Chemistry Target _Bonding_ Coordination

AIIMS compound
_ 10.05.2019 Class Test
10. In which of the following molecule Dipole
Bonding moment (Observed) is found to be greater than
1. Which of the following do not characterize ionic Dipole moment (theoretical) ?
compounds ?
(1) These compounds usually exist in solid state
(2) These posses high melting & boiling points
(3) These are insoluble in solvent with high (1) (2)
dieelectric constant
(4) These are good conductors of electricity
2. The compound with maximum negative lattice
energy is –
(1) NaF (2) NaCl (3) (4)
(3) AlF3 (4) MgF2
3. Which of the following is not an odd electron
molecule ? 11. In which of the following pair, all the bonds are
(1) NO (2) NO2 not of equal length ?
(1) BeCl2,H2O (2) CH4,CCl4
(3) O2 (4) None of these
(3) IF5, PCl5 (4) PCl3, NH3
4. Select the incorrect statement
12. What should be the correct statement wrt XeF5 ?
(1) In dsp3 hydridization d participates (1) Xe has sp3d hybridization
(2) It is square planar
(2) In sp3d2 hybridization d & d z 2 participate
(3) There are two non – bonding electron pairs,
(3) In sp3d hybridization d z 2 participates one above the plane & other below the plane
(4) None of these (4) It is an odd electron species
13. Which species has the maximum number of
5. Select the correct statement about ClO3 & SO23 lone pairs of electrons on the central atom ?
(1) Both are isostructural but not isoelectronic
(1) ClO3 (2) XeF4
(2) Both are isoelectronic but not isostructural
(3) Both are neit her i soelect ronic nor (3) SF4 (4) I3
isostructural
(4) Both are isoelectronic & isostructural 14. The geometry around the central atom is CIF4
6. Which of the following statements is incorrect ? is
(1) XeO2F2 & SF4 have see – saw shape (1) Square planar (2) Square pyramidal
(2) Among IF7 & PCl5,PCl5 has lesser number of (3) Octahedral
atoms in XY plane (4) Triagonalbipyramidal
(3) SF4 is planar molecule 15. The xenon compounds that are isostructural
(4) O atom in H2O is sp3 hybridized with IBr2 & BrO3 , respectively are –
7. Which of the following is a wrong order w.r.t. the
(1) Linear XeF2 & pyramidal XeO 3
property mentioned against each ?
(2) Bent XeF2 & pyramidal XeO3
(1) (magnetic moment) (3) Bent XeF2 & planar XeO3
(4) Linear XeF2 & tetrahedral XeO 3
(2) (Bond length)
(3) H2 > (bond energy) Coordination compound
16. Which of the following cannot act as ambidentate
(4) (bond length)
ligand ?
8. Arrange the following in decreasing order of bond (1) thiosulphate ion (2) selenocyanide ion
angles (3) thiocyanate ion (4) None of these.
COF2,COCl2, COBr2, COI2 17. The correct formula of the complex named tris
(1) COF2 > COCl2 > COBr2 > COI2 (ethane – 1, 2 –diamine) cobalt (III) sulphate is :
(2) COI2 > COBr2> COCl2 >COF2 (1) [Co(en)3]SO4 (2) [Co(en)2]SO4
(3) COF2 = COCl2 > COBr2 > COI2 (3) [Co(en)3]2SO4 (4) [Co(en)3]2(SO4)3
(4) None of these 18. The correct IUPAC na me for [ (CO ) 3
9. Which of the following paris is iso – structural ? Fe(CO)3Fe(CO)3] is :
(1) (2) HCN & SnCl2 (1) tri –  – hexacarbonyl iron (II)
(3) SO3 & CH4 (4) None of these (2) tri –  – carbonyl – bis tricarbonyl iron (o)
(3) tri –  – nanocarbonyl iron (III)

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Chemistry Target _Bonding_ Coordination
AIIMS compound
_ 10.05.2019 Class Test
(4) hexa –  – tricarbonyl ferrate (o)
19. For the complex [Co (H 2O)2(NH3)2Cl2]+, the total
number of stereoisomers is/are:
(1) 5 (2) 4
(3) 7 (4) 6 (3) (4)
20. The number of geometric isomers that can exist
for sq. planar [Pt(Cl)(Py)(NH3) (NH2OH)]+ is :
(Py = Pyridine)
(1) 2 (2) 3
(3) 4 (4)6 36. Major product :
21. How many optical isomers are possible for the
complex [Ni(H 2O)(Cl)(NH 3)(NH 2OH)]NO 2 with
magnetic moment 2.82 B.M.? (1) (2)
(1) 2 (2) 5
(3) 0 (4) 3
22. Amongst the following ions, which one has the
highest paramagnetism ? (3) (4)
(1) [Cr(H2O)6]3+ (2) [Fe(H2O)6]2+
2+
(3) [Zn(H2O)6] (4) [Cu (H2O)6]2+ 37. The product of the following reaction is :
23. The hybridisation, oxidation number of central
metal ion & shape of wilkinsons ca talyst
[Rh(PPh3)3Cl] is :
(1) dsp2, + 1, square planar Product
(2) sp3, + 1, tetrahedral
(3) d2sp3, + 1, square planar
(4) None of these
24. What is the correct configuration for a metal ion
with d7 for octahedral complex in the presence
(1) (2)
of strong field ligands ?
(1) t2g6 eg1 (2) t2g5 eg2
3 4
(3) t2g eg (4) t2g4eg3
25. Calculate EAN of Ag in [Ag(CN)2]–
(1) 50 (2) 92
(3) 66 (4) 34. (3) (4)

Reaction mechanism 38. CH 3 – CH2 – CH = CH2

34. Consider the reaction,
CH3CH2CH2Br + NaCN CH3CH2CH2CN + NaBr
This reaction will be the faster in :
(1) ethanol
Product ‘B’ is
(2) methanol
(3) N, N’–dimethylformamide (DMF)
(1)
(4) water
35. Which of the following compounds will undergo (2)
substitution of the halogen atom most readily
with CH3ONa in CH3OH ?
(3)

(4)
(1) (2)

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Chemistry Target _Bonding_ Coordination
AIIMS compound
_ 10.05.2019 Class Test

(1)
39.

(2)

(3)

This change can be done by :

(1) acid catalysed hydration
(2) oxymercuration – demercuration (4)
(3) hydroboration – oxidation
(4) any method mentioned above
Hydrocarbond
44. Acetylene gives :
40. (1) white ppt. with ammonical AgNO3 and red ppt.
with ammonical Cu (NO 3)2
Product is : (2) white ppt. with ammonical AgNO3and red ppt.
with ammonical Cu 2Cl2
(3) white ppt. with both
(1) (2) (4) red ppt. with both
45. A hydrocarbon with formula C 8H18 gives one
monochloro derivative. The hydrocarbon can be
(3) (4) :
(1) n – Octane (2) 2 – Methylheptane
(3) 2, 2, 4 – Trimethylbutane
41.
(4) 2, 2, 3, 3 Tetramethylbutane
46. Bond length of Ethane (I), Ethene (II), Acetylene
(III) and Benzene (IV) follows the order :
(1) I > II > III > IV (2) I > II > IV > III
(3) I > IV > II > III (4) III > IV > II > I
47. Ozonolysis of C 7H 14 gave 2 – methyl – 3 –
pentanone. The alkene is :
(1) 4 (2) 6 (1) 2 – Ethyl – 3 – methyl – 1 – butene
(3) 8 (4) 10 (2) 3 – Ethyl – 2 – methyl – 3 – butene
(3) 2, 5 – Dimethyl – 3, 4 – dimethylhex – 3 – ene
(4) 3 – Ethyl – 2 – methyl – 1 – butene
42. 48. Tetrabromoethane on treatment with Zn gives :
(1) ethyl bromide (2) ethane
(3) ethene (4) ethyne
49. W hich of t he following req uire s r adic al
intermediates ?
(1) (2)
(1)

(3) (4) (2)

(3)

43.

Compound ‘C’ is

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Chemistry Target _Bonding_ Coordination
AIIMS compound
_ 10.05.2019 Class Test
(1)(2)(3)(4)
(4) (1)(2)(3)(4)
50. Which is most easily dehydrohalogenated ? (1)(2)(3)(4)
(1)(2)(3)(4)
Cl (II) Cl (III) Cl (1)(2)(3)(4)
(I)
(1)(2)(3)(4)
(1) I (2) II
(3) III (4) all with same case

51. Product A, A is :

(1) (2)

(3) (4)

52. Major product :

(1) (2)

(3) (4)

53. + Ac2O

Product ‘C’ is

(1)

(2)

(3)

(4)