02-12-18 - SR - IIT IZ - Jee - Adv - 2017 - P1 - PTA-15 - QP

Sec: Sr.
IIT IZ Date: 02-12-18

Time: 09:00 AM to 12:00 NOON Max.Marks:183
Name of the Student: ___________________ H.T. NO:
2017-PAPER -I
02-12-18_Sr.IIT IZ_Jee-Adv_PTA-15_WEEKEND SYLLABUS
MATHS: Properties And Solutions Of Triangle : Relations Between Sides And Angles
Of A Triangle, Sine Rule, Cosine Rule, Half-Angle Formula And The Area Of
A Triangle, Inverse Trigonometric Functions (Principal Value Only)
Heights & Distance
PHYSICS: COM and Collisions: Systems of particles; Centre of mass and its motion;
Impulse; Elastic and inelastic collisions.
CHEMISTRY: Qualitative Analysis: Principles of qualitative analysis: Groups I to V
(only Ag+, Hg2+, Cu2+, Pb2+, Bi3+, Fe3+,Cr3+, Al3+, Ca2+, Ba2+, Zn2+,
Mn2+ and Mg2+); Nitrate, halides (excluding fluoride),sulphate and sulphide.
13TH Group elements: Isolation/preparation and properties of the Boron.
Preparation and properties of following compounds. Boron: diborane, boric acid
and borax; Aluminium: alumina, aluminium chloride and alums;
Narayana IIT Academy 02-12-18_Sr. IIT IZ_Jee-Adv_2017-P1_PTA-15_Q’P
JEE-ADVANCE-2017-P1-Model
Time: 03:00 Hr’s IMPORTANT INSTRUCTIONS Max Marks: 183
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions With Multiple Correct Choice
Sec – I (Q.N : 1 – 7) +4 -2 7 28
(partial marking scheme) (+1,0)
Sec – II (Q.N : 8 – 12) Questions With Integer Answer Type +3 0 5 15
Sec – III (Q.N : 13 – 18) Questions With Single Answer Type +3 -1 6 18

Total 18 61
CHEMISTRY:
Sec – I (Q.N : 19 – 25) +4 -2 7 28
Total 18 61
MATHEMATICS:
Sec – I (Q.N : 37 – 43) +4 -2 7 28
Total 18 61
Sec: Sr. IIT IZ space for rough work Page 2

PHYSICS Max. Marks: 61
SECTION – I
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 7 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONE OR
MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong cases
1. A particle is thrown with speed u at an angle  with the horizontal surface. The
coefficient of restitution between the particle and the surface is e. Assume the surface
is frictionless. Then
u
2u sin 
A) time of flight of the particle for the entire motion is
g 1  e 
B) displacement of the particle for the entire motion is infinite.

u 2 sin 2
C) displacement of the particle for the entire motion is
g 1  e 
D) time of flight of the particle for the entire motion is infinite

2. In each of three figures shown, two blocks are connected by a light spring and the
system is placed on smooth horizontal surface. A constant horizontal force of
magnitude F is applied to left block as shown. Assuming spring constant in all three
cases to be same, which of the following statement(s) is/are true?
1 2 3
F F F
2m 2m 3m m m 3m
fig.-1 fig.-2 fig.-3

A) Maximum compression in spring 1 is greater than that in spring 2.
B) Maximum compression in spring 3 is greater than that in spring 1.
C) Maximum compression in spring 3 is greater than that in spring 2.
D) Maximum compression in all springs is equal.
3. A smooth hemisphere of mass m and radius R is at rest. A smooth solid sphere of
mass 2m and radius R moving with velocity V0 between two horizontal smooth
surfaces separated by a distance slightly greater than 2R as shown in figure. Solid
1
sphere collides with the hemisphere. If coefficient of restitution is , then
2

/////////////////////////////////////////
V0
//////////////////////////////////////////
0
A) the speed of hemisphere after collision is V0
V0
B) the speed of solid sphere after collision is
2
mV0 2
C) the loss in kinetic energy of the system is
4
1
D) the final kinetic energy of hemisphere is th of initial kinetic energy of the solid
4
sphere
4. Two spheres of same radii but masses 2kg and 4 kg are moving towards each other.
They collide with each other and
4m/s
A 2kg
R
B
2m/s 4kg

1
restitution coefficient e  . During collision, the spheres deform and again reform to
3
their original shapes. Then
A) magnitude of impulse each sphere experienced during deformation is 8 3 Ns.
4
B) magnitude of impulse during reformation is N.s
3
C) loss in kinetic energy of the system during deformation is 18 J.
D) loss in kinetic energy of the system during entire collision process is 16 J.
5. A small block of mass ‘m’ slides along a horizontal surface with constant velocity ’v’
meets a smooth hill of mass 3m and height h(hemispherical) which can move along
the horizontal plane. The block begins to slide up the hill. If the hill is initially at rest,
then
A) the value of ‘v’ which provides the maximum subsequent velocity of the hill is just
8 gh
greater than
3
B) the value of ‘v’ which ensures the block overcome the hill subsequently is just
greater than 4 gh
3
C) the value of ‘v’ which ensures the block overcome the hill subsequently is just
greater than 8 gh
3
D) the value of ‘v’ which provides the maximum subsequent velocity of the hill is just
lesser than 8 gh
3

6. A light rope passes over a smooth, fixed pulley. One end of the rope supports a ladder
with a man and the other end supports counter weight of mass M. Mass of the man
is m . Initially, the system is stationary and the center of mass of the counter weight is
at a height h from center of mass of the man as shown in the figure. If the man starts
to climb up slowly such that his center of mass reaches at the level with that of the
counter weight,

mh
A) the distance traveled by the man with respect to ladder is
2  M  m
Mh
B) the distance traveled by the man with respect to ladder is
M m
Mh
C) the distance traveled by the ladder is
2M  m
mh
D) the distance traveled by ladder is
2  M  m
7. In the figure shown, the cart of mass 6 m is initially at rest. A particle of mass m is
attached to the end of the light rod which can rotate freely about A. If the rod is
released from rest in a horizontal position shown, then (Assume frictionless surface)
6m A
l m
//////////////////////////////////////////

7
A) velocity Vrel of the particle with respect to the cart when the rod is vertical is gl
3
7
B) velocity Vrel of the particle with respect to the cart when the rod is vertical gl
6
6 14
C) velocity v1 of the particle with respect to ground when the rod is vertical is gl
7 3
6 7
D) velocity v1 of the particle with respect to ground when the rod is vertical is gl
7 3
SECTION-II
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases.
8. A smooth hemisphere of radius R and mass 4m is free to slide with its base on a
smooth horizontal table. A particle of mass m is placed on the top of the hemisphere.
Upon small disturbance, the particle starts sliding. If the angular velocity of the
particle relative to hemisphere at an angular displacement  when velocity of
nv
hemisphere has become v is , find n.
R cos 
//////////////////////////////////////////

9. A ball of mass  1kg is hung vertically by a thread of length l  1.50 m . Upper end of the
thread is attached to the ceiling of a trolley of mass M  4kg . Initially, trolley is
stationary and it is free to move along horizontal rails without friction. A shell of
mass m  1kg moving horizontally with velocity v0  6 ms 1 collides with the ball and
gets stuck with it. As a result, thread starts to deflect towards right. If its maximum
deflection with the vertical is  max , then find 10  sin  max .  g  10ms2 
1.50m
m M
V0 m
10. Disc A of mass m collides with stationary disk B of mass 2m as shown in figure. If
the value of coefficient of restitution for which the two disks move in mutually
perpendicular directions after collision is e, then find 8e.

11. Two blocks of equal masses m are released from the top of a smooth fixed wedge as
shown in the figure. Find the magnitude of the acceleration of the centre of mass of
the two blocks in ms 2 . Take g  10m / s 2
12. Two blocks A and B of masses m and 2m respectively are connected by a spring of
force constant k. The masses are moving to the right with uniform velocity v each, the
heavier mass leading the lighter one. The spring in between them is of natural length
during the motion. Block B collides with a third block C of mass m, at rest. The
collision being completely inelastic. If the maximum compression of the spring is
mv 2 n
, find .
nk 2

SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer, out of which ONLY
ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.13, Q.14 and Q.15 by appropriately matching the information given in the
three columns of the following table
A ball of mass m1 makes collision with another ball of same radius and mass m2 , at
rest. The figure shows the situation just before collision.
m1
v

m2
Column 1, gives relative between m1 and m2 . Column 2 gives the value of  and in
Column 3, the value of co-efficient of restitution are listed

Column-I Column-II Column-III
I) m1  m2 i)   300 P) e 1
1
II) m1  2m2 ii)   37 0 Q) e
2
m2 1 1
III) m1  iii)   tan 1 R) e
2 3 3
m3 1
IV) m1  iv)   600 S) e
3 2
13. In which of the following combination, the balls will move along mutually
perpendicular directions after collision?
A) (I), (ii), P B) (I), (ii), Q C) (III), (iv), P D) (IV), (iii), R
14. In which of the following combination, the balls will move along mutually
perpendicular directions?
A) (I), (iv), Q B). (I), (iii), R C) (III), (iv), Q D) (IV), (iv), S
15. In which of the following pair, balls will move along 450 with each other after
collision?
A) (II), (iii), P B) (I), (ii), Q C) (III), (i), Q D) (IV), (ii), R

Two blocks having masses m1 and m2 are placed on a smooth surface. The spring
connecting them is initially at natural length. V1 and V2 are initial velocities of m1 and
m2 respectively.
v1 v2
m1 m2

I) m1  m2  m i) v1  0 P) v2  0
II) m1  m, m2  2m ii) v1  v0 Q) v2  v0
v0
III) m1  2 m, m2  m iii) v1  2v0 R) v2 
2
v0 v0
IV) m1  m, m2  3m iv) v1  S) v2 
2 3

16. In which of the following combinations, maximum compression in the spring in the
subsequent motion is largest?
A) (i), (ii) ,P B) (II), (ii), P C) (I), (i), Q D) (II), (iii),P
17. In which of the following combination maximum velocity of m1 in the subsequent
7
motion will be V0 .
6
A) (I), (iv), Q B) (II), (iv), Q C) (I), (ii), R D) (IV), (iii), R
18. In which of the following combinations, time period of oscillation in the frame of
center of mass of the blocks in the subsequent motion is largest?
A) (I), (iii), Q B) (II), (i), Q C) (III), (iv), R D) (IV), (iii), P

CHEMISTRY Max.Marks:61
SECTION – I
19. Choose the correct orders:
A) Atomic size: In  Tl  Al  Ga  B
B) Ionisation enthalpy: B  T  Ga  Al  In
C) Lewis Acidic nature: BF3  BCl3  BBr3  BI3
D) Lewis acidic nature: BCl3  AlCl3  GaCl3  InCl3
20. Choose the correct statement(s) regarding boric acid:
A) can be prepared by neutralization of borax with HCl.
B) has 3-D structure due to H-bonding between layers.
C) acidic nature increases on addition of salicylic acid.
D) releases H  ions from water by accepting OH  ions.
21. A metal chloride (A) shows the following reactions:
(I) When H2S is passed into acidified aqueous solution of (A), a black precipitate (B)
is formed.
(II) Precipitate (B) is insoluble in yellow ammonium sulphide
(III) When Stannous chloride is added to aqueous solution of (A), a white precipitate
(C) is obtained which turns grey (D) on addition of excess reagent.
(IV) When aqueous solution of KI is added to aqueous solution of (B) a red precipitate
(E) is formed which dissolves in excess KI to form colorless solution.
Choose incorrect option(s):
A) A is Hg 2Cl2
B) B is soluble in hot and dil HNO3
C) C is HgCl2
D) E is HgI 2
22. A metal salt gives a colourless gas (G) with dilute HCl . The gas (G) is also obtained
by treating sodium sulphite with zinc in alkali. The metal salt can produce a precipitate
with:
A) Pb(CH3COO) 2
B) BaCl2
C) Alkaline Na 2  Fe(CN)5 NO 
D) AgNO3

23. Consider the following sequence of reactions:
AgNO3
Na 2S2O3  NaCN P + Q   S (white ppt)
FeCl3 / slightly acidic medium
 blood red colouration 
excess NaF
T + U (sulphur containing)
Choose the correct statement(s):

A) ‘P’ gives red colouration with FeCl2 in slightly acidic medium.
B) ‘T’ is colourless.
C) ‘R’ and ‘T’ are paramagnetic in nature.
D) On boiling aqueous suspension of ‘S’, grey metallic silver is precipitated.

24. In which of the following case(s) precipitation occurs?
A) MgCl2 with NaHCO3
B) CaCl2 with  NH 4 2 C2 O 4 in presence of CH3COOH
C) SrCl 2 with NaHCO3 in presence of aq. NH3

D) BaCl2 with  NH 4 2 C 2 O 4 in presence of CH3COOH
25. Which of the following is/ are observed when NaOH is added to aqueous solution of
ferric alum?
A) Liberation of ammonia gas.
B) Formation of a brown precipitate.
C) No precipitation in excess NaOH.
D) Colour of the solution fades.
SECTION-II
26. If heated in water, borazine hydrolyses slowly. The total number of moles of gaseous
products obtained by hydrolysis of one mole of borazine is:
27. How many of the following combinations results in liberation of hydrogen gas?

(i) Al, NaOH
(ii) Ga, NaOH
(iii) B2H6 ,H2O
(iv) B2 H6 , NH3 (1: 2) / 200C
(v) Electrolysis of aqueous AlCl3
28. The difference in coordination numbers of Al in crystalline AlCl3 and vapour
AlCl3  ~ 200C  is:
29. Among the following hydroxides the number of white precipitates is:
Zn  OH 2 , Cd  OH  2 , Mn  OH 2 , Al  OH 3 , Ni  OH  2 , Co  OH  2 , Pb  OH 2 , Fe  OH 3 , Cu  OH 2
30. A sodium salt (V) gives a brown coloured gas with dil HCl and forms a brown
coloured complex with ferrous sulphate and acetic acid. With how many of the
following reagents, the salt (V) produces a gaseous product?
(ii) with KMnO4 in acidic medium
(ii) boiling with NH4Cl
(iii) with urea in presence of dil HCl
(iv) with sulphamic acid in presence of dil HCl
SECTION – III
Column-I, II and III contain pair of ions, reagent(s) for precipitation of both the ions
and the reagent(s) required to dissolve one of the precipitate respectively.
Column – III
Column – II
Column-I (reagent or condition can be
Reagent for precipitation of
pair of ions used to dissolve one of the
both ions
precipitate)
(i) S2 ,Cl (I) H2S / HCl (P) CH3COOH
(ii) Hg2 ,Cu 2 (II) H2S / NH4Cl  NH4OH (Q) excessaqueous NH3
(iii) Co2 ,Mn 2 (III) AgNO3 (R) Hot dilute HNO3
(iv) SO 24  ,SO32  (IV) Ba  NO 3 2 (S) HCl
(V) Pb  OAc 2 (T) heating

31. Which of the following combinations is correct for (i):
A) i, (IV), S B) i, (III), P C) i, (IV), R D) i, (III), Q
32. Choose the incorrect combination:
A) ii, (I), R B) ii, (II), R C) iii, (II), P D) iii, (I), S
33. Choose the incorrect combination:
A) iii, II, S B) iv, IV, S C) i, V, T D) iv, V, Q
Match the cations given in Column-I with their characteristic dry test(s) in column-II
and wet test(s)/reaction in column-III.
(I) Blue color in borax bead test
(i) Pb2 in oxidising flame in hot (P) Soluble complex with excess NH3
condition
(Q) Soluble complex with excess
(ii) Zn 2 (II) Blue color in flame test
KCN

(III) Green color in borax bead
(R) Soluble complex with excess
(iii) Cu 2 test in oxidising flame in hot
NaOH
condition
(IV) Green residue on heating
(S) Precipitate with K 4  Fe(CN)6  that
(iv) Co2 with cobalti nitrate in charcoal
dissolves in excess alkali
cavity
34. Choose the correct combination for group-I cation:
A) i, II, P B) i, IV, Q C) i, II, R D) i, III, P
35. Choose the incorrect combination for group-IV cation:
(A) ii, II, P B) ii, IV, R C) ii, IV, S D) ii, IV, P
36. Choose the correct combination:
(A) iii, I, P B) iii, II, S C) iv, III, R D) iv, I, Q

MATHS Max.Marks:61
SECTION – I
37. In triangle ABC, if a, b, c are the lengths of the sides and R, r are the circum radius
and inradius of the triangle respectively. Then which of the following is/are true?
abc abc
A) R 2  B) R 2 
a b c a bc
1 1 1 1 1 1 1 1 1
C) 2    D)  2 2 2 2
R ab bc ca 2 Rr a b c 4r
38. In ABC , the lengths of altitudes through A,B,C are h1 , h2 , h3 and in radius r, then
h1  r
h r is
1
A)  6 B)  9 C)  8 D)  12
39. A circle of radius 4 cm is inscribed in ABC, which touches the side BC at D.
If BD  6cm : DC  8cm then which of the following is/are true?
A) The triangle is necessarily acute angled 
A 4
B) tan  ;
2 7
C) Perimeter of the triangle ABC is 42 cm
D) Area is 84 cm2
1 1
40. If 1  sin x   cos x  then set of all values of x lies in ([x] denotes greatest integer
function)
A) 0,1 B) sin1, 1 C) cos 2,1 D) (cos1, 1]
41. In a  ABC sides b, c C are given, which of the following cannot determine a
unique  ABC
A) c  bsin C, C   /2, c  b B) c  bsin C, C   /2, c  b
C) c  bsin C, C   /2, c  b D) c  bsin C, C    2, b  c
42. In  ABC , if a 2  b2  c 2   x  2 bc  0 , then x can be equal to

1 3
A) B) C) 2 D) 4
2 2
43. Let ABC be a  with in centre at I. If P and Q are foot of the perpendicular from A to
BI & CI resp, then which of the following results is/are correct?
AP sin B / 2cos C / 2 AQ sin C / 2cos B / 2
A)  B) 
BI sin A / 2 CI sin A / 2
AP sin C / 2cos B / 2 AP AQ
C)  D)   3 if A  600
BI sin A / 2 BI CI

SECTION-II
44. The number of integral values of ‘k’ for which the equation sin 1 x  tan 1 x  2k  1 has a
solution is
45. Let OHFM is a rectangle with OM=5, FM=11, ABC is a triangle with orthocentre H,
circumcentre O. M is the midpoint of side BC of  ABC and F is the foot of the
altitude from vertex A to the side BC, then the area of the triangle ABC is k, where the
sum of the digits in k is
46. Let a  cos1 (cos 20), b  cos1 (cos30) and c  sin 1 (sin(a  b)) then the largest integer x for
which sin 1 (sin x) | x  (a  b  c) | is
47. The sides of a triangle are 11, 15 and K, K  I . If the number of values of K such that
the triangle is obtuse angled is p, then p is a two digited number, the sum of whose
digits is________
48. In a ABC , I and S are incentre and circumcentre respectively, and the distance of I
from vertex A is 4 units. If the SBC is equilateral and the inradius of ABC is equal
k, then the value of  k 2  is equal to ([.] denotes G.I.F)

SECTION – III
In triangle ABC, AD is perpendicular to BC and DE is perpendicular to AB. Column-I
represents the triangle, Column-II represents area and Column-III represents circum
diameter of the corresponding triangle.
(triangle) (Area) (circumdiameter of the triangle)
c2
I) Triangle ADB A) Sin 2 B sin 2 B P) b sin C
4
c2
II) Triangle ADC B) sin 2 B Q) c cos B
4
b2
III) Triangle ADE C) sin 2C R) c
4
c2
IV) Triangle BDE D) Cos 2 B sin 2 B S) b
4
49. Which of the following is true?
A) I, B, S B) II, C, Q C) III, A, P D) IV, D, R
A) II, A, S B) III, D, Q C) I, B, R D) IV, B, Q
A) II, C, S B) I, B, Q C) III, B, P D) IV, A, Q
let ABC be a triangle with integer sides a, b, c and C  900 and inradius r of triangle
is given in column-I, sum of the digits in maximum area and number of such possible
triangles are given in Column-II and column-III respectively, then answer the
following
Column-II
Column-III
Column-I (r) (Sum of digits in maximum
(number of possible triangles)
area of the triangle)
A) 3 I) 9 P) 3
B) 4 II) 10 Q) 4
C) 6 III) 12 R) 5
D) 8 IV) 15 S) 6
A) A, II, P B) B, I, P C) C, IV, R D) D, II, Q
A) A, III, R B) B, II, Q C) C, IV, S D) D, I, P
A) A, III, P B) C, II, Q C) B, IV, S D) D, I, R

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Sec: Sr.

IIT IZ Date: 02-12-18

Sec – III (Q.N : 13 – 18) Questions With Single Answer Type +3 -1 6 18

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B) displacement of the particle for the entire motion is infinite.

D) time of flight of the particle for the entire motion is infinite

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fig.-1 fig.-2 fig.-3

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Column-I Column-II Column-III

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FeCl3 / slightly acidic medium

 blood red colouration 

Choose the correct statement(s):

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C) SrCl 2 with NaHCO3 in presence of aq. NH3

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(iii) Co2 ,Mn 2 (III) AgNO3 (R) Hot dilute HNO3

(iv) SO 24  ,SO32  (IV) Ba  NO 3 2 (S) HCl

(V) Pb  OAc 2 (T) heating

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42. In  ABC , if a 2  b2  c 2   x  2 bc  0 , then x can be equal to

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