Punjab Group Of Colleges Federal Board Campus

Roll No. (2) (2) (2) (2) (2) (2) Answer Sheet No.___________

Sign. of Candidate._______________ Sign. of Invigilator.__________

(CHEMISTRY HSSC-I)
QUARTER TEST 1
CHAPTER#1,2&3
Time Allowed: 02 hrs Max. Marks=60
SECTION-A (1×11=11)
Q.1 Encircle the correct option A/B/C/D of the following given statement
i. Which sample contains the greatest number of molecules?
a) 1.0g of CH4 b) 1.0g of H2O c) 1.0g of HNO3 d) 1.0g of N2O4
ii. How many moles of oxygen are required for the complete combustion of two
moles of butane?
a) 2 b) 8 c) 10 d) 13
iii. The wavelength of green light is 500nm. Its frequency is equal to:
a) 6×1014Hz b) 6 Hz c) 1.5Hz d) 1.5×102Hz
iv. On the basis of VSEPR theory, a molecule with three bond pair and no lone
pair of electrons will have a
a) Linear b) Trigonal planner c) Tetrahedral d) Trigonal planer
2
v. The central atom is sp hybridized in:
a) CH4 b) BeCl2 c) BF3 d) H2O
vi. The bond energy is independent of :
a) Atomic size b) London forces c) Bond length d) Bond order
vii. What is the value of (n+l) for the 3d subshell.
a) 3 b) 5 c) 4 d) 6
viii. What is the mass of one mole of Iodine molecules?
a) 254g b) 74g c) 106g d) 127g
ix. “No two electrons in the same orbital can have the same value of four
quantum numbers” this statement is known as ,
a) Auf bau principle b) Hund’s rule
c) Pauli’s exclusion principle d) Common ion effect
x. Which of the following has greater bond energy?
a) N-N bond b) C-O bond c) C-N bond d) C-C bond
xi. The S.I unit of dipole moment is:
a) Pm b) Debye c) mC d) All of these
 Punjab Group Of Colleges Federal Board Campus
Roll No. (2) (2) (2) (2) (2) (2) Answer Sheet No.___________

Sign. of Candidate._______________ Sign. of Invigilator.__________

SECTION-B (Chapter-1&2 (H-Spectrum)

Q.2 Attempt all parts. Each part carry equal marks (6×3=18)
i. How many covalent bonds are present in 20g of N2?
ii. The actual yield is lesser than the theoretical yield. Why
iii. Give the statement of Zeeman Effect?
iv. Evaluate the mass of an electron with the help of e/m and charge value?
v. Calculate the wave number of the radiation emitted by an electron when it
jumps from 5th shell to 2nd shell?
vi. Write properties of neutron. (Any three)
SECTION-C (Chapter-2&3)
Q.3 Attempt all parts. Each part carry equal marks (6×3=18)
i. How sigma and pi bonds are formed and explain why sigma bond is stronger
than pi bond?
ii. Explain the paramagnetic behavior of oxygen molecules with the help of MOT.
iii. Define X-Rays. How Moseley law helps in the production of X-Rays?
iv. Define Hund’s rule. How it helps to determine the valancy of elements. Give
example?
v. What is dipole moment? Write its formula and unit.
vi. Write the Electronic configuration of the following element: +2Cr24 , +2Zn30
SECTION-D
Q.4 Explain the following in detail (Any One) (1×13=13)
1.
a) How much silver chloride will be formed by mixing 120.0g of silver
nitrate with a solution of 52.0g of NaCl? (7)
AgNO3 + NaCl→AgCl+NaNO3
b) Derive an Expression to calculate the radius of nth orbit of an atom. (6)
OR
2.
a) What is Hybridization? Give its types and explain sp2 hybridization in
Ethene(C2H4)? (7)
b) Explain the following molecules with the help of VSEPR theory?
CH4 , NH3 , CO2 (6)

(Ag=107.87, N=14, O=16, Na=23, Cl=35.5)