Bottom of Pyramid - Test # 17 - Structure of Atom

Contact Number: 9667591930 / 8527521718

1.
(A) Ultraviolet light
Which of the following sets of quantum numbers
represent an impossible arrangement -  (B) X-rays

       n   l    m     s (C) Visible light

(A)  3   2   -2   (+)1/2 (D) y-rays

(B)  4   0   0    (-)1/2 6.

(C)  3   2   -3   (+)1/2 Of the following transitions in hydrogen atom, the one
which gives an absorption line of lowest frequency is
(D)  5   3   0   (-)1/2
(A) n=1 to n=2
2.
(B) n=3 to n=8
Correct set of four quantum numbers for the outermost
electron of rubidium (Z=37) is: (C) n=2 to n=1

(A) 5, 0, 0, 1/2 (D) n=8 to n=3

(B) 5, 1, 0, 1/2 7.

(C) 5, 1, 1, 1/2 The maximum number of atomic orbitals associated with

a principal quantum number 5 is
(D) 6, 0, 0, 1/2
(A)9
3.
(B)12
Number of unparired electrons in 1S2 2S2 2P3 is - (C) 16
1. 2 (D) 25
2. 0 8.
3. 3
If the Planck’s constant h=6.6 x 10-34 Js, the de-Broglie
4. 1 wavelength of a particle having momentum of 3.3 x 10-24
4. kg m s-1 will be
The quantum numbers of four electrons are given below. (A) 0.002 Å
                                  n            l           m          s  (B) 0.02 Å
(1) Electron 1             3            0             0           -1/2 (C) 0.2 Å
(2) Electron 2             4            0             1           1/2 (D) 2Å
(3) Electron 3            3             2             0           1/2 9.
(4) Electron 4            3             1             0           -1/2 Rutherford's scattering experiment is related to - 
The correct order of decreasing energy of these electrons (A) Nucleus
is - 
(B) proton
(A) Electron 3 > Electron 1 > Electron 4> Electron 2
(C) Electron
(B) Electron 4> Electron 2 > Electron 3 > Electron 1
(D) Neutron
(C) Electron 3 > Electron 2 > Electron 4 > Electron 1
10.
(D) Electron 2 > Electron 4 > Electron 3 > Electron 1
The quantum numbers of most energetic electron in Ne
5. atom when it is in first excited state is
Which type of radiation is not emitted by the electronic (A) 2, 1, 0, +1/2
structure of atoms:
(B) 3, 1, 1, +1/2
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 Bottom of Pyramid - Test # 17 - Structure of Atom
Contact Number: 9667591930 / 8527521718

(C) 3, 0, 0, +1/2 2 are - 

(D) 3, 1, 0, +1/2 (A) 22
11. (B) 44
The total number of neutrons in dipositive zinc ions with (C) 66
mass number 70 is -
(D) 88
(A) 34
16.
(B) 40
The ion that is isoelectronic with CO is-
(C)36
(A) CN-
(D) 38
12. (B) O2+

With a certain exciting radiation of a particular (C) O2-

frequency, to which hydrogen atoms are exposed, the
maximum number of spectral lines obtainable in the (D) N +
2
emission is 15. The uppermost energy level to which the
electron is excited is n= 17.
(A) 4 If uncertainity in position and momentum are equal, the
uncertainty in velocity is:
(B) 5
(C) 6 (A) √h/2π

(D) 7 (B)  1

2m
√h/π

13. (C) √h/π
When accelerated electrons are direct against an (D) None
anticathode in an X-ray tube, the radiation obtained has a
continuous spectrum with a wavelength minimum, 18.
-6 When the atoms of gold sheet are bombarded with a
λ
min = (1.24 x 10 /V) m,  where V is the voltage used
beam of  α -particles, only a few a-particles get deflected
for accelerating the electrons. Calculate λmin for V= 5 x
where as most of them go straight undeflected. This is
104 volts. because
(A) 1.25 Å (A) The force of attraction on the  α-particles by the
oppositely charged electron is not sufficient
(B) 0.75 Å
(B) The nucleus occupies much smaller volume as
(C)0.25 Å compared to the volume of atom
(D) 1.00 Å (C) The force of repulsion on fast moving α-particles is
14. very small.

The wavelengths of two photons are 2000 Å and 4000 Å (D) The neutrons in the nucleus do not have any effect on
respectively. What is the ratio of their energies? α-particles

(A) 1/4 19.

(B) 4 The number of electrons in the valence shell of calcium

is 
(C) 1/2
(A) 6
(D) 2
(B) 8
15.
(C) 2
The number of electrons in one molecule of CO
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 Bottom of Pyramid - Test # 17 - Structure of Atom
Contact Number: 9667591930 / 8527521718

(D) 4 (D) None of these

20. 25.
The brackett series of spectral lines arise when an The minimum value of spin multiplicity possible, when  l
electron in an excited hydrogen atom jumps from an =3, are 
energy level
(A) 2
(A) n=5 to n=1
(B) 1
(B) n=5 to n=3
(C) 0
(C) n=5 to n=4
(D) 3
(D) n=5 to n=2
26.
21.
The total spin resulting from a d7 configuration is - 
The ratio of the wavelengths of last lines of Balmer and
Lyman series is- (A) 3/2

(A) 4:1 (B) 1/2

(B) 27:5 (C) 2

(C) 3:1 (D) 1

(D) 9:4 27.

  Two isotopes of Boron are found in the nature with

atomic weights 10.01(I) and 11.01(II). The atomic weight
22. of natural Boron is 10.81. The percentage of (I) and (II)
The splitting of spectral lines in a magnetic field, arising isotopes in it are respectively-
out of orbital motion of electrons only and the further (A) 20 and 80
splitting due to spin motion are respectively called
(B) 10 and 90
(A) Zeeman and Stark effects
(C) 15 and 75
(B) Zeeman and anomalous Zeeman effects
(D) 30 and 70
(C) Stark and Zeeman effects
28.
(D) Zeeman and Kerr effects
Rutherford's scattering experiment is related to the size of
23. the-
Which transition of electron in the hydrogen atom emits (A) Nucleus
maximum energy:
(B) Atom
(A) 2 → 1
(C) Electron
(B) 1 → 4
(D) Neutron
(C) 4 → 3
29.
(D) 3 → 2
There are three energy levels in an atom. How many
24. spectral lines are possible in its emission spectra?
Frequency ratio between violet (400nm) and red (750nm) (A) One
radiations in the visible spectrum, is-
(B) Two
(A) 8/15
(C) Three
(B) 4/15
(D) Four
(C) 15/8
30.
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 Bottom of Pyramid - Test # 17 - Structure of Atom
Contact Number: 9667591930 / 8527521718

The increasing order of energy of electromagnetic (1) H-atom

radiation can be represented as
(2) D-atom
(A) microwave < infrared < visible < X-ray
(3) T-atom
(B) X-ray < visible < infrared < microwave
(4) He-atom
(C) microwave < infrared < visible < radiowaves
36.
(D) X-ray < infrared < visible < microwave
The ratio of the difference in energy between the first and
31. second Bohr orbit to that between the second and the
third Bohr orbit is 
Mass of neutron is ........................times the mass of
electron- 1. 1/2
(A) 1840 2. 1/3
(B) 1480 3. 4/9
(C) 2000 4. 27/5
(D) None 37.
32. Which of the following pairs of d-orbitals will have
electron density along the axes?
Which of the following species has more number of
electrons in comparison with the neutrons? (a) dz2,dxz

1. Al3+ (b) dxz,dyz

2. O2- (c) dz2,dx2-y2

3. F- (d) dxy,dx2-y2
4. C 38.
33. Which is the correct order of increasing energy of the
The ratio of the difference in energy between the first and listed orbitals in the atom of titanium?
second Bohr orbit to that between the second and the (a) 3s 4s 3p 3d                   (b) 4s 3s 3p 3d
third Bohr orbit is 
(c) 3s 3p 3d 4s                   (d) 3s 3p 4s 3d
1. 1/2
39.
2. 1/3
What is the maximum numbers of electrons that can be
3. 4/9 associated with the following set of quantum numbers?
4. 27/5 n=3, l = 1 and m=-1
34. (a) 10
The radius of second stationary orbit in Bohr's atom is R. (b) 6
(c) 4
The radius of 3rd orbit will be:- (d) 2
1. 9R  
2. R/4 40.
3. 9R/4 Maximum number of electrons in a subshell with l = 3
4. 2R and n = 4 is
(a) 14
35. (b) 16
Bohr's model is not valid for:- (c) 10
(d) 12
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 Bottom of Pyramid - Test # 17 - Structure of Atom
Contact Number: 9667591930 / 8527521718

  1.  √λR(λR − 1)
41.
2.  √ λR

( λR−1 )

Which one of the following ions has electronic

configuration [Ar]3d6? 3.  √λR(λR + 1)
(At. no: Mn = 25, Fe = 26, Co = 27, Ni =28) ( λR−1 )
4.  √ λR

(a) Ni3+                (b) Mn3+

(c) Fe3+                (d) Co3+ Fill OMR Sheet

42.
If uncertainty in position and momentum are equal, then
uncertainty in velocity is

(a)  1

2m
√
h

(b) √ h

2π

(c)  1

m
√
h

(d)  h

43.
The correct Schrodinger's wave equation for a electron
with total energy E and potential energy V is given by
2 2 2
∂ ψ ∂ ψ ∂ ψ 2

1.  
8π
+ + + 2
(E − V) ψ = 0
2 2 2
∂x ∂y ∂z mh

2 2 2
∂ ψ ∂ ψ ∂ ψ
2.  
8πm

2
+ 2
+ 2
+ 2
(E − V) ψ = 0
∂x ∂y ∂z h

2 2 2
2
∂ ψ ∂ ψ ∂ ψ
3.   ∂x
2
+
∂y
2
+
∂z
2
+
8π m

h
2
(E − V) ψ = 0

4.  None of the above.

44.
Which of the following expressions represents the
spectrum of Balmer series (If n is the principal quantum
number of higher energy level) in Hydrogen atom?
R ( n−1 )   ( n+1 )
1.  v̄ = n
2
  cm
−1

R ( n−2 )   ( n+2 )
2.  v̄ = 4n
2
  cm
−1

R ( n−2 )   ( n+2 )
3.  v̄ = n
2
  cm
−1

R ( n−1 )   ( n+1 )
4.  v̄ = 4n
2
  cm
−1

45.
An excited state of H atom emits a photon of wavelength 
λ and returns in the ground state, the principal quantum

number of excited state is given by:

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Bottom of Pyramid - Test # 17 - Structure of Atom
Contact Number: 9667591930 / 8527521718

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