LATIHAN SOAL

1. Suppose that 1.0 mol H2 at 2.0 atm and 25oC and 2.0 mol N2 at 3.0 atm and 25 oC are mixed at
constant volume.
a. Calculate ΔGtot.
b. What would be the value of ΔGmix when the pressures been identical initially?
2. Draw Temperature-composition phase diagrams (T vs wt%) for binary systems with
a. complete liquid and solid solubility,
b. complete liquid but zero solid solubility, and
c. complete liquid and limited solid solubility.
(In your sketches label phase fields and give characteristic temperatures.)

3. The binary phase diagram of NaCl-H2O at 1 atmosphere pressure:

Identify the stable phases and the composition for:

a.10% NaCl, at 0oC b. 10% NaCl, at - 10oC c. 10% NaCl, at - 30oC

4. For the binary system Cu-Ni the following data are available from cooling experiments:

T(oC) Melt composition (atomic % Ni) Composition of solid first formed on

cooling (atomic % Ni)
1100 3 10
1180 20 37
1260 40 57
1340 60 80
1410 80 87
a. From these data and information provided in the Table, construct the phase diagram
(T vs Composition).
b. At each of the following (T, Composition) coordinates, i.e., combinations of temperature and
composition, what are the phases present and what are their respective compositions?

T(oC) composition (atomic % Ni)

1120 15
1200 55
1300 60
 Solutions

1. Suppose that 1.0 mol H2 at 2.0 atm and 25oC and 2.0 mol N2 at 3.0 atm and 25 oC are mixed at
constant volume. Calculate ΔGmix. What would be the value of ΔGmix when the pressures been
identical initially?

= C Joule
=A+B+C
When the pressure identical initially:

2. Draw Temperature-composition phase diagrams (T vs wt%) for binary systems with

(a) complete liquid and solid solubility,
(b) complete liquid but zero solid solubility, and
(c) complete liquid and limited solid solubility. (In your sketches label phase fields and give characteristic temperatures.)

3. Identification the stable phases and the composition for:

a.10% NaCl, at 0oC b. 10% NaCl, at - 10oC c. 10% NaCl, at - 30oC

Stable phases composition

a liquid Brine water 10% NaCl, 100% Liquid
b Ice + Liquid Ice (100 H2O) + Brine water 15%, 70% Liquid
c Ice + NaCl Ice (100 H2O) + Pure NaCl
4. For the binary system Cu-Ni the following data are available from cooling experiments:

a.

b.

5. Pada 90 °C, tekanan uap metilbenzena dan 1,3-dimetilbenzena masing-masing sebesar 53,3
dan 18,0 kPa.

a. Berapakah komposisi cairan bila mendidih pada 90 °C dan tekanan 0,40 atm?

b. Berapakah komposisi uap yang terbentuk?

6. Buatlah diagram fasa untuk etanol, air dan benzene dari data berikut! Data di bawah ini
diperoleh pada fasa tunggal

C6H6 (% 60, 65, 75, 82,5 87, 91, 45, 36, 20, 10,9 5,9 2,8
berat) 8 9 7 6 2 1 5 9
H2O (% 7,1 5,6 3,4 2,0 1,2 0,7 12, 16, 26, 37,2 46, 55,6
berat) 6 7 6 2
Etanol (% 32, 28, 21, 15,5 11, 8,1 42, 46, 52, 51,9 47, 41,6
berat) 1 5 1 2 3 8 2 9

Jawab

100

90

80

70

60

50

40

30

20

10

0.00 20.00 40.00 60.00 80.00 100.00

7. Tekanan uap larutan 0,5 M KNO3 (aq) pada temperatur 100 oC adalah 749,7 Torr. Hitunglah
aktivitas air pada temperatur tersebut.
Jawab:

Karena tekanan uap air murni pada temperatur 100 oC adalah 760,0 torr, maka kita memperoleh:
a(H2O) = 749,7 torr / 760,0 torr = 0,9864