.26 The concentrations
these equations number of carbon atoms 共Nc兲 was replaced of 共1兲 in 共2兲 predicted from Eq. 共1兲 were used as the input
by an effective value N*c = 7.68, which was calculated from data. The reference values obtained from the LLE calcula-
Eq. 共13兲. All the mentioned equations are given in the Pref- tions were afterward regressed by Eq. 共2兲
ace to Part 226 共see Table 6兲. ln x2 = ln x2,min + C2关T2,min/T − 1 − ln共T2,min/T兲兴, 共2兲
The criteria used to assign data to categories listed in
Table 7 are also described in the Preface to Part 2.26 All the where T2,min = 263.2 K, ln x2,min = −1.875, and C2 = 7.99.
experimental data and reference values are listed in Table 8 The criteria used to assign data to categories listed in
and shown in Fig. 1. Some data used in this evaluation were Table 9 are described in the Preface to Part 2.26 All the ex-
compiled for an earlier version of this work.8 Those compi- perimental data and reference values are listed in the Table
lations are not reprinted here. New compilations are pre- 10 and shown in Fig. 2.
sented following this evaluation.
References for 2-ethyl–1-hexanol/water system
Critical evaluation of the solubility of water (2) in 8
A. F. M. Barton, Editor, IUPAC Solubility Data Series, Vol.
2-ethyl–1-hexanol (1) 15, Alcohols with Water 共Pergamon, New York, 1984兲.
The experimental solubility data for 共2兲 in 共1兲 have been 11
J. L. Cabezas, L. A. Barcena, J. Coca, and M. Cockrem, J.
investigated by the authors listed in Table 6 together with Chem. Eng. Data 33, 435 共1988兲.
16
temperature range. H. Ghanadzadeh, A. Ghanadzadeh, and R. Sariri, J. Chem.
30
Thermodyn. 36, 1001 共2004兲. T. Moriyoshi, T. Sakamoto, and Y. Uosaki, J. Chem. Ther-
19
K. Hlavaty and J. Linek, Collect. Czech. Chem. Commun. modyn. 21, 947 共1989兲.
38, 374 共1973兲. 32
F. Ratkovics, B. Palagyi-Fenyes, E. Hajos-Szikszay, and A.
26
Dallos, J. Chem. Thermodyn. 22, 129 共1990兲.
bility Data Series. 82. Alcohol with Water – Revised and 33
Ref. Data 36, 191 共2007兲. Dallos, J. Chem. Thermodyn. 23, 859 共1991兲.
27 41
J. W. McBain and P. H. Richards, Ind. Eng. Chem. 38, 642 R. Stephenson, J. Stuart, and M. Tabak, J. Chem. Eng. Data
共1946兲. 29, 287 共1984兲.
TABLE 7. The data categories for solubility of 2-ethyl–1-hexanol 共1兲 in water 共2兲.
Tentative Doubtful
关data in good agreement 关data in poor agreement
T共K兲共±10% 兲 with the reference values兴共⬎10% 兲 with the reference values兴
283.4 and 293.0 Stephenson et al.41

293.1 Ratkovics et al.32
298.2 Cabezas et al.11 Ghanadzadeh et al.16
McBain and Richards27
Moriyoshi et al.30
302.8 Stephenson et al.41
303.2–313.2 Ghanadzadeh et al.16
323.4–363.5 Stephenson et al.41
TABLE 8. Experimental values for solubility of 2-ethyl–1-hexanol 共1兲 in water 共2兲.
Experimental values x1
T共K兲共T⫽tentative, D⫽doubtful兲 Reference values x1
283.4 1.83⫻ 10−4 共D; Ref. 41兲 1.10⫻ 10−4

293.0 1.73⫻ 10−4 共D; Ref. 41兲 1.01⫻ 10−4
293.1 2.80⫻ 10−4 共D; Ref. 32兲 1.01⫻ 10−4
293.2 3.00⫻ 10−4 共D; Ref. 33兲, 2.00⫻ 10−4 共D; Ref. 33兲 1.01⫻ 10−4
298.2 1.00⫻ 10−4 共T; Ref. 11兲, 4 . ⫻ 10−4共D; Ref. 16兲, 9.87⫻ 10−5
1.70⫻ 10−4 共D; Ref. 27兲, 1.00⫻ 10−3 共D; Ref. 30兲
302.8 1.34⫻ 10−4 共D; Ref. 41兲 9.75⫻ 10−5
303.2 4.00⫻ 10−4 共D; Ref. 16兲 9.75⫻ 10−5
308.2 4.00⫻ 10−4 共D; Ref. 16兲 9.79⫻ 10−5
313.2 4.00⫻ 10−4 共D; Ref. 16兲 9.82⫻ 10−5
313.3 1.52⫻ 10−4 共D; Ref. 41兲 9.82⫻ 10−5
323.4 1.02⫻ 10−4 共T; Ref. 41兲 1.03⫻ 10−4
333.5 1.19⫻ 10−4 共T; Ref. 41兲 1.12⫻ 10−4
343.3 1.37⫻ 10−4 共T; Ref. 41兲 1.25⫻ 10−4
353.3 1.50⫻ 10−4 共T; Ref. 41兲 1.43⫻ 10−4
363.5 1.62⫻ 10−4 共T; Ref. 41兲 1.69⫻ 10−4
TABLE 9. The data categories for solubility of water 共2兲 in 2-ethyl–1-hexanol 共1兲.
Tentative Doubtful
T共K兲共±5 % 兲 with the reference values兴共⬎5 % 兲 with the reference values兴
273.2 McBain and Richards27

Stephenson et al.41
297.8 Hlavaty and Linek19
TABLE 9. The data categories for solubility of water 共2兲 in 2-ethyl–1-hexanol 共1兲.—Continued
Tentative Doubtful
298.2 Cabezas et al.11

Ghanadzadeh et al.16
Moriyoshi et al.30
303.2 Ghanadzadeh et al.16
41
323.2 Stephenson et al.
343.5– Stephenson et al.41
363.5
TABLE 10. Experimental values for solubility of water 共2兲 in 2-ethyl–1-hexanol 共1兲.
273.2 0.1331 共D; Ref. 27兲 0.1541

283.0 0.1421 共D; Ref. 41兲 0.1565
293.1 0.1724 共D; Ref. 32兲 0.1603
293.2 0.1724 共D; Ref. 33兲, 0.1509 共D; Ref. 41兲 0.1603
297.8 0.0014 共D; Ref. 19兲 0.1625
298.2 0.1438 共D; Ref. 11兲, 0.1081 共D; Ref. 16兲, 0.1330 共D; Ref. 30兲 0.1627
303.2 0.1081 共D; Ref. 16兲 0.1654
303.3 0.1564 共D; Ref. 41兲 0.1655
308.2 0.1081 共D; Ref. 16兲 0.1686
312.9 0.1681 共T; Ref. 41兲 0.1716
313.2 0.1081 共D; Ref. 16兲 0.1718
323.2 0.1734 共T; Ref. 41兲 0.1794
333.4 0.1984 共D; Ref. 41兲 0.1885
343.5 0.2072 共T; Ref. 41兲 0.1987
353.2 0.2077 共T; Ref. 41兲 0.2098
363.5 0.2333 共T; Ref. 41兲 0.2230
共1兲 2-Ethyl-1-hexanol; C8H18O; 11
J. L. Cabezas, L. A. Barcena, Method/Apparatus/Procedure:
关104-76-7兴 J. Coca, and M. Cockrem, J. The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought
共2兲 Water; H2O; 关7732-18-5兴 Chem. Eng. Data 33, 435 共1988兲. into equilibrium at a given temperature in an equilibrium still and samples
of each layer were removed for analysis. Compositions were obtained
Variables: Prepared by: from densities and refractive indexes measured at either 24 or 26 ° C, to
One temperature: 25 ° C B. Wisniewska-Goclowska avoid turbidity and phase separation. Densities were measured with a
calibrated U-pycnometer and refractive indexes with a PZO-RL2 Abbe
Experimental Values
refractometer 共see Table 11兲.
TABLE 11. Solubility in the 2-ethyl–1-hexanol/water system.11
Solubility of 2-ethyl–1-hexanol in water 共1兲 Source not specified; reagent grade; distilled.
t共°C兲 g共1兲 / 100 g sln x1共compiler兲
25 0.07 0.0001 Estimated Error:
Solubility of water in 2-ethyl–1-hexanol Solubility: 0.1% 共relative accuracy兲.
25 2.27 0.1438
Experimental Values
H. Ghanadzadeh, A.
关104-76-7兴 Ghanadzadeh, and R. Sariri, J. Solubility of 2-ethyl–1-hexanol in water
共2兲 Water; H2O; 关7732-18-5兴 Chem. Thermodyn. 36, 1001
共2004兲. g共1兲 / 100 g sln
T共K兲 P共MPa兲共compiler兲 x1
Temperature: 298.2– 313.2 K B. Wisniewska-Goclowska 298.15 0.1 0.66 0.001
100 0.66 0.001
Experimental Values
TABLE 12. Solubility in the 2-ethyl–1-hexanol/water system.16 200 0.66 0.001
Solubility of water in 2-ethyl–1-hexanol

Solubility of 2-ethyl–1-hexanol in water
g共2兲 / 100 g sln
g共1兲 / 100 g sln T共K兲 P共MPa兲共compiler兲 x2
T共K兲共compiler兲 x1
298.15 0.1 2.25 0.133
298.2 0.27 0.0004
100 2.64 0.153
303.2 0.27 0.0004
200 2.84 0.163
308.2 0.27 0.0004
313.2 0.27 0.0004
Solubility of water in 2-ethyl–1-hexanol Auxiliary Information
g共2兲 / 100 g sln Method/Apparatus/Procedure:

T共K兲共compiler兲 x2 The analytical method 关T. Moriyoshi, T. Sakamoto, and Y. Uosaki, J.
Chem. Thermodyn. 20, 551 共1988兲兴 was used. The apparatus consisted of
298.2 1.78 0.1081 a high-pressure equilibrium cell, two hand operated pumps, a pressure
303.2 1.78 0.1081 exchanger, two pressure gauges and auxiliary equipment. The equilibrium
308.2 1.78 0.1081 cell was a stainless-steel cylinder of about 50 mL capacity, equipped with
313.2 1.78 0.1081 a mechanical stirrer and two pieces of pressure tubing connected to two
valves for the withdrawal of samples and immersed in a thermostat
controlled to ±0.02 K. Pressure was measured with an accuracy of
Auxiliary Information ±0.1 MPa with a Heise Bourdon gauge and a strain-gauge pressure
transducer connected to a digital integrator. Samples were analyzed by a
Method/Apparatus/Procedure: Shimadzu gas chromatograph model GC-9APT with a
The analytical method was used. Measurements were made in a 250-mL thermal-conductivity detector, equipped with an electronic integrator
glass cell where the temperature of the apparatus was controlled by a Shimadzu Chromatopac C-R3A. The results reported above are part of
water jacket and maintained with an uncertainly of within ±0.1 K The various ternary solubility measurements 共see Table 13兲.
temperature was measured using a calibrated digital thermometer traceable
to NIST. The mixture was vigorously agitated by a magnetic stirrer for Source and Purity of Materials:
4 h, and next left to settle for 8 h for phase separation. Samples were 共1兲 Wako Chemical Co., best grade material; twice distilled.
analyzed using a Konik gas chromatograph, equipped with a thermal 共2兲 De-ionized water distilled from alkaline KmnO4 and redistilled.
conductivity detector and Shimadzu C-R2AX integrator. The results
reported above are part of various ternary solubility measurements 共see Estimated Error:
Table 12兲. Temperature: ±0.02 K.
Pressure: ±0.1 MPa.
Solubility: ±0.1 mass %.
共1兲 Merck; purity 99.5%; used as received.
共2兲 Distilled.
Estimated Error: Components: Original Measurements:

Temperature: ±0.1 K. 共1兲 2-Ethyl-1-hexanol; C8H18O; 32
F. Ratkovics, B.
Solubility: ±0.05% mole fraction. 关104-76-7兴 Palagyi-Fenyes, E.
共2兲 Water; H2O; 关7732-18-5兴 Hajos-Szikszay, and A. Dallos, J.
Chem. Thermodyn. 22, 129
共1990兲.
T. Moriyoshi, T. Sakamoto, Variables: Prepared by:
关104-76-7兴 and Y. Uosaki, J. Chem. One temperature: 293.15 K B. Wisniewska-Goclowska
共2兲 Water; H2O; 关7732-18-5兴 Thermodyn 21, 947 共1989兲.
Experimental Values
Variables: Prepared by: TABLE 14. Solubility in the 2-ethyl–1-hexanol/water system.32
One temperature: 298.15 K B. Wisniewska-Goclowska
Pressure: 0.1– 200 Mpa Solubility of 2-ethyl–1-hexanol in water
T共K兲 g共1兲 / 100 g sln x1共compiler兲

293.15 0.002 0.00028
TABLE 14. Solubility in the 2-ethyl–1-hexanol/water system.32—Continued 共1兲 2-Ethyl-1-hexanol; C8H18O; 41

R. M. Stephenson, J. Stuart,
关104-76-7兴 and M. Tabak, J. Chem. Eng.
Solubility of 2-ethyl–1-hexanol in water 共2兲 Water; H2O; 关7732-18-5兴 Data 29, 287 共1984兲.
T共K兲 g共2兲 / 100 g sln x2共compiler兲 Variables: Prepared by:

293.15 0.028 0.1724
Experimental Values
Method/Apparatus/Procedure: Solubility of 2-ethyl–1-hexanol in water

The cloud-point method was used. Measurements were carried out in a t共°C兲 g共1兲 / 100 g sln x1共compiler兲
cell equipped with a magnetic stirrer and thermostatted to within ±0.05 K.
The results reported above are the part of various ternary solubility 10.2 0.132 0.000183
measurements 共see Table 14兲. 19.8 0.125 0.000173
29.6 0.097 0.000134
40.1 0.110 0.000152
共1兲 Loba Chemie; purity by glc ⬎99.8 mass %.
50.2 0.074 0.000102
共2兲 Triple distilled.
60.3 0.086 0.000119
Estimated Error: 70.1 0.099 0.000137
Temperature: ±0.05 K. 80.1 0.108 0.000150
90.3 0.117 0.000162
Components: Original Measurements: t共°C兲 g共2兲 / 100 g sln x2共compiler兲
F. Ratkovics, B.
关104-76-7兴 Palagyi-Fenyes, E. 0.0 2.08 0.1331
共2兲 Water; H2O; 关7732-18-5兴 Hajos-Szikszay, and A. Dallos, J. 9.8 2.24 0.1421
Chem. Thermodyn. 23, 859 20.0 2.40 0.1509
共1991兲. 30.1 2.50 0.1564
39.7 2.72 0.1681
Variables: Prepared by: 50.0 2.82 0.1734
One temperature: 293.15 K B. Wisniewska-Goclowska 60.2 3.31 0.1984
70.3 3.49 0.2072
Experimental Values 80.0 3.50 0.2077
TABLE 15. Solubility in the 2-ethyl–1-hexanol/water system.33 90.3 4.04 0.2333
Solubility of 2-ethyl–1-hexanol in water Auxiliary Information

g共1兲 / 100 g sln Method/Apparatus/Procedure:
T共K兲共compiler兲 x1 The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought
into equilibrium at a given temperature in a thermostat, and samples of
293.15 0.13 0.0002
each layer were removed by syringe for analysis. To each sample
Solubility of water in 2-ethyl–1-hexanol acetonitrile was added as a standard and the ratio of peaks was measured
by gas chromatography using a Gow-Mac Series 550 thermal conductivity
g共2兲 / 100 g sln GC, Chromosorb 101 packing, and Hewlett-Packard 3390A recorder-
T共K兲共compiler兲 x2 integrator 共see Table 16兲.
293.15 3.03 0.1724 Source and Purity of Materials:

共1兲 Source not stated; purity 99 mass %.
Auxiliary Information 共2兲 Not stated.
Estimated Error:
Solubility: ⱕ0.1 mass %.
The cloud-point method was used. No details were reported in the paper.
The results reported above are part of various ternary solubility
measurements 共see Table 15兲.

共1兲 Loba Chemie; purity 99 mole % 2.6. 1-Octanol ⴙ Water
共2兲 Triply distilled.
Estimated Error: Components: Evaluators:

Not stated. 共1兲 1-Octanol; C8H18O; A. Maczynski, M. Goral, and B.
关111-87-5兴 Wisniewska-Goclowska,
Components: Original Measurements: Warsaw, Poland, March, 2006.
Critical evaluation of the solubility of 1-octanol (1) in investigated by the authors listed in Table 17 together with
water (2) temperature range and pressure range if reported:
The experimental solubility data for 共1兲 in 共2兲 have been
TABLE 17. Sources of solubility data for 1-octanol 共1兲 in water 共2兲.

2 31
Addison 293 Rao et al. 303
Arce et al.6 298–308 Ratkovics et al.33 293–293
Brown et al.9 354–543 Sanemasa et al.35 298
Butler et al.7 298 Shinoda et al.37 298
Crittenden and Hixon12 298 Sobotka and Glick38 303
Janado et al.21 298 Stephenson et al.41 294–363
Kinoshita et al.22 298 Vochten and Petre45 288
Lavrova and Lesteva24 313–333 Zhuravleva et al.46 368–388
McBain and Richards27 298
The reference solubility values of 共1兲 in 共2兲 were calcu-

lated by Eq. 共3兲. This equation has one term more than equa-
tion used for prediction and described in the Preface to Part
2.26 This term was added in order to describe the solubility
up to the temperature about 10 K below critical temperature
of the solubility 共T2c = 545 K兲:
ln x1 = ln x1,min + C1关T1,min/T − ln共T1,min/T兲兴

+ D1 exp关␣1共1 − T/T2c兲兴, 共3兲
where T1,min = 304.5 K, ln x1,min = −9.67, C1 = 41.3, D1

= 1.239, and ␣1 = −50.
The above listed values of T1,min, ln x1,min, are calculated
with Eqs. 共7兲 and 共9兲 given in the Preface to Part 2.26 C1, D1,
and ␣1 were adjusted to the experimental points. Up to about
470 K Eq. 共3兲 gives practically the same values as the gen-
eral equation used for prediction and described in the Preface
to Part 2.26 共see Table 18兲.
Table 19 are also described in the Preface to Part 2.26 All the
experimental data and reference values are listed in Table 20
and shown in Fig. 3. Some data used in this evaluation were
compiled for an earlier version of this work.8 Those compi-
lations are not reprinted here. New compilations are pre-
FIG. 3. All the solubility data for 1-octanol 共1兲 in water 共2兲.
Critical evaluation of the solubility of water (2) in
1-octanol (1) investigated by the authors listed in Table 18 together with
The experimental solubility data for 共2兲 in 共1兲 have been temperature range and pressure range if reported.
TABLE 18. Sources of solubility data for water 共2兲 in 1-octanol 共1兲.
Ababi and Popa1 298 Janado et al.21 298

Arce et al.4 298 Lavrova and Lesteva24 313–333
Arce et al.5 298–298 Moriyoshi et al.30 298
Arce et al.6 298–308 Rao et al.31 303
Brown et al.9 356–526 Ratkovics et al.33 293–293
Crittenden and Hixon12 298 Stephenson et al.41 283–364
Erichsen13 273–523 Tokunaga et al.43 288–313
TABLE 18. Sources of solubility data for water 共2兲 in 1-octanol 共1兲.—Continued

15
Galan et al. 293
4
A. Arce, M. Blanco, and A. Soto, J. Chem. Eng. Data 43,
255 共1998兲.
5
A. Arce, M. Blanco, and A. Soto, Fluid Phase Equilib. 146,
161 共1998兲.
6
A. Arce, M. Blanco, A. Soto, and I. Vidal, J. Chem. Ther-
modyn. 28, 3 共1996兲.
8
15, Alcohols with Water 共Pergamon, New York, 1984兲.
9
J. S. Brown, J. P. Hallett, D. Bush, and C. A. Eckert, J.
Chem. Eng. Data 45, 846 共2000兲.
10
J. A. V. Butler, D. W. Thomson, and W. H. Maclennan, J.
Chem. Soc. 674 共1933兲. 共IUPAC - SDS, Volume 15兲.
12
E. D., Jr. Crittenden and A. N. Hixon, Ind. Eng. Chem. 46,
265 共1954兲. 共IUPAC - SDS, Volume 15兲.
13
L. Erichsen, Brennst.-Chem. 33, 166 共1952兲. 共IUPAC -
SDS, Volume 15兲.
15
J. C. Galan, J. M. M. Moreno, R. T. Valle, and A. R. Se-
gado, An. Quim. Ser. A, 85, 273 共1989兲.
21
K. Kinoshita, H. Ishikawa, and K. Shinoda, Bull. Chem.
Soc. Jpn. 31, 1081 共1958兲. 共IUPAC - SDS, Volume 15兲.
22
M. Janado, Y. Yano, Y. Doi, and H. Sakamoto, J. Solution
Chem. 12, 741 共1983兲.
24
O. A. Lavrova and T. M. Lesteva, Zh. Fiz. Khim. 50, 1617
共1976兲. 共IUPAC - SDS, Volume 15兲.
26
bility Data Series. 82. Alcohol with Water – Revised and
FIG. 4. All the solubility data for water 共2兲 in 1-octanol 共1兲.
Ref. Data 36, 191 共2007兲.
27
J. W. McBain and P. H. Richards, Ind. Eng. Chem. 38, 642
The reference solubility values of water 共2兲 in alkanol 共1兲共1946兲. 共IUPAC - SDS, Volume 15兲.
30
were determined by LLE calculations described in the Pref- T. Moriyoshi, T. Sakamoto, and Y. Uosaki, J. Chem. Ther-
ace to Part 2.26 The concentrations of 共1兲 in 共2兲 predicted modyn. 21, 947 共1989兲.
from Eq. 共3兲 were used as the input data. The reference val- 31
K. S. Rao, M. V. R. Rao, and C. V. Rao, J. Sci. Ind. Res.,
ues obtained from the LLE calculations were afterward re- Sect. B 20, 283 共1961兲. 共IUPAC - SDS, Volume15兲.
gressed by Eq. 共4兲 33
Dallos, J. Chem. Thermodyn. 23, 859 共1991兲.
ln x1 = ln x2,min + C2关T2,min/T − ln共T2,min/T兲 − 1兴 35
I. Sanemasa, Y. Miyazaki, S. Arakawa, M. Kumamaru, and
+ D2 exp关␣2共1 − T/T2c兲兴共4兲 T. Deguchi, Bull. Chem. Soc. Jpn. 60, 517 共1987兲.
37
K. Shinoda, T. Yamanaka, and K. Kinoshita, J. Phys.
where T2,min = 277.2 K, ln x2,min = −1.359, C2 = 6.250, D2 Chem. 63, 648 共1959兲. 共IUPAC - SDS, Volume 15兲.
= 0.647, ␣2 = −50, and T2c = 545 K. 38
H. Sobotka and D. Glick, J. Biol. Chem. 105, 199 共1934兲.
The criteria used to assign data to categories listed in 共IUPAC - SDS, Volume 15兲.
Table 21 are described in the Preface to Part 2.26 All the 41
R. Stephenson, J. Stuart, and M. Tabak, J. Chem. Eng. Data
experimental data and reference values are listed in Table 22 29, 287 共1984兲.
and shown in Fig. 4. 43
S. Tokunaga, M. Manabe, and M. Koda, Mem. Niihama
Technical College, Sci. Eng. 16, 96 共1980兲. 共IUPAC - SDS,
References for the 1-octanol/water system
Volume 15兲.
1 45
V. Ababi and A. Popa, An. Stiint. Univ. “Al. I. Cuza” Iasi 6, R. Vochten and G. Petre, J. Colloid Interface Sci. 42, 320
929 共1960兲. 共IUPAC - SDS, Volume 15兲. 共1973兲. 共IUPAC - SDS, Volume 15兲.
2 46
C. C. Addison, J. Chem. Soc. 98 共1945兲. 共IUPAC - SDS, I. K. Zhuravleva, E. F. Zhuravlev, and N. G. Lomakina, Zh.
Volume 15兲. Fiz. Khim. 51, 1700 共1977兲. 共IUPAC - SDS, Volume 15兲.
TABLE 19. The data categories for solubility of 1-octanol 共1兲 in water 共2兲.
Recommended
关data in good Tentative
agreement with each 关data in good Doubtful
other and 共±10% 兲 agreement 关data in poor agreement
with the reference 共±10% 兲 with the 共⬎10% 兲 with the
T共K兲 values兴 reference values兴 reference values兴
288.2 Vochten and Petre45

293.2 Addison2
Ratkovics et al.33
21
298.2 Janado et al. Arce et al.6
Kinoshita et al.22 Butleret al.10
Shinoda et al.37 Crittenden and Hixon12
McBain and Richards27
Sanemasa et al.35
303.2 Rao et al.31
Sobotka and Glick38
308.2 Arce et al.6
313.2 Lavrova and Lesteva24
313.3 and 323.2 Stephenson et al.41
333.2 Lavrova and Lesteva24
333.5–353.3 Stephenson et al.41
354.3 Brown et al.9
368.2 Zhuravleva et al.46
381.4 Brown et al.9
428.2 and 452.2 Brown et al.9
477.9–537.9 Brown et al.8
TABLE 20. Experimental values for solubility of 1-octanol 共1兲 in water 共2兲.
Experimental values x1 Reference

T共K兲 P共kPa兲共R⫽recommended, T⫽tentative, D⫽doubtful兲 values x1
288.2 7.30⫻ 10−5 共T; Ref. 45兲 6.73⫻ 10−5

293.2 5.80⫻ 10−5 共D; Ref. 4兲, 2.00⫻ 10−4 共D; Ref. 33兲, 6.51⫻ 10−5
3.00⫻ 10−4 共D; Ref. 33兲
293.7 6.80⫻ 10−5 共T; Ref. 41兲 6.49⫻ 10−5
298.2 1.00⫻ 10−4 共D; Ref. 2兲, 8.10⫻ 10−5共D; Ref. 10兲, 6.37⫻ 10−5
7.00⫻ 10−4 共D; Ref. 12兲, 6.78⫻ 10−5 共R; Ref. 22兲,
6.70⫻ 10−5 共R; Ref. 21兲, 8.10⫻ 10−5 共D; Ref. 27兲,
7.41⫻ 10−5 共D; Ref. 35兲, 7.00⫻ 10−5 共R; Ref. 37兲
303.2 1.00⫻ 10−4 共D; Ref. 31兲, 1.05⫻ 10−4 共D; Ref. 38兲 6.37⫻ 10−5
303.8 8.90⫻ 10−5 共D; Ref. 41兲 6.32⫻ 10−5
308.2 1.00⫻ 10−4 共D; Ref. 2兲 6.33⫻ 10−5
313.2 8.00⫻ 10−5 共D; Ref. 24兲 6.42⫻ 10−5
313.3 9.00⫻ 10−5 共D; Ref. 41兲 6.42⫻ 10−5
323.2 1.45⫻ 10−4 共D; Ref. 41兲 6.78⫻ 10−5
333.2 8.00⫻ 10−5 共T; Ref. 24兲 7.43⫻ 10−5
333.5 1.22⫻ 10−4 共D; Ref. 41兲 7.45⫻ 10−5
343.5 1.07⫻ 10−4 共D; Ref. 41兲 8.42⫻ 10−5
353.3 1.20⫻ 10−4 共D; Ref. 41兲 9.74⫻ 10−5
354.3 6800 共Ref. 6兲 1.22⫻ 10−4 共D; Ref. 9兲 9.91⫻ 10−5
363.5 1.19⫻ 10−4 共T; Ref. 41兲 1.16⫻ 10−4
368.2 1.40⫻ 10−4 共D; Ref. 46兲 1.27⫻ 10−4
381.4 6800 共Ref. 6兲 2.36⫻ 10−5 共D; Ref. 9兲 1.67⫻ 10−4
388.2 7.00⫻ 10−4 共D; Ref. 46兲 1.94⫻ 10−4
428.2 6800 共Ref. 6兲 5.40⫻ 10−4 共T; Ref. 9兲 5.42⫻ 10−4
452.2 6800 共Ref. 6兲 9.95⫻ 10−4 共T; Ref. 9兲 1.08⫻ 10−3
TABLE 20. Experimental values for solubility of 1-octanol 共1兲 in water 共2兲.—Continued

477.9 6800 共Ref. 6兲 1.83⫻ 10−3 共D; Ref. 9兲 2.39⫻ 10−3

479.0 6800 共Ref. 6兲 3.68⫻ 10−3 共D; Ref. 9兲 2.47⫻ 10−3
522.1 6800 共Ref. 6兲 7.36⫻ 10−3 共D; Ref. 9兲 1.15⫻ 10−2
537.9 6800 共Ref. 6兲 1.28⫻ 10−2 共D; Ref.9兲 3.19⫻ 10−2
542.7 6800 共Ref. 6兲 1.03⫻ 10−1 共D; Ref. 9兲
TABLE 21. The data categories for solubility of water 共2兲 in 1-octanol 共1兲.
Recommended
关data in good Tentative Doubtful
agreement with each 关data in good 关data in poor agreement
other and 共±5 % 兲 with agreement 共±5 % 兲 with 共⬎5 % 兲 with the
T共K兲 the reference values兴 the reference values兴 reference values兴
273.2 Erichsen13
283.2 Erichsen13
Stephenson et al.41
288.2 Tokunaga et al.43
293.2 Ratkovics et al.33 Erichsen13
Tokunaga et al.43 Galan et al.15
298.1 Arce et al.4
298.2 Ababi and Popa1 Crittenden and Hixon12
Arce et al.5 Janado et al.21
Arce et al.6 Moriyoshi et al.30
Tokunaga et al.43
303.2 Erichsen13
Rao et al.31
Tokunaga et al.43
308.2 Tokunaga et al.43 Arce et al.6
Zhuravleva et al.46
313.2 Lavrova and Lesteva24 Erichsen13
Stephenson et al.41
Tokunaga et al.43
323.2 Stephenson et al.41 Erichsen13
333.2 Erichsen13
Lavrova and Lesteva24
343.2 Erichsen13
41
343.3 Stephenson et al.
353.2 Erichsen13
356.1 Brown et al.9
363.2 Erichsen13
373.2–413.2 Erichsen13
419.3 Brown et al.9
423.2–453.2 Erichsen13
9
461.2 Brown et al.
463.2 and 473.2 Erichsen13
9
480.5 Brown et al.
9
501.9 Brown et al.
TABLE 21. The data categories for solubility of water 共2兲 in 1-octanol 共1兲.—Continued
Recommended

13
523.2 Erichsen
526.4 Brown et al.9
TABLE 22. Experimental values for solubility of water 共2兲 in 1-octanol 共1兲.

273.2 0.2028 共D; Ref. 13兲 0.2571

280.2 0.15 共D; Ref. 46兲 0.2570
283.2 0.2244 共D; Ref. 13兲, 0.2379 共D; Ref. 41兲 0.2573
288.2 0.262 共T; Ref. 43兲
292.2 0.2474 共T; Ref. 41兲 0.2591
293.2 0.2451 共D; Ref. 13兲, 0.2315 共D; Ref. 15兲, 0.2594
0.2671 共R; Ref. 33兲, 0.265 共R; Ref. 43兲
296.2 0.21 共D; Ref. 46兲 0.2604
298.1 0.2680 共T; Ref. 4兲, 0.2691 共T; Ref. 4兲 0.2611
298.2 100 共Ref. 15兲 0.26 共R; Ref. 1兲, 0.2691 共R; Ref. 5兲, 0.2611
0.2680 共R; Ref. 5兲, 0.2691 共R; Ref. 6兲,
0.1110 共D; Ref. 12兲, 0.9999 共D; Ref. 22兲,
0.1970 共D; Ref. 30兲, 0.266 共R; Ref. 43兲
303.2 0.2649 共R; Ref. 13兲, 0.2680 共R; Ref.31兲, 0.2632
0.267 共R; Ref. 43兲
303.7 0.2532 共T; Ref. 41兲 0.2635
308.2 0.2403 共D; Ref. 6兲, 0.271 共T; Ref. 43兲, 0.23 0.2658
共D; Ref. 46兲
313.2 0.2900 共D; Ref. 13兲, 0.2800 共R; Ref. 24兲, 0.2686
0.2675 共R; Ref. 41兲, 0.273 共R; Ref. 43兲
323.2 0.3118 共D; Ref. 13兲, 0.2722 共T; Ref. 41兲 0.2755
325.2 0.28 共T; Ref. 46兲 0.2771
333.2 0.3326 共D; Ref. 13兲, 0.3150 共D; Ref. 24兲 0.2838
333.4 0.2893 共T; Ref. 41兲 0.2840
343.2 0.3558 共D; Ref. 13兲 0.2934
343.3 0.2933 共T; Ref. 41兲 0.2935
347.2 0.32 共D; Ref. 46兲 0.2976
353.2 0.3761 共D; Ref. 13兲 0.3043
353.3 0.2909 共T; Ref. 41兲 0.3044
356.1 6800 共Ref. 6兲 0.314 共T; Ref. 9兲 0.3078
363.2 0.3970 共D; Ref. 13兲 0.3166
363.7 0.2981 共D; Ref. 41兲 0.3172
373.2 0.4198 共D; Ref. 13兲 0.3301
383.2 0.4356 共D; Ref. 13兲 0.3450
393.2 0.4628 共D; Ref. 13兲 0.3612
403.2 0.4843 共D; Ref.13兲 0.3789
413.2 0.5068 共D; Ref. 13兲 0.3980
419.3 6800 共Ref. 6兲 0.423 共T; Ref. 9兲 0.4104
423.2 0.5300 共D; Ref. 13兲 0.4185
433.2 0.5526 共D; Ref. 13兲 0.4406
443.2 0.5756 共D; Ref. 13兲 0.4643
453.2 0.5985 共D; Ref. 13兲 0.4898
461.2 6800 共Ref. 6兲 0.521 共T; Ref. 9兲 0.5115
463.2 0.6220 共D; Ref. 13兲 0.5170
473.2 0.6450 共D; Ref. 13兲 0.5462
480.5 6800 共Ref. 6兲 0.578 共T; Ref. 9兲 0.5692
TABLE 22. Experimental values for solubility of water 共2兲 in 1-octanol 共1兲.—Continued

483.2 0.6689 共D; Ref. 13兲 0.5778

493.2 0.6941 共D; Ref. 13兲 0.6127
501.9 6800 共Ref. 6兲 0.660 共T; Ref. 9兲 0.6477
503.2 0.7231 共D; Ref. 13兲 0.6532
513.2 0.7555 共D; Ref. 13兲 0.7054
523.2 0.7909 共T; Ref. 13兲 0.7861
526.4 6800 共Ref. 6兲 0.785 共T; Ref. 9兲 0.8252
Experimental Values
TABLE 24. Solubility of water 共2兲 in 1-octanol 共1兲.5
共1兲 1-Octanol; C8H18O; 6
A. Arce, M. Blanco, A. Soto,
关111-87-5兴 and I. Vidal, J. Chem. g共2兲 / 100 g sln
共2兲 Water; H2O; 关7732-18-5兴 Thermodyn. 28, 3 共1996兲. t共°C兲共compiler兲 x2
Variables: Prepared by: 25 5.23 0.2691
Temperature: 298.15 and B. Wisniewska-Goclowska 5.20 0.2680
308.15 K
Experimental Values
TABLE 23. Solubility study in the 1-octanol/water system.6 Method/Apparatus/Procedure:
The cloud-point method was used. The solubility cell was thermostatted to
Solubility of 1-octanol in water ±0.02 ° C. No more details were reported in the paper 共see Table 24兲.
g共1兲 / 100 g sln Source and Purity of Materials:

T共K兲共compiler兲 x1 共1兲 Aldrich; purity by glc 99.1%.
共2兲 Obtained from a Milli-Q Plus system.
298.15 0.07 0.0001
308.15 0.07 0.0001 Estimated Error:
Temperature: 0.02 ° C.
Solubility of water in 1-octanol

T共K兲共compiler兲 x2 Components: Original Measurements:
A. Arce, M. Blanco, and A.
298.15 5.23 0.2691 关111-87-5兴 Soto, J. Chem. Eng. Data 43, 255
308.15 4.53 0.2403 共2兲 Water; H2O; 关7732-18-5兴共1998兲.

Auxiliary Information One temperature: 25 ° C B. Wisniewska-Goclowska
Method/Apparatus/Procedure: Experimental Values
The cloud-point method was used. No details were reported in the paper TABLE 25. Solubility of water 共2兲 in 1-octanol 共1兲.4
共see Table 23兲.
Source and Purity of Materials: t共°C兲共compiler兲 x2
共1兲 Aldrich; purity by glc ⬎99.5%.
共2兲 Obtained from a Milli-Q Plus system. 25 5.20 0.2680
Estimated Error:
Solubility: above ±0.001 mole % 共accuracy兲. Auxiliary Information
The cloud-point method was used. The solubility was obtained using
Components: Original Measurements: jacketed cells thermostatted to ±0.02 ° C using a HetoTherm
1-Octanol; C8H18O; 关111-87-5兴 5
A. Arce, M. Blanco, and A. ultrathermostat 共see Table 25兲.
共2兲 Water; H2O; 关7732-18-5兴 Soto, Fluid Phase Equilib. 146,
161 共1998兲. Source and Purity of Materials:
共1兲 Aldrich; purity by glc 99.2%.
Variables: Prepared by: 共2兲 Obtained from a Milli-Q Plus system.
Estimated Error:
Temperature: 0.02 ° C.

Experimental Values
J. S. Brown, J. P. Hallet, D. TABLE 27. Solubility of water 共2兲 in 1-octanol 共1兲.15
关111-87-5兴 Bush, and C.A. Eckert, J. Chem.
共2兲 Water; H2O; 关7732-18-5兴 Eng. Data 45, 846 共2000兲.
20 4.0 0.23
Temperature: 354.3– 542.7 K B. Wisniewska-Goclowska
Pressure: 6.80 MPa Auxiliary Information

Experimental Values Method/Apparatus/Procedure:
TABLE 26. Solubility in the 1-octanol/water system.9 The analytical method was used. The experimental device was a constant
temperature bath, where the temperature was controlled within 0.1 ° C by
Solubility of 1-octanol in water water circulation. Mixtures were placed in tubes, vigorously shaken, and
afterwards allowed to separate. The phases were sampled using a syringe,
g共1兲 / 100 g sln and analyzed by gas chromatography using a Hewlett-Packard 5890
T共K兲共compiler兲 x1 chromatograph with a thermal-conductivity detector 共see Table 27兲.
354.3 0.081 0.000122± 0.000004 Source and Purity of Materials:

381.4 0.157 0.000236± 0.000005 共1兲 Sigma; purity by glc 99 mass %.
428.2 0.359 0.000540± 0.000011 共2兲 Twice distilled.
452.2 0.660 0.000995± 0.000020
Estimated Error:
477.9 1.21 0.00183± 0.00004
479.0 2.40 0.00368± 0.00019
522.1 4.71 0.00736± 0.00027
537.9 7.96 0.0128± 0.0003
542.7 43.5 0.103± 0.001
M. Janado, Y. Yano, Y. Doi,
Solubility of water in 1-octanol
关111-87-5兴 and H. Sakamoto, J. Solution
共2兲 Water; H2O; 关7732-18-5兴 Chem. 12, 741 共1983兲.
356.1 6.42 0.314± 0.009
One temperature: 25.0 ° C B. Wisniewska-Goclowska
419.3 9.90 0.423± 0.009
461.2 14.0 0.521± 0.007 Experimental Values
TABLE 28. Solubility of 1-octanol 共1兲 in water 共2兲.21
480.5 17.0 0.578± 0.006
501.9 22.5 0.660± 0.005
t共°C兲 mg共1兲 / L共2兲 g共1兲 / 100 g sln共compiler兲 x1共compiler兲
526.4 35.4 0.785± 0.003
25.0 489.0 0.0452 6.78⫻ 10−5
The cloud-point method was used. Phase boundaries were measured by Method/Apparatus/Procedure:
visual observing the cloud point with a change-coupled device 共CCD兲 The analytical method was used. About 10 g of water with an excess of
camera in a variable-volume windowed vessel. The temperature was 1-octanol was placed in a thermostat, stirred for 6 h, gently shaken for
measured with a hand-held readout 共HH-22 Omega兲 and thermocouple another 18 h, and next allowed to stand for separation for 6 h. A portion
共Omega Type K兲 inserted into the center of the phase equilibria vessel. of a clear solution was placed in a 15 mL vial containing a weighed
The pressure was measured with a Druck DPI 260 gauge with PDCR 910 amount of n-hexane. After extracting into n-hexane, 1-octanol was
transducer accurate to ±0.001 MPa 共see Table 26兲. determined by gas chromatography 共see Table 28兲.
Source and Purity of Materials: Source and Purity of Materials:

共1兲 Aldrich; purity 99.3%. 共1兲 Nakarai Chemicals Ltd.; analytical grade; used as received
共2兲 Aldrich; HPLC grade. 共2兲 Glass redistilled water.
Estimated Error: Estimated Error:

Temperature: ±1 K. Temperature: ±0.05 ° C.
Pressure: ±0.001 MPa. Solubility: ⬍1.2% 共average deviation from the mean兲.
Solubility: as above.

Components: Original Measurements: 共1兲 1-Octanol; C8H18O; 30
T. Moriyoshi, T. Sakamoto,
J. C. Galan, J. M. M. Moreno, 关111-87-5兴 and Y. Uosaki, J. Chem.
关111-87-5兴 R. T. Valle, and A. R.Segado, An. 共2兲 Water; H2O; 关7732-18-5兴 Thermodyn. 21, 947 共1989兲.
共2兲 Water; H2O; 关7732-18-5兴 Quim., Ser. A 85, 273 共1989兲.
Variables: Prepared by: One temperature: 298.15 K B. Wisniewska-Goclowska
Pressure: 0.1– 200 MPa Auxiliary Information
Experimental Values Method/Apparatus/Procedure:

TABLE 29. Solubility of water 共2兲 in 1-octanol 共1兲.30 The cloud-point method was used. No details were reported in the paper.
The results reported above are part of various ternary solubility
g共2兲 / 100 g sln measurements 共see Table 30兲.
T共K兲 P共MPa兲共compiler兲 x2
298.15 0.1 3.55 0.197 共1兲 Reanal; purity 99 mole %.
100 4.26 0.229 共2兲 Triply distilled.
200 5.20 0.268
Estimated Error:
Not stated.
The analytical method 关T. Moriyoshi, T. Sakamoto, and Y. Uosaki, J. Components: Original Measurements:
Chem. Thermodyn. 20, 551 共1988兲兴 was used. The apparatus consisted of 共1兲 1-Octanol; C8H18O; 35
I. Sanemasa, Y. Miyazaki, S.
a high-pressure equilibrium cell, two hand operated pumps, a pressure 关111-87-5兴 Arakawa, M. Kumamaru, and T.
exchanger, two pressure gauges and auxiliary equipment. The equilibrium 共2兲 Water; H2O; 关7732-18-5兴 Deguchi, Bull. Chem. Soc. Jpn.
cell was a stainless-steel cylinder of about 50 mL capacity, equipped with 60, 517 共1987兲.
a mechanical stirrer and two pieces of pressure tubing connected to two
valves for the withdrawal of samples and immersed in a thermostat Variables: Prepared by:
controlled to ±0.02 K. Pressure was measured with an accuracy of One temperature: 25 ° C B. Wisniewska-Goclowska
±0.1 MPa with a Heise Bourdon gauge and a strain-gauge pressure
Experimental Values
transducer connected to a digital integrator. Samples were analyzed by a
TABLE 31. Solubility of 1-octanol 共1兲 in water 共2兲.35
Shimadzu gas chromatograph model GC-9APT with a
thermal-conductivity detector, equipped with an electronic integrator
Shimadzu Chromatopac C-R3A. The results reported above are part of g共1兲 / 100 g sln x1 · 105
various ternary solubility measurements 共see Table 29兲. t共°C兲 103 · mol共1兲 / L 共compiler兲共compiler兲
Source and Purity of Materials: 25 4.11 0.0535 7.41

共1兲 Wako Chemical Co., best grade material; twice distilled.
共2兲 De-ionized water distilled from alkaline KMnO4 and redistilled. Auxiliary Information
Estimated Error: Method/Apparatus/Procedure:

Temperature: ±0.02 K. The analytical method was used. Each 60 mL of mixed solute of various
Pressure: ±0.1 MPa. compositions was added to water 共200 mL兲 in a 360 mL glass bottle with
Solubility: ±0.1 mass %. a stopper and equilibrated by stirring overnight with a Teflon-enclosed
magnet in a thermostatted bath at 25.0± 0.1 ° C. Then the series of
aqueous solutions in 20 mL portions were extracted with cyclohexane
containing an internal standard and analyzed using a Hitachi 164 gas
chromatograph with a flame ionization detector. The results reported
F. Ratkovics, B.
above are the part of various ternary solubility measurements 共see Table
关111-87-5兴 Palagyi-Fenyes, E.
31兲.
共2兲 Water; H2O; 关7732-18-5兴 Hajos-Szikszay, and A. Dallos, J.
Chem. Thermodyn. 23, 859 Source and Purity of Materials:
共1991兲. 共1兲 Analytical reagent grade; purity 95%.
Variables: Prepared by: 共2兲 De-ionized and distilled.
One temperature: 293.15 K B. Wisniewska-Goclowska Estimated Error:
Experimental Values Temperature: ±0.1 ° C.
TABLE 30. Solubility in the 1-octanol/water system.33
Solubility of 1-octanol in water Components: Original Measurements:

R. M. Stephenson, J. Stuart,
关111-87-5兴 and M. Tabak, J. Chem. Eng.
共2兲 Water; H2O; 关7732-18-5兴 Data 29, 287 共1984兲.
293.15 0.13 0.0002
Solubility of water in 1-octanol Temperature: 10.0– 90.5 ° C B. Wisniewska-Goclowska

293.15 5.18 0.2671
Experimental Values Auxiliary Information

Solubility of 1-octanol in water The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought
into equilibrium at a given temperature in a thermostat, and samples of
t 共°C兲 g共1兲 / 100 g sln x1共compiler兲 each layer were removed by syringe for analysis. To each sample
20.5 0.049 0.000068 acetonitrile was added as a standard and the ratio of peaks was measured
30.6 0.064 0.000089 by gas chromatography using a Gow-Mac Series 550 thermal conductivity
GC, Chromosorb 101 packing, and Hewlett-Packard 3390A recorder–
40.1 0.065 0.000090
integrator 共see Table 32兲.
50.0 0.105 0.000145
60.3 0.088 0.000122 Source and Purity of Materials:
70.3 0.077 0.000107 共1兲 Source not stated; purity 99 mass %.
80.1 0.087 0.000120 共2兲 Not stated.
90.3 0.086 0.000119
Estimated Error:
Solubility of water in 1-octanol Solubility: ⱕ0.1 mass %.
10.0 4.14 0.2379

2.7. 2-Octanol + Water
19.0 4.35 0.2474
30.5 4.48 0.2532 Components: Evaluators:
40.0 4.81 0.2675 共1兲 2-Octanol; C8H18O; A. Maczynski, M. Goral, and B.
50.0 4.92 0.2722 关123-96-6兴 Wisniewska-Goclowska,
60.2 5.33 0.2893 共2兲 Water; H2O; 关7732-18-5兴 Thermodynamics Data Center,
70.1 5.43 0.2933 Warsaw, Poland, March, 2006.
80.1 5.37 0.2909
90.5 5.55 0.2981
Critical evaluation of the solubility of 2-octanol (1) in
water (2)
temperature range:
TABLE 33. Sources of solubility data for 2-octanol 共1兲 in water 共2兲.

2 29
Addison 293 Mitchell 288– 298
Bartolome et al.7 298 Stephenson and Stuart40 273– 364
Crittenden and Hixon12 298
The reference solubility values of 共1兲 in 共2兲 were calcu- and shown in Fig. 5. Some data used in this evaluation were
lated by the equation: compiled for an earlier version of this work.8 Those compi-
ln x1 = ln x1,min + C1关T1,min/T − 1 − ln共T1,min/T兲兴, 共5兲 lations are not reprinted here. New compilations are pre-
where T1,min = 324.5 K, ln x1,min = −8.92, and C1 = 41.3.
T1,min, ln x1,min, and C1 were calculated with Eqs. 共7兲, 共9兲,
and 共10兲, where constants defined by Eqs. 共12兲 and 共14兲 were Critical evaluation of the solubility of water (2) in
used. All the mentioned equations are given in the Preface to 2-octanol (1)
Part 2.26 共see Table 34兲. The experimental solubility data for 共2兲 in 共1兲 have been
The criteria used to assign data to categories listed in investigated by the authors listed in Table 34 together with
Table 35 are also described in the Preface to Part 2.26 All the temperature range.
TABLE 34. Sources of solubility data for water 共2兲 in 2-octanol 共1兲.
Bartolome et al.7 298 Moriyoshi et al.30 298

Crittenden and Hixon12 298 Stephenson and Stuart40 283–364
The reference solubility values of water 共2兲 in alkanol 共1兲 were determined by LLE calculations described in the Pref-
FIG. 5. All the solubility data for 2-octanol 共1兲 in water 共2兲. FIG. 6. All the solubility data for water 共2兲 in 2-octanol 共1兲.
7
ace to Part 2.26 The concentrations of 共1兲 in 共2兲 predicted A. L. Bartolome, C. Pazos, and J. Coca, J. Chem. Eng. Data
from Eq. 共5兲 were used as the input data. The reference val- 35, 285 共1990兲.
8
ues obtained from the LLE calculations were afterward re- A. F. M. Barton, Editor, IUPAC Solubility Data Series, Vol.
gressed by Eq. 共6兲 15, Alcohols with Water 共Pergamon, New York, 1984兲.
12
E. D. Crittenden, Jr. and A. N. Hixon, Ind. Eng. Chem. 46,
ln x2 = ln x2,min + C2关T2,min/T − 1 − ln共T2,min/T兲兴, 共6兲 265 共1954兲. 共IUPAC - SDS, Volume 15兲.
26
Table 37 are described in the Preface to Part 2.26 All the
Ref. Data 36, 191 共2007兲.
experimental data and reference values are listed in Table 38 29
S. Mitchell, J. Chem. Soc. 1332 共1926兲. 共IUPAC - SDS,
and shown in Fig. 6.
Volume 15兲.
30
T. Moriyoshi, T. Sakamoto, and Y. Uosaki, J. Chem. Ther-
References for the 2-octanol/water system
modyn. 21, 947 共1989兲.
2 40
C. C. Addison, J. Chem. Soc. 98 共1945兲. 共IUPAC - SDS, R. Stephenson and J. Stuart, J. Chem. Eng. Data 31, 56
Volume 15兲. 共1986兲.
TABLE 35. The data categories for solubility of 2-octanol 共1兲 in water 共2兲.
Tentative Doubtful
273.2 and 283.2 Stephenson and Stuart40

288.2 Mitchell29
293.2 Addison2
293.3 Stephenson and Stuart40
298.0 Bartolome et al.7
298.2 Crittenden and Hixon12
Mitchell29
TABLE 35. The data categories for solubility of 2-octanol 共1兲 in water 共2兲.—Continued
Tentative Doubtful
302.8–363.7 Stephenson and Stuart40
TABLE 36. Experimental values for solubility of 2-octanol 共1兲 in water 共2兲.

T共K兲共T⫽tentative, D⫽doubtful兲 values x1
273.2 3.06⫻ 10−4 共D; Ref. 40兲 2.57⫻ 10−4

283.2 2.30⫻ 10−4 共D; Ref. 40兲 2.01⫻ 10−4
288.2 2.10⫻ 10−4 共D; Ref. 29兲 1.82⫻ 10−4
293.2 1.46⫻ 10−4 共D; Ref. 2兲 1.67⫻ 10−4
293.3 1.77⫻ 10−4 共T; Ref. 40兲 1.67⫻ 10−4
298.0 9.00⫻ 10−4共D; Ref. 7兲 1.57⫻ 10−4
298.2 6.00⫻ 10−4 共D; Ref. 12兲,1.8⫻ 10−4 共D; Ref. 29兲 1.56⫻ 10− 4
302.8 1.38⫻ 10−4 共T; Ref. 40兲 1.49⫻ 10−4
312.7 1.32⫻ 10−4 共T; Ref. 40兲 1.38⫻ 10−4
323.2 1.22⫻ 10−4 共T; Ref. 40兲 1.34⫻ 10−4
333.5 1.26⫻ 10−4 共T; Ref. 40兲 1.36⫻ 10−4
343.3 1.36⫻ 10−4 共T; Ref.40兲 1.43⫻ 10−4
353.3 1.41⫻ 10−4 共T; Ref. 40兲 1.55⫻ 10−4
363.7 1.69⫻ 10−4 共T; Ref. 40兲 1.74⫻ 10−4
TABLE 37. The data categories for solubility of water 共2兲 in 2-octanol 共1兲.
Tentative Doubtful
283.2 and 293.3 Stephenson and Stuart40

298.0 Bartolome et al.7
12
298.2 Crittenden and Hixon Moriyoshi et al.30
40
323.2–363.7 Stephenson and Stuart
TABLE 38. Experimental values for solubility of water 共2兲 in 2-octanol 共1兲.

T共K兲 P共kPa兲共T⫽tentative, D⫽doubtful兲 values x2
283.2 0.2102 共T; Ref. 40兲 0.2132

293.3 0.2140 共T; Ref. 40兲 0.2138
298.0 0.2456 共D; Ref. 7兲 0.2147
298.2 0.2200 共T; Ref. 12兲, 0.1640 共D; Ref. 30兲 0.2147
302.8 0.2188 共T; Ref. 40兲 0.2160
312.7 0.2324 共D; Ref. 40兲 0.2200
323.2 0.2310 共T; Ref. 40兲 0.2259
333.5 0.2425 共T; Ref. 40兲 0.2333
343.3 0.2452 共T; Ref. 40兲 0.2417
353.3 0.2447 共T; Ref. 40兲 0.2517
363.7 0.2624 共T; Ref. 40兲 0.2636
A. L. Bartolome, C. Pazos, and Method/Apparatus/Procedure:
关123-96-6兴 J. Coca, J. Chem. Eng. Data 35, The analytical method 关T. Moriyoshi, T. Sakamoto, and Y. Uosaki, J.
共2兲 Water; H2O; 关7732-18-5兴 285 共1990兲. Chem. Thermodyn. 20, 551 共1988兲兴 was used. The apparatus consisted of
a high-pressure equilibrium cell, two hand operated pumps, a pressure
Variables: Prepared by: exchanger, two pressure gauges, and auxiliary equipment. The equilibrium
One temperature: 298.15 K B. Wisniewska-Goclowska cell was a stainless-steel cylinder of about 50 mL capacity, equipped with
a mechanical stirrer and two pieces of pressure tubing connected to two
Experimental Values
valves for the withdrawal of samples and immersed in a thermostat
controlled to ±0.02 K. Pressure was measured with an accuracy of
±0.1 MPa with a Heise Bourdon gauge and a strain-gauge pressure
Solubility of 2-octanol in water transducer connected to a digital integrator. Samples were analyzed by a
Shimadzu gas chromatograph model GC-9APT with a
T共K兲 g共1兲 / 100 g sln x1 共compiler兲
thermal-conductivity detector, equipped with an electronic integrator
Solubility of water in 2-octanol Shimadzu Chromatopac C-R3A. The results reported above are part of
various ternary solubility measurements 共see Table 40兲.
T共K兲 g共2兲 / 100 g sln x2 共compiler兲
298.15 4.31 0.2456 共1兲 Wako Chemical Co., best grade material; twice distilled.
共2兲 De-ionized water distilled from alkaline KMnO4 and redistilled.
Auxiliary Information Estimated Error:
Temperature: ±0.02 K
Pressure: ±0.1 MPa
The cloud-point method was used. No details were reported in the paper
共see Table 39兲. Solubility: ±0.1 mass %.

共1兲 Source not specified; reagent grade, distilled, no impurities by glc. Components: Original Measurements:
共2兲 Twice distilled. 共1兲 2-Octanol; C8H18O; 40
关123-96-6兴 Stuart, J. Chem. Eng. Data 31,
Estimated Error:
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲.
Not specified.
Experimental Values
T. Moriyoshi, T. Sakamoto, TABLE 41. Solubility in the 2-octanol/water system.40
关123-96-6兴 and Y. Uosaki, J. Chem.
共2兲 Water; H2O; 关7732-18-5兴 Thermodyn. 21, 947 共1989兲.
Solubility of 2-octanol in water
One temperature: 298.15 K B. Wisniewska-Goclowska
10.0 0.166 0.000230
Pressure: 0.1– 200 MPa
20.1 0.128 0.000177
TABLE 40. Solubility of water 共2兲 in 2-octanol 共1兲.30 39.5 0.095 0.000132
50.0 0.088 0.000122
g共2兲 / 100 g sln 60.3 0.091 0.000126
T共K兲 P共MPa兲共compiler兲 x2 70.1 0.098 0.000136
80.1 0.102 0.000141
298.15 0.1 2.86 0.164
90.5 0.122 0.000169
100 3.57 0.198
200 4.01 0.218 Solubility of water in 2-octanol
10.0 3.55 0.2102

20.1 3.63 0.2140
29.6 3.73 0.2188
39.5 4.02 0.2324
50.0 3.99 0.2310
60.3 4.24 0.2425
70.1 4.30 0.2452
80.1 4.29 0.2447
90.5 4.69 0.2624
Auxiliary Information The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought
into equilibrium at a given temperature in a thermostat and samples of
Method/Apparatus/Procedure: each layer were removed by syringe for analysis. To each sample a higher
The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought boiling organic compound was added as a standard and the ratio of peaks
into equilibrium at a given temperature in a thermostat and samples of was measured by gas chromatography 关R. M. Stephenson, J. Stuart, and
each layer were removed by syringe for analysis. To each sample a higher M. Tabak, J. Chem. Eng. Data 29, 287 共1984兲兴. Temperature was
boiling organic compound was added as a standard and the ratio of peaks measured by a calibrated thermometer accurate to 0.1 ° C 共see Table 42兲.
was measured by gas chromatography 关R. M. Stephenson, J. Stuart, and
M. Tabak, J. Chem. Eng. Data 29, 287 共1984兲兴. Temperature was Source and Purity of Materials:
measured by a calibrated thermometer accurate to 0.1 ° C 共see Table 41兲. 共1兲 Commercial reagent; purity 99+ mass %.
共2兲 Not stated.
共1兲 Commercial reagent; purity 98 mass %. Estimated Error:
共2兲 Not stated. Temperature: ±0.1 ° C.
Solubility: 共a兲 0.008, 共b兲 0.03 共standard deviation兲.
Estimated Error:
Temperature: ±0.1 ° C
2.9. 1-Phenyl–1-propanol + Water

共1兲 1-Phenyl-1-propanol; 40
2.8. 3-Octanol + Water 共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲.

Components: Original Measurements: Temperature: 20– 90.5 ° C B. Wisniewska-Goclowska
关589-98-0兴 Stuart, J. Chem. Eng. Data 31,
Experimental Values
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲.
TABLE 43. Solubility in the 1-phenyl–1-propanol/water system.40
Temperature: 0 – 90.1 ° C B. Wisniewska-Goclowska Solubility of 1-phenyl–1-propanol in water
Experimental Values t共°C兲 g共1兲 / 100 g slna兲 x1 共compiler兲

20.0 1.08 0.00144
Solubility of 3-octanol in water 30.0 0.99 0.00132
t共°C兲 g共1兲 / 100 g slna兲 x1共compiler兲 40.1 0.93 0.00124
50.0 0.93 0.00124
10.0 0.197 0.000273 60.5 0.99 0.00132
19.6 0.150 0.000208 70.4 0.98 0.00131
30.6 0.121 0.000168 80.7 1.08 0.00144
40.3 0.108 0.000150 90.5 1.15 0.00154
50.1 0.103 0.000143 Solubility of water in 1-phenyl–1-propanol
60.0 0.102 0.000141
70.0 0.102 0.000141 t共°C兲 g共2兲 / 100 g slnb兲 x2 共compiler兲
80.0 0.106 0.000147
20.0 3.16 0.1979
90.1 0.116 0.000161
30.0 3.41 0.2107
Solubility of water in 3-octanol 40.1 3.61 0.2207
50.0 3.91 0.2353
t共°C兲 g共2兲 / 100 g slnb兲 x2共compiler兲 60.5 4.03 0.2410
70.4 4.23 0.2503
0.0 1.67 0.2072
80.7 4.77 0.2747
10.0 2.14 0.1365
90.5 4.95 0.2825
19.6 2.29 0.1449
30.6 2.50 0.1564
40.3 2.84 0.1744 Auxiliary Information
50.1 2.84 0.1744
60.0 3.09 0.1873
70.0 3.60 0.2126
80.0 3.49 0.2072 each layer were removed by syringe for analysis. To each sample a higher
Auxiliary Information was measured by gas chromatography 关R. M. Stephenson, J. Stuart, and
Method/Apparatus/Procedure: measured by a calibrated thermometer accurate to 0.1 ° C 共see Table 43兲.

共1兲 Commercial reagent; purity 98+ mass %.
共2兲 Not stated.
Estimated Error:
2.10. 2,6-Dimethyl–4-heptanol ⴙ Water
共1兲 2,6-Dimethyl-4-heptanol; A. Maczynski, M. Goral, and B.
C9H20O; 关108-82-7兴 Wisniewska-Goclowska,
Critical evaluation of the solubility of 2,6-dimethyl-4-

heptanol (1) in water (2)
investigated by Crittenden and Hixon12 at 298 K, Stephenson
and Stuart40 at 273– 364 K, and Vochten and Petre45 at
288 K.
ln x1 = ln x1,min + C1关T1,min兴/T − 1 − ln共T1,min/T兲, 共7兲
FIG. 7. All the solubility data for 2,6-dimethyl–4-heptanol 共1兲 in water 共2兲.
T1,min, ln x1,min and C1 were calculated with Eqs. 共7兲, 共9兲,
and 共10兲, where constants defined by Eqs. 共12兲 and 共14兲 were ln x2 = ln x2,min + C2关T2,min兴/T − 1 − ln共T2,min/T兲, 共8兲
used. In these equations number of carbon atoms 共Nc兲 was
replaced by an effective value N*c = 8.58. All the mentioned
The criteria used to assign data to categories are described
equations are given in the Preface to Part 2.26
in the Preface to Part 2.26 All the experimental data and
reference values are listed in Table 46. All the data are in
poor agreement 共greater than 5%兲 with the reference values
and are Doubtful.
References for the 2,6-dimethyl-4-heptanol/water sys-
lations are not reprinted here. New compilation is presented
tem
following this evaluation.
8
Critical evaluation of the solubility of water (2) in 2,6- 15, Alcohols with Water 共Pergamon, New York, 1984兲.
12
dimethyl–4-heptanol (1) E. D. Crittenden, Jr. and A. N. Hixon, Ind. Eng. Chem. 46,
The experimental solubility data for 共2兲 in 共1兲 have been 265 共1954兲. 共IUPAC - SDS, Volume 15兲.
investigated by Crittenden and Hixon12 at 298 K, and 26
Stephenson and Stuart40 at 273– 364 K. bility Data Series. 82. Alcohol with Water - Revised and
The reference solubility values of water 共2兲 in alkanol 共1兲 Updated. Part 2. C6 alcohols with water,” J. Phys. Chem.
were determined by LLE calculations described in the Pref- Ref. Data 36, 191 共2007兲.
ace to Part 2.26 The concentrations of 共1兲 in 共2兲 predicted 40
R. Stephenson and J. Stuart, J. Chem. Eng. Data 31, 56
from Eq. 共7兲 were used as the input data. The reference val- 共1986兲.
45
ues obtained from the LLE calculations were afterward re- R. Vochten and G. Petre, J. Colloid Interface Sci. 42, 320
gressed by Eq. 共8兲共1973兲. 共IUPAC - SDS, Volume 15兲.
TABLE 44. The data categories for solubility of 2,6-dimethyl–4-heptanol 共1兲 in water 共2兲.
Tentative Doubtful

298.2 Crittenden and Hixon12
40
303.8–323.2 Stephenson and Stuart
TABLE 45. Experimental values for solubility of 2,6-dimethyl–4-heptanol 共1兲 Experimental Values
in water 共2兲. TABLE 47. Solubility in the 2,6-dimethyl–4-heptanol/water system.40

T共K兲共T⫽tentative, D⫽doubtful兲 values x1 Solubility of 2,6-dimethyl–4-heptanol in water
273.2 1.17⫻ 10−4 共T; Ref. 40兲 1.18⫻ 10−4 t共°C兲 g共1兲 / 100 g slna兲 x1共compiler兲
283.0 1.34⫻ 10−4 共D; Ref. 40兲 9.29⫻ 10−5
9.8 0.107 0.000134
288.2 5.6⫻ 10−5 共D; Ref. 45兲 8.41⫻ 10−5
20.1 0.066 0.000082
293.3 8.2⫻ 10−5 共T; Ref. 40兲 7.76⫻ 10−5
30.6 0.053 0.000066
298.2 1.0⫻ 10−4 共D; Ref. 12兲 7.29⫻ 10−5
40.0 0.043 0.000054
303.8 6.6⫻ 10−5共T; Ref. 40兲 6.90⫻ 10−5
50.0 0.052 0.000065
313.2 5.4⫻ 10−5 共T; Ref. 40兲 6.53⫻ 10−5
60.4 0.031 0.000039
323.2 6.5⫻ 10−5 共T; Ref. 40兲 6.44⫻ 10−5
70.3 0.038 0.000047
333.6 3.9⫻ 10−5 共D; Ref. 40兲 6.63⫻ 10−5
80.4 0.032 0.000040
343.5 4.7⫻ 10−5 共D; Ref. 40兲 7.08⫻ 10−5
90.5 0.036 0.000045
353.6 4.0⫻ 10−5 共D; Ref. 40兲 7.81⫻ 10−5
363.7 4.5⫻ 10−5 共D; Ref. 40兲 8.88⫻ 10−5 Solubility of water in 2,6-dimethyl–4-heptanol

TABLE 46. Experimental values for solubility of water 共2兲 in 2,6-dimethyl–
4-heptanol 共1兲. 0.0 0.92 0.0692
9.8 1.01 0.0755
Experimental values x2 Reference 20.1 1.01 0.0755
T共K兲共D⫽doubtful兲 values x2 30.6 1.18 0.0873
40.0 1.36 0.0994
273.2 0.0692 共D; Ref. 40兲 0.1321
50.0 1.53 0.1107
283.0 0.0755 共D; Ref. 40兲 0.1330
60.4 1.68 0.1204
293.3 0.0755 共D; Ref. 40兲 0.1353
70.3 2.04 0.1429
298.2 0.0700 共D; Ref. 12兲 0.1369
80.4 2.21 0.1532
303.8 0.0873 共D; Ref. 40兲 0.1391
90.5 2.26 0.1562
313.2 0.0994 共D; Ref. 40兲 0.1437
323.2 0.1107 共D; Ref. 40兲 0.1496
333.6 0.1204 共D; Ref. 40兲 0.1570 Auxiliary Information
343.5 0.1429 共D; Ref. 40兲 0.1653
353.6 0.1532 共D; Ref. 40兲 0.1749
363.7 0.1562 共D; Ref. 40兲 0.1858
each layer were removed by syringe for analysis. To each sample a higher
Components: Original Measurements: was measured by gas chromatography 关R. M. Stephenson, J. Stuart, and
共1兲 2,6-Dimethyl-4-heptanol; 40
R. M. Stephenson and J. M. Tabak, J. Chem. Eng. Data 29, 287 共1984兲兴. Temperature was
C9H20O; 关108-82-7兴 Stuart, J. Chem. Eng. Data 31, measured by a calibrated thermometer accurate to 0.1 ° C 共see Table 47兲.
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲.
Variables: Prepared by: 共1兲 Commercial reagent; purity 99 mass %.
Temperature: 0 – 90.5 ° C B. Wisniewska-Goclowska 共2兲 Not stated.
Estimated Error:
2.11. 1-Nonanol + Water
共1兲 1-Nonanol; C9H20O; A. Maczynski, M. Goral, and B.
Critical evaluation of the solubility of 1-nonanol (1) in

water (2)
investigated by the authors listed below in Table 48 together
with temperature range:

TABLE 48. Sources of solubility data for 1-nonanol 共1兲 in water 共2兲.

22 45
Kinoshita et al. 298 Vochten and Petre 288
Stephenson and Stuart40 283–364 Tewari et al.42 298

ln x1 = ln x1,min + C1关T1,min兴/T − 1 − ln共T1,min/T兲, 共9兲
where: T1,min = 299.1 K, ln x1,min = −11.04, and C1 = 45.5.
T1,min, ln x1,min, and C1 were calculated with Eqs. 共7兲, 共9兲
and 共10兲, where constants defined by Eqs. 共12兲 were used. FIG. 8. All the solubility data for 1-nonanol 共1兲 in water 共2兲.
All the mentioned equations are given in the Preface to Part
2 共see Table 49兲.26
The criteria used to assign data to categories listed in Critical evaluation of the solubility of water (2) in
Table 50 are also described in the Preface to Part 2.26 All the 1-nonanol (1)
experimental data and reference values are listed in Table 51 The experimental solubility data for 共2兲 in 共1兲 have been
and shown in Fig. 8. Some data used in this evaluation were investigated by the authors listed below in Table 49 together
compiled for an earlier version of this work.8 Those compi- with temperature range.
TABLE 49. Sources of solubility data for water 共2兲 in 1-nonanol 共1兲.

13 43
Erichsen 273–523 Tokunaga et al. 288–313
Stephenson and Stuart40 273–364
The reference solubility values of water 共2兲 in alkanol 共1兲 Rejected and Inaccessible Data
were determined by LLE calculations described in the Pref- The data reported by Sazonov and Chernysheva,36 and
ace to Part 2 共see Tables 50 and 51兲.26 The concentrations of Zhuravleva et al.47 lack sufficient information to justify
共1兲 in 共2兲 predicted from Eq. 共9兲 were used as the input data. evaluation. Therefore these data are Rejected.
The reference values obtained from the LLE calculations
were afterward regressed by Eq. 共10兲 References for the 1-nonanol/water system
8
ln x2 = ln x2,min + C2关T2,min兴/T − 1 − ln共T2,min/T兲, 共10兲 A. F. M. Barton, Editor, IUPAC Solubility Data Series, Vol.
13
where: T2,min = 296.6 K, ln x2,min = −1.401, and C2 = 7.04. L. Erichsen, Brennst.-Chem. 33, 166 共1952兲. 共IUPAC -
The criteria used to assign data to categories listed in SDS, Volume 15兲.
21
Table 52 are described in the Preface to Part 2.26 All the K. Kinoshita, H. Ishikawa, and K. Shinoda, Bull. Chem.
experimental data and reference values are listed in Table 53 Soc. Jpn. 31, 1081 共1958兲. 共IUPAC - SDS, Volume 15兲.
26
and shown in Fig. 9. A. Maczynski and D. G. Shaw, Editor, “IUPAC-NIST Solu-

Ref. Data 36, 191 共2007兲.
36
V. P. Sazonov and M. F. Chernysheva, Zh. Obshch. Khim.
46, 993 共19760 共IUPAC - SDS, Volume 15兲.
40
共1986兲.
42
Y. B. Tewari, M. M. Miller, S. P. Wasik, and D. E. Martire,
J. Chem. Eng. Data 27, 451 共1982兲.
43
Volume 15兲.
45
R. Vochten and G. Petre, J. Colloid Interface Sci. 42, 320
47
I. K. Zhuravleva, E. F. Zhuravlev, and T. L. Khotkovskaya,
Zhur. Prikl. Khim. 49, 2586 共1976兲. 共IUPAC - SDS, Vol-
ume 15兲
FIG. 9. All the solubility data for water 共2兲 in 1-nonanol 共1兲.
TABLE 50. The data categories for solubility of 1-nonanol 共1兲 in water 共2兲.
Recommended
关data in good
agreement with Tentative Doubtful
each other and 关data in good agreement 关data in poor agreement
共±20% 兲 with the 共±20% 兲 with the 共⬎20% 兲 with the
T共K兲 reference values兴 reference values兴 reference values兴

45
288.2 Vochten and Petre
22
298.2 Kinoshita et al.
Tewari et al.42
40
353.4 and Stephenson and Stuart
363.7
TABLE 51. Experimental values for solubility of 1-nonanol 共1兲 in water 共2兲.
283.0 4.50⫻ 10 −5
共D; Ref. 40兲 1.72⫻ 10−5
288.2 1.70⫻ 10−5 共T; Ref. 45兲 1.66⫻ 10−5
293.2 3.50⫻ 10−5 共D; Ref. 40兲 1.62⫻ 10−5
298.2 1.70⫻ 10−5 共R; Ref. 22兲, 1.328⫻ 10−5 共R; Ref. 42兲 1.61⫻ 10−5
302.8 3.90⫻ 10−5 共D; Ref. 40兲 1.61⫻ 10−5
312.8 4.20⫻ 10−5 共D; Ref. 40兲 1.68⫻ 10−5
323.0 4.00⫻ 10−5 共D; Ref. 40兲 1.83⫻ 10−5
333.3 4.20⫻ 10−5 共D; Ref. 40兲 2.07⫻ 10−5
343.7 4.10⫻ 10−5 共D; Ref. 40兲 2.44⫻ 10−5
TABLE 51. Experimental values for solubility of 1-nonanol 共1兲 in water 共2兲.—Continued
353.4 3.50⫻ 10−5 共T; Ref. 40兲 2.92⫻ 10−5

363.7 3.70⫻ 10−5 共T; Ref. 40兲 3.62⫻ 10−5
TABLE 52. The data categories for solubility of water 共2兲 in 1-nonanol 共1兲.
Recommended
273.2 Stephenson and Erichsen13

Stuart40
283.0 Stephenson and
Stuart40
283.2 Erichsen13
293.2 Erichsen13 Tokunaga et al.43
Stephenson and
Stuart40
40
302.8 Stephenson and Stuart
303.2 Erichsen13
Tokunaga et al.43
Stuart40
313.2 Erichsen13
Tokunaga et al.43
Stuart40
323.2 and Erichsen13
333.2
333.3 Stephensonand
Stuart40
343.2 Erichsen13
Stuart40
353.2 Erichsen13
Stuart40
363.2 Erichsen13
Stuart40
373.2–523.2 Erichsen13
TABLE 53. Experimental values for solubility of water 共2兲 in 1-nonanol 共1兲.
T共K兲共R⫽recommended, T⫽tentative, D⫽doubtful兲 Reference values x2
273.2 0.1955 共D; Ref. 13兲, 0.2462 共T; Ref. 40兲 0.2525
283.0 0.2363 共T; Ref. 40兲 0.2484
283.2 0.2185 共D; Ref. 13兲 0.2483
288.2 0.262 共D; Ref. 43兲 0.2471
293.2 0.2410 共R; Ref. 13兲, 0.2343 共R; Ref. 40兲, 0.263 共D; Ref. 43兲 0.2465
298.2 0.265 共D; Ref. 43兲 0.2464
302.8 0.2463 共T; Ref. 40兲 0.2468
303.2 0.2630 共D; Ref. 13兲, 0.265 共D; Ref. 43兲 0.2468
TABLE 53. Experimental values for solubility of water 共2兲 in 1-nonanol 共1兲.—Continued
308.2 0.267 共D; Ref. 43兲 0.2477

312.8 0.2472 共T; Ref. 40兲 0.2488
313.2 0.2850 共D; Ref. 13兲, 0.265 共D; Ref. 43兲 0.2489
323.0 0.2467 共T; Ref. 40兲 0.2526
323.2 0.3070 共D; Ref. 13兲 0.2527
333.2 0.3290 共D; Ref. 13兲 0.2579
333.3 0.2516 共T; Ref. 40兲 0.2580
343.2 0.3505 共D; Ref. 13兲 0.2646
343.7 0.2472 共D; Ref. 40兲 0.2650
353.2 0.3720 共D; Ref. 13兲 0.2727
353.4 0.2627 共T; Ref. 40兲 0.2728
363.2 0.3940 共D; Ref. 13兲 0.2820
363.7 0.2641 共D; Ref. 40兲 0.2825
373.2 0.4150 共D; Ref. 13兲 0.2927
383.2 0.4375 共D; Ref. 13兲 0.3047
393.2 0.4590 共D; Ref. 13兲 0.3180
403.2 0.4805 共D; Ref. 13兲 0.3327
413.2 0.5020 共D; Ref. 13兲 0.3487
423.2 0.5240 共D; Ref. 13兲 0.3662
433.2 0.5460 共D; Ref. 13兲 0.3852
443.2 0.5680 共D; Ref. 13兲 0.4057
453.2 0.5900 共D; Ref. 13兲 0.4278
463.2 0.6125 共D; Ref. 13兲 0.4516
473.2 0.6350 共D; Ref. 13兲 0.4772
483.2 0.6575 共D; Ref. 13兲 0.5047
493.2 0.6805 共D; Ref. 13兲 0.5340
503.2 0.7040 共D; Ref. 13兲 0.5655
513.2 0.7280 共D; Ref. 13兲 0.5990
523.2 0.7570 共D; Ref. 13兲 0.6349
TABLE 54. Solubility in the 1-nonanol/water system.40—Continued

共1兲 1-Nonanol; C9H20O; 40
关143-08-8兴 Stuart, J. Chem. Eng. Data 31, Solubility of water in 1-nonanol
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲. t共°C兲 g共2兲 / 100 g slnb兲 x2 共compiler兲

Temperature: 0 – 90.5 ° C B. Wisniewska-Goclowska 20.0 3.68 0.2343
29.6 3.92 0.2463
TABLE 54. Solubility in the 1-nonanol/water system.40
49.8 3.93 0.2467
60.1 4.03 0.2516
Solubility of 1-nonanol in water 70.5 3.94 0.2472
80.2 4.26 0.2627
t共°C兲 g共1兲 / 100 g slna兲 x1 共compiler兲
90.5 4.29 0.2641
9.8 0.036 0.000045
20.0 0.028 0.000035 Auxiliary Information
29.6 0.031 0.000039
39.6 0.034 0.000042 Method/Apparatus/Procedure:
49.8 0.032 0.000040 The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought
60.1 0.034 0.000042 into equilibrium at a given temperature in a thermostat and samples of
70.5 0.033 0.000041 each layer were removed by syringe for analysis. To each sample a higher
80.2 0.028 0.000035
90.5 0.030 0.000037
Solubility of water in 1-nonanol measured by a calibrated thermometer accurate to 0.1 ° C 共see Table 54兲.
t共°C兲 g共2兲 / 100 g slnb兲 x2 共compiler兲
0.0 3.22 0.2462 共1兲 Commercial reagent; purity 99 mass %.
共2兲 Not stated.
Estimated Error:

共1兲 1-Nonanol; C9H20O; 42
Y. B. Tewari, M. M. Miller, S.
关143-08-8兴 P. Wasik, and D. E. Martire, J.
共2兲 Water; H2O; 关7732-18-5兴 Chem. Eng. Data 27, 451 共1982兲.

One temperature: 25.0 ° C B. Wisniewska-Goclowska
Experimental Values
TABLE 55. Solubility of 1-nonanol 共1兲 in water 共2兲s.42
g共1兲 / 100 g sln x1

t共°C兲 mol 共1兲/L sln 共compiler兲共compiler兲
25.0 7.35· 10−4 1.063· 10−2 1.328· 10−5
A generator column method was used as described by De Voe et al. 关H.
De Voe, M. M. Miller, and S. P. Wasik, J. Res. Natl. Bur. Stand. 共USA兲
86, 361 共1981兲兴 and May et al. 关W. E. May, S. P. Wasik, and D. H.
Freeman, Anal. Chem. 50, 175 共1978兲兴. A column was coated with 共1兲 by
pulling about 2 mL of liquid through the clean dry support 共Chromosorb
FIG. 10. All the solubility data for 2-nonanol 共1兲 in water 共2兲.
W-HP兲. A saturated solution was generated by pumping water into the
inlet of the coated column and was then analyzed by glc. The column was
thermostated by pumping water from a bath through a column jacket. An T1,min, ln x1,min and C1 were calculated with Eqs. 共7兲, 共9兲
average of at least three measurements is reported 共see Table 55兲. and 共10兲, where constants defined by Eqs. 共12兲 and 共14兲 were
used. All the mentioned equations are given in the Preface to
共1兲 Source not specified; purity ⬎99 mole % checked by high-temperature
Part 2.26
glc. The criteria used to assign data to categories are also de-
共2兲 Source not specified. scribed in the Preface to Part 2.26 All the experimental data
and reference values are listed in Table 56 and shown in Fig.
Estimated Error:
10. The data of Stephenson and Stuart40 at 273, 293, and
303 K are in good agreement 共within ±20%兲 with the refer-
Solubility: 1% 共estimated by the authors兲.
ence values and are Tentative. All the remaining data are in
poor agreement 共greater than 20%兲 with the reference values
2.12. 2-Nonanol + Water and are Doubtful. Some data used in this evaluation were
Components: Evaluators: lations are not reprinted here. New compilation is presented
共1兲 2-Nonanol; C9H20O; A. Maczynski, M. Goral, and B. following this evaluation.
共2兲 Water; H2O; 关7732-18-5兴 Thermodynamics Data Center, Critical evaluation of the solubility of water (2) in
2-nonanol (1)
Critical evaluation of the solubility of 2-nonanol (1) in investigated by Stephenson and Stuart40 at 273– 364 K.
water (2) The reference solubility values of water 共2兲 in alkanol 共1兲
The experimental solubility data for 共1兲 in 共2兲 have been were determined by LLE calculations described in the Pref-
investigated by Stephenson and Stuart40 at 273– 364 K, and ace to Part 2.26 The concentrations of 共1兲 in 共2兲 predicted
Vochten and Petre45 at 288 K. from Eq. 共11兲 were used as the input data. The reference
The reference solubility values of 共1兲 in 共2兲 were calcu- values obtained from the LLE calculations were afterward
lated by the equation: regressed by Eq. 共12兲
ln x1 = ln x1,min + C1关T1,min/T − 1 − ln共T1,min/T兲兴, 共11兲 ln x2 = ln x2,min + C2关T2,min/T − 1 − ln共T2,min/T兲兴, 共12兲
where: T1,min = 319.1 K, ln x1,min = −10.18, and C1 = 45.5. where: T2,min = 290.6 K, ln x2,min = −1.623, and C2 = 7.43.
TABLE 56. Experimental values for solubility of 2-nonanol 共1兲 in water

共2兲.—Continued

288.2 3.2⫻ 10−5 共D; Ref. 45兲 4.82⫻ 10−5

293.0 4.9⫻ 10−5 共T; Ref. 40兲 4.48⫻ 10−5
303.2 4.1⫻ 10−5 共T; Ref. 40兲 4.01⫻ 10−5
313.2 2.7⫻ 10−5 共D; Ref.40兲 3.80⫻ 10−5
323.2 2.4⫻ 10−5 共D; Ref. 40兲 3.79⫻ 10−5
333.3 2.6⫻ 10−5 共D; Ref. 40兲 3.94⫻ 10−5
343.4 3.1⫻ 10−5 共D; Ref. 40兲 4.25⫻ 10−5
353.5 2.7⫻ 10−5 共D; Ref. 40兲 4.75⫻ 10−5
363.7 3.5⫻ 10−5 共D; Ref. 40兲 5.47⫻ 10−5
TABLE 57. Experimental values for solubility of water 共2兲 in 2-nonanol 共1兲.

273.2 0.2007 共T; Ref.40兲 0.2002

283.1 0.1924 共T; Ref. 40兲 0.1979
293.0 0.2061 共T; Ref. 40兲 0.1974
303.2 0.2136 共D; Ref. 40兲 0.1987
313.2 0.2157 共D; Ref. 40兲 0.2014
323.2 0.2245 共D; Ref. 40兲 0.2055
333.3 0.2245 共D; Ref. 40兲 0.2110
343.4 0.2467 共D; Ref. 40兲 0.2177
353.5 0.2512 共D; Ref. 40兲 0.2256
FIG. 11. All the solubility data for water 共2兲 in 2-nonanol 共1兲. 363.7 0.2550 共D; Ref. 40兲 0.2348
The criteria used to assign data to categories are described Components: Original Measurements:
in the Preface to Part 2.26 All the experimental data and 共1兲 2-Nonanol; C9H20O; 40
reference values are listed in Table 57 and shown in Fig. 11. 关628-99-9兴 Stuart, J. Chem. Eng. Data 31,
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲.
The data of Stephenson and Stuart40 at 273– 293 K are in
good agreement 共within ±5%兲 with the reference values and Variables: Prepared by:
are Tentative. All the remaining data are in poor agreement Temperature: 0 – 90.5 ° C B. Wisniewska-Goclowska
共greater than 5%兲 with the reference values and are Doubt- Experimental Values
ful. TABLE 58. Solubility in the 2-nonanol/water system.40
References for the 2-nonanol/water system Solubility of 1-nonanol in water

8
A. F. M. Barton, Editor, IUPAC Solubility Data Series, Vol. t共°C兲 g共1兲 / 100 g slna兲 x1共compiler兲
26 0.0 0.063 0.000079
9.9 0.053 0.000066
19.8 0.039 0.000049
Updated. Part 2. C6 alcohols with water,” J. Phys. Chem. 30.0 0.033 0.000041
Ref. Data 36, 191 共2007兲. 40.0 0.022 0.000027
40
R. Stephenson and J. Stuart, J. Chem. Eng. Data 31, 56 50.0 0.019 0.000024
共1986兲. 60.1 0.021 0.000026
45
R. Vochten and G. Petre, J. Colloid Interface Sci. 42, 320 70.2 0.025 0.000031
共1973兲. 共IUPAC - SDS, Volume 15兲. 80.3 0.022 0.000027
90.5 0.028 0.000035
TABLE 56. Experimental values for solubility of 2-nonanol 共1兲 in water 共2兲.
Solubility of water in 2-nonanol
Experimental values x1 Reference t共°C兲 g共2兲 / 100 g slnb兲 x2 共compiler兲
0.0 3.04 0.2007
273.2 7.9⫻ 10−5 共T; Ref. 40兲 6.74⫻ 10−5 9.9 2.89 0.1924
283.1 6.6⫻ 10−5 共D; Ref. 40兲 5.31⫻ 10−5 19.8 3.14 0.2061
TABLE 58. Solubility in the 2-nonanol/water system.40—Continued TABLE 59. Solubility in the 3,3,5-trimethyl–1-hexanol/water
system.40—Continued
Solubility of water in 2-nonanol

t共°C兲 g共2兲 / 100 g slnb兲 x2 共compiler兲 Solubility of water in 3,3,5-timethyl–1-hexanol
30.0 3.28 0.2136
40.0 3.32 0.2157 39.8 3.02 0.1996
50.0 3.49 0.2245 50.0 3.18 0.2082
60.1 3.49 0.2245 60.1 3.41 0.2204
70.2 3.93 0.2467 70.3 3.45 0.2225
80.3 4.02 0.2512 80.3 3.54 0.2271
90.5 4.10 0.2550
Method/Apparatus/Procedure: The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought
The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought into equilibrium at a given temperature in a thermostat and samples of
into equilibrium at a given temperature in a thermostat and samples of each layer were removed by syringe for analysis. To each sample a higher
each layer were removed by syringe for analysis. To each sample a higher boiling organic compound was added as a standard and the ratio of peaks
boiling organic compound was added as a standard and the ratio of peaks was measured by gas chromatography 关R. M. Stephenson, J. Stuart, and
was measured by gas chromatography 关R. M. Stephenson, J. Stuart, and M. Tabak, J. Chem. Eng. Data 29, 287 共1984兲兴. Temperature was
M. Tabak, J. Chem. Eng. Data 29, 287 共1984兲兴. Temperature was measured by a calibrated thermometer accurate to 0.1 ° C 共see Table 59兲.
Source and Purity of Materials: 共1兲 Commercial reagent; purity 98 mass %.
共1兲 Commercial reagent; purity 99 mass %. 共2兲 Not stated.
共2兲 Not stated.
Estimated Error:
Estimated Error: Temperature: ±0.1 ° C.
Temperature: ±0.1 ° C. Solubility: 共a兲 0.005, 共b兲 0.01 共standard deviation兲.
2.14. 3,5,5-Trimethyl-1-hexanol ⴙ Water

2.13. 3,3,5-Trimethyl–1-hexanol ⴙ Water
Components: Original Measurements: 共1兲 3,3,5-Trimethyl-l-hexanol; 40
共1兲 3,3,5-Trimethyl-l-hexanol; 40
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲.
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲. Variables: Prepared by:
Variables: Prepared by: Temperature: 0 – 90.5 ° C B. Wisniewska-Goclowska
Experimental Values
TABLE 60. Solubility in the 3,5,5-trimethyl–1-hexanol/water system.40
Experimental Values
TABLE 59. Solubility in the 3,3,5-trimethyl–1-hexanol/water system.40
Solubility of 3,5,5-trimethyl–1-hexanol in water
Solubility of 3,3,5-trimethyl–1-hexanol in water t共°C兲 g共1兲 / 100 g slna兲 x1共compiler兲
0.0 0.06 0.000075
30.7 0.118 0.000148 10.1 0.05 0.000062
39.8 0.107 0.000134 29.7 0.05 0.000062
50.0 0.080 0.000100 39.7 0,.05 0.000062
60.1 0.066 0.000082 50.0 0.06 0.000075
70.3 0.087 0.000109 60.1 0.08 0.000100
80.3 0.120 0.000150 70.5 0.05 0.000062
90.5 0.137 0.000171 80.3 0.07 0.000087
Solubility of water in 3,3,5-timethyl–1-hexanol 90.5 0.08 0.000100
t共°C兲 g共2兲 / 100 g slnb兲 x2共compiler兲 Solubility of water in 3,5,5-trimethyl–1-hexanol
0.0 2.30 0.1586 t共°C兲 g共2兲 / 100 g slnb x2共compiler兲
10.0 2.42 0.1657
19.8 2.57 0.1744 0.0 2.31 0.1592
30.7 2.80 0.1874 10.1 2.47 0.1686
TABLE 60. Solubility in the 3,5,5-trimethyl–1-hexanol/water Source and Purity of Materials:

system.40—Continued 共1兲 Commercial reagent; purity 98 mass %.
共2兲 Not stated.
Solubility of water in 3,5,5-trimethyl–1-hexanol Estimated Error:
t共°C兲 g共2兲 / 100 g slnb x2共compiler兲 Temperature: ±0.1 ° C
19.9 2.66 0.1795
29.7 2.92 0.1941
39.7 3.02 0.1996 2.15. cis-3,7-Dimethyl–2,6-octadien–1-ol +
50.0 3.17 0.2077
Water
60.1 3.18 0.2082
70.5 3.72 0.2363
80.3 3.81 0.2408 Components: Original Measurements:
90.5 4.22 0.2608 共1兲 28
D. J. Miller and S, B.
cis-3,7-Dimethyl-2,6-octadien-1-ol; Hawthorne, J. Chem. Eng. Data
C10H18O; 关106-25-2兴 45, 315 共2000兲.
Auxiliary Information 共2兲 Water; H2O; 关7732-18-5兴
Method/Apparatus/Procedure: Variables: Prepared by:
The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought Temperature: 298– 423 K B. Wisniewska-Goclowska
Experimental Values
TABLE 61. Solubility of cis-3,7-dimethyl–2,6-octadien–1-ol 共1兲 in water 共2兲.28

T共K兲 P共kPa兲共compiler兲 x1
298 6800 0.05 0.000062± 0.000005

323 6800 0.06 0.000073± 0.000004
373 6800 0.15 0.00017± 0.00001
423 6900 0.43 0.00051± 0.00003
Auxiliary Information 2.16. 1-Decanol ⴙ Water

The dynamic method was used. Details of the equipment and method Components: Evaluators:
were described in the paper and in Miller and Hawthorne 关D. J. Miller 共1兲 1-Decanol; C10H22O; A. Maczynski, M. Goral, and B.
and S, B. Hawthorne, Anal. Chem. 70, 1618 共1998兲兴. A high-pressure 关112-30-1兴 Wisniewska-Goclowska,
saturation cell was filled with the test solute and placed in the oven of a 共2兲 Water; H2O; 关7732-18-5兴 Thermodynamics Data Center,
Hewlett Packard gas chromatograph Model 5890 to provide temperature Warsaw, Poland, December,
control to ±0.1 K. An Isco model 100D syringe pump was used in the 2006.
constant flow mode to supply water to the saturation cell. After an
equilibration period of 1 h, samples were collected for analysis by gas
chromatography with flame ionization detection 共see Table 61兲.
Critical evaluation of the solubility of 1-decanol (1) in
Source and Purity of Materials: water (2)
共1兲 Sigma-Aldrich, Milwaukee; highest purity available; purity 97%. The experimental solubility data for 共1兲 in 共2兲 have been
Estimated Error: temperature range:
Temperature: ±0.1 K.
Solubility: see above.
TABLE 62. Sources of dolubility data for 1-decanol 共1兲 in water 共2兲.

3 40
Addison and Hutchinson 293 Stephenson and Stuart 303– 364
Kinoshita et al.22 298 Vochten and Petre45 288
TABLE 62. Sources of dolubility data for 1-decanol 共1兲 in water 共2兲.—Continued

39 46
Stearns et al. 298 Zhuravleva et al. 376– 394

ln x1 = ln x1,min + C1关T1,min/T − 1 − ln共T1,min/T兲兴, 共13兲

and 共10兲, where constants defined by Eqs. 共12兲 were used.
2.26
Critical evaluation of the solubility of water (2) in

1-decanol (1)
temperature range. FIG. 12. All the solubility data for 1-decanol 共1兲 in water 共2兲.
TABLE 63. Sources of solubility data for water 共2兲 in 1-decanol 共1兲.

13 43
Erichsen 273– 533 Tokunaga et al. 288– 313
Galan et al.15 293 Zhuravleva et al.46 284– 356
Stephenson and Stuart40 283– 364
The reference solubility values of water 共2兲 in alkanol 共1兲 are Rejected.
were determined by LLE calculations described in the Pref-
ace to Part 2 共see Tables 64 and 65兲.26 The concentrations of References for the 1-decanol/water system
共1兲 in 共2兲 predicted from Eq. 共13兲 were used as the input data. 3
C. C. Addison and S. K. Hutchinson, J. Chem. Soc. 3387
The reference values obtained from the LLE calculations
were afterward regressed by Eq. 共14兲 8
ln x2 = ln x2,min + C2关T2,min/T − 1 − ln共T2,min/T兲兴, 共14兲 15, Alcohols with Water 共Pergamon, New York, 1984兲.
13
L. Erichsen, Brennst.-Chem. 33, 166 共1952兲. 共IUPAC -
where: T2,min = 306.7 K, ln x2,min = −1.410, and C2 = 6.98. SDS, Volume 15兲.
15
The criteria used to assign data to categories listed in J. C. Galan, J. M. M. Moreno, R. T. Valle, and A. R. Se-
Table 66 are described in the Preface to Part 2.26 All the gado, An. Quim., Ser. A 85, 273 共1989兲.
18
experimental data and reference values are listed in Table 67 W. D. Harkins and H. Oppenheimer, J. Am. Chem. Soc. 71,
and shown in Fig. 13. 808 共1949兲. 共IUPAC - SDS, Volume 15兲
22
Rejected and Inaccessible Data K. Kinoshita, H. Ishikawa, and K. Shinoda, Bull. Chem.
The data reported by Harkins and Oppenheimer18 lack suf- Soc. Jpn. 31, 1081 共1958兲. 共IUPAC - SDS, Volume 15兲.
26
ficient information to justify evaluation. Therefore these data A. Maczynski and D. G. Shaw, Editor, “IUPAC-NIST Solu-

Ref. Data 36, 191 共2007兲.
40
共1986兲.
43
Volume 15兲.
45
R. Vochten and G. Petre, J. Colloid Interface Sci. 42, 320
46
I. K. Zhuravleva, E. F. Zhuravlev, and N. G. Lomakina, Zh.
Fiz. Khim. 51, 1700 共1977兲. 共IUPAC - SDS, Volume 15兲.
48
R. S. Stearns, H. Oppenheimer, E. Simon, and W. D. Har-
kins, J. Chem. Phys. 15, 496 共1947兲. 共IUPAC - SDS, Vol-
ume 15兲.
FIG. 13. All the solubility data for water 共2兲 in 1-decanol 共1兲.
TABLE 64. The data categories for solubility of 1-decanol 共1兲 in water 共2兲.
Tentative Doubtful

3
293.2 Addison and Hutchinson
298.2 Kinoshita et al.22 Stearns et al.39
375.7 and Zhuravleva et al.46
393.7
TABLE 65. Experimental values for solubility of 1-decanol 共1兲 in water 共2兲.
288.2 3.0⫻ 10−6 共D; Ref. 45兲 4.15⫻ 10−6

293.2 4.0⫻ 10−6 共T; Ref. 3兲 4.10⫻ 10−6
298.2 4.0⫻ 10−6 共T; Ref. 22兲, 6.0⫻ 10−6 共D; Ref. 39兲 4.11⫻ 10−6
302.8 2.4⫻ 10−5 共D; Ref. 40兲 4.17⫻ 10−6
313.5 3.0⫻ 10−5 共D; Ref. 40兲 4.50⫻ 10−6
323.2 3.0⫻ 10−5 共D; Ref. 40兲 5.03⫻ 10−6
333.5 3.2⫻ 10−5 共D; Ref. 40兲 5.90⫻ 10−6
343.4 2.5⫻ 10−5 共D; Ref. 40兲 7.12⫻ 10−6
353.4 2.7⫻ 10−5 共D; Ref. 40兲 8.87⫻ 10−6
363.6 2.6⫻ 10−5 共D; Ref. 40兲 1.14⫻ 10−5
375.7 1.1⫻ 10−3 共D; Ref. 46兲 1.59⫻ 10−5
393.7 9.0⫻ 10−4 共D; Ref. 46兲 2.73⫻ 10−5
TABLE 66. The data categories for solubility of water 共2兲 in 1-decanol 共1兲.
Recommended
273.2 Erichsen13
40
283.3 Erichsen13
43
283.7 Zhuravleva et al.
293.2 Erichsen13 Tokunaga et al.43
Galan et al.15
40
303.2 Erichsen13
Tokunaga et al.43
313.2 Tokunaga et al.43 Erichsen13
323.2 Stephenson and Stuart40 Erichsen13
333.2 Erichsen13
343.2 Erichsen13
353.2 Erichsen13
40
363.2 Erichsen13
373.2–533.2 Erichsen13
TABLE 67. Experimental values for solubility of water 共2兲 in 1-decanol 共1兲.
273.2 0.1935 共D; Ref. 13兲 0.2563

283.0 0.2513 共T; Ref. 40兲 0.2499
283.3 0.2150 共D; Ref. 13兲 0.2498
283.7 0.24 共T; Ref. 46兲 0.2496
288.2 0.2570 共T; Ref. 43兲 0.2476
293.2 0.2360 共R; Ref. 13兲, 0.2362 共R; Ref. 15兲, 0.2610 共D; Ref. 43兲 0.2459
298.2 0.2590 共D; Ref. 43兲 0.2449
302.8 0.2334 共T; Ref. 40兲 0.2443
303.2 0.2575 共D; Ref. 13兲, 0.2570 共D; Ref. 43兲 0.2443
308.2 0.2550 共T; Ref. 43兲 0.2444
313.2 0.2795 共D; Ref. 13兲, 0.2520 共T; Ref. 43兲 0.2445
313.5 0.2406 共T; Ref. 40兲 0.2446
323.2 0.3015 共D; Ref. 13兲, 0.2465 共T; Ref. 40兲 0.2465
333.2 0.3235 共D; Ref. 13兲 0.2499
333.5 0.2460 共T; Ref. 40兲 0.2501
335.7 0.32 共D; Ref. 46兲 0.2510
343.2 0.3450 共D; Ref. 13兲 0.2548
343.4 0.2460 共T; Ref. 40兲 0.2549
353.2 0.3665 共D; Ref. 13兲 0.2609
353.4 0.2508 共T; Ref. 40兲 0.2611
355.7 0.36 共D; Ref. 46兲 0.2627
363.2 0.3885 共D; Ref. 13兲 0.2683
363.6 0.2587 共T; Ref. 40兲 0.2687
TABLE 67. Experimental values for solubility of water 共2兲 in 1-decanol 共1兲.—Continued
373.2 0.4100 共D; Ref. 13兲 0.2770

383.2 0.4320 共D; Ref. 13兲 0.2868
393.2 0.4540 共D; Ref. 13兲 0.2978
403.2 0.4765 共D; Ref. 13兲 0.3100
413.2 0.4980 共D; Ref. 13兲 0.3235
423.2 0.5195 共D; Ref. 13兲 0.3382
433.2 0.5410 共D; Ref. 13兲 0.3542
443.2 0.5630 共D; Ref. 13兲 0.3715
453.2 0.5850 共D; Ref. 13兲 0.3903
463.2 0.6070 共D; Ref. 13兲 0.4104
473.2 0.6290 共D; Ref. 13兲 0.4321
483.2 0.6515 共D; Ref. 13兲 0.4553
493.2 0.6745 共D; Ref. 13兲 0.4801
503.2 0.6975 共D; Ref. 13兲 0.5067
513.2 0.7220 共D; Ref. 13兲 0.5350
523.2 0.7660 共D; Ref. 13兲 0.5652
533.2 0.7730 共D; Ref. 13兲 0.5974
Experimental Values
Components: Original Measurements: TABLE 69. Solubility in the 1-decanol/water system.40
共1兲 1-Decanol; C10H22O; 15
J. C. Galan, J. M. M. Moreno,
关112-30-1兴 R. T. Valle, and A. R. Segado, Solubility of 1-decanol in water
共2兲 Water; H2O; 关7732-18-5兴 An. Quim., Ser. A 85, 273
共1989兲. t共°C兲 g 共1兲 / 100 g slna兲 x1共compiler兲

One temperature: 20 ° C B. Wisniewska-Goclowska 40.3 0.026 0.000030
TABLE 68. Solubility of water 共2兲 in 1-decanol 共1兲.15 60.3 0.028 0.000032
70.2 0.022 0.000025
t共°C兲 g共2兲 / 100 g sln x2 共compilers兲 80.2 0.024 0.000027
90.4 0.023 0.000026
20 3.4 0.24
Solubility of water in 1-decanol
Auxiliary Information t共°C兲 g 共2兲 / 100 g slnb兲 x2共compiler兲
Method/Apparatus/Procedure: 19.8 3.68 0.2513

The analytical method was used. The experimental device was a constant 29.6 3.35 0.2334
temperature bath, where the temperature was controlled within 0.1 ° C by 40.3 3.48 0.2406
water circulation. Mixtures were placed in tubes, vigorously shaken, and 50.0 3.59 0.2465
afterward allowed to separate. The phases were sampled using a syringe, 60.3 3.58 0.2460
and analyzed by gas chromatography using a Hewlett-Packard 5890 70.2 3.58 0.2460
chromatograph with a thermal-conductivity detector 共see Table 68兲.
80.2 3.67 0.2508
Source and Purity of Materials: 90.4 3.82 0.2587
共1兲 Merck; purity by glc 99 mass %.
共2兲 Twice distilled. Auxiliary Information
Estimated Error: Method/Apparatus/Procedure:
Temperature: ±0.1 ° C. The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought
Components: Original Measurements: boiling organic compound was added as a standard and the ratio of peaks
共1兲 1-Decanol; C10H22O; 40
R. M. Stephenson and J. was measured by gas chromatography 关R. M. Stephenson, J. Stuart, and
关112-30-1兴 Stuart, J. Chem. Eng. Data 31, M. Tabak, J. Chem. Eng. Data 29, 287 共1984兲兴. Temperature was
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲. measured by a calibrated thermometer accurate to 0.1 ° C 共see Table 69兲.
Variables: Prepared by: Source and Purity of Materials:

Temperature: 19.8– 90.4 ° C B. Wisniewska-Goclowska 共1兲 Commercial reagent; purity 99+ mass %.
共2兲 Not stated.
Estimated Error:
2.17. 1-Undecanol + Water
共1兲 1-Undecanol; C11H24O; A. Maczynski, M. Goral, and B.
Critical evaluation of the solubility of 1-undecanol (1)

in water (2)
investigated Stephenson and Stuart40 at 293– 364 K.
and 共10兲, where constants defined by Eqs. 共12兲 were used.
2.26 FIG. 14. All the solubility data for water 共2兲 in 1-undecanol 共1兲.
The criteria used to assign data to categories are also de-
scribed in the Preface to Part 2.26 All the experimental data
and reference values are listed in Table 70. All the data are in References for the 1-undecanol/water system
poor agreement 共greater than 20%兲 with the reference values 8
and are Doubtful. Some data used in this evaluation were
compiled for an earlier version of this work.8 Those compi- 15, Alcohols with Water 共Pergamon, New York, 1984兲.
26
lations are not reprinted here. A new compilation is presented A. Maczynski and D. G. Shaw, Editor, “IUPAC-NIST Solu-
following this evaluation. bility Data Series. 82. Alcohol with Water - Revised and
Critical evaluation of the solubility of water (2) in Ref. Data 36, 191 共2007兲.
1-undecanol (1) 40
investigated by Stephenson and Stuart40 at 293– 364 K, and 共1986兲.
43
Tokunaga43 at 288– 313 K. S. Tokunaga, M. Manabe, and M. Koda, Mem. Niihama
The reference solubility values of water 共2兲 in alkanol 共1兲 Technical College, Sci. Eng. 16, 96 共1980兲. 共IUPAC-SDS,
were determined by LLE calculations described in the Pref- Volume 15兲.
ace to Part 2.26 The concentrations of 共1兲 in 共2兲 predicted
from Eq. 共15兲 were used as the input data. The reference TABLE 70. Experimental values for solubility of 1-undecanol 共1兲 in water
共2兲.
values obtained from the LLE calculations were afterward
regressed by Eq. 共16兲 Experimental values x1
ln x2 = ln x2,min + C2关T2,min/T − 1 − ln共T2,min/T兲兴, 共16兲 T共K兲共D⫽doubtful兲 Reference values x1
293.0 3.10⫻ 10−5 共D; Ref. 40兲 1.05⫻ 10−6

303.1 5.30⫻ 10−5 共D; Ref. 40兲 1.09⫻ 10−6
313.5 9.40⫻ 10−5 共D; Ref. 40兲 1.21⫻ 10−6
in the Preface to Part 2.26 All the experimental data and 323.2 6.80⫻ 10−5 共D; Ref. 40兲 1.40⫻ 10−6
reference values are listed in Table 71 and shown in Fig. 14. 343.4 9.90⫻ 10−5 共D; Ref. 40兲 2.11⫻ 10−6
The data of Stephenson and Stuart40 at 323 K are in poor 353.3 4.10⫻ 10−5 共D; Ref. 40兲 2.72⫻ 10−6
agreement 共greater than 5%兲 with the reference values and 363.7 9.90⫻ 10−5 共D; Ref. 40兲 3.65⫻ 10−6
are Doubtful. All the remaining data are in good agreement
共within ±5%兲 with the reference values and are Tentative.
TABLE 71. Experimental values for solubility of water 共2兲 in 1-undecanol 共1兲. The analytical method was used. Alcohol 共1兲 and water 共2兲 were brought
Experimental values x2 each layer were removed by syringe for analysis. To each sample a higher
T共K兲共T⫽tentative, D⫽doubtful兲 Reference valuesx2 boiling organic compound was added as a standard and the ratio of peaks
288.2 0.255 共T; Ref. 43兲 0.2492 M. Tabak, J. Chem. Eng. Data 29, 287 共1984兲兴. Temperature was
293.0 0.2408 共T; Ref. 40兲 0.2467 measured by a calibrated thermometer accurate to 0.1 ° C 共see Table 72兲.
293.2 0.252 共T; Ref. 43兲 0.2466
298.2 0.254 共T; Ref. 43兲 0.2447
303.1 0.2337 共T; Ref. 40兲 0.2433
共2兲 Not stated.
303.2 0.251 共T; Ref. 43兲 0.2433
308.2 0.250 共T; Ref. 43兲 0.2423 Estimated Error:
313.2 0.245 共T; Ref. 43兲 0.2418 Temperature: ±0.1 ° C.
313.5 0.2337 共T; Ref. 40兲 0.2418 Solubility: 共a兲 0.004, 共b兲 0.02 共standard deviation兲.
323.2 0.2295 共D; Ref. 40兲 0.2421
333.3 0.2343 共T; Ref. 40兲 0.2438
343.4 0.2420 共T; Ref. 40兲 0.2469
353.3 0.2501 共T; Ref. 40兲 0.2512 2.18. 1-Dodecanol ⴙ Water
363.7 0.2501 共T; Ref. 40兲 0.2569
共1兲 1-Dodecanol; C12H26O; A. Maczynski, M. Goral, and B.
共1兲 1-Undecanol; C11H24O; 40
R. M. Stephenson and J. 共2兲 Water; H2O; 关7732-18-5兴 Thermodynamics Data Center,
关112-42-5兴 Stuart, J. Chem. Eng. Data 31, Warsaw, Poland, March, 2006.
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲.

Critical evaluation of the solubility of 1-dodecanol (1)
Temperature: 19.8– 90.5 ° C B. Wisniewska-Goclowska
in water (2)
Experimental Values The experimental solubility data for 共1兲 in 共2兲 have been
TABLE 72. Solubility in the 1-undecanol/water system.40 investigated by Krause and Lange23 at 289– 322 K, Robb34
at 298 K, and Stephenson and Stuart40 at 303– 364 K.
Solubility of 1-undecanol in water
t共°C兲 g共1兲 / 100 g slna兲 x1共compiler兲 lated by the equation:
19.8 0.030 0.000031 ln x1 = ln x1,min + C1关T1,min/T − 1 − ln共T1,min/T兲兴, 共17兲
29.9 0.051 0.000053
40.3 0.090 0.000094 where: T1,min = 287.7 K, ln x1,min = −15.13, and C1 = 58.1.
50.0 0.065 0.000068 T1,min, ln x1,min, and C1 were calculated with Eqs. 共7兲, 共9兲,
70.2 0.095 0.000099 and 共10兲, where constants defined by Eqs. 共12兲 were used.
80.1 0.039 0.000041 All the mentioned equations are given in the Preface to Part
90.5 0.095 0.000099 2.26
Solubility of water in 1-undecanol
t共°C兲 g 共2兲 / 100 g slnb兲 x2共compiler兲 experimental data and reference values are listed in Table 74
19.8 3.21 0.2408
29.9 3.09 0.2337
40.3 3.09 0.2337 lations are not reprinted here. A new compilation is presented
50.0 3.02 0.2295 following this evaluation.
60.1 3.10 0.2343
70.2 3.23 0.2420 Critical evaluation of the solubility of water (2) in
80.1 3.37 0.2501 1-dodecanol (1)
90.5 3.37 0.2501 The experimental solubility data for 共2兲 in 共1兲 have been
investigated by Stephenson and Stuart40 at 303– 364 K,
Auxiliary Information Tokunaga et al.43 at 302– 313 K, and Zhuravleva et al.48 at
295– 315 K.
Method/Apparatus/Procedure: The reference solubility values of water 共2兲 in alkanol 共1兲
were determined by LLE calculations described in the Pref-
ace to Part 2.26 The concentrations of 共1兲 in 共2兲 predicted
from Eq. 共17兲 were used as the input data. The reference
values obtained from the LLE calculations were afterward
regressed by Eq. 共18兲
FIG. 15. All the solubility data for 1-dodecanol 共1兲 in water 共2兲. FIG. 16. All the solubility data for water 共2兲 in 1-dodecanol 共1兲.

where: T2,min = 328 K, ln x2,min = −1.408, and C2 = 7.32. Updated. Part 2. C6 alcohols with water,” J. Phys. Chem.
The criteria used to assign data to categories listed in Ref. Data 36, 191 共2007兲.
Table 75 are described in the Preface to Part 2.26 All the 34
I. D. Robb, Aust. J. Chem. 19, 2281 共1966兲. 共IUPAC-SDS,
experimental data and reference values are listed in Table 76 Volume 15兲.
and shown in Fig. 16. 40
共1986兲.
References for the 1-dodecanol/water system 43
8
A. F. M. Barton, Editor, IUPAC Solubility Data Series, Vol. Technical College, Sci. Eng. 16, 96 共1980兲. 共IUPAC-SDS,
15, Alcohols with Water 共Pergamon New York, 1984兲. Volume 15兲.
23 48
F. P. Krause and W. Lange, J. Phys. Chem. 69, 3171 I. K. Zhuravleva, E. F. Zhuravlev, and L. N. Salamatin, Zh.
共1965兲. 共IUPAC-SDS, Volume 15兲. Obshch. Khim. 46, 1210 共1976兲. 共IUPAC-SDS, Volume
26
A. Maczynski and D. G. Shaw, Editor, “IUPAC-NIST Solu- 15兲.
TABLE 73. The data categories for solubility of 1-dodecanol 共1兲 in water 共2兲.
Tentative Doubtful
289.2 Krause and Lange23

298.2 Robb34
323.4– 364.0 Stephenson and Stuart40
TABLE 74. Experimental values for solubility of 1-dodecanol 共1兲 in water 共2兲. TABLE 74. Experimental values for solubility of 1-dodecanol 共1兲 in water
共2兲.—Continued
T共K兲共T⫽tentative, D⫽doubtful兲 Reference values x1 Experimental values x1
289.2 1.6⫻ 10−7 共D; Ref. 23兲 2.67⫻ 10−7
298.2 4.2⫻ 10−7 共D; Ref. 34兲 2.77⫻ 10−7 333.7 1.5⫻ 10−4 共D; Ref. 40兲 4.91⫻ 10−7
302.7 4.0⫻ 10−5 共D; Ref. 40兲 2.88⫻ 10−7 343.7 9.0⫻ 10−5 共D; Ref. 40兲 6.35⫻ 10−7
307.2 2.8⫻ 10−7 共T; Ref. 23兲 3.02⫻ 10−7 353.5 1.4⫻ 10−4 共D; Ref. 40兲 8.45⫻ 10−7
313.2 5.0⫻ 10−5 共D; Ref. 40兲 3.27⫻ 10−7 364.0 1.7⫻ 10−4 共D; Ref. 40兲 1.18⫻ 10−6
322.2 3.5⫻ 10−7 共T; Ref.23兲 3.82⫻ 10−7
323.4 9.0⫻ 10−5 共D; Ref. 40兲 3.92⫻ 10−7
TABLE 75. The data categories for solubility of water 共2兲 in 1-dodecanol 共1兲.
Tentative Doubtful
294.7–297.4 Zhuravleva et al.48

43
308.2 Tokunaga et al.
313.2 Tokunaga et al.43 Stephenson and Stuart40
TABLE 76. Experimental values for solubility of water 共2兲 in 1-dodecanol Experimental Values
共1兲. TABLE 77. Solubilty in the 1-dodecanol/water system.40
Experimental values x2 Reference Solubility of 1-dodecanol in water

294.7 0.07 共D; Ref. 48兲 0.2556
296.9 0.12 共D; Ref. 48兲 0.2541 29.5 0.04 0.00004
297.4 0.13 共D; Ref. 48兲 0.2537 40.0 0.05 0.00005
302.7 0.2341 共D; Ref. 40兲 0.2507 50.2 0.09 0.00009
303.2 0.248 共T; Ref. 43兲 0.2504 60.5 0.15 0.00015
304.2 0.15 共D; Ref. 48兲 0.2500 70.5 0.09 0.00009
308.2 0.246 共T; Ref. 43兲 0.2483 80.3 0.14 0.00014
313.2 0.2328 共D; Ref. 40兲, 0.244 共T; Ref. 43兲 0.2466 90.8 0.18 0.00017
314.7 0.18 共D; Ref. 48兲 0.2462
Solubility of water in 1-dodecanol
323.4 0.2224 共D; Ref. 40兲 0.2448
333.7 0.2386 共T; Ref. 40兲 0.2449 t共°C兲 g共2兲 / 100 g slnb兲 x2共compiler兲
343.7 0.2230 共D; Ref. 40兲 0.2466
353.5 0.2354 共D; Ref. 40兲 0.2496 29.5 2.87 0.2341
364.0 0.2398 共D; Ref. 40兲 0.2542 40.0 2.85 0.2328
50.2 2.69 0.2224
60.5 2.94 0.2386
Components: Original Measurements: 70.5 2.70 0.2230
共1兲 1-Dodecanol; C12H26O; 40
R. M. Stephenson and J. 80.3 2.89 0.2354
关112-53-8兴 Stuart, J. Chem. Eng. Data 31, 90.8 2.96 0.2398
共2兲 Water; H2O; 关7732-18-5兴 56 共1986兲.
Temperature: 29.5– 90.8 ° C B. Wisniewska-Goclowska Method/Apparatus/Procedure:

共2兲 Not stated.
Estimated Error:
Temperature: ±0.1 ° C
2.19. 1-Tetradecanol + Water
共1兲 1-Tetradecanol; C14H30O; A. Maczynski, M. Goral, and B.
Critical evaluation of the solubility of 1-tetradecanol

(1) in water (2)
investigated by Hoffman and Anacker20 at 277– 334 K, and
Robb34 at 298 K. FIG. 17. All the solubility data for 1-tetradecanol 共1兲 in water 共2兲.
lated by the equation: References for the 1-tetradecanol/water system
ln x1 = ln x1,min + C1关T1,min/T − 1 − ln共T1,min/T兲兴, 共19兲 8
where T1,min = 282.5 K, ln x1,min = −17.86, and C1 = 66.5. 15, Alcohols with Water 共Pergamon, New York, 1984兲.
20
T1,min, ln x1,min, and C1 were calculated with Eqs. 共7兲, 共9兲, C. S. Hoffman and E. W. Anacker, J. Chromatogr. 30, 390
and 共10兲, where constants defined by Eqs. 共12兲 were used. 共1967兲.
26
All the mentioned equations are given in the Preface to Part A. Maczynski and D. G. Shaw, Editor, “IUPAC-NIST Solu-
2.26 bility Data Series. 82. Alcohol with Water - Revised and
The criteria used to assign data to categories are also de- Updated. Part 2. C6 alcohols with water,” J. Phys. Chem.
scribed in the Preface to Part 2.26 All the experimental data Ref. Data 36, 191 共2007兲.
34
and reference values are listed in Table 78 and shown in Fig. I. D. Robb, Aust. J. Chem. 19, 2281 共1966兲.
17. The data of Hoffman and Anacker20 at 305 K, and
Robb34 at 298 K are in good agreement 共within ±35%兲 with
the reference values and are Tentative. All the remaining
data are in poor agreement 共greater than 35%兲 with the ref- 2.20. 1-Hexadecanol + Water
erence values and are Doubtful. The data used in this evalu-
ation were compiled for an earlier version of this work.8 Components: Evaluators:
共1兲 1-Hexadecanol; C16H34O; A. Maczynski, M. Goral, and B.
Those compilations are not reprinted here. 关36653-82-4兴 Wisniewska-Goclowska,
TABLE 78. Experimental values for solubility of 1-tetradecanol 共1兲 in water 共2兲 Water; H2O 关7732-18-5兴 Thermodynamics Data Center,
共2兲. Warsaw, Poland, March, 2006.
T共K兲共T⫽tentative, D⫽doubtful兲 Reference values x1 Critical evaluation of the solubility of 1-hexadecanol
(1) in water (2)
277.2 3.5⫻ 10−9 共D; Ref. 20兲 1.76⫻ 10−8 The experimental solubility data for 共1兲 in 共2兲 have been
298.2 2.6⫻ 10−8 共T; Ref. 34兲 1.92⫻ 10−8
investigated by Hoffman and Anacker20 at 316 and 334 K,
305.2 2.2⫻ 10−8 共T; Ref. 20兲 2.12⫻ 10−8
Krause and Lange23 at 307 and 328 K, and Robb34 at 298 K.
318.2 4.3⫻ 10−8 共D; Ref. 20兲 2.74⫻ 10−8
334.2 7.5⫻ 10−8 共D; Ref. 20兲 4.24⫻ 10−8
ln x1 = ln x1,min + C1关T1,min/T − 1 − ln共T1,min/T兲兴, 共20兲 Critical evaluation of the solubility of 1-heptadecanol (1)
in water (2)
where T1,min = 278.4 K, ln x1,min = −20.60, and C1 = 74.9. investigated by Robb34 at 298 K, and Upchurch and van
T1,min, ln x1,min, and C1 were calculated with Eqs. 共7兲, 共9兲, Winkle44 at 298 and 323 K.
and 共10兲, where constants defined by Eqs. 共12兲 were used. The reference solubility values of 共1兲 in 共2兲 were calcu-
All the mentioned equations are given in the Preface to Part lated by the equation:
2.26 ln x1 = ln x1,min + C1关T1,min/T − 1 − ln共T1,min/T兲兴, 共21兲
The criteria used to assign data to categories are also de-
and reference values are listed in Table 79. All the data are in and 共10兲, where constants defined by Eqs. 共12兲 were used.
poor agreement 共greater than 35%兲 with the reference values All the mentioned equations are given in the Preface to Part
and are Doubtful. The data used in this evaluation were 2.26
compiled for an earlier version of this work.8 Those compi- The criteria used to assign data to categories are also de-
lations are not reprinted here. and reference values are listed in Table 80. All the data are in
TABLE 79. Experimental values for solubility of 1-hexadecanol 共1兲 in water
共2兲. poor agreement 共greater than 35%兲 with the reference values
and are Doubtful. Some data used in this evaluation were
Experimental values x1 compiled for an earlier version of this work.8 Those compi-
T共K兲共D⫽doubtful兲 Reference values x1 lations are not reprinted here. A new compilation is presented
298.2 3.1⫻ 10 共D; Ref. 34兲
−9
1.35⫻ 10−9
following this evaluation.
307.2 6.0⫻ 10−10 共D; Ref. 23兲 1.61⫻ 10−9
316.2 2.8⫻ 10−9 共D; Ref. 20兲 2.03⫻ 10−9 Critical evaluation of the solubility of water (2) in
328.2 2.3⫻ 10−9 共D; Ref. 23兲 2.96⫻ 10−9 1-heptadecanol (1)
334.2 7.3⫻ 10−9 共D; Ref. 20兲 3.68⫻ 10−9 The experimental solubility data for 共2兲 in 共1兲 have been
investigated by Upchurch and van Winkle44 at 298 and
323 K.
References for the 1-hexadecanol/water system The reference solubility values of water 共2兲 in alkanol 共1兲
8 were determined by LLE calculations described in the Pref-
15, Alcohols with Water 共Pergamon New York, 1984兲. ace to Part 2.26 The concentrations of 共1兲 in 共2兲 predicted
20
C. S. Hoffman and E. W. Anacker, J. Chromatogr. 30, 390 from Eq. 共21兲 were used as the input data. The reference
共1967兲. values obtained from the LLE calculations were afterward
23
F. P. Krause and W. Lange, J. Phys. Chem. 69, 3171 regressed by Eq. 共22兲
共1965兲. ln x2 = ln x2,min + C2关T2,min/T − 1 − ln共T2,min/T兲兴, 共22兲
26
where T2,min = 366 K, ln x2,min = −1.337, and C2 = 5.90.
Updated. Part 2. C6 alcohols with water,” J. Phys. Chem. in the Preface to Part 2.26 All the experimental data and
Ref. Data 36, 191 共2007兲. reference values are listed in Table 81. All the data are in
34
I. D. Robb, Aust. J. Chem. 19, 2281 共1966兲. poor agreement 共greater than 5%兲 with the reference values
and are Doubtful.
References for the 1-heptadecanol/water system

8
2.21. 1-Heptadecanol + Water 15, Alcohols with Water 共Pergamon, New York, 1984兲.
26
Components: Evaluators: bility Data Series. 82. Alcohol with Water - Revised and
共1兲 1-Heptadecanol; C17H36O; A. Maczynski, M. Goral, and B. Updated. Part 2. C6 alcohols with water,” J. Phys. Chem.
关1454-85-9兴 Wisniewska-Goclowska, Ref. Data 36, 191 共2007兲.
共2兲 Water; H2O 关7732-18-5兴 Thermodynamics Data Center, 34
I. D. Robb, Aust. J. Chem. 19, 2281 共1966兲. 共IUPAC-SDS,
Volume 15兲.
44
J. C. Upchurch and M. van Winkle, Ind. Eng. Chem. 44,
618 共1952兲.
TABLE 80. Experimental values for solubility of 1-heptadecanol 共1兲 in water 共2兲.
T共K兲共D⫽doubtful兲 Reference values x1
298.2 1.8⫻ 10−9 共D; Ref. 34兲, 0.00016 共D; Ref. 44兲 3.60⫻ 10−10
323.2 0.00016 共D; Ref. 44兲 7.18⫻ 10−10
TABLE 81. Experimental values for solubility of water 共2兲 in 1-heptadecanol 共1兲.

T共K兲共D⫽doubtful兲 values x2
298.2 0.006 共D; Ref. 44兲 0.3000

323.2 0.049 共D; Ref. 44兲 0.2755

3. System Index
共1兲 1-Heptadecanol; C17H36O; 44
J. C. Upchurch and M. van
关1454-85-9兴 Winkle, J. Chem. Eng. Data 44, Page numbers preceded by E refer to evaluation text
共2兲 Water; H2O; 关7732-18-5兴 618 共1952兲.
whereas those not preceded by E refer to compiled tables
␣-Methylbenzenemethanol + Water 688
Temperature: 25 and 50 ° C B. Wisniewska-Goclowska
2-Phenylethanol + Water 688
Experimental Values Cyclooctanol + Water 688–689
TABLE 82. Solubility in the 1-heptadecanol/water system.44 2,6-Dimethylcyclohexanol + Water 689
2-Ethyl–1-hexanol + Water E689–E692, 692–694
Solubility of 1-heptadecanol in water 1-Octanol + Water E694–E700, 700–703
2-Octanol + Water E703–E705, 706–707
t 共°C兲 g / 共1兲 / 100 g sln x1 共compiler兲
3-Octanol + Water 707
25 0.1 0.00016
1-Phenyl–1-propanol + Water 707–708
50 0.1 0.00016
2,6-Dimethyl–4-heptanol + Water E708–E709, 709
Solubility of water in 1-heptadecanol
1-Nonanol + Water E710–E713, 713–714
t 共°C兲 g / 共2兲 / 100 g sln x2 共compiler兲
2-Nonanol + Water E714–E715, 715–716
25 0.1 0.006 3,3,5-Trimethyl–1-hexanol + Water 716
50 0.8 0.049 3,5,5-Trimethyl–1-hexanol + Water 716–717
cis-3,7-Dimethyl–2,6-octadien–1-ol + Water 717
1-Decanol + Water E717–E721, 721–722
1-Undecanol + Water E722–E723, 723
Method/Apparatus/Procedure: 1-Dodecanol +Water E723–E725, 725–726
The cloud-point method was used. A known amount of one component 1-Tetradecanol + Water E726
was measured into a flask from a calibrated burette and weighed. The 1-Hexadecanol + Water E726–E727
second component was then added to the first in a dropwise manner, with 1-Heptadecanol + Water E727–E728, 728
constant agitation of the flask until the solution became turbid. The results
reported above are part of various ternary solubility measurements 共see
Table 82兲.

共1兲 Union Carbide and Carbon Chemicals Corp.
共2兲 Distilled.
Estimated Error:
Solubility: 0.2 mass %.
4. Registry Number Index

Page numbers preceded by E refer to evaluation text whereas those not preceded by E refer to compiled tables
关98-85-1兴 C8H10O ␣-Methylbenzenemethanol 688

关60-12-8兴 C8H10O 2-Phenylethanol 共Benzenethanol; Benzyl carbinol; 688
Phenethyl alcohol; ␤-Phenylethyl alcohol兲
关696-71-9兴 C8H16O Cyclooctanol 688–689
关5337-72-4兴 C8H16O 2,6-Dimethylcyclohexanol 689
关104-76-7兴 C8H18O 2-Ethyl–1-hexanol E689–E692, 692–694
关111-87-5兴 C8H18O 1-Octanol 共Octyl alcohol; Capryl alcohol兲 E694–E700, 700–703
关123-96-6兴 C8H18O 2-Octanol 共Methyl hexyl carbinol兲 E703–E705, 706–707
关589-98-0兴 C8H18O 3-Octanol 共Ethyl pentyl carbinol兲 707
关93-54-9兴 C9H12O 1-Phenyl–1-propanol 共␣-Ethylbenzyl alcohol兲 707–708
关108-82-7兴 C9H20O 2,6-Dimethyl–4-heptanol E708–E709, 709
关143-08-8兴 C9H20O 1-Nonanol 共Nonyl alcohol; Nonanol兲 E710–E713, 713–714
关628-99-9兴 C9H20O 2-Nonanol E714–E715, 715–716
关1484-37-3兴 C9H20O 3,3,5-Trimethyl–1-hexanol 716
关3452-97-9兴 C9H20O 3,5,5-Trimethyl–1-hexanol 716–717
关106-25-2兴 C10H18O cis-3,7-Dimethyl–2,6-octadien–1-ol 共Nerol兲 717
关112-30-1兴 C10H22O 1-Decanol 共Decyl alcohol; n-Decyl alcohol兲 E717–E721, 721–722
关112-42-5兴 C11H24O 1-Undecanol E722–E723, 723
关112-53-8兴 C12H26O 1-Dodecanol 共Dodecyl alcohol; Lauryl alcohol兲 E723–E725, 725–726
关112-72-1兴 C14H30O 1-Tetradecanol E726
关36653-82-4兴 C16H34O 1-Hexadecanol E726–E727
关1454-85-9兴 C17H36O 1-Heptadecanol E727–E728, 728
关7732-18-5兴 H 2O Water 687–689, E689–E691,
691–694, E694-E700,
700–703, E703–E705,
706–708, E708–E709, 709,
E710–E713, 713–714,
E714–E715, 715–717,
E717–E721, 721–722,
E722–E723, 723, E723–
E725, 725–726, E726–
E728, 728
5. Author Index Dallos, A. E689–E692, 693–694, E694–E700, 702

Deguchi, T. E694–E700, 702
Doi, Y. E694–E700, 701
Page numbers preceded by E refer to evaluation text Eckert, C. A. E694–E700, 701
whereas those not preceded by E refer to compiled tables Erichsen, L. E694–E700, E710–E713, E717–E721
Frolov, A. F. 688
Ababi, V. E694–E700 Frolova, E. A. 688
Addison, C. C. E694–E700, E703–E705, E717–E721 Galan, J. C. E694–E700, 701, E717–E721, 721
Anacker, E. W. E726, E726–E727 Ghanadzadeh, A. E689–E692, 693
Arakawa, S. E694–E700, 702 Ghanadzadeh, H. E689–E692, 693
Arce, A. E694–E700, 700 Glick, D. E694–E700
Barcena, L. A. E689–E692, 692 Goral, M. 687, E689–E692, E694–E700, E703–E705, E708–E709,
Bartolome, A. L. E35, 706 E710–E713, E714–E715, E717–E721, E722–E723,
Barton, A. F. M. 687, E689–E692, E694–E700, E703–E705, E708–E709, E723–E725, E726, E726–E727, E727–E728
E710–E713, E714–E715, E717–E721, E722–E723, Hajos-Szikszay, E. E689–E692, 693–694, E694–E700, 702
E723–E725, E726, E726–E727, E727–E728 Hallett, J. P. E694–E700, 701
Blanco, M. E694–E700, 700 Harkins, W. D. E717–E721
Brown, J. S. E694–E700, 701 Hawthorne, S. B. 717
Bush, D. E694–E700, 701 Hixon, A. N. E694–E700, E703–E705, E708–E709
Butler, J. A. V. E694–E700 Hlavaty, K. E689–E692
Cabezas, J. L. E689–E692, 692 Hoffman, C. S. E726, E726–E727
Chernysheva, M. F. E708–E709 Hutchinson, S. K. E717–E721
Coca, J. E689–E692, 692, E703–E705, 706 Ishikawa, H. E694–E700, E710–E713, E717–E721
Cockrem, M. E689–E692, 692 Janado, M. E694–E700, 701
Crittenden, E. D., Jr. E694–E700, E703–E705, E708–E709
Khotkovskaya, T. L. E710–E713 Stuart, J. 688–689, E689–E692, 694, E694-E700, 702–703,

Kinoshita, K. E694–E700, E710–E713, E717–E721 E703–E705, 706–708, E708–E709, 709, E710–E713,
Koda, M. E694–E700, E710–E713, E717–E721, E722–E723, 713–714, E714–E715, 715–717, E717–E721, 721–722,
E723–E725 E722–E723, 723, E723–E725, 725
Krause, F. P. E723–E725, E726–E727 Tabak, M. E689–E692, 694, E694–E700, 702–703
Krupina, Z. V. 688 Tewari, Y. B. E710–E713, 714
Kumamaru, M. E694–E700, 702 Thomson, D. W. E694–E700
Lange, W. E723–E725, E726–E727 Tokunaga, S. E694–E700, E710–E713, E63, E722–E723, E723–E725
Lavrova, O. A. E694–E700 Uosaki, Y. E689–E692, 693, E694–E700, 701–702, E703–E705,
Lesteva, T. M. E694–E700 706
Linek, J. E689–E691 Upchurch, J. C. E726–E727, 728
Loginova, M. A. 688 Valle, R. T. E694–E700, 701, E717–E721, 721
Lomakina, N. G. E694–E700, E717–E721 van Winkle, M. E726–E727, 728
Maclennan, W. H. E694–E700 Vidal, I. E694–E700, 700
Maczynski, A. 687, E689–E692, E694–E700, E703–E705, E708–E709, Vochten, R. E694–E700, e708–E709, E710–E713, E714–E715,
E710–E713, E714–E715, E717–E721, E722–E723, E717–E721
E723–E725, E726, E726–E727, E727–E728 Wasik, S. P. E710–E713, 714
Manabe, M. E694–E700, E710–E713, E717–E721, E722–E723, Wisniewska-Goclowska,
687
E723–E725 B.
Martire, D. E. E710–E713, 714 Yamanaka, T. E694–E700
McBain, J. W. E689–E692, E694–E700 Yano, Y. E694–E700, 701
Miller, D. J. 717 Zhuravlev, E. F. E694–E700, E710–E713, E717–E721, E723–E725
Miller, M. M. E710–E713, 714 Zhuravleva, I. K. E694–E700, E710–E713, E717–E721, E723–E725
Mitchell, S. E703–E705
Miyazaki, Y. E694–E700, 702
Moreno, J. M. M. E694–E700, 701, E717–E721, 721 6. Cumulative References for the
Moriyoshi, T. E689–E692, 693, E694–E700, 701–702, E703–E705, Solubility of C8 – C17 Alcohols with Water
706
Oppenheimer, H. E717–E721 Editor’s Note - For the past articles in this series, each
Palagyi-Fenyes, B. E689–E691, 693–694, E694–E700, 702 system was presented with references for a particular sys-
Pazos, C. E703–E705, 706 tem given with the corresponding tabular data (with each
Petre, G. E694–E700, E708–E709, E710–E713, E714–E715, set of references beginning with the number one). How-
E717–E721 ever starting with this volume (Volume 82, Part 1), all
Popa, A. E694–E700
references have been collected together at the end of the
Rao, C. V. E694–E700
manuscript as well. Thus, the references are numbered
Rao, K. S. E694–E700
Rao, M. V. R. E694–E700
sequentially in this cumulative reference section, but ap-
Ratkovics, F. E689–E692, 693–694, E694–E700, 702 pear as well with each binary system, with the same num-
Richards, P. H. E689–E692, E694–E700 bering. In the Auxiliary Information sections, the refer-
Robb, I. D. E723–E725, E726, E726–E727, E727–E728 ences that occasionally occur here are not included in this
Sakamoto, H. E694–E700, 701 cumulative reference section. These same references do
Sakamoto, T. E689–E692, 693, E694–E700, 701–702, E703–E705, not occur in the Author Index either.
706
1
Salamatin, L. N. E723–E725 V. Ababi and A. Popa, An. Stiint. Univ. ⬙Al. l. Cuza⬙ lasi, Sect. 1 6, 929
Sanemasa, I. E694–E700, 702 共1960兲. 共IUPAC - SDS, Volume 15兲.
2
Sazonov, V. P. E710–E713 C. C. Addison, J. Chem. Soc. 98, 共1945兲. 共IUPAC - SDS, Volume 15兲.
3
Sariri, R. E689–E692, 692–693 C. C. Addison and S. K. Hutchinson, J. Chem. Soc. 1949, 3387.
共IUPAC-SDS, Volume 15兲.
Segado, A. R. E694–E700, 701, E717–E721, 721 4
A. Arce, M. Blanco, and A. Soto, J. Chem. Eng. Data 43, 255 共1998兲.
Shaw, D. G. 687, E689–E692, E694–E700, E703–E705, E708–E709, 5
A. Arce, M. Blanco, and A. Soto, Fluid Phase Equilib. 146, 161 共1998兲.
E710–E713, E714–E715, E717–E721, E722–E723, 6
A. Arce, M. Blanco, A. Soto, and I. Vidal, J. Chem. Thermodyn. 28, 3
E723–E725, E726, E726–E727, E727–E728 共1996兲.
Shinoda, K. E694–E700, E710–E713, E717–E721 7
A. L. Bartolome, C. Pazos, and J. Coca, J. Chem. Eng. Data 35, 285
Simon, E. E717–E721 共1990兲.
8
Skorokhodova, I. I. 688 A. F. M. Barton, Editor, IUPAC Solubility Data Series. 15, Alcohols with
Sobotka, H. E694–E700 Water 共Pergamon, New York, 1984兲.
9
J. S. Brown, J. P. Hallett, D. Bush, and C. A. Eckert, J. Chem. Eng. Data
Soto, A. E694–E700, 700
45, 846 共2000兲.
Stearns, R. S. E717–E721 10
J. A. V. Butler, D. W. Thomson, and W. H. Maclennan, J. Chem. Soc.
Stephenson, R. 688–689, E689–E692, 694, E694-E700, 702–703, 1933, 674. 共IUPAC - SDS, Volume 15兲.
E703–E705, 706–708, E708–E709, 709, E710–E713, 11
J. L. Cabezas, L. A. Barcena, J. Coca, and M. Cockrem, J. Chem. Eng.
713–714, E714–E715, 715–717, E717–E721, 721–722, Data 33, 435 共1988兲.
12
E722–E723, 723, E723–E725, 725 E. D. Crittenden Jr. and A. N. Hixon, Ind. Eng. Chem. 46, 265 共1954兲.
共IUPAC - SDS, Volume 15兲.
13
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IUPAC-NIST Solubility Data Series. 82.

Alcohols with Water–Revised

Andrzej Maczynski, Volume Editora…

David G. Shaw, Volume Editorb…

Marian Goral and Barbara Wisniewska-Goclowska, Assistants

CONTENTS 2.17. 1-Undecanol + Water*. . . . . . . . . . . . . . . . . 722

8. Experimental values for solubility of 2-ethyl– 43. Solubility in the 1-phenyl–1-propanol/water

J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007

1-dodecanol 共1兲 in water 共2兲.. . . . . . . . . . . . . . . . 725 1. Preface

J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007

2. C8 – C17 Alcohols with Water TABLE 2. Solubility in the 2-phenylethanol/water system.40—Continued

2.1. ␣-Methylbenzenemethanol ⴙ Water Solubility of 2-phenylethanol in water

0.0 7.10 0.3410

Variables: Prepared by: Auxiliary Information

Method/Apparatus/Procedure: Estimated Error:

Source and Purity of Materials:

Variables: Prepared by:

J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007

TABLE 3. Solubility in the cyclooctanol/water system.40—Continued TABLE 4. Solubility in the 2,6-dimethylcyclohexanol/water

70.3 6.05 0.3143 90.6 0.43 0.00061

Source and Purity of Materials: Auxiliary Information

Source and Purity of Materials:

Solubility of 2,6-dimethylcyclohexanol in water

Author 共s兲 T共K兲 Author 共s兲 T共K兲

J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007

J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007

283.4 and 293.0 Stephenson et al.41

TABLE 8. Experimental values for solubility of 2-ethyl–1-hexanol 共1兲 in water 共2兲.

283.4 1.83⫻ 10−4 共D; Ref. 41兲 1.10⫻ 10−4

273.2 McBain and Richards27

J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007

298.2 Cabezas et al.11

273.2 0.1331 共D; Ref. 27兲 0.1541

J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007

Solubility of water in 2-ethyl–1-hexanol

g共2兲 / 100 g sln Method/Apparatus/Procedure:

Estimated Error: Components: Original Measurements:

T共K兲 g共1兲 / 100 g sln x1共compiler兲

Solubility of water in 2-ethyl–1-hexanol

J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007

TABLE 14. Solubility in the 2-ethyl–1-hexanol/water system.32—Continued 共1兲 2-Ethyl-1-hexanol; C8H18O; 41

T共K兲 g共2兲 / 100 g sln x2共compiler兲 Variables: Prepared by:

Method/Apparatus/Procedure: Solubility of 2-ethyl–1-hexanol in water

Solubility of 2-ethyl–1-hexanol in water Auxiliary Information

293.15 3.03 0.1724 Source and Purity of Materials:

Source and Purity of Materials:

Estimated Error: Components: Evaluators:

J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007

Author 共s兲 T共K兲 Author 共s兲 T共K兲

The reference solubility values of 共1兲 in 共2兲 were calcu-

ln x1 = ln x1,min + C1关T1,min/T − ln共T1,min/T兲兴

where T1,min = 304.5 K, ln x1,min = −9.67, C1 = 41.3, D1

Author 共s兲 T共K兲 Author 共s兲 T共K兲

Ababi and Popa1 298 Janado et al.21 298

J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007

Author 共s兲 T共K兲 Author 共s兲 T共K兲

J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007

288.2 Vochten and Petre45

Experimental values x1 Reference

288.2 7.30⫻ 10−5 共T; Ref. 45兲 6.73⫻ 10−5

J. Phys. Chem. Ref. Data, Vol. 36, No. 3, 2007

Experimental values x1 Reference