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Mechanics of Materials 43 (2011) 476–486

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Mechanics of Materials
journal homepage: www.elsevier.com/locate/mechmat

The helical auxetic yarn – A novel structure for composites


and textiles; geometry, manufacture and mechanical properties
M.R. Sloan ⇑, J.R. Wright, K.E. Evans
College of Engineering, Mathematics and Physical Sciences, University of Exeter, UK

a r t i c l e i n f o a b s t r a c t

Article history: This paper introduces a novel fibre structure known as the helical auxetic yarn (HAY). The
Received 4 May 2010 geometry of the yarn is defined and the manufacturing process described. A range of HAYs
Received in revised form 5 January 2011 have been manufactured that vary the geometric properties of the structure. A systematic
Available online 1 June 2011
study of the yarns has been completed to evaluate the effect on the auxetic behaviour of
the geometry. We also characterise the component fibres and yarns and discuss the influ-
Keywords: ence of geometric and material effects on the observed Poisson’s ratio of the yarns.
Poisson’s ratio
It can be shown that the starting wrap angle of the yarn has the greatest effect on auxetic
Auxetic
Yarn
behaviour both in terms of magnitude and the strain range over which it may be observed.
Fibres The maximum negative Poisson’s ratio observed for a yarn manufactured from conven-
Mechanical properties tionally available monofilaments with positive Poisson’s ratio is 2.7.
Ó 2011 Elsevier Ltd. All rights reserved.

1. Introduction 2008; Kocer et al., 2009). Synthesised auxetic materials


are highly attractive as this allows mechanical properties
Negative Poisson’s ratio or auxetic (Lakes, 1987; Evans to be carefully tailored for specific applications by control-
et al., 1991) materials have received considerable attention ling the material structure.
over the last 3 decades due to their counter intuitive The fundamental mechanism behind auxetic behaviour
behaviour of expanding laterally when subjected to a ten- and also the length scale over which it is observed varies
sile load and vice versa under compression. This behaviour between materials. Single crystal arsenic (Gunton and
can enhance fundamental bulk properties such as the shear Saunders, 1972) and zeolites (Williams et al., 2007) dem-
modulus, indentation resistance, fracture toughness and onstrate auxetic behaviour as a result of molecular bond
synclastic curvature (Evans and Alderson, 2000). Auxetic rotation. Synthetic polymer foams (Lakes, 1987; Chan
behaviour has been demonstrated in materials ranging and Evans, 1997, 1998) show an auxetic effect at strains
from naturally occurring single crystals (Williams et al., 6 orders of magnitude greater as a result of an internal
2007) and cubic metals (Baughman et al., 1998), to biolog- re-entrant rib structure – introduced during manufacture
ical materials such as skin (Lees et al., 1991; Frohlich et al., – increasing the apparent volume of the material.
1994) bone (Williams and Lewis, 1982) and synthetic Caddock and Evans (1989) demonstrated that highly
materials such as foams (Chan and Evans, 1997, 1998), anisotropic expanded PTFE samples were auxetic by
honeycomb structures (Gaspar et al., 2005) and composites changing the material microstructure through sintering,
(Theiocaris et al., 1997; Evans et al., 2004; Hilton et al., demonstrating the application to other polymeric materi-
als. The process was repeated using Ultra-high molecular
⇑ Corresponding author. Address: College of Engineering, Mathematics weight polyethylene (Alderson et al., 2000), nylon
and Physical Sciences, University of Exeter, Harrison Building, North Park (Alderson et al., 1998), and polypropylene (Pickles et al.,
Road, Exeter, Devon EX4 4QF, UK. Tel.: +44 (0) 1392 723667; fax: +44 (0) 1996). Further developments by Ravirala et al. (2005)
1392 723616. produced auxetic fibres by melt spinning PP, PE and nylon,
E-mail address: m.r.sloan@exeter.ac.uk (M.R. Sloan).

0167-6636/$ - see front matter Ó 2011 Elsevier Ltd. All rights reserved.
doi:10.1016/j.mechmat.2011.05.003
M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486 477

Nomenclature

Ac cross section area core fibre k cyclic pitch of wrap fibre


Aw cross section area wrap fibre LG clamping Gauge length of yarn
Ay cross section area yarn LO optical gauge length of yarn
Dc diameter core fibre Lw length traced by the centre of the wrap fibre
Dw diameter wrap fibre mxy Poisson’s ratio
Dy diameter (effective) of yarn h wrap fibre angle
ex lateral engineering strain Vc linear speed crosshead
ey longitudinal engineering strain vc linear feed rate of core fibre (ms1)
fw wrap frequency

proposing their use for enhanced reinforcement in com- lower diameter and stiffer wrap component as shown in
posite materials. Fig. 1a.
Auxetic fibres provide a potential route to particular At zero strain the core and wrap fibres are in uniform
auxetic materials as they can be woven into technical tex- contact, with the core straight and the wrap helically
tiles opening up further commercial exploitation routes for wound with an internal helix diameter equal to the fibre
sporting, medical or defence applications. diameter of the core. Upon application of an axial tensile
Textiles characterised and modelled analytically by strain, the wrap fibre straightens and in doing so displaces
Shanahan and Piccirelli (2008) showed auxetic behaviour the core laterally, thus increasing the effective diameter of
through the fabric thickness due to a geometric effect as the system. At full strain the geometry of the core and
a result of the woven structure. Ugbolue et al. (2007) knit- wrap are reversed with respect to the starting configura-
ted textiles from nomex and polyester fibres and, by care- tion. Fig. 1b shows the HAY at maximum strain.
fully tailoring the textile structure, a Poisson’s ratio of 0.6 On removal of the tensile strain, if the wrap and core are
was measured across the fabric width. Hall et al. (2008) elastic, both recover to the initial starting configuration –
produced carbon nanotube sheets (buckypaper) using a provided that the elastic limit of the materials has not been
combination of single and multi walled carbon nano-tubes exceeded. The auxetic effect can be controlled by selecting
and measured an in-plane Poisson’s ratio as low as 0.2 fibre diameters, moduli, the initial geometry and also the
subject to the ratio of single and multi walled tubes. In applied strain.
all cases the auxetic behaviour was attributed to geometric The benefit of having an auxetic yarn, compared to an
effects. intrinsic auxetic fibre lies both in the relative simplicity
Auxetic yarns invented by Hook et al. (2006) combined of the manufacturing process, a simple spinning together
two conventional fibres in a helical arrangement which, of two conventional fibres and the relative ease of tailoring
when subjected to a tensile strain, exhibited a net increase properties.
in the width of the yarn. Miller et al. (2009) provided pre- Fig. 2a defines the geometric parameters associated
liminary test data for one helical auxetic yarn (HAY) sys- with a HAY having components of circular cross section.
tem, combined helical auxetic yarns in a simple weave The initial diameters of the core and wrap fibres can be de-
pattern to produce an auxetic textile and used the textile fined as Dc and Dw, respectively. The effective diameter of
to manufacture and test a low modulus composite. the yarn is defined by Dy. The cyclic frequency of the wrap
Helical auxetic yarns form the basis of this paper. We de- fibre can be defined using either the angle h which sub-
fine the geometric parameters of these yarns, describe the tends the core and wrap or by considering the cyclic pitch
manufacture and mechanical characterisation process in of the wrap fibre k. It is more intuitive to measure and
detail and also identify the mechanism behind the observed quote the angle h. However due to practicalities of mea-
auxetic behaviour. In this paper we undertake a systematic surement of the yarns as a function of strain we use the
study of monofilament HAYs to determine the parameters of pitch length to calculate the wrap angle. It is also conve-
greatest influence to the desired auxetic behaviour. nient for the manufacturing process to correlate the wrap
angle h to the linear measurement k.
The cyclic pitch and fibre diameters of a HAY can be de-
2. Geometry scribed using simple trigonometry. If we take exactly one
cycle of a HAY and roll it out on a flat surface, imagining
A helical auxetic yarn is constructed by combining two the wrap fibre sticking to the surface as it unravels from
fibrous components in a double helix as described by Hook the core. This forms a simple right angle triangle as shown
et al. (2006). It has been proposed that the components in Fig. 2b.
must possess differing moduli and diameter for the HAY where;
to function optimally. The experimental work in this paper Lw = Length traced by the centre of the wrap fibre (m)
investigates these effects on the auxetic behaviour of the Dc = Diameter of core fibre (m)
yarns. First the yarn geometry is introduced. A low modu- Dw = Diameter of wrap fibre (m)
lus, initially straight core fibre is uniformly wrapped with a k = Cyclic pitch of wrap fibre (m)
478 M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486

Fig. 1a. HAY at zero strain.

Fig. 1b. Helical auxetic yarn at maximum strain.

Fig. 2a. Geometric definitions of a monofilament helical auxetic yarn.

Fig. 3b. Cross section of HAY.

section area of the yarn at zero strain as shown in Fig. 3a.


By taking a section through the yarn normal to the applied
load, i.e. the major axis of the core fibre at zero strain we
can observe a circular core and elliptical wrap as shown
Fig. 2b. Trigonometric relationship of HAY components. in Fig. 3b.
The cross sectional area of the core (Ac) and wrap fibres
(Aw) can be calculated using Eqs. (1) and (2) respectively;

pD2c
Ac ¼ ð2Þ
4

pD2w
Aw ¼ ð3Þ
cos h
Fig. 3a. HAY at zero strain.
The cross sectional area of the yarn (Ay) is the sum of equa-
tions (2) and (3);
h = Wrap angle (deg)
Dy = Effective diameter of yarn (m) Ay ¼ Ac þ Aw ð4Þ

As the yarn is strained and the wrap straightens, its cross


From Fig. 2b; section will change from elliptical to circular whereas the
reverse is observed for the core which starts circular and
pðDc þ Dw Þ tends to an elliptical cross section once activated.
k¼ ð1Þ
tan h

Eq. (1) allows the cyclic pitch of a yarn to be calculated for 3. Methods
any given fibre diameter pair as a function of the desired
wrap angle. The pitch is used in the manufacturing process Monofilament core and wrap fibres were sourced from
to accurately produce the required yarn geometry. Monofil Technik (www.monofil-technik.de.2007). A poly-
The engineering stress in the yarn as a function of the urethane elastomer trade name TROFIL, nominal 600 lm
applied longitudinal strain is calculated using the cross diameter was selected as the core fibre as it allows large
M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486 479

strain deformations. The wrap fibre was a co-polymer whichever first. The crosshead speed Vc was set as a func-
polyamide, trade name Platil in nominal diameters tion of the sample gauge length such that.
110 lm, 130 lm and 150 lm. Accurate diameters of core
V C ¼ 0:1LG = min ð7Þ
and wrap fibres were obtained by SEM measurements at
high magnification. 3 random samples of each monofila- This equates to the lowest testing speed specified in ASTM
ment fibre were taken from the spools as supplied by the D3822-07 as it allows greater accuracy in image acquisi-
manufacturer, coated in approximately 5 nm of gold and tion of the yarns.
imaged in a Hitachi S3200 variable pressure SEM using a A high magnification, non-contact video system con-
20 kV accelerating voltage. Two images were obtained for trolled by a secondary PC was used to accurately record
each sample. Length measurements were taken using the longitudinal and lateral sample strain. A 4.9 MP digital
internal calibrated vernier callipers to determine the diam- camera (Edmund Optics EO-5012C USB) acquired images
eter of the fibres. through a variable zoom lens mounted at a fixed working
Helical auxetic yarns were manufactured using a spin- distance of approximately 160 mm from the sample. This
ner mechanism designed and built specifically for produc- allowed simple control over the field of view at a fixed res-
ing lab-scale lengths of yarns – approximately 10 m. The olution of 2560  1920 pixels. The field of view was se-
wrap fibre was used to control the two yarn geometric lected at the start of testing and remained fixed
parameters of interest in this study, the wrap fibre angle throughout the test. The smallest field of view achievable
and the wrap/core fibre diameter ratio. Yarns of varying from the hardware was approximately 8 mm2, giving the
wrap angle were manufactured using the 150 lm wrap fi- greatest resolution of images and hence accuracy in mea-
bre. A detailed description can be found in Appendix 1. surement. Camera lens focus and apertures were set using
Fibre and yarn samples were prepared for mechanical this condition. A fixed field of view was used throughout
testing according to ASTM D3822-07 – tensile properties the tensile test, and so was increased accordingly to
of single textile fibres (ASTM, 2007). Minor variations be- accommodate the accumulated strain within the fibres –
tween monofilament and HAY samples are discussed both optical and sample gauge lengths. Fig. 4 shows a sche-
below. matic of the test apparatus. A software macro was added to
Monofilament fibre samples of 70 mm length were ta- the Nexygen test procedure, instructing a TTL signal to be
ken from bulk spools of fibre and prepared for mechanical sent on the start of the test and at pre-defined regular
testing according to ASTM (2007). Sample ends were se- strain intervals to acquire images throughout the test.
cured in 10 mm card tabs using Araldite 2012 to minimise External lighting was employed using an electric lamp
clamp slip. A clamping gauge length LG of 50 mm was used and ‘‘daylight’’ bulb. White panels were used around the
and an additional gauge length for optical strain measure- test set up to reflect and diffuse the light source and so
ments LO marked onto the middle of the fibre such that; minimise light reflection effects such as halos around the
fibres.
LO ¼ 0:1LG  5% ð5Þ
Camera hardware was mounted to display the test sam-
Due to the additional geometric complexity of HAYs, the ple image in a horizontal configuration as shown in Fig. 5
sample gauge length was modified to retain accuracy and thus exploiting the maximum pixel resolution along the fi-
consistency throughout the testing. bre length.
A sample gauge length L was chosen according to the Strains were applied in the positive x direction. This ap-
conditions. plied to both monofilament and yarn samples.
Yarns were visually inspected before testing to confirm
50 mm 6 LG and 10k 6 LG ð6Þ accurate manufacture by inspecting the consistency of

This condition was specified by the authors to ensure a


minimum number of wrap cycles within a specimen gauge
length regardless of yarn geometry and can also be justi-
fied by the numerical study by Wright et al. (2010). Gauge Camera and zoom lens
length increases as wrap angle decreases so this condition
was specified to retain a minimum geometric consistency
between yarns.
Tensile measurements were performed using a Lloyd Sample Tensile clamps
Instruments (www.lloyds-instruments.co.uk) EZ 20 Camera mount
mechanical testing machine using a 50 N load cell and stage
crosshead displacement control via the internal extensom-
eter. The initial clamp separation was set to length using
calibrated verniers. The applied load and linear separation
of the clamps were recorded using the Nexygen software
(www.lloyds-instruments.co.uk) at a data capture fre- Trigger from Tensile control pc
quency of 1 kHz.
Samples were mounted vertically between clamps and Data to image acquisition pc
secured manually. Monofilaments were tested to failure;
HAYs were tested until failure of either the core or wrap, Fig. 4. Image acquisition and tensile testing apparatus.
480 M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486

Fig. 5. Configuration of test images.

Fig. 6. Rejected yarn sample.

wrap angle and conformance of the wrap with the core length measurements were determined and used to calcu-
along the entire sample gauge length. Fig. 6 shows a sam- late the absolute errors in strain measurements and subse-
ple rejected before testing due to poor conformance of quent Poisson’s ratio values.
wrap with the core. Gauge length markers can also be seen
on the sample. 4. Results
Longitudinal and lateral strain measurements were cal-
culated using the images captured during the tensile test at 4.1. Fibre characterisation
intervals of 0.01 strain. A contrasting sample background
was used to enhance the sample edge definition and min- Typical SEM images of the polyurethane elastomer core
imise image compression noise artefacts associated with are shown below in Figs. 7a and b. Width measurements
colour change rather than brightness. Raw bitmap images were taken and a median value calculated for each mono-
were converted into JPEG files in Paintshop pro filament giving their respective diameters. These diame-
(www.jasc.com) maintaining a 2560  1920 pixel resolu- ters were used to calculate the desired pitch length for
tion and using the lowest compression factor. Sample manufacture of the yarns and the cross sectional areas of
dimensions for monofilaments and yarns were calculated the monofilaments.
using the linear measuring tool in the ImageJ software
(Abramoff et al., 2004). All sample and calibration images
4.2. Mechanical testing
were processed manually using this method. The length
scale was calibrated using the zero strain image for each fi-
Fig. 8 shows the engineering stress/strain curve for the
bre and the dimensions taken from the SEM images. For
monofilament component fibres and their respective heli-
monofilaments, longitudinal strain was calculated using
cal auxetic yarn with a starting angle of 13°. The polyamide
the separation of the optical markers and lateral strain
wrap is shown to have a greater modulus and ultimate ten-
using the fibre width.
sile strength than the elastomeric core fibre. The polyure-
Image analysis for HAYs was performed in the same
thane core is able to withstand longitudinal strain 4
manner, however due to the significant change in geome-
times greater than the wrap fibre before failure but dem-
try compared to monofilaments, strain measurement defi-
onstrates a much lower tensile stress at failure. Combining
nitions were required. Longitudinal strain was determined
the two fibres in a helical arrangement produces a stress
by measuring the linear separation of the optical gauge
strain curve with a higher ultimate tensile stress and
markers. Transverse strain was calculated using the great-
elongation at break compared to the component core and
est lateral width of the yarn with respect to the axis of the
wrap fibres, respectively.
applied tensile load. At low strains this equated to the
Table 1 summarises the mechanical properties of the
width measured between peak heights of the wrap fibres.
fibres as shown in Fig. 8. The Young’s modulus was calcu-
At higher strains when the core has been activated, taking
lated using the initial linear elastic region of the engineer-
on a sinusoidal wave form, the greatest width is defined by
ing stress strain curve. The engineering stress was
the core.
calculated using circular cross sectional areas for the
Poisson’s ratio for monofilament fibres and yarns was
monofilaments and using Eq. (4) for the yarns.
calculated using engineering strains ey and ey according
to Eq. (4)
Table 1
ey Summary of mechanical properties of core, wrap and yarn.
mxy ¼  ð8Þ
ex PU core PA wrap HAY 13°

Measurement errors were taken as ±2 pixels in both longi- Young’s modulus (MPa) 30 3400 76
Ultimate tensile strength (MPa) 51 789 56
tudinal and lateral directions. Using the calibrated length
Strain at break (%) 95 17 34
scale for individual images, maximum and minimum
M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486 481

for the structure after which an equally sharp decrease in


m is shown. This is the onset of (true) auxetic behaviour.
The yarn demonstrates engineering auxetic behaviour at
0.03e when a negative m is observed. The auxetic effect
continues further as the strain is applied and a minimum
value of m at 2.79 is observed at a strain of 0.06. Contin-
ued application of strain produces a continued auxetic ef-
fect but decreasing in magnitude until failure of the
wrap. As the yarn is extended the wrap fibre straightens
before failing at a strain of 0.3, nearly twice the strain at
failure observed for the wrap fibre alone. This behaviour
of the HAY is characteristic to this particular material
and geometry.
Plotting the yarn alone in Fig. 11 clearly shows the
strain dependent behaviour of the yarn in addition to the
experimental errors in calculating the Poisson’s ratio.
The experimental error reduces as a function of the
Fig. 7a. PU core. applied longitudinal strain due to the engineering strains
used to calculate Poisson’s ratio. We can show the sensitiv-
ity of the measurement system to only be valid for strains
greater than 1% as below this value the error bars are unac-
ceptably high. The data in Fig. 11 represents the greatest
experimental error produced in this work as the images
were obtained using the lowest pixel resolution. The
experimental errors for calculating Poisson’s ratio are
shown for each data set as a percentage of the errors
shown in Fig. 11.
Fig. 12 shows the effect of varying the angle of the wrap
fibre on the auxetic effect of the yarn. The wrap fibre used
was nominally 150 lm in diameter, giving a core to wrap
diameter ratio of 4.2:1. The lowest starting angle of 13°
corresponds to the data shown previously in Fig. 11.
Increasing the starting angle to 22° shows similar low
strain behaviour in the rapid increase and subsequent de-
crease in m to a minimum value of 1.37. A change in start-
ing angle of 9° produces nearly a 50% change in the auxetic
effect of the yarn. The onset of auxetic behaviour is ob-
Fig. 7b. PU core.
served at a comparably low strain however true auxetic
behaviour is observed at a marginally higher strain as the
wrap fibre is not sufficiently straight to activate the core.
Images acquired during the tensile test were processed The yarn with a 30° angle shows the initial positive in-
to determine the gauge length and width for the core, wrap crease in m followed by a gradual decrease in magnitude
and yarn. The measured widths of the samples as a func- to a strain of 0.3 where engineering auxetic behaviour of
tion of longitudinal strain are shown below in Fig. 9. the order 0.06 is observed and maintained constant until
Using the gauge width, the engineering lateral strain failure of the wrap. With a 38° starting angle a low strain
was calculated, allowing the Poisson’s ratio to be rapid increase in m is observed, followed by a gradual in-
calculated. crease in m to 0.2e, then a slow decrease to failure at
Fig. 10 shows the Poisson’s ratio as a function of the ap- 0.56e. Engineering auxetic behaviour is not observed for
plied strain for both monofilament component fibres and this high starting angle and fibre geometry pair.
their respective helical auxetic yarn. At low strains the The ratio of core to wrap fibre diameters is the second
polyamide wrap fibre exhibits a m of approximately 2 geometric parameter we have used to tailor the auxetic ef-
which decreases to a magnitude in the region of 1 before fect. Fig. 13 shows the effect of changing the wrap diame-
failure. The polyurethane core fibre shows a measured m ter on the auxetic effect of the yarn. Three yarns were
in the range of 0.34–0.74 over a strain range 4 times that manufactured with an intended wrap angle of 30°; how-
of the wrap. At low strains the core fibre demonstrates ever variations in angle due to fibre relaxation and, pre-
the highest value for m which, as the applied strain is in- dominantly, slip due to a low friction between the fibres
creased, diminishes linearly to its minimum value. resulted in a slight variation between yarns. The measured
Combining these two monofilaments in a helical wrap angle for each yarn is stated in Fig. 13.
arrangement produces a markedly different behaviour in All three variations in wrap diameter show the initial
structural geometry as a function of applied strain. At increase in m versus strain however this effect is most pro-
strains below 0.02 we can observe a rapid increase in m nounced for the smallest diameter wrap fibre. Poisson’s ra-
482 M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486

1000

900

800

700

600
σ / MPa

500

400

300

200

100

0
0 20 40 60 80 100
ε/%

pa wrap pu core HAY 13°

Fig. 8. Stress vs elong core, wrap and yarn.

1400 as low as 2.7. The magnitude of m is dependent on yarn


1200 geometry – wrap fibre starting angle and diameter ratio
– and the m of the component fibres. High resolution
Gauge width /μm

1000
images of monofilament fibres obtained during tensile
800 testing showed a high anisotropy in the polyamide wrap fi-
600 bres as the calculated values extend beyond the range dic-
400
tated by classical theory for isotropic materials of between
0 and 0.5. The polyurethane core fibres proved to be less
200
anisotropic and demonstrated failure at much higher
0 strains and as such lend themselves well as core fibres in
0 0.2 0.4 0.6 0.8 1
ε long HAYs.
A low and predictable Poisson’s ratio is desirable for the
pa wrap pu core HAY 13°
core as any thinning of this fibre negates the auxetic effect
Fig. 9. Width vs elong core, wrap and yarn. Width Errors Yarn ±31 lm, achieved by the helical structure.
Core ±25 lm, Wrap ±10 lm. The majority of HAYs tested demonstrated a sharp in-
crease in m at low strains before peaking and reducing in
tio can then be observed to decrease in a steady manner for magnitude. We can attribute this behaviour to the internal
all fibres before tensile failure of the wrap. The only sample helix diameter of the wrap fibre conforming to the un-
to show true auxetic behaviour incorporated the nominal strained diameter of the core and hence a rapid decrease
150 lm diameter fibre – the largest diameter of the three in the net width of the yarn.
wraps. As the applied strain is increased the abrupt change in
All HAY’s tested in this study failed due to fracture of direction of m and equally rapid rate of decline is the result
the wrap fibre. Relative slip between core and wrap fibres of activation of the core fibre into a helical form and the
was not observed for any HAY’s during testing. onset of engineering auxetic behaviour. It is therefore pos-
sible to remove the initial variation in m by pre-tensioning
5. Discussion the yarns to a given strain. Once activated the core defines
the net width of the structure and is responsible for the
Helical auxetic yarns manufactured and tested in this auxetic behaviour of the yarn until failure of the wrap fibre
study have been shown to demonstrate Poisson’s ratios – at an applied strain dependent on the starting geometry
M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486 483

2
ν

0
0 0.2 0.4 0.6 0.8 1

-2

-4

-6
long

PA 150um PU core 150um wrap 13°

Fig. 10. m vs elong for monofilament component fibres and HAY.

4
Poisson's ratio

0
0 0.05 0.1 0.15 0.2 0.25 0.3 0.35
-2

-4

-6
Longitudinal strain

HAY 13°

Fig. 11. m vs elong for HAY.

of the yarn. Relative slip between core and wrap fibres was geometry dependent, i.e. a larger diameter wrap is struc-
not observed verifying a good conformance between the fi- turally stiffer than a smaller diameter of identical material,
bres. We would expect a degree of slip and frictional effects a result confirmed by numerically modelling the mechani-
were this not the case, which in turn will reduce the geo- cal behaviour of helical auxetic yarns (Wright et al., 2010).
metric effect on the auxetic behaviour of the structure. This conflicts with the desire to minimise the apparent
The transient nature of m as a function of applied strain width of the yarn at zero strain by employing a low diam-
for HAYs can be attributed to the competition between eter wrap fibre. Therefore, the greatest auxetic effect will
geometric and material effects of the yarn. Positive m val- be observed when a wrap fibre of infinitely low diameter
ues for the component fibres counteract the geometric ef- and high stiffness is used.
fect from core activation. Depending on yarn geometry, We have shown that variation in zero strain wrap angle
this competition can be seen as either a gradual or near has a greater effect on the auxetic behaviour compared to
zero change over a given strain range. the relative fibre diameters. This result is demonstrated by
For maximum auxetic effect, low strain activation of the comparing the results in Figs. 12 and 13 highlighting the
yarn is desirable so that the geometric effect of the HAY is sensitivity of auxetic behaviour to starting wrap angle.
allowed to dominate over the material dependent behav- Variation in fibre diameter ratio showed less impact on
iour of the component fibres. Early activation of the core the auxetic performance of a HAY compared to the wrap
is achieved by a low starting wrap angle and a high stiff- angle whilst highlighting the importance of wrap geomet-
ness wrap. The stiffness of the wrap is both material and ric stiffness. Modulus of the wrap material is important
484 M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486

ν 2

0
0 0.1 0.2 0.3 0.4 0.5 0.6
-2

-4
ε long

13° 22° 30° 38°

Fig. 12. Variation in wrap angle on auxetic performance of HAY. Error in Poisson’s ratio measurement as a percentage of 13° yarn. 22° (86%), 30° (89%), 38°
(75%).

ν 2

0
0 0.1 0.2 0.3 0.4 0.5 0.6
-1
ε long
90um wrap 32° 130um wrap 31° 150um wrap 30°

Fig. 13. Variation on fibre diameter ratio on auxetic performance of HAY. Error in Poisson’s ratio measurement as a percentage of 13° yarn. 90 lm wrap 32°
(65%), 130 lm wrap (70%), 150 lm wrap (75%).

however it is the stiffness of the fibre geometry that should  The starting angle of the wrap fibre dominates the mag-
be considered foremost. nitude of auxetic behaviour.
Applications for auxetic textiles include shockwave pro-  The auxetic performance is also affected by the diame-
tection fabrics – blast, flood, and storm – smart filters, com- ter ratio of wrap to core fibres and the inherent Pois-
posite reinforcement, body armour and geo-textiles. son’s ratio of the fibres.

6. Conclusions
Acknowledgements
Helical auxetic yarns using monofilament polymeric fi-
bres have been defined, manufactured and characterised in The authors of this work would like to acknowledge the
this work. This work represents the first detailed, experi- EPSRC for financial support and also the industrial collabo-
mental study of the auxetic properties of simple HAYs. rators – Auxetix Ltd., Monofil Trading Company Ltd, Home
For these monofilament yarns the effect on m as a function Office Scientific Development Branch, Centre for the Pro-
of applied strain and manufactured geometry has been dis- tection of National Infrastructure. We are very grateful
cussed and the key geometric parameters used to tailor for the assistance and skills of the staff at Exeter University,
auxetic behaviour identified. namely Peter Gerry, Mike Burns and Dave Baker.

 Auxetic yarns have been accurately manufactured by Appendix A


spinning together two, commercially available, low cost
fibres. The manufacture of helical auxetic yarns used a spe-
 The maximum auxetic effect observed for the yarns was cially designed and manufactured spinner as shown in
2.7, using monofilament fibres with Poisson’s ratios Fig. 14. Preparing the spinner for yarn manufacturer re-
ranging from 0.35 to 1.95. quired loading core and wrap fibres onto spools 1 and 2
M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486 485

Electric spinner motor settings


Motors 12

10 y = 0.1388x - 0.014

linear speed (mm/s)


Core 2
fibre R = 0.9996
8
Wrap
fibre
Spool 1 6
feed
4

Spool 2 Yarn 2
Wrapper
0
0 20 40 60 80 100
motors 1&3 LCD setting

Fig. 15. Linear speed of core versus motors 1 and 3 control.


Spool 3
winder
Motor 2 settings
Fig. 14. Schematic of HAY yarn spinner. 6

Revolutions per second


5
respectively. Fibres were manually wound onto the spools
to ensure an even lay of fibre under minimal tension. Rota- 4
tion of the feed spool allowed the core to be threaded
3
through the centre of spool 2 and then onto the winder
spool 3. A number of eyelet guides and fibre tension either 2 -0.9859
y = 240.48x
side of spool 2 gave both directional and tension control of 2
R = 0.9988
the fibre. Stability of both these parameters is fundamental 1
to accurate and consistent manufacture of helical auxetic
yarns. 0
0 100 200 300 400 500
Handling elastomeric fibres has many inherent prob-
Motor 2 LCD setting
lems due to the low elastic modulus of the materials. Great
care was taken throughout the spinning process to mini- Fig. 16. Rotational frequency of wrap versus motor 2 control.
mise the tension on both core and wrap fibres whilst
retaining close control of the fibres. The elastomeric core
was fed through the spinner at a constant linear feed rate h = Wrap angle (deg)
by setting the feed and winder spools at equal speeds using
electronic motor controllers. Fine tension adjustments to The linear feed rate of the core is taken from the numer-
the core and wrap fibres were made using counterbalance ical relationship calculated in Fig. 15.
weights and a simple brake mechanism of the respective Knowing the desired pitch length we can define the
feed spools. A line counter recorded the linear throughput wrap frequency by dividing by the linear feed rate of the
of fibre. core fibre as defined by equation 7
Yarn geometry was controlled by adjusting the rota- vc
tional speed of motors 1, 2 and 3 via an LCD control panel. fw ¼ ð7Þ
k
Spools 1 and 3 dictated the linear speed and tension of the
where;
core fibre, spool 2 controlled the rotational frequency of
fw ¼ Wrap frequency (s-1)
the wrap fibre around the core. Empirical trials were em-
k = Cyclic pitch of wrap fibre (m)
ployed to quantify these parameters with respect to the
numerical values set on the motor control panel.
v c = Linear feed rate of core fibre (ms-1)
Figs. 15 and 16 show the numerical relationship be-
Practically, it is desirable to set a high linear feed of the
tween motor setting and linear core speed and wrap rota-
core fibre to enable a high throughput; however, in prac-
tional frequency respectively.
tice there is a compromise as lower speeds stabilise the
The geometry of the yarns as previous defined is de-
process by minimising accumulated stretch in the elasto-
scribed in Eq. (6)
meric material. Once a stable linear feed of the core was
pðDc þ Dw Þ established, the rotational frequency of the wrap was
k¼ ð6Þ defined.
tan h
The wrap frequency can also be defined as a function of
where; the rotational speed of motor 2 which has been calculated
Dc = Diameter of core fibre (m) using Fig. 16 and is defined in equation 8.
Dw = Diameter of wrap fibre (m)
k = Cyclic pitch of wrap fibre (m) fw ¼ 240:48m1
2 ð8Þ
486 M.R. Sloan et al. / Mechanics of Materials 43 (2011) 476–486

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Gunton, D.J., Saunders, G.A., 1972. The Young’s modulus and Poisson’s
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