Bottom of Pyramid - Test # 3 - Haloalkanes &

Haloarenes Contact Number: 9667591930 / 8527521718

1.
(b) CH 3 Cl >CH
3 CH2 Cl >(CH 3)
2
CHCl >(CH3)
3
CCl

When CH3CH2CHCl2 is treated with NaNH2, the

(c) CH CH2 Cl >CH Cl >(CH 3) CHCl >(CH 3) CCl
product formed is                              3 3
2 3

(a) CH3-CH=CH2                     (b) CH3-C≡CH (d) (CH 3)

2
CHCl >CH 3 CH2 Cl >CH 3 Cl >(CH3)
3
CCl

8.
(c) CH3CH2CH< NH2

NH2
                  (d) CH3CH2C< Cl

NH2

Action of RMgX with vinyl chloride gives:

2.
(a) alkane                                  (b) alkyne
Reagent

R-CH2-CCl2-R −−−−→R-C≡C-R. The reagent is (c) alkene                                  (d) all of these

(a) Na                                   (b) HCl in H2O  
(c) KOH in C2H5OH                (d) Zn in alcohol 9.
Cl2 Hydrolysis
3. X → Benzotrichloride −−−−−→ Y
Ethyl chloride is converted into diethyl ether by                X and Y respectievely are:
                                  
(a) benzene, benzaldehyde
(a) Wurtz reaction                           (b) Grignard reaction
(b) toluene, benzaldehyde
(c) Perkin's reaction                         (d) Williamson's
synthesis (c) toluene, benzoic acid

4. (d) benzene, benzoic acid

The alkyl halide is converted into an alcohol by                 

                     10.
(a) addition                       (b) substitution Benzene on reaction with a mixture of HNO3 and H2SO4
(c) dehydrohalogenation     (d) elimination followed by reaction of Cl2/FeCl3 gives:
5. (a) 3-chloro -1 -nitrobenzene
Addition of Br2 on cis-butene-2 gives: (b) 2-chloro -1 -nitrobenzene
(a) a racemic mixture of 2,3-dibromobutane (c) 4-chloro -1 -nitrobenzene
(b) meso form of 2,3-dibromobutane (d) a mixture of 2-chloro and 4-chloro -1 -nitrobenzene
(c) dextro form of 2,3-dibromobutane 11.
(d) laevo form of 2,3-dibromobutane  Which is gem dihalide?
6. (a) CH 3. CHBr2                             (b) CH 2 Br. CH2 Br  
The number of different substitution products possible (c) CH . CHBr. CH Br                   (d) None of these
3 2

when ethane is allowed to react with bromine in sunlight

are: 12.

(a) 9           (b) 6 Hydrogenation of benzoyl chloride in the presence of Pd

on BaSO  gives: 4

(c) 8           (d) 5
(a) benzyl alcohol                         (b) benzaldehyde
7.
(c) benzoic acid                            (d) phenol 
In  S   reactions, the correct order of reactivity for the
N
2

following compounds :  CH Cl,  CH CH Cl,  13.

3 3 2

(CH ) CHCl and (CH ) CCl is :

3 3 Friedel-Craft's reaction of bromobenzene with methyl
2 3

iodide gives:
(a) CH Cl>(CH ) CHCl>CH CH Cl>(CH ) CCl
3 3 2 3 2 3 3

(a) o-bromotoluene                      Page: 1

 Bottom of Pyramid - Test # 3 - Haloalkanes &
Haloarenes Contact Number: 9667591930 / 8527521718

(b) p-bromotoluene (c) propan-1-ol                         

(c) o-and p-bromotoluenes              (d) propan-2-ol
(d) m-bromotoluene 19.
14. Iodoform can be prepared from all except :
When vinyl chloride is passed through alcoholic KOH (a) isopropyl alcohol
solution:
(b) 3-methyl-2-butanone
(a) it dissolves                                 
(c) isobutyl alcohol
(b) it forms vinyl alcohol
(d) ethyl methyl ketone
(c) it forms acetylene                     
20.
(d) it has no action
Identify (Z) in the following reaction reaction series,
15. Alcoholic Br2 KCN

Acetone
C2H5I −−−−→(X) −
→ (Y) −
−→(Z):

The reaction, RCl +NaI  −−−−→ R − I  + NaCl is known

KOH

as:
(a) Wurtz reaction                       (b) Fittig reaction           
       (a) CH3-CH2-CN     (b) 
(c) Frankland's  reaction                (d)
Finkelstein's reaction                               
16. (c)       (d) 
(CH3)3CMgCl on reaction with D2O gives: 21.
(a) (CH3)3CD The reaction of toluene with  Cl   in presence of  FeCl
2 3

 gives predominantly :
(b) (CH3)3OD
(a) m- chlorobenzene                   
(c) (CD3)3CD
(b) benzoylchloride
(d) (CD3)3OD (c) benzyl chloride                         
17. (d) O- and p-chlorotoluene                    
Benzoyl Chloride is prepared from benzonic acid by: 22.
(a) Cl2, hv Arrange the following halides in the decreasing order of 
S 1 reactivity
(b) SO2Cl2 N

(I) CH CH2 CH2 Cl

(c) SOCl2
3

(II) CH 2 = CHCH(Cl) CH3

(d) Cl2, H2O
(III) CH 3
CH2 CH(Cl) CH3

18.
1. I>II>III                            2. II>I>III
In the following sequences of reactions;
3. II>III>I                            4. III>II>I
KOH(alc.) HBr KOH(aq)

CH3 CH2 CH2 Br −−−−−→ (A)−→(B)−−−−→ (C) 23.

the product (C) is: Arrange the following compouds in the order of leaving
group ability
(a) propene                               
(b) propyne
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 Bottom of Pyramid - Test # 3 - Haloalkanes &
Haloarenes Contact Number: 9667591930 / 8527521718

The product X is :-

              
(a) (b)

(c)

          
1. I > II > III > IV (d)
2. IV > III > I > II 26.
3. III > II > I > IV excess   HI  (conc.)

Anisole−−−−−−−−−−→Product
4. II > III > IV > I reflux

24.
Which of the following alkyl halide undergo 1. 
rearrangement in SN1 reaction?
CH3

|
2. 
(a)  CH 3 − C − CH − CH3
| |

CH3 I

3. 

4. 
(b)  
 
27.
HC≡CNa + Cl-CH2-CH2-CH2-I  → (A); Major product
(c)  
(A) is:
(d) All of these
(a) H-C≡C-CH2-CH2-CH2-I
25.
(b) CH2 = CH-CH2-I
 
                                            LiBr/DMSO   (c) H-C ≡ C-CH2-CH2-CH2-Cl

(d) CH2 = CH-CH2-Cl

→    
28.
        Major

product (X)
EtOH

                                             SN2 conditions
−−→(A)
Δ

Page: 3
 Bottom of Pyramid - Test # 3 - Haloalkanes &
Haloarenes Contact Number: 9667591930 / 8527521718

Major product (A) is:

1. 

2. 
2. 

3. 

4. 
3. 
29.

KOH

  −−−−→ (A)
EtOH,Δ
( major )

Product (A) is:

4. 
31.
1. 
1-2-dichloro ethane + NaSCH2CH2SNa →C4H8S2 + (P)
Unknown product (p) of the above reaction is:
2. 

(a) 
3. 

4. 
(b)  
30.
Which is the major product of the following reaction?
(c) H-S- = -CH=CH-S-H

(d) H- = -CH-S-H
32.
Which alkyl halide has maximum density?
(a) C3H7I                     

(b) C2H5I                 

(c) CH3I                 

1.  (d) CH3Br

Page: 4
33.
 Bottom of Pyramid - Test # 3 - Haloalkanes &
Haloarenes Contact Number: 9667591930 / 8527521718

Grignard reagent shows addition on: (c) propanal

(a) >C=O                             (b) -C≡N (d) propane chloride
(c) >C=S                              (d) all of these 40.
34. Identify (Z) in the following reaction series,
Pick up the correct statement about alkyl halides:- Alcoholic   Br2 KCN

C2H5I−−−−−→ (x) −
→ (Y) −
−→(Z):
KOH
(a) They show H-bonding.
(b) They are soluble in water. (a) CH3-CH2-CN
(c) They are soluble in organic solvents.
(d) They do not contain any polar bond. CH2 − CH2
(b)  | |

35. CN CN

Sodium ethoxide reacts with ethyl iodide to yield: CH2 − CH2

(c)  | |

(a) CH3CH3                               (b) C2H5OCH3 Br CN

CH = CH
(c) C2H5OC2H5                          (d) none of these (d)  | |

Br CN

36.
41.
Which set of reagents will produce freon (CCl2F2)?
Identity ‘Z’ in the following reaction series,
(a) C + F2 + Cl2 →                       aq. NaOH Al2O3(Heat) HOCl
CH3.CH2CH2Br→  (X)    →   (Y) →(z)
(b) CH3Cl + F2 →
SbCl5
(a)Mixture of
(c) CCl4 + HF −−→ CH3-CH-CH2 and CH3-CH-CH2
           l     l                l     l
(d) CCl4 + F2 →
         Cl    Cl              OH Cl
37.
An alkyl iodide on standing darkens, due to: (b)CH3-CH-CH2
              l       l
(a) hydrolysis                          (b) conversion into ether              OH   Cl
(c) liberation of iodine              (d) formation of alkanes
(c)CH3-CH-CH2
38.               l      l
In the following sequences of reactions;              Cl   OH

CH3CH2CH2I →KOH(alc.) (d)CH3-CH-CH2

(A)→Br2(B)→NaNH2/NH3(C) the end product (C) is:                l     l
(a) alkene               Cl   Cl

(b) alkanol 42.

(c) alkyne A compound A of formula C3H6Cl2 on reaction with

alkali can give B of formula C3H6O or C of formula
(d) alkyl amine
C3H4. B on oxidation gave a compound of the formula
39. C3H6O2. C with dilute H2SO4  containing Hg2+ ion gave
PCI5 reacts with propanone, to give: D of formula C3H6O, which with bromine and NaOH
gave the sodium salt of C2H4O2. Then A is:
(a) gem dichloride
(b) vic dichloride (a) CH3CH2CHCl2
(b) CH3CCl2CH3 Page: 5
 Bottom of Pyramid - Test # 3 - Haloalkanes &
Haloarenes Contact Number: 9667591930 / 8527521718

(d) CH3CHClCH2Cl (d) C6H5CH2Br

(c) CH2ClCH2CH2Cl

43. Fill OMR Sheet

Which chloro derivative of benzene among the following
would undergo hydrolysis most readily with aqueous
NaOH to furnish the corresponding hydroxy derivative?

1. 

2. 

3. 
4. C 6 H5 Cl

44.
The reaction, 

− NaCl

+ CH3 CH2 Cl −−−→

+ CH2 − CH3

is called
(a) Williamson synthesis
(b) Willamson continuous etherification process
(c) Etard reaction
(d) Gattermann-Koch reaction
 
45.
Which one is the most reactive toward SN1 reaction?

(a) C6H5CH(C6H5)Br

(b) C6H5CH(CH3)Br

(c) C6H5C(CH3)(C6H5)Br
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 Bottom of Pyramid - Test # 3 - Haloalkanes &
Haloarenes Contact Number: 9667591930 / 8527521718

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