5/21/2020 CN102277227B - Method for extracting mustard oil and mustard essential oil from mustard seeds - Google

rom mustard seeds - Google Patents

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Method for extracting mustard oil and mustard essential oil from mustard seeds

Abstract
CN102277227B
The invention provides a method for extracting mustard oil and mustard essential oil from mustard
China
seeds. The method provided by the invention comprises the following steps of: coldly pressing
mustard seeds at 40-45 DEG C to produce a mustard seed dreg cake and mustard oil; adding water
which is 4-10 times as much as the weight of the mustard seed dreg cake into the mustard seed Download PDF Find Prior Art Similar
dreg cake; agitating the mixture of the mustard seed dreg cake and the water and heating the
mixture to about 40-70 DEG C; distilling the mixture of the mustard seed dreg cake and the water by Other languages: Chinese
utilizing steam to produce an oil-water mixture and residues; separating mustard essential oil and
Inventor: 廖英崇, 吴耀军, 赵展鹏
water in the distilled oil-water mixture; drying the residues by a belt-type lter press and a heat pump
and then pressing or extracting by an organic solvent to produce the mustard oil and nal residues,
wherein the nal residues can be used as raw materials of animal feed. According to the method Worldwide applications
provided by the invention, the mustard essential oil can be extracted from the mustard seeds in a
2010 CN
large batch; as the technical ow is improved, the output and the output e ciency of the mustard oil
and the mustard essential oil are improved in a large scale and the mustard seeds are completely
utilized. Application CN 201010208371 events

2010-06-13 Application led by 宏芳香料（昆山）有限公司

2010-06-13 Priority to CN 201010208371

2011-12-14 Publication of CN102277227A

2012-12-12 Application granted

2012-12-12 Publication of CN102277227B

Info: Patent citations (2), Non-patent citations (2), Cited by (2),

Legal events, Similar documents, Priority and Related
Applications

External links: Espacenet, Global Dossier, Discuss

Claims (5) Hide Dependent

1. method of from the mustard seed, extracting mustard oil and mustard essential oil is characterized in that said method comprises the following step:

A. at 40 ℃～45 ℃ following cold press mustard seeds, generate a mustard seed blob of slag and mustard oil;

B. add in water to the said mustard seed blob of slag of 4～10 times of said mustard seed blob of slag weight;

C. stir the mixture of a said mustard seed blob of slag and water and be heated to 40 ℃ of-70 ℃ of fermentations that are hydrolyzed, the pH value of said hydrolysed ferment is
controlled at 4 to 7;

D. use the mixture of a vapor distillation said mustard seed blob of slag and water, generate oil-water mixture and residue;

E. separate mustard essential oil and water in the said oil-water mixture of distilled;

F. said residue squeezes or carries with organic solvent extracting after with belt lter press and heat pump drying, generates mustard oil and nal dregs.

2. the method for from the mustard seed, extracting mustard oil and mustard essential oil according to claim 1 is characterized in that, uses the said mustard seed of
screw oil expeller cold press with cooling system.

3. the method for from the mustard seed, extracting mustard oil and mustard essential oil according to claim 1 is characterized in that the hydrolysed ferment time of the
mixture of a said mustard seed blob of slag and water is 2 hours.

4. the method for from the mustard seed, extracting mustard oil and mustard essential oil according to claim 1 is characterized in that the speed that stirs the mixture of
a said mustard seed blob of slag and water is 30rpm.

5. the method for from the mustard seed, extracting mustard oil and mustard essential oil according to claim 1 is characterized in that the staple of said mustard
essential oil is allyl mustard oil or hydroxy-benzyl mustard oil.

Description

A kind of method of from the mustard seed, extracting mustard oil and mustard essential oil

Technical eld

The invention relates to a kind of mustard seed treatment process, especially about a kind of method of from the mustard seed, extracting mustard oil and mustard
essential oil.

Background technology

The mustard seed is a kind of agricultural-food of very economically valuable, and it includes abundant grease, has pressed the dregs rich in proteins behind the oil, is
good animal feed ingredient.In addition, also contain a kind of chemical ingredients-sinigrin in the mustard seed, sinigrin is being hydrolyzed under the myrosin effect and
after distillation, can obtaining being mainly the mustard essential oil of allyl mustard oil or hydroxy-benzyl mustard oil.

https://patents.google.com/patent/CN102277227B/en 1/5
5/21/2020 CN102277227B - Method for extracting mustard oil and mustard essential oil from mustard seeds - Google Patents
The mustard essential oil is wide a kind of seasonings popular to people, and its main pungency component is allyl mustard oil or hydroxy-benzyl mustard oil, and its
pungent is strong, but the secretion of saliva stimulating and gastric juice has the effect of appetizing, can whet the appetite.The choke staple of nose of mustard is an
allyl mustard oil, and this composition not only can prevent decayed tooth, to preventing cancer, and anti-hemostatic tube grumeleuse, treatment asthma waits also has
certain effect.Mustard oil also has the effect of beautifying face and moistering lotion, and in body beauti cation circle, mustard oil is good massage oil.

Mustard essential oil and mustard oil all are to be processed by the mustard seed.The precursor substance that contains the pungent substance allyl mustard oil in the
mustard seed---sinigrin; Its hydrolyzable under the effect of myrosin goes out pungent substances such as allyl mustard oil; Yet; Myrosin is a kind of protein, and the tool
thermolability will begin because of the protein denaturation loss of activity being higher than under 45 ℃ the environment.

Because what traditional milling process used is the hot moulding method; And high temperature can make the myrosin loss of activity; Make it can't the hydrolysis
sinigrin to generate allyl mustard oil or hydroxy-benzyl mustard oil, therefore, in order to bring into play the economic worth of mustard seed effectively; The practice in
past is to be crushed to 20-40 purpose particle size to doing earlier to roll before the mustard seed oil expression, adds the water fermentation that is hydrolyzed.Then
with steam distilled mode the mustard essential oil is taken out, mustard seed dregs extract oil after drying again.Owing to must remove the moisture in the mustard
seed dregs before the oil expression; Therefore generally only add a spot of water in the process of hydrolysed ferment; Be 30%～40% of mustard seed weight
approximately, so just can't effectively let the fermentation that is hydrolyzed of myrosin catalysis sinigrin, the e cient of extracting the mustard essential oil is quite low.

Moreover because before extracting the mustard essential oil, mustard oil does not separate taking-up, when steam distillation, the mustard oil that proportion is lighter
than water can bring inconvenience to steam extraction mustard essential oil, has more lowered the amount that can extract the mustard essential oil.Such situation also
can cause the increase of vapor distillation energy consumption.

At last, the remaining residue of vapor distillation squeezes after with belt lter press and heat pump drying again or proposes remaining mustard oil with organic solvent
extracting, can improve as the relative protein contnt in the nal dregs of animal-feed raw material.

Application number is 89107746.4 patent---mustard oil making technology is traditional mustard seed complete processing; Following narration is wherein arranged:
work as processing condition; (amount of water＜30% when being lower than the lower value of above-mentioned each operation; PH value＜5, stewing system time＜2
hour, distillation time＜0.5 hour) the going out rate and will reduce of tori seed oil; When being higher than the higher limit of above-mentioned each operation, go out the
rate except that in uencing tori seed oil, to return the production operation management and bring a series of trouble, economical effectiveness is also bad.This amount
of water that is traditional technology when extracting the mustard essential oil is restricted to 30%～40% reason of mustard seed weight.

Summary of the invention

In view of this, to the defective in the treatment process of existing mustard seed, the invention provides a kind of method of from the mustard seed, extracting mustard
oil and mustard essential oil.

According to an aspect of the present invention, a kind of method of from the mustard seed, extracting mustard oil and mustard essential oil is provided, the method
includes the steps of: at 40 ℃～45 ℃ following cold press mustard seeds, generate a mustard seed blob of slag and mustard oil; Water to a mustard seed blob of slag
that adds 4～10 times of mustard seed blob of slag weight; Stir the mixture of a mustard seed blob of slag and water and be heated to about 40 ℃-70 ℃; The condition
that keeps 40 ℃-70 ℃ and PH4～7, hydrolysis 2 hours; Use the mixture of a vapor distillation mustard seed blob of slag and water, generate oil-water mixture and
residue; Separate mustard essential oil and water in the distilled oil-water mixture; Residue squeezes or carries with organic solvent extracting after with belt lter press
and heat pump drying, generates mustard oil and nal dregs.

Wherein, cold press mustard seed is to use the screw oil expeller cold press mustard seed with cooling system.

Wherein, the hydrolysed ferment pH value of the mixture of a mustard seed blob of slag and water is 4～7, and the hydrolysed ferment time is about 2 hours.

Wherein, the speed of the mixture of a stirring mustard seed blob of slag and water is 30rpm.

Wherein, the staple of mustard essential oil is allyl mustard oil or hydroxy-benzyl mustard oil (look employed mustard seed kind and decide).

Wherein, this method also comprises: separate residue and moisture.

The screw oil expeller cold press mustard seed that employing has cooling system has following advantage, and the utilization screw oil expeller can large batch of
continous way production.The press for extracting juice thorax of screw oil expeller is under the effect of cooling system, and processing temperature is no more than 45
℃, under the operation of continous way in enormous quantities, most mustard oil is separated taking-up, the activity of myrosin in the mustard seed blob of slag that
can also keep being left.

Because most of mustard oil takes out, can add more water in the step of hydrolysed ferment, generally speaking can add the water of 4～10 times of mustard seed blob
of slag weight, preferably add the water of 4～5 times of mustard seed blob of slag weight, fermentation is hydrolyzed.The consumption of water is big, can stir
effectively and a mustard seed blob of slag is mixed with water fully, and myrosin also can fully play effect, and sinigrin is changed into allyl mustard oil or hydroxy-benzyl
mustard oil.

Then, in the vapor distillation that extracts the mustard essential oil, taking out under most of mustard oil condition, except that steam can extract the mustard essential
oil effectively, steam distilled power consumption can reduce.

At last, residue with belt lter press and heat pump drying after with the remaining mustard oil of SX, the protein relative content in the nal dregs is improved, thereby
has promoted the quality of the nal dregs that can be used as the animal-feed raw material.

Use method provided by the invention can realize from the mustard seed, extracting in enormous quantities the mustard essential oil; Because the improvement of
technical process; Except that can obtaining high-quality mustard oil; The output of mustard essential oil and output e ciency also can both increase substantially, and
nal dregs can be used as high-quality animal-feed raw material because of the protein relative content is higher, the mustard seed is all utilized.

Description of drawings

The reader with reference to advantages after the embodiment of the present invention, will become apparent all respects of the present invention.Wherein,

Fig. 1 illustrates the conventional process ow gure that from the mustard seed, extracts mustard oil and mustard essential oil; And

Fig. 2 illustrates the process ow sheet that from the mustard seed, extracts mustard oil and mustard essential oil according to an embodiment of the present invention.

[primary clustering nomenclature]

100～110: step

200～212: step

Embodiment

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5/21/2020 CN102277227B - Method for extracting mustard oil and mustard essential oil from mustard seeds - Google Patents
Below will and specify clear explaination embodiment of the present invention with accompanying drawing.

Referring to Fig. 1, it illustrates the conventional process ow gure that from the mustard seed, extracts mustard oil and mustard essential oil.As shown in the gure; In
step 100; The moisture that in the mustard seed raw material, adds its weight 30%～40% fermentation that is hydrolyzed; Owing to contain precursor substance---the
sinigrin of pungent substance allyl mustard oil or hydroxy-benzyl mustard oil in the mustard seed, it is understood hydrolysed ferment 6 hours and produces pungent
substances such as allyl mustard oil or hydroxy-benzyl mustard oil under the effect of myrosin.Then get into step 102, use the oil-water mixture that steam distilled
method will contain allyl mustard oil or hydroxy-benzyl mustard oil to distillate.In step 104; Oil-water mixture to containing allyl mustard oil or hydroxy-benzyl mustard oil
carries out oily water separation; So just obtained containing the mustard essential oil of allyl mustard oil or hydroxy-benzyl mustard oil, last, step 106; The mustard
essential oil is made with extra care, is nally obtained nished product---high purity mustard essential oil.After step 102; Also will carry out step 108; In step 108, allyl
mustard oil in the mixture of mustard seed and water or hydroxy-benzyl mustard oil are distillated, and also contain 40% vegetables oil---the mustard oil of having an
appointment in the remaining mustard seed; Therefore the mixture with mustard seed and water dries, and just removes moisture.Following step 110 is carried out hot
moulding with the mustard seed of removing most of moisture and is handled, and extracts the mustard oil that wherein contains.

Can know by the process ow sheet shown in Fig. 1; Because the mustard seed is used hot moulding technology; Its processing temperature is up to about 100 ℃; Such
high temperature can destroy myrosin, makes it loss of activity and can't in follow-up step, be hydrolyzed and generate allyl mustard oil or hydroxy-benzyl mustard oil by
the catalysis sinigrin.Therefore must before to the oil expression of mustard seed, carry out hydrolysed ferment.But must remove the moisture in the mustard seed
before the oil expression; Therefore can only add less water in the process of hydrolysed ferment; Be about 30%～40% of mustard seed weight, and contain a large
amount of mustard oils in the mustard seed this moment, so not only thorough hydrolysed ferment; And when carrying out vapor distillation, be present in the mustard oil
of having separated out in the still kettle, can in uence steam to the mustard extracts essential oil.

Then please with reference to Fig. 2, it illustrates the process ow sheet that from the mustard seed, extracts mustard oil and mustard essential oil according to an
embodiment of the present invention.In step 200; Use has the screw oil expeller cold press exsiccant mustard seed of cooling system; Because the cold press
temperature is between about 40 ℃～45 ℃; Myrosin can loss of activity under this temperature, still can the catalysis sinigrin in follow-up step is hydrolyzed and
generates allyl mustard oil or hydroxy-benzyl mustard oil.In this step, also can the most of mustard oil that contain in the mustard seed be squeezed out.The mustard
seed is generated a mustard seed blob of slag and mustard oil by cold press in step 200 back, gets into step 202, owing to contain myrosin in the mustard seed blob of
slag, in a mustard seed blob of slag, adds the water of 4～10 times of a mustard seed blob of slag weight this moment, generally speaking is preferably about 4～5
times.The mixture heating up of a blob of slag and water to about 40 ℃-70 ℃, is controlled at about 4-7 with PH, and stirs, and the hydrolysed ferment through about 2
hours fully acts on myrosin, generation allyl mustard oil or hydroxy-benzyl mustard oil.Follow step 204; Use steam distilled method to distillate, in this step, will obtain the
residue that contains the oil-water mixture of allyl mustard oil or hydroxy-benzyl mustard oil and contain moisture with the oil-water mixture that the stirring velocity of
about 30rpm will contain allyl mustard oil or hydroxy-benzyl mustard oil.In step 206, the oil-water mixture that contains allyl mustard oil or hydroxy-benzyl mustard oil is
carried out oily water separation, obtain the mustard essential oil.Then in step 208, the mustard essential oil made with extra care and obtain high purity mustard
essential oil, the pick-up rate of high purity mustard essential oil (by mustard seed Mass Calculation) is about 5 ‰.After step 204; Also will carry out step 210, owing to
still contain a small amount of mustard oil in the mustard seed blob of slag that in step 200, generates, in order to utilize the mustard seed more economically; The
method of using belt lter press and heat pump drying is with the water sepn in the residue; Carry out step 212 at last, the exsiccant residue is extracted oil once more or
carries out the extraction of mustard oil with organic solvent, to obtain wherein remaining mustard oil to reach the purpose that makes full use of the mustard seed.Last
dregs can be used as one of raw material of making animal-feed because of the protein relative content is higher.

Can know by process ow sheet shown in Figure 2; Because the mustard seed is used cold pressing process; Make the myrosin can Yin Gaowen and lose activity,
therefore can earlier mustard oil be extracted, so just can in containing the mustard seed blob of slag of myrosin, add large quantity of moisture to make its abundant
hydrolysed ferment; Under stirring effectively, can get more complete with shorter time hydrolysed ferment.And, because most mustard oil is squeezed out in the mustard
seed, when carrying out vapor distillation, do not have a large amount of mustard oils and disturb, make that the mustard extracts essential oil is more e cient.

Use the method for from the mustard seed, extracting mustard oil and mustard essential oil provided by the invention, utilization has the screw oil expeller of cooling
system can realize large batch of continous way production.The press for extracting juice thorax of screw oil expeller is under the effect of cooling system, and
processing temperature is no more than 45 ℃, under the operation of continous way in enormous quantities, most mustard oil is separated taking-up, the activity of
myrosin in the mustard seed blob of slag that can also keep being left.Utilization cold press mode can be except can obtaining high-quality mustard oil; Under the
situation that most of mustard oil has been removed; Through strict control hydrolysis condition and hydrolytic process, the yield of mustard essential oil can reach 5～
10 ‰, has improved the utilization ratio of mustard seed greatly; In the process ow sheet shown in Figure 1, the oil yield of mustard essential oil is then generally 3～5
‰.In the mixture of the follow-up fermentation hydrolysis of a blob of slag; In the step with steam extraction mustard essential oil; Can reduce the distillatory energy
consumption, nal dregs can obtain better economic bene t because of the protein relative content is higher as the animal-feed raw material, have so just realized from
the mustard seed, extracting in enormous quantities the mustard essential oil; And the output and the output e ciency of mustard oil and mustard essential oil all
increase substantially, and the mustard seed is all utilized.

In the preceding text, illustrate and describe embodiment of the present invention.But those skilled in the art can understand, and under situation without departing from
the spirit and scope of the present invention, can also speci c embodiments of the invention do various changes and replacement.These changes and replacement all
drop in claims of the present invention institute restricted portion.

Patent Citations (2)

Publication number Priority date Publication date Assignee Title

CN1050896A * 1989-10-13 1991-04-24 天津市调味品研 Mustard oil making technology

究所

CN1579222A * 2003-08-07 2005-02-16 酒井四郎 Fractionation of allyl isothiocyanate, p-hydroxybenzyl-isothiocyanate, protein and ber
from mustard

Family To Family Citations

* Cited by examiner, † Cited by third party

Non-Patent Citations (2)

Title

田福祯等.从芥末中提取芥子油的研究.《化学世界》.1992,(第9期),第395-397页. *

https://patents.google.com/patent/CN102277227B/en 3/5
5/21/2020 CN102277227B - Method for extracting mustard oil and mustard essential oil from mustard seeds - Google Patents
赵元藩等.丙烯基芥末油的生产工艺研究.《云南化工》.1995,(第2期),第13-16页. *

* Cited by examiner, † Cited by third party

Cited By (2)

Publication number Priority date Publication date Assignee Title

Family To Family Citations

CN103315956B * 2013-06-17 2015-12-23 武汉大学 A kind of mustard oil nano-emulsion and preparation method thereof

CN104366502B * 2014-11-08 2016-03-16 全椒县尹氏油脂有限公司 A kind of health care scallion oil and preparation method thereof

* Cited by examiner, † Cited by third party, ‡ Family to family citation

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Priority And Related Applications

Priority Applications (1)

Application Priority date Filing date Title

CN 201010208371 2010-06-13 2010-06-13 Method for extracting mustard oil and mustard essential oil from mustard seeds

Applications Claiming Priority (1)

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5/21/2020 CN102277227B - Method for extracting mustard oil and mustard essential oil from mustard seeds - Google Patents

Application Filing date Title

CN 201010208371 2010-06-13 Method for extracting mustard oil and mustard essential oil from mustard seeds

Legal Events

Date Code Title Description

2011-12-14 C06 Publication

2011-12-14 PB01 Publication

2012-02-01 C10 Entry into substantive examination

2012-02-01 SE01 Entry into force of request for substantive examination

2012-12-12 C14 Grant of patent or utility model

2012-12-12 GR01 Patent grant

2017-06-23 CP03 Change of name, title or address

2017-06-23 CP03 Change of name, title or address Address after: Kunshan City, Jiangsu Province town of 215337 Beijing Granville Road, No. 68

Patentee after: Hong Fang Biotechnology (Kunshan) Co., Ltd.

Address before: 215337 No. 267 Sinpo Road, Newtown, Jiangsu, Kunshan

Patentee before: Hongfang Flavor (Kunshan) Co., Ltd.

Concepts

machine-extracted Download Filter table

Name Image Sections Count Query match

mustard seed title,claims,abstract,description 92 0

mustard oil title,claims,abstract,description 90 0

mustard oil title,claims,abstract,description 87 0

Brassica title,claims,abstract,description 52 0

Brassica cretica title,claims,abstract,description 52 0

Brassica rupestris title,claims,abstract,description 52 0

volatile oil title,claims,abstract,description 50 0

mixtures claims,abstract,description 16 0

oil-water mixture claims,abstract,description 11 0

drying claims,abstract,description 7 0

organic solvents claims,abstract,description 5 0

slag claims,description 27 0

hydroxybenzyl group claims,description 18 0

oil claims,description 17 0

oils claims,description 17 0

distillation claims,description 9 0

cooling claims,description 7 0

fermentation claims,description 6 0

heat treatment abstract,description 2 0

Show all concepts from the description section

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