IIIT RK Valley (Idupulapaya)

Rajiv Gandhi University of Knowledge Technologies - Andhra Pradesh

Academic Year 2018 – 19: Semester I
Mid Semester Test-1
Metallurgical and Materials Engineering
MM1101- Metallurgical Thermodynamics
R16 Batch & Regular Mode of Examinations
Year: ENGG-1 Date of Examination: 8th Sep 2018
Time: 45 Minutes Max Marks: 15
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3X5 Marks= 15
Answer all the questions

1. In the dead roasting of Zinc sulphide, the reaction occurs as

2 Zns+ 3O2 =2 ZnO+ 2 S O 2
With the help of following data, find the standard heat of reaction at 25˚C and 827˚C.
For ZnS: ∆ H 0298 =−48.2 kcal/mole
C p=12.6+1.24 x 10−3 T −1.36 x 105 T −2 cal/ deg /mole
For O2: C p=7.16+1 x 10−3 T −0.4 x 105 T −2 cal/deg /mole
For ZnO: ∆ H 0298 =−83.2kcal /mole
C p=11.71+1.22 x 10−3 T −2.18 x 105 T −2 cal/deg/mole
For SO2: ∆ H 0298 =−70.95 kcal /mole
C p=10.38+2.54 x 10−3 T−1.42 x 10 5 T −2 cal/deg/mole

OR

2. With the help of following data, find the standard heat of reaction at 25˚C and 827˚C.
ZnO+C=Zn+CO
For ZnO: ∆ H 0298 =−83.2kcal /mole
C p=11.71+1.22 x 10−3 T −2.18 x 105 T −2 cal/deg/mole
For C: C p=4.1+1.02 x 10−3 T −2.1 x 105 T −2 cal /deg/mole
For Zn: C p=5.35+2.4 x 10−3 T cal/deg /mole
For CO: ∆ H 0298 =−26.4 kcal/mole
C p=6.8+1.0 x 10−3 T −0.11 x 105 T −2 cal/deg /mole
3. Determine the work done and heat exchanged for Isothermal and Isobaric processes
OR
4. Determine the work done and heat exchanged for Isochoric and Adiabatic processes

5. a) State first law of thermodynamics

b) Define enthalpy
OR
6. a) State Krichoff’s Law
b) Define Specific heat