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a r t i c l e i n f o a b s t r a c t
Article history: This paper introduces a novel fibre structure known as the helical auxetic yarn (HAY). The
Received 4 May 2010 geometry of the yarn is defined and the manufacturing process described. A range of HAYs
Received in revised form 5 January 2011 have been manufactured that vary the geometric properties of the structure. A systematic
Available online 1 June 2011
study of the yarns has been completed to evaluate the effect on the auxetic behaviour of
the geometry. We also characterise the component fibres and yarns and discuss the influ-
Keywords: ence of geometric and material effects on the observed Poisson’s ratio of the yarns.
Poisson’s ratio
It can be shown that the starting wrap angle of the yarn has the greatest effect on auxetic
Auxetic
Yarn
behaviour both in terms of magnitude and the strain range over which it may be observed.
Fibres The maximum negative Poisson’s ratio observed for a yarn manufactured from conven-
Mechanical properties tionally available monofilaments with positive Poisson’s ratio is 2.7.
Ó 2011 Elsevier Ltd. All rights reserved.
0167-6636/$ - see front matter Ó 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.mechmat.2011.05.003
M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486 477
Nomenclature
proposing their use for enhanced reinforcement in com- lower diameter and stiffer wrap component as shown in
posite materials. Fig. 1a.
Auxetic fibres provide a potential route to particular At zero strain the core and wrap fibres are in uniform
auxetic materials as they can be woven into technical tex- contact, with the core straight and the wrap helically
tiles opening up further commercial exploitation routes for wound with an internal helix diameter equal to the fibre
sporting, medical or defence applications. diameter of the core. Upon application of an axial tensile
Textiles characterised and modelled analytically by strain, the wrap fibre straightens and in doing so displaces
Shanahan and Piccirelli (2008) showed auxetic behaviour the core laterally, thus increasing the effective diameter of
through the fabric thickness due to a geometric effect as the system. At full strain the geometry of the core and
a result of the woven structure. Ugbolue et al. (2007) knit- wrap are reversed with respect to the starting configura-
ted textiles from nomex and polyester fibres and, by care- tion. Fig. 1b shows the HAY at maximum strain.
fully tailoring the textile structure, a Poisson’s ratio of 0.6 On removal of the tensile strain, if the wrap and core are
was measured across the fabric width. Hall et al. (2008) elastic, both recover to the initial starting configuration –
produced carbon nanotube sheets (buckypaper) using a provided that the elastic limit of the materials has not been
combination of single and multi walled carbon nano-tubes exceeded. The auxetic effect can be controlled by selecting
and measured an in-plane Poisson’s ratio as low as 0.2 fibre diameters, moduli, the initial geometry and also the
subject to the ratio of single and multi walled tubes. In applied strain.
all cases the auxetic behaviour was attributed to geometric The benefit of having an auxetic yarn, compared to an
effects. intrinsic auxetic fibre lies both in the relative simplicity
Auxetic yarns invented by Hook et al. (2006) combined of the manufacturing process, a simple spinning together
two conventional fibres in a helical arrangement which, of two conventional fibres and the relative ease of tailoring
when subjected to a tensile strain, exhibited a net increase properties.
in the width of the yarn. Miller et al. (2009) provided pre- Fig. 2a defines the geometric parameters associated
liminary test data for one helical auxetic yarn (HAY) sys- with a HAY having components of circular cross section.
tem, combined helical auxetic yarns in a simple weave The initial diameters of the core and wrap fibres can be de-
pattern to produce an auxetic textile and used the textile fined as Dc and Dw, respectively. The effective diameter of
to manufacture and test a low modulus composite. the yarn is defined by Dy. The cyclic frequency of the wrap
Helical auxetic yarns form the basis of this paper. We de- fibre can be defined using either the angle h which sub-
fine the geometric parameters of these yarns, describe the tends the core and wrap or by considering the cyclic pitch
manufacture and mechanical characterisation process in of the wrap fibre k. It is more intuitive to measure and
detail and also identify the mechanism behind the observed quote the angle h. However due to practicalities of mea-
auxetic behaviour. In this paper we undertake a systematic surement of the yarns as a function of strain we use the
study of monofilament HAYs to determine the parameters of pitch length to calculate the wrap angle. It is also conve-
greatest influence to the desired auxetic behaviour. nient for the manufacturing process to correlate the wrap
angle h to the linear measurement k.
The cyclic pitch and fibre diameters of a HAY can be de-
2. Geometry scribed using simple trigonometry. If we take exactly one
cycle of a HAY and roll it out on a flat surface, imagining
A helical auxetic yarn is constructed by combining two the wrap fibre sticking to the surface as it unravels from
fibrous components in a double helix as described by Hook the core. This forms a simple right angle triangle as shown
et al. (2006). It has been proposed that the components in Fig. 2b.
must possess differing moduli and diameter for the HAY where;
to function optimally. The experimental work in this paper Lw = Length traced by the centre of the wrap fibre (m)
investigates these effects on the auxetic behaviour of the Dc = Diameter of core fibre (m)
yarns. First the yarn geometry is introduced. A low modu- Dw = Diameter of wrap fibre (m)
lus, initially straight core fibre is uniformly wrapped with a k = Cyclic pitch of wrap fibre (m)
478 M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486
pD2c
Ac ¼ ð2Þ
4
pD2w
Aw ¼ ð3Þ
cos h
Fig. 3a. HAY at zero strain.
The cross sectional area of the yarn (Ay) is the sum of equa-
tions (2) and (3);
h = Wrap angle (deg)
Dy = Effective diameter of yarn (m) Ay ¼ Ac þ Aw ð4Þ
Eq. (1) allows the cyclic pitch of a yarn to be calculated for 3. Methods
any given fibre diameter pair as a function of the desired
wrap angle. The pitch is used in the manufacturing process Monofilament core and wrap fibres were sourced from
to accurately produce the required yarn geometry. Monofil Technik (www.monofil-technik.de.2007). A poly-
The engineering stress in the yarn as a function of the urethane elastomer trade name TROFIL, nominal 600 lm
applied longitudinal strain is calculated using the cross diameter was selected as the core fibre as it allows large
M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486 479
strain deformations. The wrap fibre was a co-polymer whichever first. The crosshead speed Vc was set as a func-
polyamide, trade name Platil in nominal diameters tion of the sample gauge length such that.
110 lm, 130 lm and 150 lm. Accurate diameters of core
V C ¼ 0:1LG = min ð7Þ
and wrap fibres were obtained by SEM measurements at
high magnification. 3 random samples of each monofila- This equates to the lowest testing speed specified in ASTM
ment fibre were taken from the spools as supplied by the D3822-07 as it allows greater accuracy in image acquisi-
manufacturer, coated in approximately 5 nm of gold and tion of the yarns.
imaged in a Hitachi S3200 variable pressure SEM using a A high magnification, non-contact video system con-
20 kV accelerating voltage. Two images were obtained for trolled by a secondary PC was used to accurately record
each sample. Length measurements were taken using the longitudinal and lateral sample strain. A 4.9 MP digital
internal calibrated vernier callipers to determine the diam- camera (Edmund Optics EO-5012C USB) acquired images
eter of the fibres. through a variable zoom lens mounted at a fixed working
Helical auxetic yarns were manufactured using a spin- distance of approximately 160 mm from the sample. This
ner mechanism designed and built specifically for produc- allowed simple control over the field of view at a fixed res-
ing lab-scale lengths of yarns – approximately 10 m. The olution of 2560 1920 pixels. The field of view was se-
wrap fibre was used to control the two yarn geometric lected at the start of testing and remained fixed
parameters of interest in this study, the wrap fibre angle throughout the test. The smallest field of view achievable
and the wrap/core fibre diameter ratio. Yarns of varying from the hardware was approximately 8 mm2, giving the
wrap angle were manufactured using the 150 lm wrap fi- greatest resolution of images and hence accuracy in mea-
bre. A detailed description can be found in Appendix 1. surement. Camera lens focus and apertures were set using
Fibre and yarn samples were prepared for mechanical this condition. A fixed field of view was used throughout
testing according to ASTM D3822-07 – tensile properties the tensile test, and so was increased accordingly to
of single textile fibres (ASTM, 2007). Minor variations be- accommodate the accumulated strain within the fibres –
tween monofilament and HAY samples are discussed both optical and sample gauge lengths. Fig. 4 shows a sche-
below. matic of the test apparatus. A software macro was added to
Monofilament fibre samples of 70 mm length were ta- the Nexygen test procedure, instructing a TTL signal to be
ken from bulk spools of fibre and prepared for mechanical sent on the start of the test and at pre-defined regular
testing according to ASTM (2007). Sample ends were se- strain intervals to acquire images throughout the test.
cured in 10 mm card tabs using Araldite 2012 to minimise External lighting was employed using an electric lamp
clamp slip. A clamping gauge length LG of 50 mm was used and ‘‘daylight’’ bulb. White panels were used around the
and an additional gauge length for optical strain measure- test set up to reflect and diffuse the light source and so
ments LO marked onto the middle of the fibre such that; minimise light reflection effects such as halos around the
fibres.
LO ¼ 0:1LG 5% ð5Þ
Camera hardware was mounted to display the test sam-
Due to the additional geometric complexity of HAYs, the ple image in a horizontal configuration as shown in Fig. 5
sample gauge length was modified to retain accuracy and thus exploiting the maximum pixel resolution along the fi-
consistency throughout the testing. bre length.
A sample gauge length L was chosen according to the Strains were applied in the positive x direction. This ap-
conditions. plied to both monofilament and yarn samples.
Yarns were visually inspected before testing to confirm
50 mm 6 LG and 10k 6 LG ð6Þ accurate manufacture by inspecting the consistency of
wrap angle and conformance of the wrap with the core length measurements were determined and used to calcu-
along the entire sample gauge length. Fig. 6 shows a sam- late the absolute errors in strain measurements and subse-
ple rejected before testing due to poor conformance of quent Poisson’s ratio values.
wrap with the core. Gauge length markers can also be seen
on the sample. 4. Results
Longitudinal and lateral strain measurements were cal-
culated using the images captured during the tensile test at 4.1. Fibre characterisation
intervals of 0.01 strain. A contrasting sample background
was used to enhance the sample edge definition and min- Typical SEM images of the polyurethane elastomer core
imise image compression noise artefacts associated with are shown below in Figs. 7a and b. Width measurements
colour change rather than brightness. Raw bitmap images were taken and a median value calculated for each mono-
were converted into JPEG files in Paintshop pro filament giving their respective diameters. These diame-
(www.jasc.com) maintaining a 2560 1920 pixel resolu- ters were used to calculate the desired pitch length for
tion and using the lowest compression factor. Sample manufacture of the yarns and the cross sectional areas of
dimensions for monofilaments and yarns were calculated the monofilaments.
using the linear measuring tool in the ImageJ software
(Abramoff et al., 2004). All sample and calibration images
4.2. Mechanical testing
were processed manually using this method. The length
scale was calibrated using the zero strain image for each fi-
Fig. 8 shows the engineering stress/strain curve for the
bre and the dimensions taken from the SEM images. For
monofilament component fibres and their respective heli-
monofilaments, longitudinal strain was calculated using
cal auxetic yarn with a starting angle of 13°. The polyamide
the separation of the optical markers and lateral strain
wrap is shown to have a greater modulus and ultimate ten-
using the fibre width.
sile strength than the elastomeric core fibre. The polyure-
Image analysis for HAYs was performed in the same
thane core is able to withstand longitudinal strain 4
manner, however due to the significant change in geome-
times greater than the wrap fibre before failure but dem-
try compared to monofilaments, strain measurement defi-
onstrates a much lower tensile stress at failure. Combining
nitions were required. Longitudinal strain was determined
the two fibres in a helical arrangement produces a stress
by measuring the linear separation of the optical gauge
strain curve with a higher ultimate tensile stress and
markers. Transverse strain was calculated using the great-
elongation at break compared to the component core and
est lateral width of the yarn with respect to the axis of the
wrap fibres, respectively.
applied tensile load. At low strains this equated to the
Table 1 summarises the mechanical properties of the
width measured between peak heights of the wrap fibres.
fibres as shown in Fig. 8. The Young’s modulus was calcu-
At higher strains when the core has been activated, taking
lated using the initial linear elastic region of the engineer-
on a sinusoidal wave form, the greatest width is defined by
ing stress strain curve. The engineering stress was
the core.
calculated using circular cross sectional areas for the
Poisson’s ratio for monofilament fibres and yarns was
monofilaments and using Eq. (4) for the yarns.
calculated using engineering strains ey and ey according
to Eq. (4)
Table 1
ey Summary of mechanical properties of core, wrap and yarn.
mxy ¼ ð8Þ
ex PU core PA wrap HAY 13°
Measurement errors were taken as ±2 pixels in both longi- Young’s modulus (MPa) 30 3400 76
Ultimate tensile strength (MPa) 51 789 56
tudinal and lateral directions. Using the calibrated length
Strain at break (%) 95 17 34
scale for individual images, maximum and minimum
M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486 481
1000
900
800
700
600
σ / MPa
500
400
300
200
100
0
0 20 40 60 80 100
ε/%
1000
images of monofilament fibres obtained during tensile
800 testing showed a high anisotropy in the polyamide wrap fi-
600 bres as the calculated values extend beyond the range dic-
400
tated by classical theory for isotropic materials of between
0 and 0.5. The polyurethane core fibres proved to be less
200
anisotropic and demonstrated failure at much higher
0 strains and as such lend themselves well as core fibres in
0 0.2 0.4 0.6 0.8 1
ε long HAYs.
A low and predictable Poisson’s ratio is desirable for the
pa wrap pu core HAY 13°
core as any thinning of this fibre negates the auxetic effect
Fig. 9. Width vs elong core, wrap and yarn. Width Errors Yarn ±31 lm, achieved by the helical structure.
Core ±25 lm, Wrap ±10 lm. The majority of HAYs tested demonstrated a sharp in-
crease in m at low strains before peaking and reducing in
tio can then be observed to decrease in a steady manner for magnitude. We can attribute this behaviour to the internal
all fibres before tensile failure of the wrap. The only sample helix diameter of the wrap fibre conforming to the un-
to show true auxetic behaviour incorporated the nominal strained diameter of the core and hence a rapid decrease
150 lm diameter fibre – the largest diameter of the three in the net width of the yarn.
wraps. As the applied strain is increased the abrupt change in
All HAY’s tested in this study failed due to fracture of direction of m and equally rapid rate of decline is the result
the wrap fibre. Relative slip between core and wrap fibres of activation of the core fibre into a helical form and the
was not observed for any HAY’s during testing. onset of engineering auxetic behaviour. It is therefore pos-
sible to remove the initial variation in m by pre-tensioning
5. Discussion the yarns to a given strain. Once activated the core defines
the net width of the structure and is responsible for the
Helical auxetic yarns manufactured and tested in this auxetic behaviour of the yarn until failure of the wrap fibre
study have been shown to demonstrate Poisson’s ratios – at an applied strain dependent on the starting geometry
M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486 483
2
ν
0
0 0.2 0.4 0.6 0.8 1
-2
-4
-6
long
4
Poisson's ratio
0
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35
-2
-4
-6
Longitudinal strain
HAY 13°
of the yarn. Relative slip between core and wrap fibres was geometry dependent, i.e. a larger diameter wrap is struc-
not observed verifying a good conformance between the fi- turally stiffer than a smaller diameter of identical material,
bres. We would expect a degree of slip and frictional effects a result confirmed by numerically modelling the mechani-
were this not the case, which in turn will reduce the geo- cal behaviour of helical auxetic yarns (Wright et al., 2010).
metric effect on the auxetic behaviour of the structure. This conflicts with the desire to minimise the apparent
The transient nature of m as a function of applied strain width of the yarn at zero strain by employing a low diam-
for HAYs can be attributed to the competition between eter wrap fibre. Therefore, the greatest auxetic effect will
geometric and material effects of the yarn. Positive m val- be observed when a wrap fibre of infinitely low diameter
ues for the component fibres counteract the geometric ef- and high stiffness is used.
fect from core activation. Depending on yarn geometry, We have shown that variation in zero strain wrap angle
this competition can be seen as either a gradual or near has a greater effect on the auxetic behaviour compared to
zero change over a given strain range. the relative fibre diameters. This result is demonstrated by
For maximum auxetic effect, low strain activation of the comparing the results in Figs. 12 and 13 highlighting the
yarn is desirable so that the geometric effect of the HAY is sensitivity of auxetic behaviour to starting wrap angle.
allowed to dominate over the material dependent behav- Variation in fibre diameter ratio showed less impact on
iour of the component fibres. Early activation of the core the auxetic performance of a HAY compared to the wrap
is achieved by a low starting wrap angle and a high stiff- angle whilst highlighting the importance of wrap geomet-
ness wrap. The stiffness of the wrap is both material and ric stiffness. Modulus of the wrap material is important
484 M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486
ν 2
0
0 0.1 0.2 0.3 0.4 0.5 0.6
-2
-4
ε long
Fig. 12. Variation in wrap angle on auxetic performance of HAY. Error in Poisson’s ratio measurement as a percentage of 13° yarn. 22° (86%), 30° (89%), 38°
(75%).
ν 2
0
0 0.1 0.2 0.3 0.4 0.5 0.6
-1
ε long
90um wrap 32° 130um wrap 31° 150um wrap 30°
Fig. 13. Variation on fibre diameter ratio on auxetic performance of HAY. Error in Poisson’s ratio measurement as a percentage of 13° yarn. 90 lm wrap 32°
(65%), 130 lm wrap (70%), 150 lm wrap (75%).
however it is the stiffness of the fibre geometry that should The starting angle of the wrap fibre dominates the mag-
be considered foremost. nitude of auxetic behaviour.
Applications for auxetic textiles include shockwave pro- The auxetic performance is also affected by the diame-
tection fabrics – blast, flood, and storm – smart filters, com- ter ratio of wrap to core fibres and the inherent Pois-
posite reinforcement, body armour and geo-textiles. son’s ratio of the fibres.
6. Conclusions
Acknowledgements
Helical auxetic yarns using monofilament polymeric fi-
bres have been defined, manufactured and characterised in The authors of this work would like to acknowledge the
this work. This work represents the first detailed, experi- EPSRC for financial support and also the industrial collabo-
mental study of the auxetic properties of simple HAYs. rators – Auxetix Ltd., Monofil Trading Company Ltd, Home
For these monofilament yarns the effect on m as a function Office Scientific Development Branch, Centre for the Pro-
of applied strain and manufactured geometry has been dis- tection of National Infrastructure. We are very grateful
cussed and the key geometric parameters used to tailor for the assistance and skills of the staff at Exeter University,
auxetic behaviour identified. namely Peter Gerry, Mike Burns and Dave Baker.
10 y = 0.1388x - 0.014
Spool 2 Yarn 2
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