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Section 2.

10
SUPERHEATERS AND REHEATERS

Saturated steam can be corrosive and erosive, especially to turbines. Superheaters and
reheaters are used to create dry steam, which is less corrosive and erosive. Some equipment
and process operations require steam below a specified temperature. For these applications,
steam attemperation or temperature adjustment is needed. This section will discuss these
topics, explaining the differences and applications.

PRINCIPLES AND PURPOSE


Heat applied to water in a closed vessel converts In general, there are two types of superheaters:
the water to steam. As long as any liquid integral units and separately fired units. Integral
remains, the temperature of the water and steam units are situated within the boiler and are by far
remain roughly at the saturation temperature. the most common.
When all the water is evaporated, or when the
steam is removed from the presence of the Integral superheaters are installed directly in the
water, adding more heat will raise the tempera- path of the hot gases, but generally shielded
ture of the steam. from the radiant section in the furnace itself.
The exact superheater-reheater locations depend
Steam at a temperature greater than the satura- on the particular boiler design. Integral super-
tion temperature is referred to as superheated heaters may be called radiant or convection
steam. The difference in temperature between superheaters, depending on whether they are
the superheat temperature and the saturation installed in the radiant or convection section of
temperature is referred to as degrees of super- the boiler. (See Figure 2.10.1.)
heat. Superheated steam has no entrained
moisture, so it is less corrosive and erosive than
wet steam. For superheated turbine operations, REHEATER DESIGN
these dry conditions are imperative. Saturated Reheaters and superheaters are similar in design.
steam turbines are designed for some moisture Reheaters are used to reheat steam that has been
in the steam. (See Section 2.11 Turbines.) extracted from the turbine. For example, by
utilizing a reheater, primary steam may be
Superheaters and reheaters function similarly in supplied to a high-pressure turbine at 2400 psig
that they both serve to elevate the steam tem- (16.5 MPag) and 1000°F (538°C). The steam is
perature above its saturation temperature. In the exhausted at 600 psig (4.1 MPag) and 600°F
superheater, the steam is obtained directly from (316°C), reheated to 1000°F (538°C), and then
the main steam drum or header; in the reheater, passed through a second low-pressure turbine.
the steam heated is the steam returned after it Reheaters significantly increase the efficiency of
passes through a high-pressure turbine or turbine the boiler condensing steam turbine cycle,
stages. reducing the operating costs for fuel and han-
dling, and making their use quite advantageous
In addition to reducing moisture erosion prob- in most electric utility plants.
lems in turbines, superheated steam has the
important advantage of being able to do more
work before it condenses. Reheated superheated
steam improves the cycle efficiency of a power
plant by 4-5% for each 200°F (111°C) increase
in superheat temperature.

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Section 2.10
SUPERHEATERS AND REHEATERS

Figure 2.10.1 – Integral superheaters in a subcritical drum-type utility boiler

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SUPERHEATER OPERATIONAL Periodic steam purity studies and fireside


PROBLEMS inspections will help keep such problems at a
Problems in the superheater section can result in minimum.
blown tubes and plant downtime. Some of the
most common problems experienced in super-
heater tubes are discussed here. PROTECTION DURING START-UP
During normal operation, every superheater tube
Deposition – On the steam side, deposition must have steam flow sufficient to prevent
results from improper steam/water separation or overheating. During start-up, there is insufficient
carryover. Deposits will lay down in the inlet steam flow through every tube. The flue gas
sections and low sections of the superheater, temperature, entering the superheater section,
causing the tubes to overheat and eventually fail. must be held to the following limits to control
Deposition on the fireside of the tubes can result superheater metal temperature:
in low superheat temperature and high fireside
pressure drop. • 900°F (482°C) for carbon steel tubes
• 950-1000°F (510-538°C) for alloy tubes
Tube overheating – Steam has a much lower
specific heat than that of liquid water. Super- During start-up, the superheater drains and
heater tubes overheat when more heat is applied vents, if present, must be open to provide steam
than can be carried off by the steam. Too high a flow for cooling the tubes until the boiler
heat input may result from broken or improper reaches line pressure. If superheater drains are
baffling or overfiring. Tube blockage (e.g., water not present, the initial firing rate must be very
in the tube at startup) or oxide scale buildup low so all of the water is removed through
may prevent heat from dissipating rapidly evaporation. Although firing rate is the primary
enough. This overheating often takes the form of means of controlling flue gas temperature,
mild, prolonged overheating, which eventually other means such as excess air and flue gas
weakens the superheater tubes and causes recirculation can help prevent overheating of
them to fail. Boiler water carryover into the the superheater tubes.
superheater tubes will leave deposits in the
superheaters, resulting in the potential of over- The two requirements for steam flow through
heating the tubes. every superheater tube are:
1. All water must be removed from each tube
Corrosion – Corrosion to both the steam side 2. Total steam flow must be equal to or greater
and fireside is always a potential problem. than 10% of rated steam flow
Steam side corrosion can result from oxygen
attack on the metal, if not protected during Header drains are used to remove water from
downtime, or from caustic concentration from drainable superheaters. On nondrainable units,
boiler water carryover evaporating to dryness. the water must be boiled away. Care must be
Fireside corrosion normally results from the taken to minimize excess heat input to the tubes.
deposition of sulfur-bearing ash and soot on the Thermocouples attached to the outlet of the
tube surfaces. superheater tubes indicate saturation temperature
when water remains in the tube. A substantial
It is important to realize the potential problems increase in temperature above saturation will be
that can occur in the superheater section and to noticed after removing all moisture from the
take precautionary steps to minimize them. superheater and establishing proper flow.

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Superheaters normally collect some condensate STEAM TEMPERATURE


when firing is stopped. This condensate must be ADJUSTMENT AND CONTROL
drained or boiled out before start-up of the unit.
Following are the basic reasons for adjusting and
controlling steam temperature:
CLEANING • To prevent overheating and failure of the
Internal cleaning of drainable superheaters is superheater and reheater tubes
normally accomplished using condensate or • To prevent overheating and failure of the
demineralized water to remove any deposits. turbine components
(Non-drainable superheaters generally cannot be
flushed without the installation of a large • To prevent thermal expansion, thereby
temporary pump capable of supplying enough reducing turbine clearances to the danger point
flow to get even distribution through all the • To minimize blade erosion caused from
parallel paths.) Most deposits found in super- excessive steam condensation in the later
heaters are water soluble. The conductivity of stages of the turbine blades
the wash water gives a good indication of
cleaning progress. After washing, the super- Steam temperature adjustment typically includes
heater should be drained or boiled out, as only off-stream methods used to affect steam
previously outlined. temperature. On-stream methods are called
steam temperature controls.
Cleaning requirements of the external (fireside)
of the superheater vary considerably, based upon The control of fluctuations in temperature
the fuel burned and deposit composition. The caused by uncertainties of operation (such as
reason for deposition should be thoroughly slag or ash accumulation) has some effect on
analyzed, and corrective actions taken to mini- steam temperature. However, superheat and
mize future occurrences. reheat steam temperatures are mainly
affected by variations in steam output.
Never make cleaning recommendations on (See Figure 2.10.2.)
boiler system components without consulting
Nalco technical support. Severe liabilities exist In drum-type industrial boilers, steam output and
in these systems for poor performance and pressure are normally kept constant by firing
equipment damage. rate, while resulting superheat and reheat steam
temperatures depend upon such variables as the
ratio of convection to radiant heat absorbing
METALLURGY surface, excess air, feedwater temperature, and
Table 2.10.1 lists the materials of construction changes in the type of fuel burned. Standard
commonly used in the U.S. for superheaters performance from a properly operated and
today. The table also establishes the maximum controlled system is a deviation of not more than
allowable stresses and temperatures these tubes 10°F (5.6°C) in the outlet superheated steam
can tolerate. temperature.

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SUPERHEATERS AND REHEATERS

Table 2.10.1 – Maximum allowable design stresses for superheater and reheater tubes

ASME Max. Stress for Metal Temperature not Exceeding °F, psig
Spec.
Material Number Grade 900 950 1000 1050 1100 1150 1200 1300
Carbon Steel SA210 A1 5000 3000 - - - - - -
Carbon Moly SA209 T1a 12500 8500 - - - - - -
Croloy 1⁄2 SA213 T2 12500 10000 6250 - - - - -
14
Croloy 1 ⁄ SA213 T11 13100 11000 6550 4050 - - - -
14
Croloy 2 ⁄ SA213 T22 13100 11000 7800 5800 4200 - - -
Croloy 5 SA213 T5 - - 5600 4150 3050 2000 - -
Croloy 9M SA213 T9 - - 8500 5500 3300 2200 - -
Croloy 18-8 SA213 TP304H* - - 13700 12150 9750 7700 6050 3700
Croloy 18-8 SA213 TP304H - - 9750 9500 8850 7700 6050 3700
Croloy 18-8 SA213 TP321H* - - 14000 11700 9050 6900 5350 3150
Croloy 18-8 SA213 TP321H - - 10450 10100 8800 6900 5350 3150

ASME Max. Stress for Metal Temperature not Exceeding °C, Mpag
Spec.
Material Number Grade 482 510 538 566 593 621 649 704
Carbon Steel SA210 A1 34 21 - - - - - -
Carbon Moly SA209 T1a 86 59 - - - - - -
12
Croloy ⁄ SA213 T2 86 69 43 - - - - -
14
Croloy 1 ⁄ SA213 T11 90 76 45 28 - - - -
Croloy 2 1⁄4 SA213 T22 90 76 54 40 29 - - -
Croloy 5 SA213 T5 - - 39 29 21 14 - -
Croloy 9M SA213 T9 - - 59 38 23 15 - -
Croloy 18-8 SA213 TP304H* - - 94 84 67 53 42 26
Croloy 18-8 SA213 TP304H - - 67 66 61 53 42 26
Croloy 18-8 SA213 TP321H* - - 97 81 62 48 37 22
Croloy 18-8 SA213 TP321H - - 72 70 61 48 37 22

*Due to relatively low yield strength of these materials, these higher stress values were established at temperatures
where the short time tensile properites govern to permit the use of these alloys where slightly greater deformation is
acceptable. The stress values in this range exceed 62 1/2% but do not exceed 90% of the yield strength at temperature.
Use of these stesses may result in dimentional changes due to permanent strain. These stress values are not
recommended for the flanges of gasketed joints of other applications where slight amounts of distortion can
cause leakage or malfunction.

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Excess air – For a change in the amount of


excess air entering at the burners, there is a
corresponding change in the quantity of gas
flowing over a convection superheater; there-
fore, an increase in excess air tends to raise the
steam temperature.

Feedwater temperature – An increase in


feedwater temperature reduces superheat be-
cause, for a given steam flow, less fuel is fired
and less gas passes over the superheater.

Heating surface cleanliness – Removing ash or


slag deposits from heat-absorbing surfaces ahead
of the superheater reduces gas temperature and
steam temperature. Removing deposits from the
superheater surface increases superheater
absorption and raises steam temperature.
Figure 2.10.2 – Substantially uniform final
steam temperature over a range of output can
Use of saturated steam – If saturated steam
be attained by a series arrangement of radiant
and convection superheaters
from the boiler is used for soot blowers or for
auxiliaries, such as pumps and fans, an increased
firing rate is required to maintain constant main
VARIABLES AFFECTING FINAL STEAM steam output. This raises the steam temperature.
TEMPERATURE
Many operating variables can affect the tem- Burner operation – The distribution of heat
perature of the steam that a boiler produces; to input among burners at different positions or a
maintain constant steam temperature, means change in the adjustment of a burner usually has
must be provided to compensate for the vari- an effect on steam temperature through changes
ables that affect final steam temperature. in the furnace heat-absorption rate.

Load – As the load increases, the quantity and Fuel – Variations in steam temperature may
temperature of combustion gases increase. In a result from changing the type of fuel burned or
convection superheater, steam temperature from changes in the characteristics of a given
increases with load because the quantity and fuel from time to time. For example, changing
temperature of combustion gases increase. In a from blast furnace gas, which releases heat
radiant superheater, steam temperature decreases higher in the boiler, to oil, which releases heat in
as load increases. Sometimes, a convection and a the lower portion of the boiler, will have an
radiant superheater are installed in series in a impact of increasing steam temperature.
single steam-generating unit to maintain sub-
stantially constant steam temperature over a
considerable range of load. (See Figure 2.10.2.)

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ADJUSTMENT OF STEAM furnace surface. While a refractory coating on


TEMPERATURE water-cooled furnace surfaces can have a
Adjustment of steam temperature means a favorable effect on combustion and carbon
change in the arrangement of equipment, which loss, it should not be added in areas where
affects the final steam temperature, but cannot undesirable ash would deposit.
be used to vary the temperature during actual • One of the simplest, least expensive, and most
operation. An example of temperature adjust- effective means of adjustment is to change the
ment is the installation or removal of superheater gas mass velocity over the steam-heating
tubes. elements by baffle changes, if the design of
the unit will permit such changes. Several of
Importance of Adjustment the standardized boilers, especially in the
Power-generating units today represent a large smaller sizes, have an adjustable baffle
capital investment, and means should be pro- suitable for steam-temperature regulation.
vided to regulate steam temperature to meet any This design makes it possible to vary the
changes affecting the system. For instance, a steam temperature range as much as 20%.
change in the type of fuel a unit burns will affect The limit of variation is the effect on draft
the resultant steam temperature considerably. loss and efficiency.
Adjustments in equipment design will be
necessary unless the plant controls (e.g.,
attemperation) can compensate for such CONTROL OF STEAM TEMPERATURE
changes. Control of steam temperature may consist of one
of the following:
Means of Adjustment
• Regulating steam pressure during actual
The following methods can be used to adjust
operation (generally not practical)
steam temperature:
• Direct spray attemperation
• The basic method of steam temperature
adjustment is to add or remove superheater or • Attemperation using a heat exchanger, e.g.,
reheater tubes a heat exchanger in the bottom drum
• Another method is to reduce or increase the • By-passing hot gases past the superheater
amount of saturated surface ahead of the
steam-heating elements. Such alterations Importance of Steam Control
modify the gas temperature at the inlet to these Controls must be used to regulate steam tem-
elements. Removing saturated surface to perature within required limits. The primary
increase steam temperature is relatively simple reason for regulating steam temperature is that
and, in general, costs less than adding steam- ash deposits can form on the tube surface of both
heating elements. However, adding saturated the steam generating section and the superheater
surface in order to decrease steam temperature sections. This condition can usually be corrected
can be difficult and expensive, or, in some by simple changes in the operating schedules of
cases, impractical. soot and slag blowers along with fuel treatment.
• The gas temperature at the superheater inlet To hold the optimum heat rate of a turbine
can also be adjusted by changing the designed to use full first-stage pressure over a
effectiveness of the heat-absorbing surface in given load range, the steam temperature must be
the furnace. This is accomplished by adding or regulated over this range by an effective means
removing refractory covering on parts of the of control.

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The time in which a turbine may be brought to Excess air – Boiler operators have long known
full load is established by the turbine manufac- that the steam outlet temperature of a convection
turer in accordance with a safe steam tempera- superheater on a drum- or separator-type unit
ture-time curve. Because the temperature of the can be increased at fractional loads by decreas-
steam is directly related to the degree of expan- ing the furnace heat absorption through an
sion of the turbine elements, and consequently increase in the amount of excess combustion air.
the maintenance of safe clearances, it must be Additional volumes of excess air result in higher
regulated within permissible limits by some gas velocities and less contact time in the
means of accurate control. furnace. The resulting greater gas weight to the
stack increases the stack loss, but the drop in
The removal of feedwater heaters for servicing boiler efficiency is made up to some extent with
is an example of variable operation. Maintain- an increase in turbine efficiency. Such an
ing the same load with feedwater heaters out arrangement is illustrated in Figure 2.10.4.
requires an increase in the heat input to the
boiler unit, with a corresponding increase in Gas recirculation – One of the most attractive
superheater or reheater absorption. Unless some methods of controlling superheat or reheat, both
means of control is available for regulating from economic and operational viewpoints, is
steam temperature to cover this condition, a drop gas recirculation. As the name implies, this
in load might be required to protect both the involves a method by which gas from the boiler,
superheater tubes and the turbine. economizer, or air heater outlet is reintroduced
to the furnace by means of a suitable fan and
Methods of Controlling Steam ducts. In the following discussion, recirculated
Temperature gas introduced in the immediate vicinity of the
There are numerous methods for controlling initial burning zone of the furnace and used for
steam temperature. The choice depends on the steam temperature control will be referred to as
particular boiler system design and operation. “gas recirculation”; recirculated gas introduced
Following are the most commonly used methods near the furnace outlet and used for control of
of controlling steam temperature: gas temperature will be referred to as “gas
tempering”. Figure 2.10.5 shows an application
Separately fired superheater – A superheater of gas recirculation on a hopper-bottom radiant
completely separate from the steam generating boiler. In most instances, the gas is obtained
unit and independently fired may serve one or from the economizer outlet. The effect desired
several saturated steam boilers. This arrange- dictates the point of reintroduction. The recircu-
ment is not generally economical for power lated gas should be introduced into the furnace
generation, where a large quantity of high- so that interference with the combustion of the
temperature steam is needed. Its use is largely fuel is avoided. The amount of recirculated gas
confined to process industries, such as chemical is generally expressed as a percentage of the gas
manufacture and petroleum refining, to meet that remains after the point of take-off of the
special requirements. Because heat absorption recirculated gas.
can be varied independent of the quantity of
steam delivered, the separately fired superheater Recirculated gas may be used for several
has great flexibility in operation and a wide purposes; however, its basic function is to
range of steam temperature regulation at all provide a means of altering the heat-absorption
loads. Either oil or natural gas is customarily pattern within a steam generating unit. An
used as fuel. (See Figure 2.10.3.) important feature of recirculated gas is that its
use changes only the pattern of heat absorption

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SUPERHEATERS AND REHEATERS

Figure 2.10.3 – Typical arrangements for separately fired superheaters

through a boiler. Its effect on the total boiler heat is transferred mainly be radiation. Hence, the
absorption, the gas weight up the stack, and the introduction of gas recirculation into the furnace
boiler efficiency is negligible. hopper reduces furnace absorption by altering
the gas-temperature pattern.
Figure 2.10.6 shows the variation in heat absorp-
tion with gas recirculation introduced into the The major portion of the heat absorbed in the
hopper. Introduction of gas at this location superheater, reheater, and economizer is trans-
produces a marked reduction in furnace absorp- ferred by convection, which depends on gas
tion and increases the absorption of the convec- temperature and gas mass velocity. Both are
tion section. The total heat absorption remains affected by gas recirculation. Therefore, when
unchanged. the gas mass velocity through a convection bank
is increased by gas recirculation, the amount of
Furnace heat absorption is primarily a function heat transferred may increase, decrease, or
of the gas temperature and gas-temperature remain unchanged, depending on the changes in
patterns throughout the furnace, because the heat the relationship between gas temperature and

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Figure 2.10.4 – Steam temperature control by use of increased excess air

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Figure 2.10.5 – One arrangement for gas recirculation

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SUPERHEATERS AND REHEATERS

control can be improved by distributing the


burners over a considerable height of the burner
wall or by installing a special burner near the
furnace outlet.

Movable burners – Regulation of steam tem-


perature by changing the furnace absorption
pattern can also be effected by the use of mov-
able burners operated to shift the main combus-
tion zone in the furnace. Burners that can be
tilted are used for this purpose.

Gas by-pass – If the convection banks of a


steam-generating unit are separated by gas-tight
baffles into two or more parallel gas passes
isolating portions of the superheater and reheater
surfaces, the proportion of gas flow over all or
part of the superheater and reheater may be
varied by regulating dampers. This method has
the advantage of low initial cost. Disadvantages
include the following:
Figure 2.10.6 – Effect of gas recirculation on • It is difficult to keep the dampers operable
heat absorption pattern at constant firing rate unless they are placed in a cool gas zone
• Draft loss through the unit is increased for
gas weight entering the bank. Figure 2.10.6 some designs, particularly if control is desired
illustrates a condition in which the gas tempera- with alternate fuels
ture entering the secondary superheater (furnace • Control is more sluggish than with
exit temperature) is relatively unchanged by gas attemperators
recirculation. Therefore, increasing the amount
of gas recirculation increases the heat absorption • High gas temperature exists at the bypass
in the secondary superheater. The heat absorp- dampers unless there is a heat-absorbing
tion in the reheater, primary superheater, and surface in the pass
economizer is also increased, with the greatest
increase occurring at the cold end of the unit. Attemperation – All of the methods discussed
This is a typical example of variation in the above are based on varying the amount of heat
convection pass heat absorption pattern gas absorbed by the steam-heating elements. In the
recirculation. two most common types of attemperators, steam
temperature is regulated by removing heat from
Burner selection – Steam temperature can often the steam or by diluting higher temperature
be regulated by selective burner operation. High steam with lower temperature water.
steam temperature may be obtained at less than
full load by operating only the burners giving The attemperator may be located in one of three
the highest furnace outlet temperature. When places:
lower steam temperature is required, firing may 1. Between the saturated steam outlet and the
be shifted to the other burners. This method of superheater

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2. At some intermediate point between two


sections of the superheater
3. At the superheater outlet

An attemperator located before the superheater


will condense some of the saturated steam
passing through it and will deliver wet steam
of reduced enthalpy to the superheater.

There are important advantages to locating an


attemperator between two stages of a super-
heater. With this arrangement, the average steam
temperature never exceeds the final steam
temperature desired. Additionally, the steam
from the various circuits of the first-stage
superheater is so thoroughly mixed that it enters Figure 2.10.7 – Drum-type surface attemperator
the second-stage superheater at a uniform
temperature. This is, therefore, the most pre- In the shell-type surface attemperator, the
ferred location. Its only disadvantage is the superheated steam flows through a bundle of
amount of piping required from the first-stage tubes fitted in a cylindrical shell through which
superheater to the attemperator and from the cooling water circulates. A valve in the base of
attemperator to the second-stage superheater. the shell diverts the proper proportion of the
superheated steam (through the tubes) to give
Attemperators may be classified into two types: the final steam temperature desired. The shell is
surface and direct contact. In the surface type, connected to the boiler circulating system,
steam is isolated from the cooling medium by assuring a positive flow of water in the shell at
the heat exchanger surface. In the direct-contact all times. Thermal-sleeve ferrules at the steam
type, the steam and the cooling medium (water) inlet ends connect the tubes to an inlet box,
are mixed. The surface attemperator includes which protects the tubesheets from severe
both shell and drum types. The direct-contact thermal stresses. Disadvantages of this type of
attemperator is exemplified by the spray type. attemperator are the relative inaccessibility of
the tubes and tubesheet for inspection.
When a drum-type attemperator (Figures 2.10.7
and 2.10.8), located in the mud drum, is used The direct-contact type spray attemperator
interstage, a part of the steam from the primary (Figure 2.10.9) has proved most satisfactory for
superheater is diverted to it by an automatic regulating steam temperature. High-purity water
valve. The diverted steam is reduced in tempera- is introduced into the superheated steam line
ture by giving up heat to the boiler water. It is through a spray nozzle at the throat of a venturi
then mixed with the rest of the steam from the section within the line. Because of the spray
primary superheater and passes on to the second- action at the nozzle and the high velocity of the
ary superheater. The final temperature of the steam through the venturi throat, the water
steam is regulated by the position of the auto- vaporizes, mixes with, and cools the superheated
matically operated valve that controls the steam. An important feature of construction is
amount of steam diverted through the the continuation of the venturi section into a
attemperator. thermal sleeve, downstream from the spray

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Figure 2.10.8 – Automatic control for drum-type attemperator

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nozzle, to protect the high-temperature piping


from thermal shock that could result from any
incompletely evaporated water droplets striking
the hot surface of the piping.

The spray attemperator provides a quick acting,


sensitive means of regulating steam temperature.
The spray water must be of highest purity, since
solids entrained in the spray water enter the
steam and may, if excessive, cause troublesome
deposits on superheater tubes, piping, or turbine
blades. High-pressure heater drains are a source
of extremely pure water, but they require a
separate high-pressure corrosion-resistant pump
if used to supply the attemperator. Boiler
feedwater may be satisfactory, provided that
only volatile treatment chemicals are present
and that only polished deionized makeup water
is used.

A sweet water condenser can be used to provide


a source of high-purity water for attemperation.
A sweet water condenser is a stainless steel, or
other corrosion resistant alloy tube and shell
condenser that uses boiler feedwater as a coolant Figure 2.10.9 – Spray attemperator showing
source and saturated steam as the source of the thermal sleeve
condensate. High-purity polished condensate or
condensate from a sweet water condenser are the
preferred sources of attemperator water.

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