AliTS-6 - XII - APT 3 - Set-D PDF

JEE
FIITJEE- ALL (Advance)

INDIA iNTERNAL TEST SERIES
CHEMISTRY, MATHEMATICS & PHYSICS
SET – D
APT - 3 CODE: 080093.4 Ai2TS - 6
Time Allotted: 3 Hours Maximum Marks: 180
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
CLASS-XII
3. Section-1 is Chemistry, Section-2 is Mathematics and Section-3 is Physics.

4. Each section is further divided into two Parts: Part-A & Part-C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will
be provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and
electronic devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your
Enrolment No. and write in ink your Name, Test Centre and other details at the designated
places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Parts.
(i) Parts-A (01 – 10) contains 10 Multiple Choice Questions which have only one correct
answer. Each question carries +2 marks for correct answer and no negative marks for wrong
answer.
(ii) Part-A (11 – 15) contains 05 Multiple Choice Questions which have one or more than one
correct answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
(iii) Parts-C (01 – 05) contains 05 Numerical Based Questions with single digit integer as answer,
ranging from 0 to 9. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
Website: www.fiitjee.com
2
Ai2TS-6-(APT-3)-SET-D-CMP-XII ALL INDIA iNTERNAL TEST SERIES
SECTION – 1 (Chemistry)
PART – A
(Single Correct Choice Type)
This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
1. Which of the following hydrogen is the strongest reducing agent?
(A) Molecular Hydrogen (B) Ortho Hydrogen

(C) Nascent Hydrogen (D) Para Hydrogen
2. Which of the following contains the most acidic hydrogen atom?
H H
H
H
(A) (B) (C) (D)
3. How many optically active cyclic isomer(s) is/are possible with formula C 5H10?
(A) One (B) Two (C) Three (D) Four
Ka
4. The pH of a buffer of CH3COOH and CH3COONa will be equal to the p of CH3COOH. In order to
have this pH, CH3COOH and NaOH should be taken respectively in the molar ratio of
(A) 1:2 (B) 2:1 (C) 1:1 (D) 1:4
5. The class of drugs used for the treatment of stress is:
(A) Analgesics (B) Antiseptics (C) Antihistamine (D) Tranquillizers
6. Which of the following compound is not formed by the reaction between sodium metal and oxygen
gas?
(A) Na2O (B) NaO (C) Na2O2 (D) NaO2
Space for rough work
3
7. Which of the following chloride does not undergo nucleophilic substitution reaction?
Cl Cl CH2Cl CH2Cl
(A) (B) (C) (D)
8. Which of the following compound displays the highest number of isomerism?
Cl Cl
Cl Cl
(A) (B) (C) (D)
Cl Cl
Cl Cl
9. C2H5
CH3CHCH2CH2Cl 
Anhy. AlCl3
 Major product P 
CH3
P  
 Monochloro product  s 
Cl2
h
How many monochloro product(s) is/are formed in the above reaction?

[Do not consider stereoisomerism]
(A) 3 (B) 6 (C) 5 (D) 4
Hg OAC 2,H2O B2H6 ,THF

10. Y   CH3 CH  CH2  X
NaBH4 H2O2 ,OH
Which of the following statement is not correct about the products(X and Y) of above reaction?
(A) ‘X’ forms CH3CH = CH2 when reacts with conc.H2SO4 at high temperature.
(B) ‘X’ and ‘Y’ are position isomers.
(C) ‘Y’ forms a saturated hydrocarbon when reacts with HI/P.
(D) X and Y contain different functional groups.
4
(Multi Correct Choice Type)

which ONE OR MORE may be correct.
11. CH3
Cl /h Cl2 /Fe

S 
2
  P  Q  R
Choose correct statement(s) regarding the above monochlorinated products P, Q, R and S?
(A) P, Q, R from the same product when undergo electrophilic nitration.

(B) ‘S’ undergoes the easiest nucleophilic substitution reaction than P, Q and R.
(C) P, Q and R undergo oxidation with hot alkaline KMnO4 to form substituted benzoic acid.
(D) ‘S’ on hot alkaline permanganate oxidation forms benzoic acid.
12. Which of the following statement(s) is/are correct for a base, M(OH) 2 which solubility product is 4 
–12 o
10 at 25 C?
–4 –1
(A) The maximum solubility of the base in water is 10 mol L at room temperature.
(B) The pH of its saturated solution is 10.3.
(C) The solubility of the base increases if NH4Cl is added to the system.
–1
The solubility of the base at pH = 6 is 4  10 mol L .
4
(D)
13. CH3
CH 3 - C The correct statement regarding the above carbocation is:
CH 2CH 3
(A) The maximum number of hyperconjugation structures possible for the carbocation is 8.
2
(B) All carbon atoms of the carbocation are sp -hybridized.
(C) The carbon atom that holds the positive charge is an electron deficient species.
(D) The CH3 groups stabilize the carbocation by +R effect.
14. CH2CH2CH3
The isomerism shown by the given compound is/are:

CH2CH2CH3
CH3 CH3
(A) Chain Isomerism (B) Position Isomerism

(C) Geometrical Isomerism (D) Optical Isomerism
15. Which of the following substance(s) on heating produce a raddish brown colour gas?
(A) LiNO3 (B) NaNO3 (C) Mg(NO3)2 (D) Ca(NO3)2
5
PART – C
(Integer Answer Type)
This section contains 05 multiple choice questions. The answer to each question is a single digit integer, ranging
from 0 to 9 (both inclusive).
1. How many acyclic isomer(s) is/are possible with formula C4H8?
2. What is the pH of 0.001 M aqueous solution of sodium acetate(CH 3COONa)?

–5
[Ka(CH3COOH) = 10 ]
3. How many hyperconjugation structure(s) is/are possible for the following species?
4. How many stereoisomers (geometrical + optical) are possible for the compound below?
Cl
CH3CH = CH - CH - CH = CHCH3
5. How many minimum number of chlorine atom(s) does a polychloride contain, which on hydrolysis
forms a  - keto acid?
6
SECTION – 2 (Mathematics)
PART – A
x
x
1. dx 
x2  1
x2 x2
(A)  x2  1  c (B)  x2  1  c
2 2
x3 x3
1
x   
3/2 3/2
(C)  2
1 c (D)  x3  1 c
3 3 3
x5
2.
x 2
1
dx 
x4 x2 x4 x2
(A)
4

2
 tan1 x  C (B)
4

2

1
2
 
log x 2  1  C
x4 x3 x4 x2
(C)   tan1 x  C (D)   tan1 x  C
4 3 4 3
x2 y2
The curve x  y  5 and
2 2
3.   1 cut each other at any common point at an angle
18 8
  
(A) (B) (C) (D) None of these
4 3 2
4. The centroid of the triangle whose three sides are given by the combined equation
x 2

 2y2  7xy  y  1  0 is
2  7 2  7 2
(A)  , 0 (B)  ,  (C)  ,  (D) None of these
3  3 3  3 3
The distance between the origin and the normal to the curve y  e  x 2 at x = 0 is
2x
5.
2 2 2
(A) (B) (C) (D) None of these
3 5 7
7
x  3x  7x  x  1
9 5 3  /4
6. If f(x)  2
cos x
, then

 /4
f(x)dx is equal to
(A) Zero (B) /2 (C) 2 (D) 1
f  x  2t
7. Let f : R  R be a differentiable function and f 1  4 . Then the value of lim
x 1 4 x  1
dt is

(A) 8f ' 1 (B) 4f ' 1 (C) 2f ' 1 (D) f ' 1
x tan1 x k1 tan1 x  k 2
8. If
 (1  x 2 )3/2
dx 
1  x2
c
where k1, k2 are polynomial function of variable x and c is any real constant then value of
2
 max k ,k dx is
0
1 2
2 2 3 1
(A) (B) (C) (D)
3 3 2 2
9. The angles of intersection of curves y   sin x  cos x  and x2  y 2  5 , where [.] denotes
the greatest integer function is
 1 
(A) tan1 2 (B)
 1
tan1  
2
(C) tan1  2 (D) tan1 
 2

10. Solution of  3x  2y  1 dx   3x  2y  1 dy  0 is
log 15x  10y  1  c

5
(A) (B) log 15x  10y  1  x  y  c
2
5
(C)  x  2  log 15x   c (D) None of these
2
8

3 2
11. The curve y = ax + bx + cx + 5 touches the x - axis at P(-2, 0) and cuts the y - axis at a point Q
where its gradient is 3, then
(A) 2a+4b+c = -1 (B) 2a+4b+c = 1 (C) 4a+4b+c = -2 (D) 2a+3b+c = 4
12. The sides of a triangle are x  y  1, 8y  x and 3y  x  0 then the following is an interior point of
the triangle
(A) Circumcentre (B) Centroid (C) Incentre (D) Orthocentre
13. Which of the following is /are true?
1 2 1 1
     
sin 2x 1
(A) sin x 2  2x  1 dx – sin x 2dx  0 (B) esinx dx  e dx  0
0 1 1 0
4 1 4 1
 sin  x   sin  x   cos x 

dx  8 cos16  2x  1 dx  0
2
(C)
2
 3 dx  2
 12x  33 dx  0 (D)
2
5 2 4 0
14. If the equations of hypotenuse and a side of a right angled isosceles triangle be x  my  1 and
x  k respectively then
(A) m=1 (B) m=k (C) m = –1 (D) m+k=0
15. A straight line through the point A(-2, -3) cuts the line x + 3y = 9 and x + y + 1 = 0 at B and C
respectively. If AB.AC = 20 then equation of the possible line is
(A) x–y=1 (B) x–y+1=0 (C) 3x – y = 3 (D) 3x – y + 3 = 0
9
PART – C
Area bounded by the curve x  ky, k  0 and the line y = 3 is 12 sq. units then k is ________
2
1.
x 2
  f  t    f  t 
1 1
2. If f (x) = 2
dt and 2
dt  3 6 , then f (9) is equal to
0 0

14f(0)
3. A function f is defined by f(x)  cos t cos(x  t)dt, 0  x  2, then maximum value of is
0

 /3
 
4. If f  x  is an integrable function in  ,  and I 
6 3 1
 /6

sec 2  .f  2 sin 2 d and
 /3

I2
I  cosec 2    .f  2 sin 2 d, then is ________
2 I1
 /6
5. A particle moves in a straight line such that the distance covered by it in time t seconds measured
t3
from a fixed point on the line is given by s =  16t cms. The acceleration when the velocity is
3
zero is
10
SECTION – 3 (Physics)
PART – A
1. A thin uniform rod of mass 1 kg and length 2 m is free to rotate about its upper end. When it is at
rest, it receives an impulse of 10 Ns at its lowest point, normal to its length. The value of angular
velocity of rod just after impact is
(A) 10 rad/s (B) 15 rad/s (C) 20 rad/s (D) 25 rad/s
2. A recording disc rotates steadily at 45 rev/min on a table. When a small mass of 0.02 kg is dropped
gently on the disc at a distance of 0.04 m from its axis and stocks to the disc, the rate of revolution
falls to 36 rev/min. The moment of inertia of the disc about its centre is
–4 –5 –3 –2
1.28  10 kg – m 1.28  10 1.28  10
2 2 2
1.28  10 kg – m
2
(A) (B) kg – m (C) kg – m (D)
3. Moment of inertia of a uniform symmetric plate as shown in figure y-axis

about x-axis is I. Moment of inertia of this plate about an axis
passing through centre of plate O and perpendicular to the plane of
plate is 600
(A) 2I O
x-axis
(B) I
(C) I/2
(D) I/4
4. A body (solid sphere) of mass m makes an elastic collision with another identical body at rest. Just
after collision the angle between the velocity vector of one body with the initial line of motion is 15°
then the angle between velocity vector of the other body with the initial line of motion is
0 0 0 0
(A) 75 (B) 60 (C) 45 (D) 30
5. In the given figure a ring of mass m is kept on a horizontal surface while a particle of equal mass ‘m’
attached through a string, which wounded on the ring. When the system is released the ring rolls
without slipping. Consider the following statements and choose the correct option.
(i) acceleration of the centre of mass of ring is 2g/3
(ii) acceleration of the hanging particle is 4g/3 m
(iii) frictional force (on the ring) acts along forward direction
(iv) frictional force (on the ring) acts along backward direction
(A) Statement (i) and (ii) only
(B) Statement (ii) and (iii) only
(C) Statement (iii) and (iv) only m
(D) None of these
11
6. A ball after falling through a distance h collides with an inclined plane of

inclination  as shown. It moves horizontally after the impact. The co-efficient h
of restitution between inclined plane and ball is (inclined surface is friction
less) 
(A) 1 (B) tan2  (C) cot2  (D) sin2 

7. A solid sphere of radius R is rolled by a force F acting at the
top of the sphere as shown in the figure. There is no slipping
and initially sphere is at rest. Then
Rough
(A) Work done by force F when the center of mass moves a distance S is 2FS
20 RS
(B) Speed of the c.m. when c.m. moves a distance S is
9 M
(C) Work done by the force F when c.m. moves a distance S is FS
4RS
(D) Speed of the c.m. when c.m. moves a distance S is
M
8. A uniform body of mass M of radius R has a small mass m attached at edge as shown in the figure.
The system is placed on a perfectly rough horizontal surface such that mass m is at the same
horizontal level as the centre of body. It is assumed that there is no slipping at point A. If IA is the
moment of the inertia of combined system about point of contact A then the normal reaction at point
2
A just after the system is released from rest is (M = 6 kg, m = 2 kg, I A = 4kg m , R = 1m,
2
g = 10m/s )
(A) 60N M
m
(B) 80 N
(C) 75 N
(D) 70 N A
9. The mass collide in air stick together. After how much time m Just dropped
combined mass will fall to the ground (calculate the time from the
starting when the motion was started
(A) 1  2  s 20 m
20 m/s
(B) 2 2s
(C) 2  2  s m
(D) None of these
10. After a totally inelastic collision, two objects of the same mass and same initial speed are found to
move together at half of their initial speed. The angle between the initial velocities of the objects is
(A) 120° (B) 90° (C) 60° (D) 30°
12

11. A disc is given an initial angular velocity 0 and placed on rough horizontal
surface as shown. The quantities which will not depend on the coefficient of
friction is/ are
(A) The time until rolling begins
(B) The displacement of centre of mass of the disc until rolling begins
(C) The velocity when rolling begins
(D) Angular velocity when rolling begins
12. A constant force F is applied at the top of a ring as shown in figure. Mass of the ring is M and radius
is R. The angular momentum of ring about point of contact at time t
(A) is constant
(B) increases linearly with time F
(C) is 2F Rt
(D) decreases linearly with time
13. A rod of mass 'M  m' carries an insect of mass ‘m’ at its bottom end and its top end is connected
with a string which passes over a smooth pulley and the other end of the string is connected to a
counter mass M. Initially the insect is at rest. Choose the correct option(s).
(A) As insect starts moving up relative to rod, the acceleration of centre of mass of
the system (insect + rod + counter mass) becomes non-zero.
(B) As insect starts moving up relative to rod, tension in the string remains constant
and is equal to Mg.
(C) As insect starts moving up relative to rod, the tension in the string becomes M
more than Mg. M m
(D) Acceleration of centre of mass of the system (insect + rod +counter mass) is
zero when insect moves with constant velocity m
14. The end B of the rod AB which makes angle  with the floor is y
being pulled with a constant velocity vo as shown. The length of A
the rod is . At the instant when  = 37
o
 vo
O B x
4 5 vo
(A) velocity of end A is v o downwards (B) angular velocity of rod is
3 3 
(C) angular velocity of rod is constant (D) velocity of end A is constant
15. A cannon shell is fired to hit a target at a horizontal distance R, however it breaks into two equal
parts at its highest point, one part returns to the cannon. The other part
(A) will fall at a distance R beyond target (B) will fall at a distance 3R beyond target
(C) will hit the target (D) have nine times kinetic energy of first
13
PART – C
1. 2 –
A ball of diameter 40 cm is rolling on a table without slipping with velocity of centre of mass  ms
5
1
. If the ball leaves the edge of the table at time t = 0 sec horizontally and falls to the ground 20 m
below. Find the number of rotations performed by the ball before hitting the ground.
2. A tangential force F acts at the top of a thin spherical shell of

mass m and radius R. If it rolls without slipping then F
xF
acceleration is given by a  . What is the value of x? R
5m
m
3. Figure shows a uniform disc of radius R from which a hole of Y
radius R/2 has been cut out from left of the centre and is
placed on right of the centre of disc. The centre of mass of
resulting disc is at a distance R/n from centre of uniform disc.
(-R/2,0) (-R/2,0)
Find the value of n
4. A solid and rigid sphere of mass m = 80 kg and radius 0.2 m is spun

about a horizontal axis at an angular speed of  and then dropped
without initial speed onto a stationary cart of mass
M = 200 kg from a height of h = 1.25 m. It hits the cart exactly at the
centre. The cart can roll smoothly, its deformation in the collision is
perfectly elastic, and the collision is momentary. The sphere keeps
sliding throughout the entire duration of the collision. The coefficient of
kinetic friction between the sphere and the cart is  = 0.1. The sphere
rebounds from the cart and falls back onto it again. The minimum
10x
possible length of the cart is X. The value of is.
4
5. A ball of mass 1 kg moving with velocity 10 m/s collides m Vo = 10 m/s

perpendicularly on a smooth stationary wedge of mass 2kg. If
the coefficient of restitution is e = 7/20 then find the velocity of
M
–1
ball after the collision. [in ms ]
 = 30°

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JEE

FIITJEE- ALL (Advance)

APT - 3 CODE: 080093.4 Ai2TS - 6

Time Allotted: 3 Hours Maximum Marks: 180

3. Section-1 is Chemistry, Section-2 is Mathematics and Section-3 is Physics.

B. Filling of OMR Sheet

C. Marking Scheme For All Parts.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

1. Which of the following hydrogen is the strongest reducing agent?

(A) Molecular Hydrogen (B) Ortho Hydrogen

2. Which of the following contains the most acidic hydrogen atom?

(A) One (B) Two (C) Three (D) Four

(A) 1:2 (B) 2:1 (C) 1:1 (D) 1:4

5. The class of drugs used for the treatment of stress is:

(A) Analgesics (B) Antiseptics (C) Antihistamine (D) Tranquillizers

(A) Na2O (B) NaO (C) Na2O2 (D) NaO2

Space for rough work

(A) (B) (C) (D)

8. Which of the following compound displays the highest number of isomerism?

(A) (B) (C) (D)

How many monochloro product(s) is/are formed in the above reaction?

(A) 3 (B) 6 (C) 5 (D) 4

Hg OAC 2,H2O B2H6 ,THF

Space for rough work

(Multi Correct Choice Type)

Cl /h Cl2 /Fe

Choose correct statement(s) regarding the above monochlorinated products P, Q, R and S?

(A) P, Q, R from the same product when undergo electrophilic nitration.

CH 3 - C The correct statement regarding the above carbocation is:

The isomerism shown by the given compound is/are:

(A) Chain Isomerism (B) Position Isomerism

(A) LiNO3 (B) NaNO3 (C) Mg(NO3)2 (D) Ca(NO3)2

Space for rough work

1. How many acyclic isomer(s) is/are possible with formula C4H8?

2. What is the pH of 0.001 M aqueous solution of sodium acetate(CH 3COONa)?

Space for rough work

Space for rough work

(A) Zero (B) /2 (C) 2 (D) 1

log 15x  10y  1  c

Space for rough work

(Multi Correct Choice Type)

(A) 2a+4b+c = -1 (B) 2a+4b+c = 1 (C) 4a+4b+c = -2 (D) 2a+3b+c = 4

(A) Circumcentre (B) Centroid (C) Incentre (D) Orthocentre

13. Which of the following is /are true?

 sin  x   sin  x   cos x 

(A) m=1 (B) m=k (C) m = –1 (D) m+k=0

(A) x–y=1 (B) x–y+1=0 (C) 3x – y = 3 (D) 3x – y + 3 = 0

Space for rough work

Space for rough work

(A) 10 rad/s (B) 15 rad/s (C) 20 rad/s (D) 25 rad/s

3. Moment of inertia of a uniform symmetric plate as shown in figure y-axis

Space for rough work

6. A ball after falling through a distance h collides with an inclined plane of

(A) 1 (B) tan2  (C) cot2  (D) sin2 

(A) 120° (B) 90° (C) 60° (D) 30°

Space for rough work

(Multi Correct Choice Type)

Space for rough work

2. A tangential force F acts at the top of a thin spherical shell of

3. Figure shows a uniform disc of radius R from which a hole of Y

4. A solid and rigid sphere of mass m = 80 kg and radius 0.2 m is spun

Batch :__ Date of Examination :_