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C H A P T E R

2
Approaches to WQI Formulation
O U T L I N E

2.1. Introduction 9 2.5. Assignment of Weightages 15


2.1.1. Indices for ‘Water Quality’ and
2.6. Aggregation of Subindices to Produce
‘Water Pollution’ 9
a Final Index 15
2.2. The Common Steps 10 2.6.1. Linear Sum Index 16
2.6.2. Weighted Sum Index 16
2.3. Parameter Selection 10
2.6.3. Root Sum Power Index 17
2.4. Transformation of the Parameters of 2.6.4. Multiplicative Form Indices 17
Different Units and Dimensions to 2.6.5. Maximum Operator Index 17
a Common Scale: Making Subindices 11 2.6.6. Minimum Operator Index 18
2.4.1. Developing Subindices 12
2.7. Characteristics of Aggregation Models 18
2.4.2. Different Types of Subindices 12
2.7.1. Ambiguity and Eclipsing 18
2.4.2.1. Linear Function Subindices 12
2.7.2. Compensation 18
2.4.2.2. Segmented Linear Function
2.7.3. Rigidity 18
Subindices 13
2.4.2.3. Nonlinear Function 13
2.4.2.4. Segmented Nonlinear
Function 13

2.1. INTRODUCTION
numbers decrease with the degree of pollution
(decreasing scale indices). One may classify the
2.1.1. Indices for ‘Water Quality’
former as ‘water pollution indices’ and the latter
and ‘Water Pollution’ as ‘water-quality indices’. But this difference is
Water-quality indices can be formulated in essentially cosmetic; ‘water quality’ is a general
two ways: one in which the index numbers term of which ‘water pollution’ e which indi-
increase with the degree of pollution (increasing cates ‘undesirable water quality’ e is a special
scale indices) and the other in which the index case.

Water Quality Indices DOI: 10.1016/B978-0-444-54304-2.00002-6 9 Copyright Ó 2012 Elsevier B.V. All rights reserved.
10 2. APPROACHES TO WQI FORMULATION

2.2. THE COMMON STEPS 2.3. PARAMETER SELECTION


The following four steps are most often asso- As we have elaborated in Chapter 1, a water
ciated with the development of any WQI; sample may have hundreds of constituents,
depending on the sophistication being aimed including elements in neutral or ionic form
at, additional steps may also be taken: (metals, non-metals, metalloids); organics
(pesticides, detergents, other organics of indus-
1. Parameter selection.
trial or natural origin); anions such as carbonate,
2. Transformation of the parameters of different
bicarbonate, sulphate, nitrate, nitrite etc. It may
units and dimensions to a common scale.
also have suspended solids which, in turn,
3. Assignment of weightages to all the
constitute a bewildering range of chemicals. It
parameters.
may also have radioactivity, and may have
4. Aggregation of subindices to produce a final
colour and odour. Then it may have pathogenic
index score.
bacteria, fungi, helminthic cysts etc.
Of these, steps 1, 2 and 4 are essential for all A WQI would become unwieldy if each and
indices. Step 3 is also commonly taken through every possible constituent is included in the
some indices may be formed without this step index. Instead, one needs to choose a set of
as well. parameters which, together, reflect the overall
Water-quality indices make it very easy for water quality for the given end use. It is an
a lay person to judge whether a water source exercise similar to the one involved in the
is usable or not and how one source compares selection of a few dozen or a few hundred
to another, but the development of WQI is shares out of thousands to construct a share
by no means an easy task. It, in fact, is market index. To reduce the number of shares
fraught with several complications and to be incorporated in the index, yet keep the
uncertainties. index representative of the overall stock
As we may see from the following discussion, market situation, those shares are picked up
and from the numerous examples given in the which have a high ‘driver power’ e i.e shares
following chapters on how different WQIs of whose movement influences a large number
have been developed for different needs, it of other shares. In this manner, the share price
would be clear that a great deal of subjective index is made ‘sensitive’ to the stock market as
opinion and judgement is associated with each a whole even as it is computed on the basis of
step, particularly steps 1 and 3. There is no tech- the prices of only a fraction of the listed shares.
nique or device by which 100% objectivity or Water-quality indices are also made on the
accuracy can be achieved in these steps. Even basis of a few parameters chosen for their
parameter selection through statistical analysis ‘forcing’ or ‘driver power’. But it is here that
of past data (detailed in Chapter 4), though subjectivity creeps in. Different experts and
apparently objective, is fraught with inherent end users may have different perceptions of
uncertainties and incompleteness. the importance of a parameter vis a vis a given
One can only try to reduce subjectivity and end use. For example, a medical expert may
inaccuracy by involving large number of perceive water carrying a faint odour but other-
experts in collecting opinion, and doing it by wise free from harmful constituents as good. In
well-developed opinion-gathering techniques his/her opinion, odour may be a parameter of
such as Delphi (Abbasi 1995, Abbasi and very little significance. But to others even the
Arya 2000). faintest odour in their drinking water may be

I. WATER QUALITY INDICES BASED PREDOMINANTLY ON PHYSICO-CHEMICAL CHARACTERISTICS


2.4. TRANSFORMATION OF THE PARAMETERS OF DIFFERENT UNITS AND DIMENSIONS TO A COMMON SCALE 11
totally unacceptable. They will advocate that correlations can occur by sheer chance and need
odour must be included as a key parameter in not have a cause-effect link. For example, data on
any WQI dealing with drinking water. chloride may strongly correlate with data on
Even the water-quality standards, on which abundance of a fish species but the two may, in
much of our decisions on fitness or otherwise reality, have no link whatsoever.
of a water source depend, are not common to
all countries. Further, as new research
brings to light new facts on the beneficial or 2.4. TRANSFORMATION OF THE
harmful effects of a constituent, or gives PARAMETERS OF DIFFERENT
new information on the concentration beyond UNITS AND DIMENSIONS TO
which a constituent becomes harmful or the A COMMON SCALE: MAKING
concentration below which a constituent ceases SUBINDICES
to be helpful, the standards are continuously
revised. Different water-quality parameters are
The criteria of ‘acceptability’ also vary from expressed in different units. For example,
region to region. In regions well-endowed temperature is expressed in degrees celsius
with water resources e for example the State or fahrenheit, coliforms in numbers, electrical
of Kerala, India e drinking water containing conductivity in micro-mhos, and most chemi-
more than 500 mg/L of total dissolved solids cals in milligramme per litre (or microgram
(which is the BIS (Bureau of Indian Standards) per ml). Further, the ranges of levels to which
limit for ideal drinking water) may be consid- different parameters can occur vary greatly
ered unfit for drinking because the state may from parameter to parameter. For example,
find ample drinking water in an alternative dissolved oxygen would rarely be beyond the
source meeting with the BIS standard. On the range 0e12 mg/L but sodium can be in the
other hand, people in arid or semi-arid range 0e1000 mg/L or beyond. Toxic elements
regions, for example in the Indian states of such as mercury rarely occur above 1 mg/L
Rajasthan, Tamil Nadu and elsewhere, level, whereas acidity/alkalinity, hardness,
routinely drink water with TDS well above chloride and sulphate nearly always occur at
500 mg/L. levels above 1 mg/L. Yet again, water contain-
Therefore, parameter selection is as fraught ing 10 mg/L of chloride is as fit for drinking as
with uncertainty and subjectivity as it is crucial water containing fifteen times higher chloride.
to the usefulness of any index. Enormous care, But a water sample containing 0.001 mg/L of
attention, experience, and consensus-gathering mercury is acceptable while a water with
skills are required to ensure the most represen- even twice this concentration of mercury
tative parameters are included in a WQI. is not.
In an attempt to reduce the subjectivity in In other words, different parameters occur in
parameter selection, statistical approaches have different ranges, are expressed in different units,
been attempted, as described in Chapter 4. While and have different behaviour in terms of concen-
in theory such approaches are objective e trationeimpact relationship. Before an index
because they select parameters on the basis of can be formulated, all this has to be transformed
considerations such as frequency of occurrence into a single scale e usually beginning with zero
of different parameters, the number of other and ending at 1. Some index scales have the
parameters to which they seem to correlate, range 0e100. But this, again, makes only
etc e they can lead to erroneous results because a cosmetic difference.

I. WATER QUALITY INDICES BASED PREDOMINANTLY ON PHYSICO-CHEMICAL CHARACTERISTICS


12 2. APPROACHES TO WQI FORMULATION

2.4.1. Developing Subindices or a multiplication operation, in which a product


is formed of some or all the subindices, or some
Subindices, one for each parameter selected other operation; some of the common aggrega-
for the index, are developed so that different tion methods are given in Section 6.
parameters, their units and the range of The overall process: calculation of subindices
concentrations (from highly acceptable to and aggregation of subindices to form the index
highly unacceptable) are all transformed onto can be illustrated as in Figure 2.1.
a single scale.
If we consider a set of n pollutant variables
denoted as (x1, x2, x3 . xi, xn), then for each 2.4.2. Different Types of Subindices
pollutant variable xi, a subindex Ii is computed Subindices can be classified as one of four
using subindex function fi, (xi): general types:
Ii ¼ Fi ðxi Þ (2.1) 1. Linear
2. Nonlinear
In most indices, different mathematical 3. Segmented linear
functions are used to compute different 4. Segmented nonlinear
pollutant variables, yielding the subindex func-
tions f1 (x1), f2 (x2) . fn (xn). Such functions may
2.4.2.1. Linear Function Subindices
consist of simple multiplier, or the pollutant
variable raised to a power, or some other func- The simplest subindex function is the linear
tional relationship. equation:
Once the subindices are calculated, they I ¼ ax þ b (2.3)
usually are aggregated together in a second
where I is the subindex, x the pollutant variable
mathematical step to form the final index:
and a, b the constants.
I ¼ gðI1, I2 .In Þ (2.2) With this function, a direct proportion exists
between the subindex and the pollutant vari-
The aggregation function, (2.2), usually able. The linear indices are simple to compute
consists either of a summation operation, in and easy to understand but have limited
which individual subindices are added together, flexibility.

FIGURE 2.1 The index develop- Information flow


ment process.
Parameter x1 Subindex I1 Aggregation

Parameter x2 Subindex I2
Water quality
=
Data =
Index I

Parameter xn Subindex In

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2.4. TRANSFORMATION OF THE PARAMETERS OF DIFFERENT UNITS AND DIMENSIONS TO A COMMON SCALE 13
2.4.2.2. Segmented Linear Function plotted on a graph sheet. Such nonlinear func-
Subindices tions are of two basic types:
A segmented linear function consists of two 1. an implicit function, which can be plotted on
or more straight line segments joined at break a graph but for which no equation is given
points (threshold level). It offers more flexibility 2. an explicit function, for which a
than linear function and is especially useful for mathematical equation is given.
incorporating administratively recommended
limits, such as Bureau of Indian Standards Implicit functions usually arise when some
(BIS) limits, WHO limits etc. One of the impor- empirical curve has been obtained from
tant types of segmented linear functions is the a process under study. For example, Brown
step function, which exhibits just two states et al. (1970) proposed an implicit nonlinear
and therefore is called a dichotomous function. subindex function for pH.
The segmented linear function subindices may Explicit nonlinear functions automatically
also consist of a staircase of steps, giving lead to nonlinear curves. An important general
a multiple-state function. For example, Horton nonlinear function is one in which the pollutant
(1965) has used subindex functions containing variable is raised to a power other than one, the
three, four, and five steps. In Horton’s dis- power subindex function:
solved oxygen subindex, one finds I ¼ 0 for x
I i ¼ xc (2.5)
less than 10% saturation, I ¼ 30 for x between
10% and 30% saturation, and I ¼ 100 for x where c s 1
above 70% saturation. Walski and Parker (1974) used the following
Mathematically, the general form of general parabolic form in evolving the subindi-
segmented linear function can be formulated ces for temperature and pH:
as follows.
Given that x and I coordinates of the break b
Ii ¼  ðx  aÞ2 þ b, 0  x  2a (2.6)
points are represented by (a1, b2), (a2, b2),., a2
(aj, bj), any segmented linear function with m
segments can be presented by the following Another common nonlinear function is the
general equation: exponential function, in which pollutant vari-
able x is the exponent of a constant:
biþ1  bi
Ii ¼ ðx  ai Þ þ bi , ai  x  aiþ1 (2.4) Ii ¼ Cx (2.7)
aiþ1  ai
The constant usually selected is either 10 or e,
where, i ¼ 1, 2, 3, ., m: the base of the natural logarithm. If a and b are
Although segmented linear functions are constants, the general form of an exponential
flexible, they are not ideally suited to some situ- function is written as follows:
ations, particularly those in which the slope
changes very gradually with increasing levels Ii ¼ aebx (2.8)
of pollution. In these instances, a nonlinear
function is usually more appropriate. 2.4.2.4. Segmented Nonlinear Function
Segmented nonlinear function consists of
2.4.2.3. Nonlinear Function line segments similar to the segmented linear
When a causeeeffect relationship does not function; however, at least one segment is
vary linearly, it leads to a curvature when nonlinear. Usually, each segment is represented

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14 2. APPROACHES TO WQI FORMULATION

TABLE 2.1 The Segments, Ranges and Functions Used by Prati et al. (1971)
for pH

Segment Range Function

1 0x5 Ii ¼ 0.4x2 þ 14
2 5x7 Ii ¼ 2x þ 14
3 7x9 Ii ¼ x2  14x þ 49

4 9  x  14 Ii ¼ 0.4x2 þ 11.2x  64.4

FIGURE 2.2 Typical subindex


functions.

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2.6. AGGREGATION OF SUBINDICES TO PRODUCE A FINAL INDEX 15
by a different equation which applies over this is one reason why we do not find as
a specific range of the pollutant variable. many new indices based on Delphi being
Segmented nonlinear function being more flex- proposed as we otherwise might have.
ible than the segmented linear function has
been used for a number of water-quality subin-
dices. For example, Prati et al. (1971) used 2.6. AGGREGATION OF
a segmented nonlinear function for the pH SUBINDICES TO PRODUCE
subindex in their water-quality index. The pH A FINAL INDEX
subindex function contained four segments
(Table 2.1). In the final step, the subindices are aggre-
Typical subindex functions are presented in gated to obtain the final index. Several methods
Figure 2.2. of aggregation are possible; the three most basic
ones are:
Additive: In additive aggregation, the subindi-
2.5. ASSIGNMENT ces (referring to transformed values of parame-
OF WEIGHTAGES ters) are combined through summation
(e.g., arithmetic mean). This has been the most
We have explained at some length in Chapter 1 oft-used aggregation method. Indices of Horton
and in Section 2.3 of this chapter that it is a neces- (1965), Brown et al., (1970), Prati et al., (1971),
sary as well as a very challenging task to shortlist Dinius (1972), Otto (1978) e among others e
a few from among hundreds of water-quality have been based on this model.
parameters so that a balance is achieved between Multiplicative: In multiplicative aggregation,
size of an index, genuineness of the water-quality the subindices are combined through product
data and effectiveness of the index. operation (e.g., geometric mean). Indices of
But even after a shortlist of 10e20 parame- Landwehr et al. (1974), Walski and Parker
ters has been made, it still remains a major (1974), Bhargava (1985), Dinius (1987), etc,
task to assign weightage to each parameter. have been based on this model.
Because even as all short-listed parameters are Logical: In logical aggregation, the subindices
deemed to be important as water-quality indi- are combined through logical operation (e.g.,
cators, they would still not be equally impor- minimum or maximum). The index of Smith
tant. Within the selected parameters, some (1990) is an example.
would be of greater importance than some The combination of operations is also used,
others. for example the WQI of Inhaber (1975) is based
Some of the indices assume equal weightage on the weighted root sum square function and
of all the parameters. But in great many, the WQI of Dojlido et al. (1994) employs square
different weightage is given to the different root harmonic mean.
parameters. The assignment of weightage is, In recent years, attempts have been made to
like selection of parameters, a matter of relate the indices to some sort of ‘acceptability’
opinion, hence subjective. For this, too, well- measure that can be interpreted as the member-
formulated techniques of opinion gathering ship of a fuzzy set (Sadiq et al., 2007, Sadiq and
such as Delphi (Abbasi & Arya 2000) are uti- Rodriguez, 2004, Lu and Lo, 2002, Chang et al.,
lised to minimise subjectivity and enhance 2001, Lu et al., 1999, and Tao and Xinmiao,
credibility. It must be brought to the attention 1998). There is increasing use of factor analysis,
of the readers that Delphi is a rather cumbur- principal-component analysis, and other
some and time-consuming exercise. Perhaps concepts such as entropy and genetic

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16 2. APPROACHES TO WQI FORMULATION

algorithms in making ‘hybrid’ indices or in permissible limits. This phenomenon is called


enhancing the applicability of conventional ‘ambiguity problem’.
indices (Peng, 2004; Nasiri et al., 2007; Bonnet
et al., 2008; Meng et al., 2009; Taheriyoun
et al., 2010; Thi Minh Hanh et al., 2011). In addi-
2.6.2. Weighted Sum Index
tion, there is a class of generalised mean opera- A weighted sum index is given by
tors developed by Yager (1988), known as
Ordered Weighted Averaging (OWA) opera- X
n
I ¼ Wi Ii (2.11)
tors, which have been used to develop a WQI
i¼1
(Sadiq and Tesfamariam, 2007). These aspects
are covered in more detail in the following where Ii is the subindex for ith variable and Wi
chapters. However, the three types of aggrega- the weight for ith variable:
tion models described above continue to be X
n
used very extensively. Wi ¼ 1 (2.12)
The manner in which these aggregation i¼1
models are used is illustrated in the following This index steers clear of the kind of ambi-
examples. guity which dogs the linear sum index but
suffers an equally serious problem called
2.6.1. Linear Sum Index ‘eclipsing’. Eclipsing occurs when at least one
A linear sum index is computed by the addi- subindex reflects poor water quality as
tion of unweighted subindices, in which no explained below:
subindex is raised to a power other than 1: For the two variable case,
Xn I ¼ W 1 I 1 þ W2 I 2 (2.13)
I ¼ Ii (2.9)
W1 þ W2 ¼ 1 (2.14)
i¼1

where Ii is the subindex for pollutant variable i Equations (2.13) and (2.14) can be written in
and n is the number of pollutant variables a single equation as
The simplicity of linear summation is out-
I ¼ W1 I1 þ ð1  W1 ÞI2 (2.15)
weighed by the disadvantage that the resulting
index can project poor water quality even From Equation (2.15), it is clear that I ¼ 0 when
when no individual parameter is below accept- both I1 and I2 ¼ 0, i.e. the zero pollution is indi-
able level as explained below. cated properly. Further, I will not be 100 until
A linear sum water pollution index is formed and unless one of the subindices is more or equal
consisting of just two subindices, I1 and I2: to 100. Hence, the problem of ambiguity is also
I ¼ I1 þ I2 (2.10) removed.
But in situations such as the ones arising when
Assuming that I1 ¼ 0 and I2 ¼ 0 represent zero I1 ¼ 50 and I2 ¼ 110 with W1 and W2 both equal
concentration and I1  100 or I2  100 represent to 0.5, gives I ¼ 80. In other words, the overall
concentration at the cut-off or below the permis- score indicates acceptable water quality even
sible level. If the summation leads to I > 100, the though one of the constituents as reflected in I2
users would infer that permissible level is was above the permissible limit of 100. This
violated by at least one subindex, whereas, in type of situation when the index score ‘hides’
reality, one can get I > 100 even when both the the unacceptable level of one or more constituent
individual parameters constituting I are within parameters is called ‘eclipsing’.

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2.6. AGGREGATION OF SUBINDICES TO PRODUCE A FINAL INDEX 17

2.6.3. Root Sum Power Index For this situation, w ¼ 1/n, Equation (2.17)
becomes the geometric mean of subindices:
The root sum power index is formed by a
" #w " #1=n
nonlinear aggregation function: Yn Yn
" #1=p I ¼ Ii ¼ Ii (2.20)
Xn
i¼1 i¼1
p
I ¼ Ii (2.16)
i¼1 Thus, the geometric mean is a special case of
where p is a positive real number, greater than 1. the weighted product aggregation function.
As p becomes larger, the ambiguous region A common version of the weighted product is
becomes smaller. For large values of p, the the geometric aggregation function:
ambiguous region is almost entirely eliminated. " #1=g
Yn
gi
The root sum power function is a good means I ¼ Ii (2.21)
for aggregating subindices, because it neither i¼1
yields an eclipsing region nor an ambiguous
region. However, because it is a limiting func- where
tion, it is somewhat unwieldy. X
n
g ¼ gi (2.22)
i¼1
2.6.4. Multiplicative Form Indices
The most common multiplicative aggrega- 2.6.5. Maximum Operator Index
tion function in such indices is the weighted
The maximum operator index can be viewed
product, which has the following general form:
" # as the limiting case of the root sum power index
Yn
as p approaches infinity. The general form of the
I ¼ Ii Wi (2.17)
i¼1
maximum operator is as follows:
where I ¼ maxfI1 , I2 , . In g (2.23)
X
n
Wi ¼ 1 (2.18) In the maximum operator, I takes on the
i¼1 largest of any of the subindices, and I ¼ 0 if
and only if Ii ¼ 0 for all i. It is ideally suited to
In this aggregation function, as with all multi- determine if a permissible value is violated
plicative forms, an index is zero if any one and by how much.
subindex is zero. This characteristic eliminates The limitation of the maximum operator
the eclipsing problem, because if any one becomes apparent when fine gradations of
subindex exhibits poor water quality, the overall water quality, rather than discrete events, are
index will exhibit poor water quality. to be reported and a number of subindices are
Conversely, I ¼ 0 if and only if at least one to be aggregated.
subindex is zero; this characteristic eliminates The maximum operator is ideally suited to
the ambiguity problem. applications in which an index must report if
If the weights in Equation (2.18) are set equal, at least one recommended limit is violated and
Wi ¼ w for all I, then Equation (2.18) can be by how much. Of course, if several subindices
written as follows: violate a recommended limit, the maximum
Xn operator will accordingly yield increasingly
Wi ¼ nw ¼ 1 (2.19) desirable subindex. The suitability of the
i¼1 maximum operator for use in water pollution

I. WATER QUALITY INDICES BASED PREDOMINANTLY ON PHYSICO-CHEMICAL CHARACTERISTICS


18 2. APPROACHES TO WQI FORMULATION

indices has not been explored as it ought to have The other characteristics of aggregation
been, however, and none of the published methods are compensation and rigidity.
water-quality indices has employed this aggre-
gation function.
2.7.2. Compensation
An aggregation method model with good
2.6.6. Minimum Operator Index
compensation is one that is not biased towards
The minimum operator index, when extremes (i.e., highest or lowest subindex
summing decreasing scale subindices, performs value). But this attribute comes in the way
in a fashion similar to the increasing scale when ambiguity-free and eclipsing-free models
maximum operator index. The general form of are desired. For example, maximum (or
the minimum operator is minimum) operators which are free from ambi-
guity and eclipsing have poor compensation as
I ¼ minfI1, I2 , . In g (2.24) they are biased toward the highest (or the
lowest) subindex values. Hence, the virtues of
As g is within the maximum operator func-
compensation have to be balanced with the
tions, eclipsing does not occur with this aggre-
disadvantages of ambiguity (and eclipsing).
gation method, nor does an ambiguous region
Generally, aggregation methods are regarded
exist. Consequently, the minimum operator
as having good compensation when they satisfy
appears to be a good candidate for aggregating
the following constraint:
decreasing scale subindices. However, none of
the published environmental indices employ minN N
i¼1 ðsi Þ  Aggðs1 , s2 , ., sN Þ ¼ I  maxi¼1 ðsi Þ
the minimum operator, and its potential, too,
remains unexplored. (2.25)
An overview of parameters, the type of sub- However, this constraint does not necessarily
indices, weightages and aggregation methods apply to some methods where the compensa-
used in some of the commonly used indices is tory property is undefined. It has been reported
presented in Table 2.2. that operators resulting in aggregate values less
than minimum and greater than maximum,
respectively, lack compensation properties
2.7. CHARACTERISTICS OF (Zimmermann and Zysno, 1980).
AGGREGATION MODELS

2.7.1. Ambiguity and Eclipsing 2.7.3. Rigidity


In the preceding section, examples were Rigidity is manifested when necessity arises
given of how certain aggregation methods cause for additional variables to be included in an
ambiguity or eclipsing. These are two of the index to address specific water quality
characteristics of aggregation methods. To wit, concerns, but the aggregation model does not
ambiguity is caused in an aggregation method allow this. For example, it is common for a regu-
when index I exceeds the critical level (unac- latory agency to have an existing overall index,
ceptable value) without any of the subindices but the agency would like to add one or more
exceeding the critical level, and eclipsing is additional parameters. This situation may arise
caused when index I does not exceed the critical when at a particular site the index may show
level (unacceptable value) despite one or more the water quality to be good and yet the water
of the subindices exceeding the critical level. may be adversely impacted by constituents not

I. WATER QUALITY INDICES BASED PREDOMINANTLY ON PHYSICO-CHEMICAL CHARACTERISTICS


TABLE 2.2 Formulations of Some Oft e used Water Quality Indices

Index Parameter Subindex, SIi Wi Aggregation formulation Range of WQI


I. WATER QUALITY INDICES BASED PREDOMINANTLY ON PHYSICO-CHEMICAL CHARACTERISTICS

NSFeWQI DO (%) 142 experts drew curves 0.17 X


N
0-25 ¼ very bad
SIi Wi
(Brown et al. for raw data and assigned a i¼1
1970) value ranging from 0
(worst) to 100 (best) and
FC, MPN/100 mL 0.16 26-50 ¼ bad
final curves were obtained
pH with the weighting curves 0.11 51-70 ¼ regular
for each parameter
BOD5 (ppm) 0.11 71-90 ¼ good
Nitrates (ppm) 0.10 91-100 ¼ excellent

2.7. CHARACTERISTICS OF AGGREGATION MODELS


Total phosphates 0.10
(ppm)
Temp. ( C) 0.10
Turbidity, NTU/JTU 0.08
Total solids (ppm) 0.07 vffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
u N
u
O-WQI (Dunnette Temp ( C) 1,a uP 10-59 ¼ very poor
t N 1
1979; Cude 2001) i¼2
SIi2
DO (%) 1,2 60-79 ¼ poor

BOD5 (mg/L) 2 80-84 ¼ fair


pH 2 85-89 ¼ good
Ammonia+Nitrate 2 90-100 ¼ excellent
nitrogen (mg/L)
Total phosphorus 1,b
(mg/L)
Total solids (mg/L) 2
FC (#/100 mL) 2
P3
i¼1 SIi
PW-WQI (Pesce DO (mg/L) 4 0 ¼ minimum quality
3
and Wunderlin
2000)

(Continued)

19
TABLE 2.2 Formulations of Some Oft e used Water Quality Indices (cont’d)

20
Index Parameter Subindex, SIi Wi Aggregation formulation Range of WQI
I. WATER QUALITY INDICES BASED PREDOMINANTLY ON PHYSICO-CHEMICAL CHARACTERISTICS

Conductivity 100 ¼ maximum


(mS/cm) quality
Turbidity, NTU
X
N
CPCB e WQI DO (%) 3 0.31 SIi Wi <38 ¼ bad to very bad
(Sarkar and i¼1 38-50 ¼ bad
Abbasi 2006)
BOD5 (mg/L) 3 0.19 50-63 ¼ medium to
good
pH 3 0.22 63-100 ¼ good to
excellent

2. APPROACHES TO WQI FORMULATION


FC (MPN/100 mL) 5 0.28
X
3
River pollution DO (mg/L) 4 SItemp SIpH SItox SIi Wi Value varies from
index (RPI) BOD5 (mg/L) i¼1 0-64.8 and are divided
#1=3
(Liou et al. X
2 X
1 into nonpolluted,
2004)  SIj Wj  SIk lightly polluted,
j¼1 k¼1
moderately polluted,
and grossly polluted

Ammonia nitrogen SIj ¼ subindex for two particulate


(mg/L) parameters
Suspended solids SIk ¼ sub-index for FC
(mg/L)
Turbidity (NTU) SIi ¼ sub -index for last three
parameter

Temp. ( C)
FC (MPN/100 m/L)
pH
Toxicity
PN
i¼1 SIi
U-WQI Cadmium, cyanide, N/A N/A N/A
N
(Boyacioglu, mercury, selenium,
I. WATER QUALITY INDICES BASED PREDOMINANTLY ON PHYSICO-CHEMICAL CHARACTERISTICS

2007) arsenic, fluoride,


nitrate-nitrogen, DO,
BOD5, total
phosphorus, pH
and total coliform

S-WQI (Said DO (%)  


et al. (2004) DO1:5 <1 ¼ poor
log TP TP 0:5
ð3:8Þ ðTurbÞ 15FC=1000 þ 0:14ðConÞ
Con (mS/cm) <2 ¼ marginal
and remediation

2.7. CHARACTERISTICS OF AGGREGATION MODELS


Turbidity, Turb (NTU) 3-2 ¼ acceptable

FC, MPN/100 mL 3 ¼ very good


Total phosphorus, TP 0 ¼ minimum quality
(mg/L)

ISQA* Temp. ( C) 3 SITEMP ðSITOC þ SISS þ SIDO þ SICon Þ 100 ¼ maximum


quality
TOC (mg/L) 3

SS (mg/L) 3
DO (mg/L) 3
Con (mS/cm) 5
pffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
ffi
F21 þ F22 þ F23
Not fixed F1: scope (% of variables 100  0-44 ¼ poor
1:732
that do not meet their 45-64 ¼ marginal
objectives at least 65-79 ¼ fair
once); F2: frequency 80-94 ¼ good
(% of individual tests 95-100 ¼ excellent
that do not meet their
objectives); F3: amplitude
(amount by which failed
tests do not meet their
objectives)

(Continued)

21
22
I. WATER QUALITY INDICES BASED PREDOMINANTLY ON PHYSICO-CHEMICAL CHARACTERISTICS

TABLE 2.2 Formulations of Some Oft e used Water Quality Indices (cont’d)
Index Parameter Subindex, SIi Wi Aggregation formulation Range of WQI

S-T WQI Not fixed Monotonically  X


N 
ðN1Þ 1=log2 N1 0-0.25 ¼ poor
log
decreasing 1Nþ SIi 2
i¼1
(Swamee and Subindices, 0.26-0.50 ¼ fair

2. APPROACHES TO WQI FORMULATION


Tyagi 2007)
 m
P
SI ¼ 1þ 0.51-0.70 ¼ medium/
PC
average
Nonuniformly decreasing 0.71-0.90 ¼ good
subindices,
 4
P

PT
SI ¼  4  8 0.91-1.0 ¼ excellent
P P
1þ3 þ3
PT PT

Unimodal subindices,
 r
P
qr þ ðn þ qÞð1  rÞ þ
PC
SI ¼  nþq
P
q þ nð1  rÞ
PC

Adopted with Permission from Islam et al., 2011.


REFERENCES 23
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I. WATER QUALITY INDICES BASED PREDOMINANTLY ON PHYSICO-CHEMICAL CHARACTERISTICS

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