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• Rotary filters
• Water additives
• Nuclear decommissioning
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products more environmentally acceptable and improving its environmental profile. He is well
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16
Interview with
Dr David Carmell,
BWA Water
Additives’ CEO &
chairman Technology
8
News
Contents • Features
IFAT Germany previewed 14
Looking ahead to the high-profile exhibition in Munich
• Editorial 1 during May.
In his editorial, managing editor Alan Burrows discusses the views
of BWA Water Additives’ CEO and chairman Dr David Cartmell. BWA Water Additives’ boss speaks out 16
We interview Dr David Cartmell, CEO and chairman of BWA
Water Additives, about the environment and the filtration
• Industry news 4 industry's responsibility towards it.
All the latest news from the filtration sector. Filtration in nuclear decommissioning 20
Chris Chadwick and Adam Swain of Porvair Filtration Group’s
Nuclear Services Division put forward their views on some of
• Technology news 8 the most important considerations for those involved in filtration
Our overview of the latest technical advances and developments in in the nuclear industry.
the industry.
Filtration and sedimentation in clean water production 24
Ken Sutherland looks at the role of filtration and sedimentation
in the production of safe drinking water, and of pure water for
other purposes.
14
Event Preview
Drinking &
24
other pure water
production
Process water
28
Water &
16 wastewater
Dates to remember
• 4-7 March • 7-8 April
Smagua, Zaragoza, Spain Global Water Summit, Paris, France
IDE Technologies’ reverse osmosis solution chosen for India’s largest desalination plant
IDE Technologies has announced water capacity needs of the “Over the past several years, to taking our partnership to the
that Reliance Industries, India’s plant at one of India’s largest oil we’ve established a strong next level. We are excited that
largest private sector company, refineries. partnership with Reliance built one of India’s largest seawater
has ordered its first seawater on trust and success with our desalination plants is to follow in
reverse osmosis (SWRO) The new SWRO plant will yield reliable desalination solutions,” the tradition of our other large-
desalination solution from IDE. pure processed water. The plant said Avshalom Felber, CEO scale SWRO plants, including our
will be close to the sea, decreasing of IDE Technologies. “With leading projects.”
Reliance chose IDE’s SWRO the length of pipes and thereby Reliance’s first installation of our
solution to meet the increased reducing costs related to pumping. SWRO solution, we look forward www.ide-tech.com
SOME THINGS ARE
HARDER TO GET
THROUGH THAN OTHERS.
ABSOLUTE™ –
THE MOST RELIABLE HEPA FILTER
Absolute™ is the most reliable HEPA filter when
you want to protect people and process air from
dangerous particles.
Absolute™ air filters is a series of high quality HEPA filters. Whatever your
needs are, there is an Absolute™ filter for you. Absolute™ filters are avai-
lable in several sizes in plastic, metal and wood frame.
www.camfil.com
10 Technology news
Filtration+Separation January/February 2014
Composite mesh filter by Porvair DOW goes global with Tequatic Plus Fine
offers high cleaning efficiency Particle Filter deliveries to China and Europe
Dow Water & Process Solutions separation and solids collection
has introduced the Tequatic Plus into one device to meet the
fine particle filter to the China demands of extreme water
and European markets in October environments. It is unique to
and November respectively, The the tough water space, reliably
move comes one year after its handling high and variable total
launch in North America. suspended solids up to 10,000
mg/L without frequent filter
Since then, the company has said, changes, even in the presence of
it has gained momentum in many oil. These features enable it to
applications for difficult, high- overcome the shortcomings of
solids water, including industrial conventional technologies such as
wastewater treatment and reuse, bag and cartridge filters.
supported by a new manufacturing
plant in California. John Patrin, global marketing
manager, Filtration, cited a
“Customers have a growing recent success in the wastewater
need to protect important water treatment and reuse market at a
The four and five layer composite meshes are produiced as self-supporting cylinders. resources with a cost-effective, meat processing plant.
high-performance solution,” said
Porvair Filtration Group has slurry oil filters, the multi-layer Cedella Beazley, business unit “When integrated into an
introduced four and five layer composite mesh filters are director, Filtration, DW&PS. existing wastewater treatment
composite mesh filters, produced designed to be cleaned in-situ. system, the Tequatic Plus filter
at its US facility in Ashland, “The Tequatic Plus filter can help removed 98% of the solids above
Virginia, that provide extremely These new products offer the customers improve the efficiency 20 microns – using a 35-micron
high efficiency filtration in both highest cleaning efficacy of any of their operations while also filter – in a feedwater stream
gas and liquid applications. conventional metallic filter, the reducing their environmental containing total suspended solids
company claims, combined with footprint through, for example, levels of 2,000 mg/L above 20
The new four and five layer good permeability to maintain less waste, high water recovery micron,” he said. “This was
composite meshes are made as good throughput of filtered media. and high uptime.” achieved with no fouling or
self-supporting cylinders that, backwash cycles, and with a 99%
when incorporated into dedicated Porvair Filtration Group is an The filter combines the power water recovery.”
filtration systems, enable routine international business involved of continuously cleaning, cross-
filtration down to sub-micron levels. in the development and supply flow filtration with centrifugal www.dowwaterandprocess.com
of materials and products for
Suitable for use in a wide range applications in filtration and
of applications such as critical separation. ‘Revolutionary’ programme for sustainable
chemical filtration duties and for
high challenge backwash refinery www.porvair.com
wastewater treatment is rolled out by US
duo Chemtreat and World Water Works
Andritz Separation claims reduction in power USA-based companies Chemtreat The ACP combines World
consumption of up to 40% with centrifuges and World Water Works claim Water Works’ wastewater
their partnership will deliver a technologies with Chemtreat’s
International technology group for the scroll drive, which cuts ‘revolutionary’ new system for chemical solutions to gain a
Andritz has launched a new series power consumption by reducing sustainable wastewater treatment highly efficient and economical
of decanter centrifuges for the frictional and electrical losses in the industrial sector. result with proven reliability.
environment sector, achieving up from pulleys, belts, motors, and Using services from each
to 40% less power consumption, variable-frequency drives. They have launched the Assured company, the team’s engineers
while maintaining throughput Compliance Program (ACP), and technicians evaluate every
and efficiency. Further advantages are a solution that uses ‘the most aspect of the problem before
the Andritz TurboJet weir plates advanced’ wastewater automation implementing a customised
The new series was developed at the (also available as retrofit for many and control technology to solution.
company’s Center of Competence decanters) and the High Hydraulic deliver lowest lifecycle treatment
in Châteauroux, France, to counter Pressure (HHP) decanter design to costs while ensuring sustainable Solution development
rising power costs and enable cut the power loss. The combined environmental compliance. includes in-depth exploration
customers to obtain an attractive effect of these features accounts of opportunities for water
return on investment. for up to 40% power savings The programme, specifically reuse, resource recovery, waste
claims the company, and therefore tailored to each customer, uses minimisation, and energy and
Its power-saving features are reducing operating costs and total a proprietary automation and chemical reduction.
available on the new D5 to cost of ownership. control system that provides
D10 decanters and benefit robust, automated, and highly www.chemtreat.com
from a direct-drive gearbox www.andritz.com reliable industrial process control. www.worldwaterworks.com
Technology news 11
Filtration+Separation January/February 2014
Make plans to attend the largest filtration and separation technical conference in the U.S.
Visit http://spring.afssociety.org/ for more information and to see the conference schedule.
Plenary Sessions (include, but not limited to): Technical Sessions (include but not limited to):
Quality control of potable water Veolia unveils software aimed to help change
via Automatic Particle Counting attitudes to municipal wastewater treatment
Engineers at Veolia Water
This particle counter measures Solutions & Technologies have
online during operation. If pre- developed a software package,
defined limits are exceeded, the Ocean, which is aimed to help
WaterViewer will instantaneously change attitudes and approaches
give an alert, ensuring that any to municipal wastewater
deterioration of the water quality treatment.
is known and communicated.
‘A sewage treatment plant should
For condition monitoring, no longer be viewed as a disposal
the PAMAS WaterViewer facility,’ the company’s literature A summary of the useful features of Ocean.
may be connected to up to 32 states.
measuring points. With the aid of as retrofits like improved process
microprocessor controlled valves, it ‘It can be an opportunity control or capital investments
is easy to change between measuring to generate energy, recover like thermal hydrolysis.
The Pamas waterviewer. points and bypass connections. resources, and recycle water
The PAMAS WaterViewer may be thus reducing our reliance on Ocean calculates energy balances,
German-based company PAMAS fitted optionally with an automatic fresh water supplies. Ocean sludge production and carbon
is preparing to showcase its Sensor Flushing Unit, the can contribute to this by, for dioxide emissions so that the
WaterViewer product at this PAMAS SFU. This attachment example, identifying energy- options can be properly evaluated.
year’s Analytica 2014 event in will automatically remove saving solutions and changing
April, and IFAT the following mineral deposits (eg, manganese, wastewater treatment from a net The inputs to the software are
month. calcium, iron oxide, etc) from the importer of resources into a net the treatment process units, the
optical cell windows which may exporter.’ design loads and the operating
The device takes measurements otherwise diminish the laser light parameters.
online and is installed as a fixed beam. The instrument works 24 ‘’Raw sewage has a potential to
stationary instrument for water hours a day without the need for generate 0.6 kW/m3, but most Using benchmark data collected
condition monitoring. It is used supervision, PAMAS states. of this is lost in the treatment from over 3,500 Veolia municipal
for the cleanliness control of process,” said Kieran Healey, wastewater treatment plants
potable water, raw water and The WaterViewer can be seen at synergies and integration manager around the world, Ocean
purified waste water or process the two shows this Spring. of Veolia. constructs a plant model including
water. chemical consumption, sludge
www.pamas.de “With a typical plant consuming production, energy balance and
0.3 – 0.4 kW/m3 of raw carbon dioxide emissions.
wastewater treated, there is
Biwater awarded North Carolina clearly potential for improving
energy sustainability.”
Ocean displays these graphically
so that alternatives can then
reverse osmosis project contract be quickly compared against
To achieve this improvement the current parameters to
Biwater has been awarded a RO trains; as well as providing it is necessary to know how the assess potential performance
reverse osmosis (RO) contract appropriate chemical dosing various treatment process units improvements and cost-savings.
for use in North Carolina, USA, systems, pre-treatment cartridge interact with each other so that
by T A Loving Company to filtration, plant instrumentation, options can be identified – such www.veoliawaterst.com
support Dixon Water Treatment PLC, supervisory control and
Plant improvement works being data acquisition (SCADA) and
carried out by Onslow Water and Remote IO stations. Tosoh launches its latest separation media
Sewer Authority (ONWASA) in
Jacksonville. Commenting on the contract Tosoh has launched its new high-performance separation
award, Richard Smith, director separation media Toyopearl AF-r media that achieves 30% to 50%
Biwater’s RO system will increase for the Americas, Biwater Protein A HC-650F. greater antibody adsorption than
Dixon Water Treatment Plant’s International, and president, similar products, the company
potable water production Biwater AEWT, said: “With The biopharmaceutical industry claims.
capacity, and comply with new the largest installed municipal is growing rapidly, and Protein
Environmental Protection membrane treatment capacity A–affinity separation media is That represents binding capacity
Agency (EPA) standards, in North America, Biwater necessary for the purification of 70 grams of antibody volume
removing silica and organics from continues to lead the way. We of monoclonal antibodies in per litre of separation media. Even
the influent. continually ensure that the latest the production of antibody when Toyopearl AF-r Protein A
technology is incorporated in biopharmaceuticals. Tosoh’s new HC-650F is used on high titre
This design, manufacture, our designs and environmental Protein A–affinity separation samples, its high adsorption
supervise and commission standards are adhered to, and media exhibits high binding ensures quality antibodies, the
contract will see Biwater where possible, exceeded.” affinity, alkaline resistance, and Japanese company states.
delivering three one million mechanical stability. Toyopearl
gallons per day (MGD (US)) www.biwater.com AF-r Protein A HC-650F is a www.tosoh.com
Technology news 13
Filtration+Separation January/February 2014
Leading Manufacturer of
specialist Activated Carbons
Eurocarb, the European subsidiary of Haycarb plc, offers a complete range of Activated Carbon products for
Gas and Liquid purification. Extensive facilities in the UK are backed up by parent company manufacturing
and product innovation capabilities, allowing rapid delivery of high quality products throughout Europe,
matching precisely the needs of our customers.
14 Events
Filtration+Separation January/February 2014
Show preview:
A sneek peek
at what’s in store
for IFAT 2014
xclusive previews and pre-show announcements were the order of
E the day at the IFAT ‘media dialogue’ early in the New Year. The ICM at
the Munich trade fair centre hosted the event, which drew over 150
exhibitors and journalists to Germany four months before the event itself.
In January this year 80 journalists industry marketing water sustainable natural resource on show. The company’s new
travelled to Munich to meet with solutions, who attended the management.” Turbulence Optimiser for these
around 70 companies preparing to media dialogue especially to pumps increases efficiency by 2%,
exhibit at this year’s IFAT show. launch the solid/liquidation Ultrafiltration technology Grundfos claims, and delegates
The event was a preview of the separation advance. specialist Inge, which became at the exhibition will be able to
exhibition which will be held part of BASF in 2011, will also see these as two-metre-high KPL
over five days, May 5-9, in the “Today’s industrial and municipal have a presence at IFAT, and pumps at the company’s stand.
German city. water treatment plants are will be highlighting its Multibore
challenged to achieve maximum membrane solution. Grundfos also reported that it
Organisers chose the special performance under increasing cost has developed the Grundfos KLP
preview to announce that IFAT pressure. Grundfos was equally newsworthy, Pump App, for free download
2014 was now fully booked, with its plan to launch ‘new key from Apple – the Google Play
with 3,000 exhibitors scheduled “Zetag Ultra has proven its developments’ to its Optomised version is coming soon, the
to attend in 230,000m2 of excellent performance in a variety Water Solutions at IFAT. company has said – to show
exhibition space. It was also of extensive plant trials worldwide. how the pump’s features provide
announced that the showcase will Our customers report that “We are raising the bar for benefits to customers and IFAT
also host Germany’s GreenTec cake solids of dewatered sludge sustainable product solutions attendees are invited to Grundfos’s
Awards – billed as ‘Europe’s increased on average by 15%, within energy efficiency and stand to have their picture taken
largest environmental and which is a step-change. Other water,’’ said Tao Bindslev, beside the ‘augmented reality’
business prize’ – with many of customer cases show a significant Grundfos’s group vice president. pump.
the exhibitors who attended the dose saving of up to 20%.”
preview entering the competition. A new ‘Demand Driven Alfa Laval, the global provider of
GreenTec’s awards night will be Mr Fuest said the company was Distribution Controller’ helps specialised engineering solutions,
staged on the eve of IFAT itself. advantaged because it could reduce water leakage losses and will highlight its Iso-Disc cloth
‘bundle’ its expertise in its various gives ‘unbeatable efficiency’. media filters which allows for
The preview itself attracted some divisions into business-facing Building on its 2012 IFAT launch high-quality effluent and its
of the major names who will units, and market solutions to – the company’s SE/SL heavy screw press for effective sludge
attend in May, including BASF, those who need them. duty wastewater pumps with dewatering.
which launched its new cationic S-tube impeller – the business
powder flocculant range with Matthias Halusa, vice president of will reveal a new range extension The Iso-Disc is a new product
Zetag Ultra for high dewatering BASF’s Water Solutions business, within the SE/SL portfolio at this from the company, based on
performance at low dosage rates commented: “The introduction year’s event. technology from US-based
at the preview event. of Zetag Ultra is an important Ashbrook Simon-Hartley which
milestone for positioning BASF as Grundfos confirmed it plans to Alfa Laval acquired in 2012. The
“We’ve developed this because a leading provider of innovative have its improved KPL and KWM filters capture solids to 10 microns
we saw a special market need,’’ chemical solutions in the water Axial and mixed flow pumps in size, without having to build
said Marcus Fuest, BASF global industry worldwide, supporting for flood control applications up a filter mat and without any
Events 15
Filtration+Separation January/February 2014
acquisition had given extra funds at flow levels as low as 3cm. i Test Equipment validation
i Instrument calibration
for Aquabio to bid and invest in i Supply of APC calibration suspensions
large developments, including The complete “Mini” sensor i R&D of new test methods for ISO, CEN and industrial customers
BW Water Additives
Inside the
water world of
a sustainable
solution finder
iltration+Separation interviewed Dr David Cartmell, executive
F chairman and CEO of BWA Water Additives, and asked him about
the character of his company and its product launch at Aquatech.
BWA Water Additives’ executive chairman should be approaching our work, how do we
and CEO Dr David Cartmell is passionate achieve the long-term view, and our long-term
about his company’s environmental work, view to me is a better environmental profile.’’
and that its biodegradable credentials are
strong – so much so that his philosophy is that He believes if more companies in the
BWA’s products and their contact with the sector adopted the same approach ‘‘things
environment must go above and beyond the could move forward for the better, not just
regulated levels set. the water industry but for the whole chemical
industry’’.
‘‘If I was just taking a short-term, hard-
nosed business decision, I’d say ‘we meet the But what about his company, how does it
regulations, we’ll sell the cheapest product operate?
we can, and try and get the most sales we
can’,’’ he says. ‘‘But instead I believe I’ve got a ‘‘We’re different,’’ says Dr Cartmell. ‘‘We only
responsibility as CEO of a good-sized chemical sell to one market. We sell a whole range
company, I want to do something for the of products, but we only want to sell to one
environment as well as make money.’’ market, because we want to understand that
market from top to bottom.’’
Dr Cartmell doesn’t mince his words. Long-
experienced in the water industry, he has That specialisation is what his company
helped BWA steer a path towards a stronger is all about, he says; it is that and industry
financial future with North American knowledge that sets BWA Water Additives
investors while keeping a refreshing, apart from the others in this competitive
principled view on the company’s work and sector, Dr Cartmell insists.
on-going legacy.
‘‘We’re a specialty water treatment chemicals
‘‘I think that there’s more responsibility company, and actually there’s very, very few
to business leadership than just making of those around, because most chemical Dr David Cartmell: Wants to take the industry forward.
profit,’’ he says. ‘‘We’ve got to take the companies are product-focused in that they
industry forward, and I think having a better sell a particular range of products, but sell it to ‘‘Also, what most of our customers appreciate
environmental profile is what people want. a number of different markets. from us is a chemical ‘+’ knowledge, because
Ask the UK population what do you think we we know how to use our products in the
should do – make a little bit more money, or ‘‘So most companies will say they are market- market, and we can advise the customer.’’
make our products a bit safer, not just safer but focused,’’ he smiles, ‘‘but we truly are, because
more acceptable to the environment? – and we’re a single market-focused business, and The majority of the ‘technology people’ BWA
they’d go for the latter. That’s how I think we that’s our differentiation. employs in sales and marketing, he says,
Feature 17
Filtration+Separation January/February 2014
Specialisation is what the company is all about, says Dr Cartmell. BW Water Additives: An exceptional knowledge bank.
come from the water industry, therefore Dr give you Legionnaire’s Disease; or algae, ‘‘But put antiscalant in the water, it will keep
Cartmell suggests that the company knows its the green slime, or general slime, but general those wells clean, and that’s what we’re about
customers’ needs very well. bacteria. as a company.’’
‘‘We’re giving them a knowledge [bank] as ‘‘And then the third thing to look at is One of the other markets Dr Cartmell
well as ‘the product in the drum’, and that’s corrosion of steel, the corrosion of metals like mentions is what he terms as the ‘classic
why we’re successful in what we do, and why mild steel, or even copper and brass. industrial water treatment market’ – cities
people come to us.’’ populated by air-conditioning towers, and
“So, scale control, microbiological control, desalination. This is a specialty for the
Dr Cartmell says the company’s success is and corrosion are the three main product company, and one that Dr Cartmell claims
due to this in-depth knowledge which can be groups that we treat.” BWA is the market leader of in terms of
called upon when problems occur in the water selling chemicals into desalination globally,
sector. Target market especially in the Middle East.
‘‘If anybody has a problem in water, a real ‘‘Wherever water problems occur,” states Dr ‘‘Much of the Middle Eastern market is
sticky situation perhaps, they call on us first, Cartmell, ‘‘that’s my target market.’’ thermal desalination,’’ he says. ‘‘Basically,
because we’ve got that technical leadership you’re boiling the water, you’re boiling
position in the market space, and the These problems occur, for instance, in North seawater and collecting the steam, but
knowledge. That’s what our goal is – to be Sea exploration. obviously in a vast plant that again can scale
the high performance, high knowledge-based, up in a matter of hours, or a day or so, without
chemical producer.’’ antiscalant.
“That’s what our goal is – to
BWA’s business is concentrated in the water be the high performance, high ‘‘So we supply the chemicals that go into
industry, but it is one that has implications that, and we have about a 60% market share
for other sectors, Dr Cartmell explains. For
knowledge-based chemical
worldwide of that market, but most of that
instance, regarding scale that is found at the producer” market is in the Middle East.’’
bottom of kettles in residential hard water
areas. It is this, in an industrial size, that his ‘‘To get the oil out of the ground, you pump And the company is involved in reverse
company is tasked to prevent, he explains. seawater into the ground,’’ explains Dr osmosis, or the membrane market which,
Cartmell, ‘‘that’s how it works. significantly, due to global differences, BWA
‘‘If scale occurs in a massive plant, like a produces solutions for on an individual-
large desalination plant, or a cooling tower, ‘‘So basically, when that seawater goes in the problem-solving-basis, rather than developing
or down an oil well, [the operator] is putting ground, it’s going to be heated up, it’s under bulk treatments.
themselves in a difficult position, because it’s pressure, and it mixes with other water that’s
pretty hard stuff, you want to prevent that. already down there, and that then starts the ‘‘Everybody thinks H2O is simply H2O,’’ Dr
formation of scale. Cartmell explains, ‘‘but what gives all the
‘‘So we prevent that happening; we don’t problems is all the other stuff that naturally
clean it up, we prevent scale from forming, ‘‘If you get the scale, like calcium carbonate occurs in water, from dissolution of rocks, or
that’s the first matter to consider. or calcium sulphate, happening in those calcium, magnesium.
wells, all those millions of dollars spent
‘‘Secondly, bacteria. We sell biocides, which drilling out those wells is going to be ‘‘For example, seawater around Australia has
kill bacteria such as legionella, that can completely wasted. got a much higher level of magnesium than
18 Feature
Filtration+Separation January/February 2014
Dr Cartmell says the company continues to strive to improve the environmental profile of its products.
breaks down quickly, then I think that’s really ‘‘But then there’s a whole range of the market ‘‘So we did a private equity backer buyout in
what people should be looking for.’’ that likes to have the product they sell to the 2006 with a UK PE firm, and then we did a
end user to be really effective,’’ he enthuses, secondary buyout in 2008 with a Middle East
Dr Cartmell said the company continues to ‘‘and that’s the customer groups that we have. private equity group.’’
work hard to achieve more on the overall
environmental profile of its products. ‘‘So we have a very loyal customer base, Then, in 2011, the company was given the
because once people start using that higher financial backing from a private American
‘‘It must be safe to handle, safe for the performance product, they don’t really want to family which Dr Cartmell is very happy about.
environment and easy to detect when in use,’’ move away from it.’’
he says, ‘‘so we put that ‘engineering’ into it, if ‘‘It’s a family investment company, which
you will, adding to its value.’’ Another characteristic of BWA’s products Dr means that they take a long-term view, and
Cartmell wants to underscore is that they are we’re in a very good position,’’ he says.
In terms of profile, BWA’s products are higher all developed in-house, from the company’s
priced than its competitors, but its customers own research teams which, he proudly says, ‘‘Since 2011, for the first time in many
understand this, Dr Cartmell says. has been a continuous feature of the business years, we’ve been able to take a long-term
over the last ‘25, 30 years’. view to investment in technology, so we are
‘‘Our products are, in general, ‘higher looking at that three, four, five-year [product
performance’, but then there’s a premium to It’s time to discuss briefly the company’s development] window.’’
pay for that,’’ he says. ‘‘So when it comes to history, and what its plans are for the
the customers, there’s clearly a portion of the immediate future. Dr Cartmell says the company has now moved
market that will not pay a premium, because into a period ‘great stability’ which is allowing
they’re at the lower end of the market, and ‘‘The business was created in 1973,’’ he says, for more investment in technology than
they’re not too worried about their plant ‘‘and has been part of a number of large multi- previously in its history.
downtime and problems from scale and national chemical companies.
biological fouling. Following its launch at Aquatech and its
‘‘They were all multi-billion dollar chemical financial credentials, it is clear that BWA is a
‘‘Our product isn’t suitable for them, because
if they don’t need that high performance
companies until, in 2006, I was able to buy
out the business and take it independent with
company to watch out for in the future. •
product, they aren’t going to pay for it. private equity. www.wateradditives.com
20 Feature
Filtration+Separation January/February 2014
Nuclear power
Filtration in nuclear
decommissioning
uclear filtration in general – and developments for filtration in the
N field of nuclear decommissioning in particular – pose some of the
most diverse and technically demanding challenges in engineering.
Here, Chris Chadwick and Adam Swain of Porvair Filtration Group’s
Nuclear Services Division, put forward their views on some of the
most important considerations for those involved in future filtration
applications for the nuclear industry.
The nuclear industry presents filtration Many problems in the nuclear industry, more often than not
professionals with a range of unique and the circumstances dictate the requirement
difficult challenges, demanding to the highest When developing filtration solutions for for custom-designed solutions delivered by an
levels of technical expertise, quality and social nuclear applications, the following problems engineering company, fully expert in filtration
responsibility. Due to the nature of this sector are amongst some of the factors which should and both capable and willing to meet the
a cavalier attitude is not acceptable and often be considered: chemical attack, high and low demands of the industry.
only a custom-designed solution should be temperatures, gross quantities of fine solids,
considered. radiation, and even the need for the reactor One particular area which regularly
to be remotely handled. This non-exhaustive features on the industry agenda is one
The requirements for applications in nuclear list of parameters presents the engineer with which does not immediately fall into the
filtration are far from 'off-the-shelf'catalogue an intricately interconnected set of problems category of decommissioning, but is of vital
products. They require a dedicated, meaning that even the most optimised system importance and serves as a good example
engineering analysis to present a tailored is only ever a compromise, rather than an of the complexities presented by a typical
solution and often require several iterations ideal solution. Taking these factors into application. In the language of water cooled
of the original concept to offer the customer a account highlights the fact that although reactors (PWR, BWR, CANDU, RMBK,
fully optimised solution. there is a place for standard products with VVER, etc.) a LOCA is a ‘Loss Of Coolant
Accident’.
Precautionary equipment
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The level of suspended solids makes the treatment of river water quite complex. Picture courtesy of Shutterstock.com
changing so as no longer being willing to The purification processes that are used to with a possible UF membrane filtration as a
accept what was once acceptable, in terms of achieve the required reduction in contaminant polishing step, and maybe a separate softening
taste, odour, colour and turbidity. levels are a mix of traditional schemes, which step as well.
have been steadily improved over the years,
Water treatment processes and novel systems that are quite exciting River water treatment is more complex,
developments. The treatment processes are because of the greater level of suspended
The steadily improving processes for fresh designed to deal with the problems of: solids:
water treatment, leading to a sanitary drinking • colour (from dissolved organic molecules • disinfection, probably combined with Fe
water, are needed firstly for the conventional mainly); and Mn removal;
purification of raw water, drawn from surface • turbidity (ie, suspended solids); • clarification (involving flocculation and
and underground sources, to provide water • taste and odour (dissolved organics); gravity settling or flotation);
of a safe drinking quality. Increasingly, this • hardness (from dissolved inorganics); • deep bed filtration; and
is extended to include the treatment of • corrosiveness (from divergence, either way, • disinfection;
unconventional sources of water so as to from pH = 7); and
increase the quantity of fresh water that is • harmfulness to human and animal health. maybe with a UF membrane process, for final
available. These unconventional sources particulate and colour removal (which may
include the desalination of salt and brackish Disinfection alone may be enough to produce also use carbon adsorption).
waters, the collection and recycle of rain water an acceptable drinking water from relatively
and of grey water from residential premises, pure groundwater. Where water is needed and only salty water is
and, as public conceptions start to change to available, then a desalination process will be
accept it, the recycling of municipal waste Drinking water production necessary, usually involving:
waters. • clarification, probably with flocculation
The processes used to treat raw water in and settling or flotation;
These two groups of treatment process bulk depend obviously on the source of the • multi-layer deep bed filtration;
provide the means to satisfy human needs water – whether it be from underground • successive membrane processes, UF
for adequate drinking water, from a wide aquifers (and therefore clean but hard) or followed by RO; and
range of raw water supplies. In addition there from surface water (and therefore polluted but • remineralisation to give the water its
is then a third group of processes, basically softer). Groundwater has the simplest process natural flavour.
intended to produce water of a higher quality, scheme:
by means of the further treatment of potable • soluble iron and manganese precipitation; (If energy is really cheap then a
water supplies, for use in specific industrial • deep bed filtration; and thermal desalination process may be
applications. • disinfection; preferred.)
26 Feature
Filtration+Separation January/February 2014
Process water
A new trend in
mobile water
treatment plant hire
lant breakdowns can be solved by hiring a mobile water treatment
P facility. However, with a mains water supply it is not always as simple
as that. The change of water supply from river to borehole, or vice
versa, on an industrial water treatment plant can be devastating. One
solution, writes Mark Dyson of Aquamove, is a mobile fleet including
a range of pre-treatment processes.
When Aquamove established its mobile No standby capacity treatment processes including coagulation
water treatment plant facility in the United and flocculation, clarification, filtration,
Kingdom, it was aimed at providing temporary Financial constraints often mean that there activated carbon adsorption and softening, all
solutions for plant breakdowns, planned is no standby capacity in the on-site water in modular configurations to provide the right
maintenance and commissioning. It was treatment plant, so when a vessel internal fails, process route to treat any raw water quality to
ultimately for temporary requirements, and or there’s a fire in the plant room, production achieve any treated water quality and quantity
that is still the main application, but over is at risk. When an emergency like this does required.
recent years a new trend has been developing: occur the simplest solution is to hire a trailer
long-term plant rentals. mounted mobile water treatment system while Expanding production
repairs are carried out. But the introduction
Initially the mobile fleet was equipped of common carriage and extended water While many of the applications for mobile
with just reverse osmosis and ion exchange supply networks has brought a different kind units are emergencies, not all of them
demineralisation to cover mechanical of problem. Mains water, unlike gas, oil and are about the nasty things in life. An
breakdown of on-site systems, and these electricity, is not always the same: seasonal algal unexpectedly full order book often creates an
are still the two most widely used packages. growth on a reservoir can increase the organic urgent need to expand production quickly,
Deionisation trailers typically provide content causing rapid fouling of ion exchange and a mobile plant can provide the additional
two streams of cation, anion and mixed resins and reverse osmosis membranes. treated water you need while you’re waiting
bed ion exchange which are capable of for a permanent plant to be installed.
producing 100 m3/h of 0.1 μS/cm high purity Another possibility is that the water supplier Sometimes companies need to carry out
water. may have to change the source of the water production trials, and may want to look at the
supply from river to borehole or vice versa, effects of water quality on their production
When the ion exchange resins are with a sudden and dramatic change in total processes.
exhausted, the complete trailer is returned dissolved solids. The water still meets the
to the central regeneration facility, requirements for drinking water but the effect Temporary deionisation plants provide a
which means zero discharge on-site and on an industrial water treatment plant can cost-effective means of finding out if it
no problems of handling or disposal of be devastating: Ion exchange plants designed is worthwhile making substantial capital
regenerant chemicals. Since the plant for thin, upland waters may have insufficient investment in a permanent plant. And, of
footprint is bigger than ion exchange, capacity to treat thicker borehole waters course, many mobile customers hire temporary
containerised reverse osmosis units are whilst those designed for hard, borehole plants to provide treated water during
generally capable of producing up to 25 waters may suffer from fouling by higher planned maintenance shutdowns of the water
m3/h of permeate of conductivity typically concentrations of natural organic matter in treatment plant and similar ‘non-emergency’
less than 2 0μS/cm in a single pass. If higher supplies derived from moorland reservoirs. situations. Over the last year the service has
quality treated water is needed, two units can provided, among many others, a filtration and
be configured in series as ‘twin pass’ giving To meet this demand, the mobile fleet reverse osmosis plant to treat an unexpectedly
permeate of less than 5 μS/cm. was expanded to include a range of pre- large volume of landfill leachate resulting
Feature 29
Filtration+Separation January/February 2014
All the equipment is installed in a standard 40 ft trailer which is insulated and supplied with heating and lighting so that, inside the container, the environment resembles most
plant rooms.
from high rainfall; a reverse osmosis system pressure boilers or even ultrapure water for of a cation exchanger, anion exchanger and
to upgrade a poorly performing river water semiconductor manufacturing. If the treated mixed bed polishing but this was failing to
treatment plant; and a reverse osmosis and water quality needs to be upgraded, it is an meet the 20μg/l silica water quality required.
deionisation plant to feed a power and steam easy matter to change the trailer for one using
utilities plant at a major chemical complex a more advanced treatment process. The initial solution was to provide three
during a planned outage. mobile temporary mixed bed polishers to
polish the water from the demineralisation
But, perhaps surprisingly, an increasing ‘Long-term rental of mobile water plant mixed beds and reduce the silica to
number of customers are making a case less than 10μg/l. Continuous treated water
for long-term hire. This may be because treatment solutions means the quality monitoring for conductivity and silica
the capital investment in a permanent was also provided. The ionic load on to the
plant would not pay back within the life
plant is available immediately, and mobile units is very low and exhaustion is
of the project – a nuclear power station has no associated capital cost’ infrequent. They are not regenerated on
decommissioning project and a limited site but returned to the central regeneration
life power station refurbishment were real station in exchange for a regenerated unit.
examples where this approach proved to be Waste plant example The “temporary” solution proved so reliable
cost-effective. and cost-effective that it is still in use more
Energy from one waste plant incinerates than twelve months later.
The temporary plant approach also provides 225,000 tonnes per year of non-recyclable
other advantages. The quality of the treated domestic waste to produce 400°C superheated Long-term rental of mobile water treatment
water is guaranteed and the treatment process steam in a 46 bar water tube boiler. This steam solutions means that the plant is available
is tailored to meet current water quality needs, drives a turbine which generates electricity for immediately, has no associated capital
whether that is for dealkalised water for soft export to the National Grid. Make-up water cost and does not require any housing: the
drinks manufacturing, purified water for for the boiler is produced in an on-site ion equipment is all installed in a standard 40ft
pharmaceuticals, demineralised water for high exchange demineralisation plant consisting trailer which is insulated and supplied with
30 Feature
Filtration+Separation January/February 2014
The trailers are kitted out with the appropriate safety equipment and are complete with all necessary instrumentation and controls.
heating and lighting so that, inside the Latest addition products; it can impair shelf life and taste.
container, the environment is just like most Remox is the first membrane degasser to be
plant rooms. The trailers are also maintained The latest addition to the range is Remox, available on the rental market and can treat
with the appropriate safety equipment and a membrane degassing process which up to 100 m3/h of water. The degassing system
complete with all necessary instrumentation removes carbon dioxide and oxygen from is fully automatic with on-line monitoring for
and controls. They can be positioned to make water. Dissolved carbon dioxide reduces the complete operational security and is complete
the best use of available space and connected efficiency of ion exchange and continuous with all necessary compressed air, nitrogen and
to existing pipework using flexible hoses. electrodeionisation processes. Membrane vacuum equipment.
degassing works by passing the water across a
In terms of process technology, the range is gas-permeable membrane, on the other side Operational problems with mobile plants are
almost unlimited. Mobile units are completely of which is a flow of atmospheric air. Carbon rare, there are hardly any chemical additions
modular, so any configuration of processes can dioxide transfers across the membrane from and no chemical handling and disposal issues,
be combined to make up a complete system the gas rich water to the carbon dioxide lean and regular maintenance service visits are
to suit any application, which means that inert gas. The process reduces dissolved carbon included in the hire contract. This means
borehole, river and reservoir waters can be dioxide to less than 0.3 mg/l. Replacing the that total operational costs can be forecast
handled as easily as mains waters. air with an inert gas – either nitrogen or water with a high level of certainty, and with no
vapour generated under vacuum – allows requirement for capital investment. If the
A typical temporary or mobile plant might dissolved oxygen to be removed. raw water quality changes, the mobile plant
consist of pre-treatment by multi-media can easily be reconfigured. No wonder that
filtration, organic scavenging or granular Oxygen causes corrosion in boiler systems so more temporary solutions are becoming
activated carbon adsorption in pre-treatment
trailers; reverse osmosis in a second trailer
it has to be removed from boiler feed water
by adding oxygen scavenging chemicals like
permanent. •
Contact:
and even mixed bed ion exchange polishing sulphite or carbohydrazide. Remox removes ELGA Process Water,
in a third. Temporary tanks and pumps can dissolved oxygen to less than 0.01 mg/l, Marlow International, Parkway,
also be provided in trailers together with all dramatically reducing the consumption of Marlow, Bucks SL7 1YL UK.
interconnecting flexible hoses, water meters oxygen scavengers. Dissolved oxygen in semi- Tel: + 44 (0) 1628 897000
and fittings, and, of course, mobile generators conductor rinse water can result in wafer sales.uk@veoliawater.com
to make the system completely stand-alone. surface defects and, in food and beverage www.elgaprocesswater.co.uk
meet
your
future
at
global
growth for
your
business
Development Trend:
Rotary fibre disk
filtration in the
treatment of
oilfield wastewater
urrently, the Rotary Fibre Disk Filtration (RFDF) is the proven tertiary
C filtration system for municipal wastewater treatment, but applying
RFDF technology to oilfield wastewater is challenging work. In this
article engineers Jian Jiang, Zongkuan Liu and Professor Yanling He
explore its uses in China.
According to the ‘12th Five-Year Plan’, Applying the RFDF technology to the the oilfields becomes increasingly high. And,
China’s accumulative total investment oilfield wastewater is both promising and statistically, China’s water injection rate has
will inject about 5.4 trillion RMB into challenging work. As China’s oil fields have reached 1 billion m3/a. For the produced
environmental protection, which has huge entered the late stage, the water injection of fluid with high water content, it not only
potential in the field of energy conservation
and as well as environmental protection
itself. It is clear that the new technology of
environmental protection will be a ‘sunrise
industry’ in China’s industrialisation process.
While the new filtering technologies play
an important role in the grand project, the
research and development of filters have an
important practical significance.
Figure 2: The RFDF consists of parallel filter disks installed vertically on the Figure 3: The filter cloth weaved by special process plays a vital role in
central conduit. the filtration process.
solves the problem concerning the source of it flows through the soaked fibre remain still. technology, the fibrous materials have
water flooding, but brings huge economic, With the accumulation of SS, the dirt-holding generally experienced two patterns – random
environmental and social benefits to oil fields, capacity and the filtration flux will decrease, and structured fibre.
so huge that oily wastewater was reinjected along with the rising liquid level. As a result,
after being processed. the system will eventually become full of Accordingly, the fibre filters have generally
trapped solids, at which point the filter must experienced short fibre filter, brush filter,
Consequently, discussing the application be cleaned by backwashing. HW depth filter, fibre-ball filter, comet-
of the RFDF technique, especially when fibre filter and long fibre bundle filter, etc.
applied to oil field wastewater filtration, is The PLC can automatically start the suction Although filters have made great progress, the
significant. It is, of course, true that broad pump to clean. Once started, however, it can deficiencies exposed in practical engineering
market prospects will motivate China’s water be controlled to switch the electric valve on hinder wide application of these systems
treatment market. the suction pump pipe, realising the alternate which highlight the small throughput, bad
cleaning among the filter disks. Because the backwashing, deposition in fibre core and the
The structure of RFDF contact area between suction device and vulnerable working conditions resulting from
filter cloth is very small, as for a single disk, fluctuation of inflow.
For a set of devices, the number of filter the instantaneous backwashing area takes
disks is commonly between two and 20. Each up about 1% of the whole filter area, which The RFDF may also be derived from the
filter disk is comprised of six preservative does not interfere with other filtering process, combination between short fibre filter and
sector plates covered with a fibre cloth. The especially in the multi-disk system, to achieve brush filter accordingly, linking the random
backwashing system is composed of a water a continuous filtration process. characteristic with regular characteristic.
pump, suction device and valve. A sludge This special structure not only keeps fibre
discharge system is composed of a sludge pipe, Trends in the oilfield wastewater media compacting under the hydraulic shock,
sludge pump and valve. Often, the sludge but prevents forming the washing dead zone
pump and backwashing water pump are one- From the development process of fibre because of the tangle fibres.
and-the-same. filtration technology, modern filtration has
entered into the ‘bottleneck period’. It is true In comparison, RFDF has the following
Note that as part of the filter, the filter cloth that seeking new growth must be considered advantages:
weaved by a special process plays a vital role from two aspects: 1) fibre media material and 1. Change the filtering surface vertically,
in the filtration process. The upright fibre structure; 2) filter form and structure. which can reduce footprint without adding
will droop until it is soaked with a valid filter area. The accessory equipment is
filtration depth 3-5mm. Furthermore, when It is worth mentioning that fibre has been compact and take up less space;
the equivalent bore diameter is only 10μm, applied to water-treatment as filter media 2. The filter disks are almost always in a
the fibrous filter media will capture the for decades. For such an application, fibrous state of filtering and the filtration system
particle in the valid filtration depth. When it media have attracted great interest due to needs less electric equipment, so the total
is backwashing, the fibre close to the suction their good properties, such as stable property, installed power is very low;
device will stand up again. As a result, it is larger specific surface area, greater holding 3. Backwashing water is less than 0.03% of the
convenient to remove the particles captured capacity, varying porosity and lower filter total circulation of water;
by the fibre, to achieve a perfect cleaning. resistance. In addition, the polymer fibre, 4. Automation control and low idleness ratio
a kind of flexible filamentous materials, of plant;
During an operation cycle, the running can be easily processed into various types 5. Easy installation and maintenance friendly.
process includes filtering, backwashing and of filter media according to the need of the
sludge discharging. The filter disks which filtering process. As we all know, during As for the application of RFDF, as mentioned
clarify water by depth filtration mechanism as the development process of fibre filtration above, these advantages of RFDF provide a
34 Feature
Filtration+Separation January/February 2014
Figure 4 and Figure 5: In 2007, a coking plant applied the TH10000 filter-a new type of RFDF to the circulating water system, which served for 1.1 million ton of coking items.
RFDF has the following advantages: small footprint, great throughput, automation control, easy installation and maintenance friendly. The system has been running well and the
control result is satisfying.
good opportunity to change from a municipal quartz sand, magnetite, walnut shell and other China’s water injection rate has reached
wastewater treatment to an industrial media replaced the single media of quartz sand. 1 billion m3/a, which certainly represents
wastewater treatment, especially to the oilfield a huge water treatment market. However,
wastewater treatment. It is proposed that the Although the filtering effect has improved, there the ‘out-moved’ water treatment facilities
effluent quality can achieve the injected water exist some technical problems, such as filter have been one of the factors restricting the
quality standard of a low permeability oilfield, material quality, grading, backwashing intensity development of oil industry, which provides a
through double slow sand filters (primary and backwashing methods. new stage for the fibre filtering technology.
filter speed 8m/h, secondary filter speed 4m/h),
as many tests have shown. But, at the same By 2008, the geological reserves of low At the moment, developing oil-resistance
time, it still has low speed, more filtering permeability oilfields accounted for 37.6% fibre has drawn attention. If the oil-resistance
tanks, large footprint, and so on. Therefore, of total reverses. With regards to the fibre combines with the advanced RFDF
the throughput should not be too large and low permeability oilfield, injected water technology, it will have a very promising
the processing scale is limited. Afterwards, the meeting the standards is the core issue of application in the future.
application of multi-layer media of anthracite, oilfield production. By this statistically,
Additionally, the geometric structure of the
fibre has a great influence on the performance
of fibrous filter. Researchers have applied the
model to the numerical simulation, while
numerical simulation results can be fed back
to the development of the fibre media model.
By this procedure, new fibre media with many
advantages such as great porosity, large specific
surface area, low pressure drop and high flow
rate will be designed, which is a better guide
to the development of RFDF. •
Contacts:
Jian Jiang (Assistant Engineer)
Tel: +86 183 9213 9229,
Email: jiangjian@stu.xjtu.edu.cn
Yanling He (Professor)
Tel: +86 138 9193 9065,
Email: heyl@ mail.xjtu.edu.cn
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36 Application
Filtration+Separation January/February 2014
Rainwater harvesting:
Vortex filters make
cost savings at
German hospital
hrough careful planning and the right filtration technology, rainwater
T harvesting and its use can result in significant savings in utility
costs. Architect Klaus Koenig of Ueberlingen, Germany outlines to
Filtration+Separation how this worked at a hospital in Bad Hersfeld.
Klinikum Bad Hersfeld in Germany, showing the town's clinic. Rainwater use in a hospital
Building services and modern medical certification of the central sterilisation In 1996, in an environmental guide, the
technology are complex issues in a hospital. A facilities according to DIN-ISO as well as Bavarian Ministry of State for Regional
working group for environmental protection integration of a RISK management system, Development and Environmental Affairs
was organised in the Bad Hersfeld clinic as were pre-requisites for the establishment of a wrote the following guidelines:
early as 1988. The management had already comprehensive quality management system.
pursued a stringent quality management The technical department, which is responsible Install model facilities in public buildings.
concept for many years. Certification of the for procurement and maintenance, was also Benefit from the fact that these buildings are
clinic as a whole with respect to environmental responsible for the most recently published open to the public and can be used to publicise
management (re-certification, EMAS II), environmental statement in 2011. the concept of rainwater harvesting. Using
Application 37
Filtration+Separation January/February 2014
Hygiene
Water demand rainwater by the system. In 2008, another warm into the sewage system. Today, rainwater
40 toilets for a 140-bed ward in the south flows through a closed circuit at 20°C into the
According to Heiko Kohlrenken, the officer part of the building were connected up to cisterns, where the waste heat is dissipated.
for environmental management and technical the rainwater system. This brought in further To keep the circulating water fresh, a certain
director at the clinic in Bad Hersfeld, overall savings of 1,613 m3 per year. share of the cooling water that is fed into the
water consumption has decreased over the circuit, is gradually replaced.
past five years from 3.06 m3 per in-patient to According to Kohlrenken, the cooling system
2.69 m3. Use of rainwater to water the grounds for vacuum pumps used in the sterilisation Compared with an approximate 80,000m3
was introduced during the first construction process is particularly effective. The steriliser of drinking water consumed in 1992, only
phase as early as 1995. A fountain and pond manufacturer claims that 4,000m3 of softened 60,000m3 is now needed per year in the
are also fed with water from the cisterns. water at a maximum of 14°C was previously buildings monitored. Of the 20,000m3 of
Since 2001, 71 toilets have been supplied with used on an annual basis, and subsequently fed drinking water saved, 20% (4,000m3) was
38 Application
Filtration+Separation January/February 2014
related basis at a price of €0.66 for each filter has to be cleaned at least once a year.
square metre of sealed area that was drained This kind of vortex filter is also in continuous
into the sewage system. Cisterns designed for operation in industrial units, and is cleaned
rainwater usage that include a sewer junction, automatically by a spray nozzle. The filters
as used in the clinic, can accommodate a roof were manufactured by WISY AG of Kefenrod,
area of 15m2 for each cubic metre of holding Germany.
capacity. The rainwater storage tank, which
holds 45.4m3, therefore leads to a reduction of Amortisation
681m2, or in other words €449.46. Together
with drinking water fees, Bad Hersfeld Clinic Mr Kohlrenken evaluated the rainwater/
saved €13,551.06 in 2007 by using rainwater. operating water technology for the year 2010
Operating costs, including filter maintenance with a view to future expansion and additional
and electricity for the rainwater pumps, were building projects at the Bad Hersfeld Clinic.
largely offset by the fact that the drinking His evaluation revealed investment costs
water no longer had to be softened for of €21,000 (€71,100 minus the subsidy of
the cooling process. €50,100 in 1995 that was funded by the State
of Hessen). Taking the costs saved in 2009
Rainwater technology amounting to €13,728 into consideration, the
amortisation period was less than two years.
The rainwater storage tank, which was This also includes investments for spare parts
created in 1995, is made of steel. The battery and increasing operating costs. Projected over
of tanks that was additionally installed in an operating period of 20 years, the clinic will
2001 comprises eight plastic tanks. Both save a sum of €274,554.
storage systems are connected to each other
and both collect rainwater. Before the Plans have now been formed to expand the
rainwater enters the cistern, it goes through a system by another 100 toilets in new buildings
Cross-sectional drawing of the self-cleaning vortex filter filter. The filter is an important component of and building conversions. The need for water
for rainwater. (WISY AG) a rainwater harvesting system, as it contributes will be balanced to suit the water yield by
to the quality of the water and trouble-free enlarging the storage tanks by a further 10m3.
saved from applying rainwater cooling operation of the system. The vortex filter Mr Kohlrenken estimates targeted savings of
technology. principle, which is applied in this system, was an additional €5,373 per year, which, in 20
invented in Vogelsberg just in time before years will amount to €107,465. Investments
Fees saved in one year the boom began in the 1990s. The vortex will cost between €31,500 and €58,000,
filter provided a solution. The filter sleeve producing an amortisation period of 6-11
A volume of 2,564m3 was extracted from the
cistern, while 384m3 of drinking water had
is a cylindrical, perforated component with
a filter mesh of 0.28 mm, which snugly lines
years. •
to be resupplied during dry periods, leaving the wall of the feed pipe without narrowing Contact:
a used rainwater yield of 2,180m3. Add to the cross-section of the pipe. It enables dirt Klaus W. Koenig
this the 4,000m3 that is saved with regard to be removed (filter type C in accordance
to cooling water, and the volume of water with DIN 1989-2:2004-08). Filtered particles
totals 6,180m3. At a drinking water price are swilled into the sewer pipe without
of €2.12/m3, costs have been reduced by blocking the filter or having to be disposed Jakob-Kessenring-Str. 38
€13,101.60. Since 1 January 2003, the clinic of. This results in a highly effective system 88662 Ueberlingen
has also profited from an amendment to the with a long useful lifetime, ie, a large water Germany
statutes of the city of Bad Hersfeld. In 2007, yield, good purification and it is low on Tel: +49 07551 61305
rainwater was accounted for on a source- maintenance. In compliance with 1989-1 a www.klauswkoenig.com
2nd International Conference on
Ionic Liquids in Separation and
Purification Technologgyy
June 29 – July 2, 2014,
The Westin Harbour Castle, Toronto, Canada
CONFERENCE CHAIRS:
Prof. Edward Maggin, Univver
e si
sity
tyy of Notre Dame, USA
Dr. Mark Shiflett, Dupont, USA A
PLENARY SPEAKERS
Prof. Wolfgang Arlt, Der Universitat Erlangen Nurnberg, Germa
m ny
Prof. Daniel Armstrong, University of Texas, USA
Prof. Martin Atkins, Petronas, Malaysia
Prof. Joao Couutinho, University of Aveiro, Portugal
Prof. Robin Rogers, University of Alabama, USA
KEYNOTE SPEAKERS
Prof. Joan Brennecke, University of Notre Dame, USA
Prof. Margarida Costa Gomes, Université Blaise Pascal, France
Dr. John Holbrey, Queen’s University, Unitede Kingdom
Prof. Philip Jessop, Queen’s University, Kingston, Ontario, Canada
Prof Udo Kragl, Universität Rostock,
Prof. Rostock Germany
Prof. Agilio Padua, Université Blaise Pascal, France
Dr. Paul Painter, Pennsylvania State University, USA
Dr. Thomas Schubert, Iolitec, Germany
Prof. Suojiang Zhang, CAS Institute of Process Engineering, China
Rainwater harvesting
Mexican rainwater
re-use project
leads to amazing
transformation
drainage project in Monterrey, Mexico has created a sustainable
A blueprint for rainwater re-use, which could be replicated in central
America and elsewhere to help tackle the challenges of urban
regeneration and water scarcity. In this case, a solution pioneered the
use of stormwater treatment technologies and helped to combat the
country’s severe water scarcity problems.
Monterrey is the capital of Mexico’s Nuevo
Leon state in the north east of the country.
With a population of four million it is the
third biggest city in Mexico. In the arid
northern regions of the country, water scarcity
is becoming an increasing problem caused by
over-extraction from underground aquifers.
Ambitious project
Quick completion
The urban and social regeneration of the to form The Trust Poligono Edison. The including a children’s playground, exercise
Edison district is achieved by grassroot Stormwater solution was supported by FEMSA equipment, and public fountains. Cultural
development and citizen participation. This Foundation as part of its programme in activities will be organised for the areas 24,000
project is being led by OXXO, Mexico’s sustainable development of water resources. residents to provide a central community focus
national convenience store chain which has
its headquarters in the area. OXXO gathered The project has seen the islands transformed
and encourage improved social conditions. •
together a group of investors and sponsors into a series of family recreation areas www.hydro-int.com
42 Product focus
Filtration+Separation January/February 2014
Polymers
Polyvinylidene
fluoride fibres
for multiple high
performance uses
olyvinylidene fluoride (PVDF) has long been used for industrial
P monofilament applications. In this article for Filtration+Separation
Sean M Stabler, James Henry, and Jerome Chauveau of Arkema,
developers of the new Kynar PVDF, discuss how fresh grades allow
the dimensions of fibres to be scaled down to very low diameter
fibres, giving access to new opportunities. They state it is an
adaptable fluoropolymer, whioh can be applied to many markets
including transportation and chemical processing.
Kynar PVDF is available as a bioprocess and pharmaceutical of a linear material. For fibres, density material as compared to
homopolymer or copolymer disposable systems; high purity denier is defined as grams per common synthetic fibre materials
resin especially designed to components for semiconductor 9,000m of fibre. Specific gravity such as polypropylene and
be manufactured into mono water and chemical processing; is the unit mass per volume. polyester. As such, density should
and multi filament fibres to flame and smoke resistant wire Relatively speaking, Kynar PVDF be considered when comparing
be converted into woven and and cable jacketing for plenum material is considered to be a high denier per filament (dpf) of
nonwoven articles. rated products; protective
paints for architectural coatings;
Polyvinylidene fluoride (PVDF) membranes for filtration of water
is a high performance engineering and food; foams for light weight
polymer which was introduced in applications; and most recently
the 1960s when Arkema began fibres for woven and nonwoven
manufacturing the trademarked applications 1,2,3,4,5.
Kynar PVDF family of materials.
Today, there are more than 40 Background
different Kynar PVDF grades
available to the market for a Terminology often associated with
wide range of manufacturing the traditional polymer industry is
processes including extrusion, quite different than that used for
injection moulding, rotational the fibre industry. It is important
moulding, coatings, and solution to note a key term and how it
casting. The ease of processing relates to specific polymers and
has led to applications which the design of components made
include: corrosion resistant from said polymers.
liners for tanks and pipes;
protective films for photovoltaic Denier is simply the term used to
solar panels; barrier films for describe the mass per unit length Figure 1: Kynar nonwoven point bonded.
Product focus 43
Filtration+Separation January/February 2014
• sails opportunities and applications Solvent Boiling Point (°C) Flash Point (°C)
• geomembranes where a lower diameter fibre Dimethyl Acetamide 166 70
product is desired for liquid & air N-Methyle-2-Pyrrolidone 202 95
The excellent UV resistance of filtration, flat sheet membrane
Dimethyl Formamide 153 67
Kynar PVDF has been proven supports, woven textiles, battery
Dimethyl Sulfoxide 189 35
in the paint and solar energy separators, personal protective
industry for over 45 years and this fabrics, flame barrier, and Triethyl Phosphate 215 116
performance would translate to chemical resistant barriers. Tetramethyl Urea 177 65
textile fibres. Table 3: Active Kynar PVDF Solvents.
Manufacturing Processes
There are also several niche
markets which Kynar PVDF is Last, and potentially most
an excellent material choice. importantly, Kynar PVDF parts
Perhaps one of the most can be manufactured on standard
innovative markets is for battery melt processing equipment by
applications9. Kynar PVDF is many processing techniques.
commercially used as a binder Kynar PVDF fluoropolymer is
in lithium-ion batteries for the easily melt processable. From the
consumer electronic markets perspective of a polymer resin
because of its excellent oxidative converter, it is very important
resistance properties8. The that standard melt processing
chemical stability has also gained equipment can be used to make
interests for using Kynar fibres a broad range of products. Many
as battery membrane separators. fluoropolymers require melt
The fibre separators are used processing equipment with Table 4: Kynar PVDF solution viscosities in NMP.
to keep positive and negative specialised corrosion resistant
electrodes apart while allowing steel and very high temperature
transport of ionic charge carriers capabilities. As a fluoropolymer,
in electro chemical cells. The Kynar PVDF is an exception as it
chemical resistance and long term does not require a special metal
durability of Kynar PVDF for alloy extruder, barrel, or screw for
lithium ion battery has created melt processing nor does it require
great interests in the anode and high temperature capabilities.
the cathode section of the battery Standard melt processing
and now technology is trending equipment used for polyolefins
towards better separator materials and other commodity resins is
and/or membranes with improved all that is necessary. Whereas,
oxidative properties – where other fluoropolymers, such as
Kynar fibres is likely a solution. FEP, ETFE, ECTFE, PTFE, etc.
do require specialised processing
Kynar resins have been actively equipment and techniques to Table 5: Kynar PVDF Solutions in DMAc.
used for microporous ultra and manufacture into products.
micro filtration membranes These specialised processes strength thermal welds. Kynar References
for decades. Kynar PVDF and equipment contribute to PVDF can be thermally formed
fibres can further be used as higher costs for the final product. into shapes by the use of heat. Please contact the authors for a
a complimentary membrane For example, a Kynar PVDF filter complete list of references.
filtration support for food and Kynar PVDF can also be produced could easily be thermally welded
water. In particular, a great deal by solution casting and spinning. from a flat sheet into a tubular Contacts:
of interest is in Kynar PVDF There are very few solvents structure simply using heat. This Sean M Stabler is a business
nonwoven technologies. As which will dissolve Kynar PVDF, is advantageous for assembly and development engineer in the
the fibres continue to reach the most common are listed in design of filters which may require Fluoropolymers business group
lower nanometer diameters, the Table 3. Specific grades of Kynar geometries beyond flat sheet, such at Arkema, responsible for Kynar
filtration efficiency is improved PVDF and solvents have different as a pleated design. PVDF foams, fibres, membrane and
tremendously. The majority of interactions with each other. See industrial water markets.
the liquid filtration markets use Tables 4 and 5 for a comparison Conclusion Email: sean.stabler@arkema.com
harsh chemical agents such as of solution viscosity versus solids James Henry is a senior research
chlorines, bromines, alcohols, content in different solvents. Kynar PVDF is a high engineer at Arkema, responsible for
acids, ozone, etc. to clean the performance polymer with Kynar PVDF development activities
filtration systems. Kynar PVDF Solution viscosity information is versatile properties allowing in wire & cable, chemical processing
is known for resistance to all of important for solvent spinning of it to be used in the harshest and fibres & textiles.
these cleaning and/or sterilisation Kynar PVDF fibres. conditions. The processability Email: james.henry@arkema.com
techniques. of the polymer allows it to take Jerome Chauveau is a business
In addition to being processable, many general forms from pipe to development engineer at Arkema,
Kynar PVDF monofilaments have Kynar PVDF also has another coatings and now to low diameter responsible for Kynar PVDF
been used in pulp & paper and important property. Kynar fibres. As the grades of Kynar development activities in energy
fishing markets for many years. PVDF is easily welded and PVDF continue to evolve, so (Cable, Li-ion battery, etc.) and
By market demand, Arkema has thermoformed. Many polymers will the applications and final fibres & textiles industries.
now developed appropriate Kynar cannot easily be welded, but products. For more information, Email: jerome.chauveau@arkema.
PVDF grades to address new Kynar PVDF is known for high contact this paper’s authors. • com
46 Product finder
Filtration+Separation January/February 2014
Product Finder
ACTIVATED AIR MEDIA FILTER COMPONENTS FILTER PLEATING LIQUID FILTER MEDIA
CARBON FILTER & END CAPS MACHINES Blücher GmbH
Mettmanner Str. 25
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United Kingdom BLADE PLEATERS AND a2zfiltration@vsnl.net/ a2zfiltration@vsnl.net/ Fax: +33 3 28 43 74 72
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info@a2zfiltration.com Mettmanner Str. 25 Exclusive Distribution
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Products A2Z offers automated lines/solutions Tel: + 49 (0) 211 92 44 123 Louisville, KY 40299 Website: www.alfalaval.com
Reliance Works, Saltaire Road that are flexible, fit for purpose and Fax: + 49 211 92 44 211 USA
Shipley, West Yorkshire cost effective for filter manufacturers. E-mail: nicole.weber@bluecher.com Tel: +1 502 261 8222
BD18 3HL, UK Website: www.bluecher.com Fax: +1 502 261 8225 MICROFIBER
Tel: +44 1274 530 155 EXPANDED & MICRO BWF Tec GmbH & Co. KG Contact Person: Chris Lyons TECHNOLOGY
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E-mail: sales@purification.co.uk EXPANDED METAL BWF Envirotec
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Activated carbon filter media. Dexmet Corporation Bahnhofstrasse 20 Company
Other active powders can be 22 Barnes Industrial Road South 89362 Offingen FILTER 200 South Wilcox Drive.
Wallingford, CT 06492 Germany Kingsport
incorporated. Custom medias
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ADHESIVES E-mail: sales@dexmet.com Website: www.bwf-envirotec.com Corporation E-mail: microfibers@eastman.com
www.dexmet.com 2-7-19 Okata Website: www.EastmanCyphrex.com
Franklin Adhesives & Haver & Boecker OHG Atsugi-shi
Polymers Wire Weaving Division Kanagawa-ken
Ennigerloher Strasse 64 243-0021 MICROFILTRATION
2020 Bruck Street D-59302 OELDE, Germany Japan
Columbus, Ohio, USA, 43207 Tel: + 49 (0)2522 300 Tel: +81 (0) 46 227 0461 Alfa Laval
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Tel: +1 508 850 2000
Fax: +1 508 668 3557 Arai Machinery
E-mail: info@hovo.com Corporation
Website: www.hollingsworth-vose.com 2-7-19 Okata
Atsugi-shi
PGI France Kanagawa-ken
ZI de la Blanche Maison 243-0021
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BP 109, 59270 Bailleul, France Tel: +81 (0) 46 227 0461
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Alpine rescue:
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