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Your partner for
BASF SE BASF S.A.
2K PU raw materials
Resins & Additives for Cond. Rochavera Torre Crystal
Automotive and Industrial Coatings Av. das Nações Unidas 14171,
E-EDC/RA – J 550 11° andar
67056 Ludwigshafen Morumbi
Germany 04794-000 São Paulo, SP
Brazil
Phone: +49 621 60 71128
Fax: +49 621 60 66 71128 Phone: +55 11 2039-3680
Fax: +55 11 2039-2040
www.basf.com/resins
The data contained in this publication are based on our current knowledge and experience. In view of the many factors that may affect processing and application of our product, these data do not relieve
processors from carrying out their own investigations and tests; neither do these data imply any guarantee of certain properties, nor the suitability of the product for a specific purpose. Any descriptions, drawings,
photographs, data, proportions, weights, etc. given herein may change without prior information and do not constitute the agreed contractual quality of the product. The agreed contractual quality of the product
results exclusively from the statements made in the product specification. It is the responsibility of the recipient of our product to ensure that any proprietary rights and existing laws and legislation are observed. When
handling these products, advice and information given in the safety data sheet must be complied with. Further, protective and workplace hygiene measures adequate for handling chemicals must be observed.
EDC 0815e
2 We create chemistry
On the journey of innovation
Preferred applications
On the journey of innovation 3
BASF is your reliable supplier for the formulation of 2K PU coatings. With our strategic Automotive & transportation coatings Industrial coatings Furniture & floor coatings
investments in R&D, capacities, and technical and formulation know-how for high solid
Protective/maintenance
and water-based binders and crosslinkers, we are the right partner for the conversion to
Automotive refinish
Automotive OEM
future-proof technologies. With our Sustainable Solution Steering method, our portfolio Product
Plastic coatings
Transportation
Wind power
has furthermore been systematically evaluated under sustainability criteria. This allows
Aerospace
Car parts
Container
Furniture
Flooring
Marine
us to assess the sustainability performance of each of our products in its specific
ACE
application. We create chemistry that makes performance love sustainable solutions.
Joncryl®
0 1 1 1 1 1 2 1 1 1 2 1 1
Acrylic polyols
Basonol® HPE
Hyperbranched 2 2 2 2 2 1 2 1 1 2 2 - -
polyesters
For industrial coatings, we identified durability and the Let’s take a joint look at your specific requirements and
reduction of emissions to be among the key drivers for find out how we can improve both your, as well as our, Sovermol®
more sustainable formulations. Raw materials that con- sustainability profile! Natural oil-based 1 1 1 - 1 0 2 2 - 1 1 - 2
polyols
tribute substantially to these drivers along the value chain
have been classified as Sustainability Accelerators. Learn more about BASF’s commitment to driving Luhydran®
1 - 1 0 1 - 1 0 1 1 1 2 -
sustainable solutions at: www.basf.com/sustainability Acrylic dispersions
Joncryl® OH
1 - 1 0 1 - 1 0 1 1 1 2 1
Acrylic dispersions
Joncryl® U/HYB
1 - 1 0 1 - 1 0 1 1 1 2 1
PU/Hybrid dispersions
Basonat®
Aliphatic polyisocy- 2 1 2 2 2 2 2 1 2 2 2 1 1
anates
4 Binders for high-performance applications
On the journey of innovation
Binders for high-performance applications
On the journey of innovation 5
Joncryl® polyol grades are hydroxyfunctional acrylic co-polymers for solvent-based For environmental and workers’ protection in 2K PU coatings, low to medium solid
coatings. They can be used as binders for crosslinking with polyisocyanates such solvent-borne systems can be substituted by high solids solvent-borne systems. Two
as Basonat® or in combination with other binder chemistries to improve performance options to achieve high solid content are reducing the molecular weight of polyols
at reduced VOC levels. Especially in combination with Basonol® HPE, outstanding and reducing the glass transition temperature. To leverage the full potential of these
coatings performances in low VOC systems can be achieved. systems, a complementing solution is needed to address a possible drop of curing
speed and hampered hardness and resistance of the cured film. Using Basonol® HPE
as a co-binder improves curing speed and lacquer performances in systems based
on low molecular weight polyacrylates and polyisocyanates. The recommended ratio
solids on solids is 5–30% on total binder.
2 Good weather resistance with proper light stabilizer package 3 Good weather resistance even without light stabilizer package
Sustainability Solid content OH value on solids OH number on solids Viscosity Color in Weather
Product Solvent Tg [°C] Description
Accelerator* [%] [mg KOH/g] [%] [Pa∙s, 23 °C] hazen resistance**
Joncryl® 592 - 73 n-Butylacetate 26 140 4.2 7.5 > 100 2 Non-fast-cure version of Joncryl® 942. High brilliance for 2K PU high solid applications for automotive refinish, ACE and industrial 2K PU applications
With excellent exterior durability with good chemical and solvent resistance, ideal for high-performance, lower VOC maintenance, rail, and transportation
Joncryl® 902 - 75 n-Butylacetate 20 112 3.4 9.0 < 50 3
topcoats
Joncryl® 922*** 1 80 n-Butylacetate –7 140 4.2 5.5 < 100 2 Low VOC polyol offering good drying time and pot life characteristics; useful as a sole binder or a modifier for higher Tg polyols
Acrylic low-molecular polyol with good hardness, stain resistance, and pigment dispersibility at a very low VOC level; broad resin compatibility and useful
Joncryl® 507 1 80 n-Butylacetate –7 140 4.2 3.8 < 50 2
as a low VOC modifier for appliance, office furniture, and general metal coatings
Very soft and reactive polyol with a high OH number to obtain a very good chemical resistance against several solvents, used to plasticize and / or
Joncryl® 963 1 100 - –63 130 3.9 7.5 < 100 2 to reduce VOC in 2K PU coatings; as a sole binder it forms a rubber-like coating with extremely high flexibility and very good adhesion on difficult
substrates; good outdoor durability with proper light stabilization
Hyperbranched polyesters
Shows low impact on VOC for 2K PU high solid coatings; significantly faster drying, early hardness development and crosslinking. Improved chemical
Basonol® HPE 1170 B
1 69–71 n-Butylacetate 20 270 8.2 4.0 < 40 3 resistances and reflow behavior for 2K PU high solid refinish clear coats and 2K PU high solid topcoats, but also usable for conventional systems to
(HPE-108)
improve chemical resistances
Basonol® HPE 1265 B Low OH value alternative with similar property profile as Basonol® HPE 1170 B, at slightly higher VOC. It shows fast curing speed with fast hardness
1 64–66 n-Butylacetate 38 180 5.5 2.4 < 40 3
(HPE-026) development for early handling and early polishing
* Product that has been evaluated with BASF’s Sustainable Solution Steering method and contributes substantially to sustainability in the value chain.
** Experience of artificial weathering according to DIN 11341, DIN 11507, SAEJ 1960, ASTM G154-06 light stabilizer used with Tinuvin® 384-2 / Tinuvin® 292
*** Fast cure modification
6 Binders for high-performance applications
On the journey of innovation
Binders for high-performance applications
On the journey of innovation 7
Joncryl 942
®
- - 1 1 - Joncryl® 902
Joncryl® 592 1 1 1 1 -
450 Joncryl® 942
Joncryl® 902 1 1 1 - -
Joncryl® 592
Joncryl® 510 1 1 1 - -
Joncryl® 510
400
Joncryl® 922 - 1 1 - - Very low VOC coatings
Joncryl® 922
Joncryl 507
®
1 1 1 - -
250
100 110 120 130 140 150
Fields of application – Main focus on high solid 2K PU OH value on resin solid [mg KOH/g]
Coating composition: Polyol to isocyanate at index 1; solvent xylene 3:2 butyl acetate at 20" DIN 4 flow cup time
Performance level §§ Early block resistance, early handling
§§ Excellent weather resistance
§§ Faster curing speed
Typical area for low VOC coatings Typical area for very low VOC coatings Typical area for 100% liquid coatings
§§ Improved chemical resistance
+HPE §§ High solid pigmented §§ High solid clearcoats §§ Plasticizing effect
§§ Improved reflow behavior
§§ Good curing §§ Mainly chemical drying §§ VOC reduction
§§ Improved final hardness
§§ Acceptable physical drying §§ Adhesion promotion
§§ Increased pot life
Conventional 2K PU High solid 2K PU §§ Minimal impact on VOC
* For details see product selection guide “Resins and additives for furniture and floor coatings”.
8 Natural oil-based binders
On the journey of innovation
Natural oil-based binders
On the journey of innovation 9
The Sovermol® range has been specially designed for use in coatings, adhesives, a nd
putty applications. These natural oil-based, solvent-free binders help you comply with
environmental legislation while meeting even the toughest production regulations.
Improving the environmental profile of your processes will make you more attractive
to both existing and new customers.
Improves glass transition temperature Tg; high crosslinking density, hydrophilic; improvement of chemical resistance; raw materials
Sovermol® 100 1 Branched polyether 3.0 880 64 6 - Co-polyol
registered in EU Directive 2002/72/EG or 2007/19/EC as amended
High shore D hardness (D ~ 80); hydrophobic; high saponification stability; excellent chemical resistance; hydrolysis-stable;
Sovermol® 750 1 Branched polyether/polyester 3.0 315 178 1,100 (20 °C) 65–80 Base polyol
high Tg polyol
High shore D hardness (D ~ 90); hydrophobic; high saponification stability; excellent chemical resistance; hydrolysis stable;
Sovermol® 760 1 Branched polyether/polyester 3.5 390 145 2.3 65–80 Base polyol
extremely high Tg polyol; high heat resistance
Sovermol® 908 1 Aliphatic dimer alcohol 2.0 206 272 2.3 80–100 Base polyol Crack-bridging coatings; good saponification stability; hard elastic performance; hydrophobic
Sovermol® 1055 1 Fatty acid ester with epoxy groups - Ep content 4.6–5.0% EEW = 333 15 (20 °C) 80–100 Non-reactive diluent VOC-free acc. to 2004/42/EU; UV-stable performance; plasticizer for polyols and epoxy resins
Sovermol® 750**
Sovermol® 45 Increase
Sovermol® 908**
Sovermol® 100 chemical stability
Sovermol® 760
Reactive Non-reactive
Sovermol® 1102 Sovermol® 1055
diluent diluent
* Product that has been evaluated with BASF’s Sustainable Solution Steering method and contributes substantially to sustainability in the value chain.
** Low color
10 Natural oil-based binders
On the journey of innovation
Natural oil-based binders
On the journey of innovation 11
Low viscosity universal polyol; binder for pigment pastes; crack-bridging floorings; good chemical resistance; hydrophobic; good
Sovermol® 815 1 Branched polyether/polyester 3.5 215 260 1.5 80–100 Base polyol
elastic-memory effect
Low viscosity universal polyol; extremely hydrophobic; good self-leveling properties; excellent flexibility at temperatures below 0 °C;
Sovermol® 818 1 Fatty chemistry polyester 2.6 236 238 750 80–100 Base polyol
good bonding properties
Low viscosity universal polyol; extremely hydrophobic; good self-leveling properties; good bonding properties; raw materials registered
Sovermol® 819 1 Fatty chemistry polyester 2.6 240 234 850 80–100 Base polyol
in EU Directive 2002/72/EG or 2007/19/EC as amended
Gel-time prolonger; reactive diluent; hydrophobic; good adhesive properties on metal surfaces; contains epoxy groups (Ep-O = 0.3 to
Sovermol® 860 1 Aliphatic polyol 2.5 210 270 530 (20 °C) 80–100 Co-polyol
1.4%)
Hydrophobic; plasticizer for polyol; soft elastic performance; raw materials registered in EU Directive 2002/72/EG or 2007/19/EC as
Sovermol® 1005 1 Slightly branched aliphatic diol 2.0 122 460 800 (20 °C) 80–100 Co-polyol
amended
Sovermol® 1058 1 Fatty acid ester - - - 5 (20 °C) 80–100 Non-reactive diluent VOC-free acc. to 2004/42/E+P6U; hydrophobic; plasticizer for polyols
Sovermol® 1083 1 Branched polyether/polyester 3.3 170 330 2.1 65–80 Base polyol Universal polyol; excellent impact resistance; shore D hardness (D ~ 60)
Base polyol
Sovermol® 1092 1 Branched polyether/polyester 2.8 283 198 800 65–80 Low viscosity, extremely hydrophobic; hardness similar to epoxy systems; hard elastic performance; good self-leveling properties
and co-polyol
Sovermol® 1093 1 Polyether/polyester 2.1 229 245 2.5 65–80 Co-polyol Hardness similar to epoxy systems; hard elastic performance
Sovermol 1140
®
1 Fatty chemistry polyester 2.7 210 267 1.0 80–100 Co-polyol Gel-time prolonger; hard flexible performance; hydrophobic
Sovermol® 805
Sovermol® 815
Sovermol® 1092
Gel-time Sovermol® 1111 Sovermol® 818 Increase
Sovermol® 1095
prolonger Sovermol® 1140 Sovermol® 819 chemical stability
Sovermol® 100
Sovermol® 1083
Sovermol® 1092
* Product that has been evaluated with BASF’s Sustainable Solution Steering method and contributes substantially to sustainability in the value chain.
12 Water-based dispersions
On the journey of innovation
Water-based dispersions
On the journey of innovation 13
Long pot life (> 6 hours), improved weather resistance, good chemical resistance, good water resistance, good block Durable OH-functional dispersion for amino resin crosslinked industrial foils, and heat-curable coatings, and for economic
Luhydran® S 945 T 1 45.0 2.0 75 60 100
resistance, can be formulated at index 1 to 0.75 ambient curing 2K PU exterior industrial coatings
Excellent adhesion on various plastics (PS, PC, ABS, PMMA) and metals, highly water-resistant, high chemical and RC acrylic polyol emulsion for very hydrophobic ambient-curing 2K PU coatings industrial applications on wood, plastic,
Joncryl® OH 8311 1 42.0 7.6 40 50 120
solvent resistance, good flexibility and metal
Long pot life up to 6 hours, low level of coalescing solvent, excellent chemical resistance, good scratch resistance, For water-based 2K PU high-quality industrial coatings for kitchen and bathroom applications and exterior industrial
Joncryl® OH 8312 1 44.0 8.2 300 48 100
good hardness development at ambient conditions topcoats
Joncryl® OH 8313 1 Low pH version of Joncryl® OH 8312 45.0 2.7 360 48 100 OH-functional dispersion for water-based 2K PU high-quality industrial coatings and exterior industrial topcoats
PU dispersions
Aliphatic PES water-based polyurethane dispersion for high-performance 2K PU coatings for wood and industrial
Good balance of film hardness, flexibility, and toughness, excellent adhesion to metal, e-coat, and various plastic
Joncryl® U 4190 1 36.5 8.5 200 23 - applications; used alone or in combination with other binders; additional use of polyisocyanates improves chemical
substrates; good abrasion resistance and water resistance
resistances
Could be used alone or as co-binder to improve adhesion on difficult metal substrates like galvanized steel, for coatings
Soft PUD with good adhesion on metal substrates, very elastic at good toughness, high chemical resistance,
Joncryl® U 4310 1 40.0 8.0 100 <2 - with fast block resistance at high flexibility, good water-resistant topcoats or primers, also suitable for coatings at low pH
heat resistant, high gloss, good barrier to water and water steam
values; additional use of polyisocyanates improves chemical resistances
Soft PUD with improved adhesion on plastic (ABS/PC) substrates compared to Joncryl® U 4310, with addition of Could be used alone or as co-binder to improve adhesion on difficult metal substrates like galvanized steel; plastics like
Joncryl® U 4320 1 41.0 8.0 50 <0 -
polyisocyanates excellent resistance to boiling water PC/ABS and is also suitable for coatings at low pH values; additional use of polyisocyanates improves chemical resistances
PU dispersions matt
PC-polyurethane dispersion used as stand-alone binder for very deep matt surfaces or as co-binder to reduce gloss levels
Deep matt, medium hardness, high elasticity / flexibility, low temperature flexibility, excellent heat resistance, with effectively; the dispersion is especially recommended for automotive interior applications and industrial applications like
Joncryl U 4170
®
1 35.0 8.0 - <0 -
good haptic, very good hydrolysis resistance consumer design finishes; additional use of polyisocyanates improves chemical resistances; compatible with all anionic
binders, additives, dyes and pigments conventionally used in aqueous finishes
PE-PES-based polyurethane dispersion used alone for very deep matt surfaces or as co-binder to reduce gloss levels
Deep matt, with medium hardness, high elasticity / flexibility, low temperature flexibility, excellent heat resistance, effectively for coatings, especially for applications on plastic substrates; the dispersion is especially recommended for
Joncryl® U 4171 1 high light-fastness, with good haptic, improved adhesion on several plastic substrates and improved creme resis- 35.0 8.0 - <0 - high-performance automotive interior applications and industrial applications like consumer design finishes; additional
tance compared to Joncryl® U 4170 use of polyisocyanates improves chemical resistances; compatible with all anionic binders, additives, dyes, and pigments
conventionally used in aqueous finishes
Deep matt combined with soft touch effect, very good haptic, medium hardness, high elasticity / flexibility, PE-PES-based polyurethane dispersion designed to be used alone or as co-binder for water-based very deep matt topcoats
Joncryl® U 4181 1 low temperature flexibility, excellent heat resistance, high light-fastness, good matt stability at polishing, improved 35.0 10 1,750 <0 - with soft feel effect; additional use of polyisocyanates improves chemical resistances; compatible with all anionic binders,
jetness, good creme and sun creme resistances, improved adhesion on plastic substrates like ABS, ABS/PC additives, dyes, and pigments conventionally used in aqueous finishes
PU dispersions hybrids
Cost-effective, self-crosslinking polyurethane acrylic hybrid for high-quality, water-based coatings; additional use of
Joncryl® HYB 6336 1 Economic, excellent appearance, clarity, improved chemical and scratch resistance 38.0 8.0 50 40 -
polyisocyanates improves chemical resistances
Aliphatic polyurethane / acrylic hybrid with good chemical resistance for high-quality, water-based coatings additional use
Joncryl® HYB 6340 1 Good scratch resistance at high flexibility 40.0 7.6 50 45 -
of polyisocyanates improves chemical resistances
Good adhesion to various plastic substrates such as: ABS, PC, ABS/PC, PMMA, PVC, e-coat, excellent flexibility, Aliphatic polyurethane / acrylic hybrid with good chemical resistance for high-quality, water-based coatings; use alone or
Joncryl® HYB 6341 1 excellent abrasion resistance, high scratch resistance, fast hardness development and high final hardness, good 41.0 7.7 70 45 - in combinations with other binders for water-based primers, functional layers, topcoats; additional use of polyisocyanates
chemical resistance improves chemical resistances
Valid for all products: Zero add-on of NMP (N-Methylpyrrolidone), NEP (N-Ethylpyrrolidone) and other organic solvents
Valid for all products: Zero add-on of formaldehyde, APEO, and tributyl tin compounds
* Product that has been evaluated with BASF’s Sustainable Solution Steering method and contributes substantially to sustainability in the value chain.
14 Water-based dispersions
On the journey of innovation
Water-based dispersions
On the journey of innovation 15
Flooring
Product Automotive Transportation General industry Furniture* Flooring*
(concrete)* Polyurethanes (PU): Improve performance Blends:
excellent performance by replacing part of PU possibility of phase
OH-functional acrylic dispersions for water-based 2K PU coatings (toughness, flexibility, abrasion resis- with polyacrylate (PA) separation
tance, film-forming properties)
Luhydran® S 938 T 1 1 1 1 1 1
Luhydran® S 945 T 1 1 1 1 1 1
Joncryl OH 8311
®
- 1 1 1 - - High tensile strength and elongations as a
Joncryl OH 8312
®
1 1 1 1 1 1 consequence of the multi-phase structure
Joncryl® OH 8313 1 1 1 1 1 1 Tensile strength [N/mm2]
50 Hybrid nanoscale mixing Blend microscale mixing
PU dispersions Polyurethane
40
Joncryl® U 4190 1 1 1 1 1 1
30
Joncryl® U 4310 1 1 1 1 1 1
Joncryl® U 4320 1 1 1 1 1 1 20
High
PU PU
PU dispersions matt 10
Polyacrylate
PA PA
Joncryl U 4170
®
1 - 1 - - - 0
100 200 300 400 500
Joncryl® U 4171 1 - 1 - - - Elongation [%]
Joncryl® U 4181 1 - 1 - - -
Target: development of PU / PA hybrids
PU dispersions hybrids
§§ Improved performance with respect to PU / PA blends
Joncryl® HYB 6336 - - 1 1 1 - §§ Synergistic effects possible (e.g., reduced water uptake, improved chemical resistance)
Joncryl® HYB 6340 - - - 1 1 -
* For details see product selection guide “Resins and additives for furniture and floor coatings”.
16 Crosslinkers
On the journey of innovation
Crosslinkers
On the journey of innovation 17
Basonat®
aliphatic polyisocyanates
Sustainability
Product Type NCO [%] Solid content [%] Solvent cut Viscosity [mPa∙s] Description and application
Accelerator*
Basonat® HB 175 MP/X - 16.0–17.0 74–76 Methoxypropyl acetate / Xylene 1:1 130–300 Biuret grades known as polyisocyanate for general use in 2K PU coatings; applications extend from automotive topcoats, especially for plastic substrates, to general industry
HDI biuret
Basonat HB 275 B
®
- 16.0–17.0 74–76 n-Butyl acetate 100–180 and high-performance wood coatings
Basonat® HB 475 B/X - 16.0–17.0 74–76 n-Butyl acetate / Xylene 1:1 100–250
Basonat® HI 268 B/S - 14.5–15.5 67–69 n-Butylacetate / Solvesso®1 100 1:1 39–55
Basonat® HW 1180 PC 1 13.0–14.0 79–81 Propylene carbonate (Solvenon® PC) 450–850 Basonat® HW 1000 in an 80% solution of propylene carbonate for better incorporation in water-based 2K PU systems; performance is directly comparable to Basonat® HW 1000
Easier to incorporate version of Basonat® HW 1000; modern emulsification chemistry leads to faster hardener distribution in water-based coatings, providing better gloss levels and better
Basonat® HW 2000 1 17.5–18.5 100 - 1,500–3,000
Hydrophilic mechanical properties; high chemical reactivity with low impact on pot life
General-purpose hydrophilic polyisocyanate for use in water-based high performance 2K PU coatings with low VOC; balanced property profile regarding resistance, reactivity, and
Basonat® HW 2100** 1 16.9–17.9 100 - 2,000–3,600
compatibility with primary and secondary dispersions
A special polyisocyanate for fast-drying 2K PU water-based coatings; the touch to dry time in primary and secondary dispersions is significantly decreased compared to conventional
Basonat® HW 3180 B 1 11.5–12.5 79–81 n-Butylacetate 500–1,500
hydrophilic polyisocyanates; in primary dispersion pot life is significantly longer without reduced chemical-resistance development
Basonat HA 1000
®
1 Low-viscous 21.0–23.0 100 - 900–1,500 For use in secondary dispersions, these low-viscous polyisocyanates are recommended for fast distribution in the coatings system while mixing; all our low-viscous polyisocyanate products
Basonat HA 2000
®
1 18.5–21.5 100 - 500–900 are miscible in most available secondary dispersions, when combined with Basonat® HW types, faster incorporation, better appearance and improved mechanical properties can be achieved
HDI allophanates
Basonat® HA 3000 1 19.0–20.0 100 - 200–400
BASF offers additives for a wide spectrum of applications. Part of our portfolio are UV
absorbers (UVA) and hindered amine light stabilizers (HALS) for effective stabilization
against the detrimental effects of light and weathering. To complement the comprehen
sive offer for coatings, we provide a full range of formulation additives.
Product Description
Light stabilizers
UV absorber for water-based and solvent-based coatings; prevents degradation
UV absorbers Tinuvin®
of both coatings and substrates by filtering out the harmful UV radiation
Formulation additives
Rheovis® (organic)
Rheology modifiers Efka®
Attagel® (clays)