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1 © 2018 Infineum
© 2018 International
Infineum Limited.
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All Rights 2018012.
2018160.
Reserved. 2018012.
Performance you can rely on.
Outline
• A lubricant component
– Roughly 80-99+% of petroleum products
• Usually doesn’t have all required properties – needs additive enhancement
• Mineral oil base stocks
Found in minerals,
– Refined from crude oil
not made of minerals
• Petroleum = “Petra-oleum” = “Rock Oil”
– Common processes
• Solvent extraction
– Separate “good” from “bad” molecules
• Hydrocracking
– Convent “bad” molecules into “good” molecules Most of the starting
• Synthesis materials come
from crude oil
– “Built” from chemical reactions
• Animal and vegetable oils also used
Performance you can rely on.
80%
Component
60%
40%
20%
Additives
0%
Industrial PCEO HDDO Marine
Product Type
4 © 2018 Infineum International Limited. All Rights Reserved. 2018012.
Performance you can rely on.
Base Stock B
Base Stock A
0
0 Time
Performance you can rely on.
Base Stock E
Base Stock D
0
0 Soot, percent
• Viscometrics
– SAE viscosity grade (e.g., SAE 5W-30)
– Pour point and low temperature fluidity
– Fuel economy
– Wear protection
• Oxidation
– Viscosity increase
– Acid formation, that leads to corrosion
– Deposit control
• Dispersancy and solvency
– Soot control (HDD)
– Viscosity increase and filter plugging
– Sludge
– Deposit control
• Foaming and air entrainment
• Volatility (evaporation)
– Oil Consumption and Flash Point
7 © 2018 Infineum International Limited. All Rights Reserved. 2018012.
Performance you can rely on.
H H H H
C5H12 = H C C H =
(pentane) C C C H
H
H H H H
(three-dimensional)
= C C =
C C C
C C
• Six-membered rings with three double bonds H C H
• Aromatic
9 © 2018 Infineum International Limited. All Rights Reserved. 2018012.
Performance you can rely on.
Low VI (<60)
• Aromatics Very poor oxidation
(unsaturated rings) Low pour point
• Sulfur
Antioxidant
– Dibenzothiophene
S
Corrosive
– Dialkylsulfide S
Performance you can rely on.
12 © 2018 Infineum
© 2018 International
Infineum Limited.
International All Rights
Limited. Reserved.
All Rights 2018012.
2018160.
Reserved. 2018012.
Performance you can rely on.
Refinery overview
Performance you can rely on.
Crude oil
Sources: Shell; Stratas Advisors; Sanford C. Bernstein
14 © 2018 Infineum International Limited. All Rights Reserved. 2018012.
Performance you can rely on.
Refining in a nutshell
• Start
– Crude oil
– Mixtures of GOOD and BAD molecules
• Goal
– REDUCE the Proportion of BAD molecules
– INCREASE the Proportion of GOOD molecules
• How Do They Do That?
– Refining
– Separation Solvent Extraction
• Remove the BAD molecules
– Throw them away?
– Use them for something else!
– Conversion Hydrocracking
• Change BAD molecules into GOOD molecules
– Synthesis Synthetics
• Build GOOD molecules from small ones
15 © 2018 Infineum International Limited. All Rights Reserved. 2018012.
Performance you can rely on.
• De-salting
– To avoid corrosion in refinery units
• Distillation
– Separates lighter from heavier fractions
– Selects viscosity “cut” and controls volatility (evaporation)
– Also used at end as a “clean-up” step
• Major Base Stock Refining Process
– Solvent Extraction
– Hydrocracking
• De-asphalting
– Removes asphaltenes (heavy aromatics)
• Dewaxing
– Removes wax and improves low temperature properties
– Either solvent dewaxing or catalytic dewaxing or catalytic iso-dewaxing
• Processes are combined to create refinery ‘schemes’
– Optimized based on crude source and refinery assets
16 © 2018 Infineum International Limited. All Rights Reserved. 2018012.
Performance you can rely on.
Performance you can rely on.
Jet Fuel
12%
Gasoline
36%
Distillate
31%
Performance you can rely on.
Gases
Naphtha
Vacuum gas oil (VGO)
Atmospheric
Distillation
Crude S100N
Distillation
S150N
Hydrofinishing
Vacuum
Extraction
Dewaxing
Solvent
Solvent
residuum
Atmospheric
S600N
Lube Raffinates Dewaxed Base
oil oil stocks
distillates
Bright
Extract stock
Vacuum residuum
Deasphalted resid Wax
Deasphalting
Asphalt
Distillation
Crude
Vacuum
Atmospheric
Medium
Distillation
oil
Hydrofinishing
Hydrocracking
Distillation
Vacuum
Dewaxing
Catalytic
Heavy
residuum
Atmospheric
VGO
Hydrogen
Hydrogen
Performance you can rely on.
Solvent extraction
Hydrocracking
Performance you can rely on.
H H
C C
H H 1-decene
ethylene -decene
poly -olefin
double bond PAO
(olefin)
an olefin
• GTL = Gas-to-Liquids
– Process of turning natural gas into liquid hydrocarbons
– Primary focus is liquid fuel production, but base stocks can also be made
• Steam-Methane Reforming (SMR) to make “syngas” Also other ways to make syngas
CH4 + H2O CO + 3H2 Net Reaction:
CO + H2O CO2 + H2 CH4 + H2O 2CO + 3H2
CH4 + CO2 2CO + 2H2 “Syngas”
*”Chemistry and Technology of Lubricants,” 3ed., Mortier, Fox, and Orszulik (Eds.), Springer, 2010
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Performance you can rely on.
Gas-to-liquids
Heavy Paraffin Synthesis
Synthesis Gas (CO + H2)
Catalytic Isomerization
Fischer-Tropsch Wax
Hydroprocessing
Dewaxing
Natural GTL
Gas Base
Stock
• Esters
– Diesters
– Polyol esters
– Phosphate esters
• PolyAlkylene Glycol (PAG)
• Alkylated naphthene (AN)
• Polyphenyl ether
• Silicones
• Bio-based
– Natural oils
– Chemically-functionalized vegetable oils
– Biotechnology renewable oils (e.g., from plant sugars via algae)
• Many others
Ref: “Synthetics, Mineral Oils, and Bio‐Based Lubricants, Chemistry and Technology”
L. R. Rudnick (ed.), CRC Taylor and Francis, 2006
27 © 2018 Infineum International Limited. All Rights Reserved. 2018012.
Performance you can rely on.
28 © 2018 Infineum
© 2018 International
Infineum Limited.
International All Rights
Limited. Reserved.
All Rights 2018012.
2018160.
Reserved. 2018012.
Performance you can rely on.
• Viscosity (D445)
– Sometimes kinematic viscosity at 100C
• Examples: HC4, HC6, HC12
– Sometimes “Neutral Number” – approx. 4.6 times kinematic viscosity at 40C
• Examples: S100N, S150N, S600N
– ISO Grade for Industrial Oils – related to kinematic viscosity (mm2/s) at 40C
• Viscosity Index (D2270)
– Rate of change of viscosity with temperature
• Low temperature properties
– CCS (D5293), MRV (D4684), SBV (D5133), or Pour point (D97)
• Saturates (D2007)
– Measure of “stable” vs. “reactive” molecules
– Intended as an approximation of oxidative stability – Not perfect
• Sulfur (D4294)
– Corrosive and poison to exhaust catalysts
• Volatility (D5800)
– Evaporation
• Chemical properties are also very important
29 © 2018 Infineum International Limited. All Rights Reserved. 2018012.
Performance you can rely on.
30 © 2018 Infineum
© 2018 International
Infineum Limited.
International All Rights
Limited. Reserved.
All Rights 2018012.
2018160.
Reserved. 2018012.
Performance you can rely on.
Performance you can rely on.
Volatility
60%
Percent Off at 371C by GCD
Group V (Naphthenic)
40%
20%
Group I
Group IV
(PAO) Group III Group II
0%
2 4 6 8 10 12
Viscosity at 100C, mm2/s
Performance you can rely on.
34 © 2018 Infineum
© 2018 International
Infineum Limited.
International All Rights
Limited. Reserved.
All Rights 2018012.
2018160.
Reserved. 2018012.
Performance you can rely on.
Performance you can rely on.
Performance you can rely on.
38 © 2018 Infineum
© 2018 International
Infineum Limited.
International All Rights
Limited. Reserved.
All Rights 2018012.
2018160.
Reserved. 2018012.
Performance you can rely on.
Performance you can rely on.
Performance you can rely on.
Performance you can rely on.
Performance you can rely on.
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