Chemistry v2 PDF

PAPER-3 (B.E./B. TECH.
JEE (Main) 2020

COMPUTER BASED TEST (CBT)
Questions & Solutions
Date: 09 January, 2020 (SHIFT-1) | TIME : (9.30 am to 12.30 pm)
Duration: 3 Hours | Max. Marks: 300

SUBJECT : CHEMISTRY
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| JEE MAIN-2020 | DATE : 09-01-2020 (SHIFT-1) | PAPER-3 | OFFICAL | CHEMISTRY
PART : CHEMISTRY
SECTION – 1 : (Maximum Marks : 80)
Straight Objective Type (lh/ks oLrqfu"B izdkj )
This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
bl [k.M esa 20 cgq&fodYih iz'u gSaA izR;sd iz'u ds 4 fodYi (1), (2), (3) rFkk (4) gSa] ftuesa ls flQZ ,d lgh gSA
1. Which of these will produce the highest yield in Friedel Craft reaction ?
ÝhMy Øk¶V vfHkfØ;k esa buesa ls dkSu vf/kdre mRikn nsxk \
CONH2 NH2 Cl
OH
(1) (2) (3) (4)
Ans. (4)
Sol. Aniline and phenol form complex with lewis acid so most reactive among the given compounds for Friedel
Craft reaction is chlrobenzene.
Sol. ,uhfyu rFkk fQukWy yqbZl vEy ds lkFk ladqy cukrs gSA blfy;s fn;s x;s ;kSfxdks es ls Dyksjkscsathu ÝhMy Øk¶V
vfHkfØ;k ds izfr vf/kdre fØ;k'khy gksxkA
2. The correct order of heat of combustion for following alkadienes is :

fuEu ,sYdkMkbUl ds fy, ngu dh Å"ek dk lgh Øe gS &
(A) (B) (C)
(1) (b) < (c) < (a) (2) (c) < (b) < (a) (3) (a) < (b) < (c) (4) (a) < (c) < (b)
Ans. (3)
Sol. In isomers of hydrocarbon heat of combustion depends upon their stabilities.
As the stability increases heat of combustion decreases.
Stability order > >
Sol. gkbMªksdkcZu ds leko;oh;ksa es ngu dh Å"ek muds LFkkf;Ro ij fuHkZj djrh gSA
LFkkf;Ro c<+us ds lkFk] ngu dh Å"ek es deh gksrh gSA
LFkkf;Ro dk Øe > >
3. 'X' melts at low temperature and is a bad conductor of electricity in both liquid and solid state. X is :
(1) Carbon tetrachloride (2) Zinc sulphide (3) Silicon carbide (4) Mercury
'X' fuEu rki ij fi?kyrk gS rFkk nzo rFkk Bksl nksuksa voLFkkvksa esa fo|qr dk dqpkyd gSA X gS %
(1) dkcZu VsVªkDyksjkbM (2) ftad lYQkbM (3) flfydkWu dkckZbM (4) edZjh
Ans. (1)
Sol. CCl4  Non-conductor in solid and liquid phase.
CCl4  Bksl rFkk æo izkoLFkk esa dqpkyd gSA

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4. A chemist has 4 samples of artificial sweetener A,B, C and D. To identify these samples, he performed
certain experiments and noted the following observations :
(i) A and D both form blue-violet colour with ninhydrin.
(ii) Lassaigne extract of C gives positive AgNO3 test and negative Fe4[Fe(CN)6]3 test.
(iii) Lassaigne extract of B and D gives positive sodium nitroprusside test.
Based on these observations which option is correct ?
(1) A : Alitame ; B : Saccharin ; C : Aspartame; D : Sucralose
(2) A : Aspartame; B : Alitame ; C : Saccharin ; D : Sucralose
(3*) A : Aspartame; B : Saccharin ; C : Sucralose ; D : Alitame
(4) A : Saccharin ; B : Alitame ; C : Sucralose ; D : Aspartame
,d dsfeLV ds ikl Ñf=ke e/kqjdksa A,B, C rFkk D dk 4 izfrn'kZ gSaA bu izfrn'kksZ dks igpkuus ds fy, mlus dqN iz;ksx
fd;s x;s rFkk fuEu izs{k.kksa dks uksV fd;k %
(i) A rFkk D nksuksa fuugkbfMªu ds lkFk uhyk cSaxuh jax nsrs gSA
(ii) C dk ySlsa lkjdÙk (Lassaigne extract) AgNO3 ds lkFk ldkjkRed rFkk Fe4[Fe(CN)6]3 ds lkFk udkjkRed
ijh{k.k nsrk gSA
(iii) B rFkk D dk ySlsa lkjdÙk lksfM;e ukbVªksiqz lkbM ds lkFk ldkjkRed ijh{k.k nsrk gSA
bu izs{k.kksa ds vk/kkj ij dkSu lk fodYi lgh gS\
(1) A : ,syhVse ; B : lSdjhu ; C : ,sLijVse ; D : lqØkykst
(2) A : ,sLijVse; B : ,syhVse ; C : lSdjhu ; D : lqØkykst
(3*) A : ,sLijVse; B : lSdjhu ; C : lqØkykst ; D : ,syhVse
(4) A : lSdjhu ; B : ,syhVse ; C : lqØkykst ; D : ,sLijVse
Ans. (3)
Sol. A – Aspartame
B – Saccharine
C – Sucralose
D – Alitame

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(i) A & D give positive test with ninhydrin because both have free carboxylic and amine groups.
(ii) C form precipitate with AgNO3 in the lassaigne extract of the sugar because it has chlorine atoms.
(iii) B & D give positive test with sodium nitroprusside because both have sulphur atoms.
Sol. A – ,sLikVsZe
B – lSdjhu
C – lqØkykst
D – ,sfyVse
(i) A vkSj D fuugkbMªhu ds lkFk ldkjkRed ijh{k.k nsrs gSa] D;ksafd nksuksa es isIVkbM cU/k ik;s tkrs gSA
(ii) C 'kdZjk ds yslkus fu"d"kZ eas, AgNO3 ds lkFk vo{ksi nsrk gS] D;ksafd bles Dyksjhu ijek.kq gksrs gSA
(iii) B vkSj D lksfM;e ukbVªksizqlkbM ds lkFk ldkjkRed ijh{k.k nsrk gSA D;ksafd nksuksa es lYQj ijek.kq gksrs gSA
5. The electronic configurations of bivalent europium and trivalent cerium are :

(atomic number : Xe = 54, Ce = 58, Eu = 63)
(1) [Xe] 4f 4 and [Xe] 4f 9 (2) [Xe] 4f 7 and [Xe] 4f 1
7 2 2 2
(3) [Xe] 4f 6s and [Xe] 4f 6s (4) [Xe] 4f 2 and [Xe] 4f 7
f}la;kstd ;wjksfi;e rFkk f=kla;kstd lhfj;e ds bysDVªkWfud foU;kl gSa %
(ijek.kq la[;k : Xe = 54, Ce = 58, Eu = 63)
(1) [Xe] 4f 4 rFkk [Xe] 4f9 (2) [Xe] 4f 7 rFkk [Xe] 4f1
(3) [Xe] 4f 7 6s2 rFkk [Xe] 4f 2 6s2 (4) [Xe] 4f 2 rFkk [Xe] 4f7
Ans. (2)
Sol. Eu2+ : [Xe]4f 7
Ce3+ : [Xe]4f 1

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6. Complex X of composition of Cr(H2O)6Cln has a spin only magnetic moment of 3.83 BM. It reacts with
AgNO3 and shows geometrical isomerism. The IUPAC nomenclature of X is :
(1) Dichloridotetraaqa chromium(IV) chloride dehydrate
(2) Hexaaqua chromium(III)chloride
(3) Tetraaquadichlorido chromium(III) chloride dehydrate
(4) Tetraaquadichlorido chromium(IV) chloride dihydrate
Cr(H2O)6Cln la?kVu ds ladqy X dk fLiu ek=k dk pqEcdh; vk?kw.kZ 3.83 BM gSA ;g AgNO3 ds lkFk vfHkfØ;k djrk
gS vkSj T;kferh; leko;ork iznf'kZr djrk gSA X dk IUPAC uke gS %
(1) MkbDyksjkbMkVsVªk,sDok Øksfe;e(IV) DyksjkbM MkbgkbMªsV
(2) gsDlk,DokØksfe;e(III) DyksjkbM
(3) VsVªk,sDokMkbDyksjkbMks Øksfe;e(III) DyksjkbM MkbgkbMªsV
(4) VsVªk,sDokMkbDyksjkbMks Øksfe;e(IV) DyksjkbM MkbgkbMªsV
Ans. (3)
Sol. Cr(H2O)6Cln (complex)spin = 3.83 B.M.
From data of magnetic moment oxidation number of Cr should be +3
Hence complex is Cr(H2O)6Cl3.
Complex shows geometrical isomerism therefore formula of complex is [Cr(H2O)4Cl2]Cl2H2O.
It's IUPAC Name: Tetraaquadichloridochromium(III) chloride dihydrate
Cr(H2O)6Cln (ladyq )pØ.k = 3.83 B.M.
pqEcdh; vk?kw.kZ ds eku ls Cr dk vkWDlhdj.k vad +3 gksuk pkfg,A
bl izdkj ladqy Cr(H2O)6Cl3 gSA
ladqy T;kferh; leko;ork n'kkZrk gSA blfy, ladqy dk lw=k [Cr(H2O)4Cl2]Cl2H2O gSA
bldk IUPAC uke VsVªk,DOkkMkbZDyksjkbMksaØksfe;e (III) DyksjkbM MkbZgkbMªsV gSA 
7. The major product Z obtained in the following reaction scheme is
fuEu vfHkfØ;k Ldhe esa izkIr gksus okyk eq[; mRikn Z gS %
NH2
NaNO2 + HCl Cu2Br2 HNO3
X Y Z
273-278 K H2SO4
Br
Br
NO2 Br NO2
O2N
(1) (2) (3) Br Br (4) Br
Br Br Br NO2 NO2
Ans. (4)
NH2 N2+Cl– Br
Br
Sol. (1) NaNO2 + HCl (2) Cu2Br2 (3)HNO3
Br Br Conc. H2SO4 Br
Br
NO2

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8. The major product (Y) in the following reactions is :

fuEu vfHkfØ;kvksa esa eq[; mRikn (Y) gS %
CH3
HgSO4, H2SO4 (i) C2H5MgBr, H2O
H3C–CH—CCH3 X Y
H3O (ii) Conc. H2SO4
CH3 CH3 CH2 CH3

(1) CH3–CH–C=CH2 (2) CH3–C=C–CH3 (3) CH3–C–CH–CH3 (4) CH3–CH–C=CH–CH3
CH2–CH3 CH2–CH3 CH2–CH3 CH3
Ans. (2)
CH3 O CH3 OH CH3
(1) EtMgBr/Ether H+/
Sol. H3C–CH—C–CH3 CH3–CH—C–CH3 CH3–C=C–CH3
(2) H3O
CH2–CH3 CH2–CH3
CH3 O CH3 OH CH3

(1) EtMgBr/bZFkj H+/
Sol. H3C–CH—C–CH3 CH3–CH—C–CH3 CH3–C=C–CH3
(2) H3O
CH2–CH3 CH2–CH3
9. B has a smaller first ionization enthalpy than Be. Consider the following statements :
(I) It is easier to remove 2p electron than 2s electron
(II) 2p electron of B is more shielded from the nucleus by the inner core of electrons than the 2s electrons
of Be
(III) 2s electron has more penetration power than 2p electron
(IV) atomic radius of B is more than Be
(atomic number B = 5, Be = 4)
The correct statement are :
(1) (I), (III) and (IV) (2) (II), (III) and (IV)
(3) (I), (II) and (IV) (4) (I), (II) and (III)
B dh izFke vk;uu ,UFkSYih Be ls de gSA fuEu dFkuksa ij fopkj dhft,%
(I) 2s bysDVªkWu dh rqyuk esa 2p bysDVªkWu gVkuk vklku gSA
(II) Be ds 2s bysDVªkWuksa dh rqyuk esa B ds 2p bysDVªkWu vkarfjd dksj bysDVªkWuksa }kjk ukfHkd ls T;knk ifjjf{kr gSaA
(III) 2p bysDVªkWuksa dh rqyuk esa 2s bysDVªkWu dh izos'kh lkeF;Z (penetration power) T;knk gSA
(IV) B dh ijek.kq f=kT;k] Be ls T;knk gSA
(ijek.kq la[;k B = 5, Be = 4)
lgh dFku gS %
(1) (I), (III) rFkk (IV) (2) (II), (III) rFkk (IV)
(3) (I), (II) rFkk (IV) (4) (I), (II) rFkk (III)
Ans. (4)
Sol. Theory Based.
lS)kfUrd

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10. Identify (A) in the following reaction sequence :

O
C
(i) CH3MgBr O3/Zn, H2O H
(A) +
(B)
(ii) H , H2O CH3
Gives Positive
(3) Conc. H2SO4 /  H3C C=O
Iodoform test
CH3
fuEu vfHkfØ;k vuqØe esa (A) dh igpku dhft, &

O
C
(i) CH3MgBr O3/Zn, H2O H
(A) +
(B)
(ii) H , H2O CH3
ldkjkRed (3) lkUnz H2SO4/
vkbMksQkeZ H3C C=O
ijh{k.k nsrk gSA CH3
CH3 CH3
CH3 CH3
(1) (2) (3) (4)
O CH3 O CH3 O CH3 O CH3
Ans. (4)
Sol. (1) CH3MgBr
(2) H3O+
O HO
H , 
CH=O
O
O3
C
CH3 Zn, H2O
H3C CH3
11. According to the following diagram, A reduces BO2 when the temperature is :
–600
Gº/kJmol–1
–800
A + O2  AO2
–1000
–1200 B + O2  BO2
200 400 600 800 1000 1200 1400 1600

T(ºC)
(1) < 1200ºC (2) > 1200ºC but < 1400ºC
(3) < 1400ºC (4) > 1400ºC

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fuEu fp=k ds vuqlkj A, BO2 dk vip;u djrk gS tc rki gS %
Gº/kJmol–1 –600
–800
A + O2  AO2
–1000
–1200 B + O2  BO2
200 400 600 800 1000 1200 1400 1600

T(ºC)
(1) < 1200ºC (2) > 1200ºC ijUrq < 1400ºC
(3) < 1400ºC (4) > 1400ºC
Ans. (4)
Sol. A + BO2   B + AO2
G = –ve
Only above 1400°C
dsoy 1400°C ds Åij
12. The acidic, basic and amphoteric oxides, respectively, are :
vEyh;] {kkjh; rFkk mHk;/kehZ vkWDlkbMsa Øe'k% gSa &
(1) Na2O, SO3, Al2O3 (2) N2O3, Li2O, Al2O3
(3) Cl2O, CaO, P4O10 (4) MgO, Cl2O, Al2O3
Ans. (2)
Sol. Non-metal oxides are acidic in nature
alkali metal oxides are basic in nature
Al2O3 is amphoteric.
vèkkfRod vkWDlkbM vEyh; izd`fr ds gksrs gSA
{kkjh; èkkrq vkWDlkbM {kkjh; izd`fr ds gksrs gSA
Al2O3 mHk;èkehZ gSA
13. If the magnetic moment of a dioxygen species is 1.73 B.M., it may be :

(1) O 2 or O 2 (2) O2 or O 2 (3) O2 or O 2 (4) O2, O 2 or O 2
,d MkbZvkWDlhtu Lih'kht dk pqEcdh; vk?kw.kZ 1.73 B.M. gS] ;g gks ldrh gS %
(1) O 2 vFkok O 2 (2) O2 vFkok O 2 (3) O2 vFkok O 2 (4) O2, O 2 vFkok O 2
Ans. (1)
Sol. O2 = 1s2 *1s22s2*2s22pz22px2 = 2py2 *2px1 = *2py1
–
O2 = 1s2 *1s22s2*2s22pz22px2 = 2py2 *2px2 = *2py1
+
O2 = 1s2 *1s22s2*2s22pz22px2 = 2py2 *2px1 = *2py0
14. The Ksp for the following dissociation is 1.6 × 10–5
 
PbCl2(s) Pb2aq   2Cl aq
Which of the following choices is correct for a mixture of 300 mL 0.134M Pb(NO 3)2 and 100 mL 0.4 M
NaCl ?
(1) Q = Ksp (2) Q > Ksp
(3) Not enough data provided (4) Q < Ksp

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fuEu fo;kstu ds fy;s Ksp dk eku 1.6 × 10–5 gS]

 
PbCl2(s) Pb2aq   2Cl aq
0.134M Pb(NO3)2 ds 300 mL rFkk 0.4 M NaCl ds 100 mL dks feykdj cuk;s x;s feJ.k ds fy, fuEu eas ls dkSu
lk fodYi lgh gS \
(1) Q = Ksp (2) Q > Ksp
(3) i;kZIr vk¡dM+k miyC/k ugha (4) Q < Ksp
Ans. (2)
Sol. Q = [Pb2+][Cl–]2
2
300  0.134 100  0.4 
  
400  400 
3  0.134
  0.1
2

4
= 0.105 × 10–2
=1.005 ×10–3
Q > Ksp
15. If enthalpy of atomisation for Br2(I) is

x kJ/mol and bond enthalpy for Br2 is
y kJ/mol the relation between them :
(1) is x = y (2) is x < y (3) does not exist (4) is x > y
;fn Br2(I) ds fy, d.ku ,UFkSYih (enthalpy of atomisation) x kJ/mol gks
rFkk Br2 ds fy, vkcU/k ,UFkSYih y kJ/mol gks] rks
muds chp lEcU?k &
(1) x = y gksxk (2) x < y gksxk (3) curk ugha gSA (4) x > y gksxk
Ans. (4)
Hatomisation = x kJ/mole ijek.oh;dj.k = x kJ/mole
Br2() 2Br(g) Br2() 2Br(g)
HVap. HVap.
Sol. Br2(g)
Bond energy = y kJ/mole
Br2(g)
caèk ÅtkZ = y kJ/mole
Hatomisation = Hvap + Bond energy

Hence x > y
Hijek.oh;dj.k = Hvap + caèk ÅtkZ
bl izdkj x > y
16. [Pd(F)(Cl)(Br)(I)]2– has n number of geometrical isomers. Then, the spin-only magnetic moment and
crystal field stabilisation energy [CFSE] of [Fe(CN)6]n–6, respectively, are :
[Note : Ignore the pairing energy]
(1) 5.92 BM and 0 (2) 0 BM and –2.4 0
(3) 1.73 BM and –2.0 0 (4) 2.84 BM and –1.6 0
[Pd(F)(Cl)(Br)(I)]2– ds T;kferh; leko;oksa dh la[;k n gSA rc [Fe(CN)6]n–6 dk fLiu ek=k pqEcdh; vk?kw.kZ rFkk
fØLVy {ks=k LFkk;hdj.k ÅtkZ [CFSE] Øe'k% gSa%
[uksV : ;qXeu ÅtkZ dks NksM+ nhft,A]
(1) 5.92 BM rFkk 0 (2) 0 BM rFkk –2.4 0
(3) 1.73 BM rFkk –2.0 0 (4) 2.84 BM rFkk –1.6 0
Ans. (3)

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Sol. Number of Geometrical Isomers in square planar [PdFClBrI]2– are = 3

Hence, n = 3
[Fe(CN)6]3–
221 00
Fe3+ = 3d5 , According to CFT configuration is t2g eg
  n  n  2
=1.73 B.M.
CFSE  –0.40  nt2g  0.60  neg
= –0.40 × 5 = –2.00
Sol. oxZ leryh; [PdFClBrI]2– esa T;kfefr; leko;oh;ksa dh la[;k = 3 gSA
blfy;s, n = 3
[Fe(CN)6]3–
Fe3+ = 3d5 , CFT ds vuqlkj foU;kl t2g
221 00
eg
  n  n  2
=1.73 B.M.
CFSE  –0.40  nt2g  0.60  neg = –0.40 × 5 = –2.0 0
17. The de Broglie wavelength of an electron in the 4th Bohr orbit is

pkSFkh cksj d{kk esa ,d bysDVªkWu dh Mh&czksXyh rjaxnS/;Z gksxh %
(1) 4a0 (2) 2a0 (3) 6a0 (4) 8a0
Ans. (4)
Sol. 2 r = n
n2
2× a0 = n
Z
42
2× a0 = 4
1
 = 8 a0
18. The compound that cannot act both as oxidising and reducing agent is :
og ;kSfxd tks mipk;d rFkk vipk;d nksuksa dh rjg dk;Z ugha dj ldrk gS &
(1) HNO2 (2) H3PO4 (3) H2SO3 (4) H2O2
Ans. (2)
Sol. As in H3PO4 Phosphorous is present it's maximum oxidation number state hence it cannot act as reducing
agent.
pwafd H3PO4 esa QkWLQksjl bldh mPpre vkWDlhdj.k voLFkk esa mifLFkr gSA blfy, ;g vipk;d ds leku dk;Z ugha
dj ldrk gSA
19. The increasing order of basicity for the following intermediates is (from weak to strong)
fuEu e/;ofrZ;ksa ds fy, {kkjh;rk dk c<+rk Øe gS (nqcZy ls izcy) :
CH3
H3C–C H2C=CH–CH2 HCC CH3 CN
CH3
(i) (ii) (iii) (iv) (v)
(1) (iii) < (iv) < (ii) < (i) < (v) (2) (iii) < (i) < (ii) < (iv) < (v)
(3) (v) < (iii) < (ii) < (iv) < (i) (4) (v) < (i) < (iv) < (ii) < (iii)
Ans. (3)
Sol. Basicity is inversely proportional to electronegativity.
Sol. {kkjh;rk] fo|qr_.krk ds O;qRØekuqikrh gksrh gSA

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20. For following reactions

700K
A   product
500K
A  product
catalyst
it was found that the Ea is decreased by 30 kJ/mol in the presence of catalyst. If the rate remains
unchanged, the activation energy for catalysed reaction is (Assumer pre exponential factor is same) :
(1) 105 kJ/mol (2) 195 kJ/mol (3) 135 kJ/mol (4) 75 kJ/mol
fuEu vfHkfØ;k ds fy,
700K
A   mRikn
500K
A  mRikn
mRizsjd
;g ik;k x;k gS fd mRizsjd dh mifLFkfr esa Ea , 30 kJ/mol ls ?kV xbZA ;fn nj vifjofrZr jgs rks mRiszfjr vfHkfØ;k
ds fy, lafØ;.k ÅtkZ gksxh (eku yhft;s iwoZ pj?kkrkadh xq.kd ogh jgrk gS ) :
(1) 105 kJ/mol (2) 195 kJ/mol (3) 135 kJ/mol (4) 75 kJ/mol
Ans. (4)
Sol. Kcat = K
Ea1 Ea2
 
RT1 RT2
Ae = Ae
Ea1 Ea2
 Ea1 = Ea2 – 30
T1 T2
Ea2  30 Ea2
=
500 700
5Ea2 = 7Ea2 – 210
210
Ea2 = = 105 kJ/mole
2
Activation energy of the catalysed reaction = 105 – 30 = 75 kJ/mole
mRizsfjr vfHkfØ;k dh lafØ;.k ÅtkZ = 105 – 30 = 75 kJ/mole
SECTION – 2 : (Maximum Marks : 20)
 This section contains FIVE (05) questions. The answer to each question is NUMERICAL VALUE with two
digit integer and decimal upto one digit.
 If the numerical value has more than two decimal places truncate/round-off the value upto TWO decimal
places.
 Full Marks : +4 If ONLY the correct option is chosen.
 Zero Marks : 0 In all other cases
[kaM 2 ¼vf/kdre vad% 20)
 bl [kaM esa ik¡p (05) iz'u gSA izR;sd iz'u dk mÙkj la[;kRed eku (NUMERICAL VALUE) gSa] tks f}&vadh; iw.kkZad
rFkk n'keyo ,dy&vadu eas gSA
 ;fn la[;kRed eku esa nks ls vf/kd n’'keyo LFkku gS ] rks la[;kRed eku dks n'keyo ds nks LFkkuksa rd VªadsV@jkmaM
vkWQ (truncate/round-off) djsaA
 vadu ;kstuk :
 iw.kZ vad % +4 ;fn flQZ lgh fodYi gh pquk x;k gSA
 'kwU; vad % 0 vU; lHkh ifjfLFkfr;ksa esaA

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21. 108 g of silver (molar mass 108 g mol –1) is deposited at cathode from AgNO3(aq) solution by a certain
quantity of electricity. The volume (in L) of oxygen gas produced at 273 K and 1 bar pressure from water
by the same quantity of electricity is _________________
,d fuf'pr fo|qr ek=kk }kjk AgNO3(tyh;) ls 108 g flYoj (eksyj nzO;eku 108 g mol–1) dSFkksM+ ij fu{ksfir fd;k
x;kA fo|qr dh mlh ek=kk }kjk 273 K rFkk 1 ckj nkc ij cuk;h xbZ vkWDlhtu dk vk;ru (L esa) gksxk
_________________
Ans. 5.66 to 5.67
Sol.  nAg deposit  108
108
 1 mole
Ag   e–   Ag
1F charge is required to deposit 1 mole of Ag
Ag ds ,d eksy fu{ksi.k ds fy, 1 F vkos'k dh vko';drk gksrh gSA
1
H2O   O2  2H   2e –
2
1
2F charge deposit   mole
2
1
2F vkos'k fu{ksfir djrk gS   mole
2
1
1F charge will deposit   mole
4
1
1F vkos'k fu{ksfir djrk gS   mole
4
nRT
VO2 
P
1 0.08314  273
= 
4 1
VO2 = 5.674 L
22. How much amount of NaCl should be added to 600 g for water ( = 1.00 g/mL) to decrease the freezing
point of water to –0.2ºC ? __________. (The freezing point depression constant of water = 2 K kg mol –1)
600g ikuh ( = 1.00 g/mL) esa NaCl dh fdruh ek=kk feyk;h tk;s fd mldk fgekad ?kVdj –0.2ºC gks tk;s ?
__________. (ikuh ds fy, fgekad voueu fLFkjkad = 2 K kg mol–1)
Ans. 1.74 to 1.76
Sol. Tf = 0.2°C
Tf = ikfm
w 1000
0.2 = 2×2× 
58.5 600
0.2  58.5  600
w
1000 4
1.2  58.5

40
= 1.76g

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23. The hardness of a water sample containing 10–3 M MgSO4 expressed as CaCO3 equivalents (in ppm) is
_____________.
(molar mass of MgSO4 is 120.37 g/mol)
10–3 M MgSO4 okys ty ds izfrn'kZ dh dBksjrk ftldks CaCO3 lerqY; (ppm esa) vfHkO;Dr fd;s tkus ij] gksxh
_____________.
(MgSO4 dk eksyj lagfr (molar mass) 120.37 g/mol)
Ans. 100.00 to 100.00
Sol. 10–3 molar MgSO4  10–3 moles of MgSO4 present in 1 L solutions.
10–3 eksyj MgSO4  1 L foy;u esa mifLFkr MgSO4 ds 10–3 eksy
nCaCO3  nMgSO4
103  100
ppm(in term of CaCO3 ) = × 106
1000
ppm(in term of CaCO3 ) = 100 ppm
24. The mass percentage of nitrogen in histamine is _____________

fgLVSfeu esa ukbVªkstu dh nzO;eku izfr'krrk gS _____________
Ans. 37.80 to 38.20
N NH2
Sol. Structure of Histamine is
NH
Molecular formula of Histamine is C5H9N3
Molecular mass of Histamine is 111
42
Percentage nitrogen by mass in Histamine =  100 = 37.84%
111
N NH2
Sol. fgLVkfeu dh lajpuk NH
fgLVkfeu dh vkf.od lajpuk C5H9N3
fgLVkfeu dk vkf.od nzO;eku 111
42
fgLVkfeu es nzO;eku ls ukbVªkstu dk izfr'kr =  100 = 37.84%
111
25. The molarity of HNO3 in a sample which has density 1.4 g/mL and mass percentage of 63% is
__________. (Molecular Weight of HNO 3 = 63 )
ml izfrn'kZ esa] ftldk ?kuRo 1.4 g/mL rFkk nzO;eku izfr'krrk 63% dh gks] HNO3 dh eksyjrk gksxh __________.
(HNO3 dk v.kqHkkj = 63 )
Ans. 14.00 to 14.00
Sol. 63% w/w HNO3 solution foy;u
63  1.4
M= × 1000 mole/L = 14 mole/L
63  100

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PAPER-3 (B.E./B. TECH.

JEE (Main) 2020

Duration: 3 Hours | Max. Marks: 300

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2. The correct order of heat of combustion for following alkadienes is :

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5. The electronic configurations of bivalent europium and trivalent cerium are :

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8. The major product (Y) in the following reactions is :

CH3 CH3 CH2 CH3

CH3 O CH3 OH CH3

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10. Identify (A) in the following reaction sequence :

fuEu vfHkfØ;k vuqØe esa (A) dh igpku dhft, &

200 400 600 800 1000 1200 1400 1600

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fuEu fp=k ds vuqlkj A, BO2 dk vip;u djrk gS tc rki gS %

200 400 600 800 1000 1200 1400 1600

13. If the magnetic moment of a dioxygen species is 1.73 B.M., it may be :

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fuEu fo;kstu ds fy;s Ksp dk eku 1.6 × 10–5 gS]

15. If enthalpy of atomisation for Br2(I) is

Hatomisation = Hvap + Bond energy

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Sol. Number of Geometrical Isomers in square planar [PdFClBrI]2– are = 3

17. The de Broglie wavelength of an electron in the 4th Bohr orbit is

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20. For following reactions

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24. The mass percentage of nitrogen in histamine is _____________

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