Topic Practice 3

Very Short Answer Type Questions |1 Mark|

1. Fill in the Blanks
(i) Elements from atomic number 57 to 71 are called …….. (A) and from 89 to 103 are called
………. (A).
In the above sentence (A) and (B) are
(a) transition elements, lanthanoids
(b) p-block elements, actinoids
(c) lanthanoids, actinoids
(d) actinoids, lanthanoids
(ii) Element europium has atomic number ……. .
(iii) Atomic number of element lutetium is …….. .
(iv) The last member of actinoid series with atomic number 103 is ……… .
2. Objective Type Questions
(i) Arrange Ce3+, La3+, Pm3+ and Yb3+ in increasing order of their ionic radii.
(a) Yb3+ < Pm3+- < Ce3+ < La3+
(b) Ce3+ < Yb3+ < Pm3+ < La3+
(c) Yb3+ < Pm3+ < La3+ < Ce3+
(d) Pm3+ < La3+ < Ce3+ < Yb3+
(ii) Lanthanoid contraction is caused due to
(a) the appreciable shielding on outer electrons by 4f electrons from the nuclear charge
(b) the appreciable shielding on outer electrons by 5d electrons from the nuclear charge
(c) the same effective nuclear charge from Ce to Lu
(d) the imperfect shielding on outer electrons by 4f electrons from the nuclear charge
(iii) Identify the incorrect statement among the following.
(a) d-block elements show irregular and erratic chemical properties among themselves
(b) La and Lu have partially filled d-orbitals and no other partially filled orbitals
(c) The chemistry of various lanthanoids is similar
(d) 4f and 5f-orbitals are equally shielded
3. Match Column I with Column II and choose the correct option using the codes given
below:
Column I Column II
(Symbol) (Atomic Number)
A. Pr (i) 95
B. Yb (ii) 93
C. Np (iii) 70
D. Am (iv) 59

Codes
A B C D A B C D
(a) (i) (ii) (iii) (iv) (b) (iv) (iii) (ii) (i)
(c) (iv) (iii) (i) (ii) (d) (ii) (i) (iii) (iv)
4. What are the different oxidation states exhibited by lanthanoids ?
5. State the common oxidation state of
(i) lanthanoids (ii) actinoids
6. Name a member of the lanthanoid series which is well known to exhibit +4 oxidation state.

Short Answer Type I Questions |2 Marks|

7. Name the members of the lanthanoid series which exhibit +4 oxidation states and those
which exhibit +2 oxidation states. Try to correlate this type of behaviour with the electronic
configuration of those elements.
8. Use Hund’s rule to derive the electronic configuration of Ce3+ ion and calculate its
magnetic moment on the basis of ‘spin only’ formula.
9. Although, Zr belongs to 4d and Hf belongs to 5d transition series but it is quite difficult to
separate them, why ?
10. Actinoid contraction is greater from element to element than lanthanoid contraction.
Why?
11. The chemistry of the actinoid elements is not so smooth as that of the lanthanoids. Justify
this statement by giving some examples from the oxidation state of these elements.

Short Answer Type II Questions |3 Marks|

12. What are alloys ? Name an important alloy which contains some of the lanthanoid metals.
Mention its uses.
13. Which is the last element in the series of the actinoids ? Write the electronic configuration
of this element. Comment on the possible oxidation state of this element.
14. Compare the chemistry of actinoids with that of the lanthanoids with reference to
(i) electronic configuration (ii) oxidation state
(iii) chemical reactivity

Long Answer Type Questions |5 Marks|

15. (i) Yb2+ acts as a reductant while Tb4+ act as an oxidant. Why ?
(ii) Account for the following.
(a) Paramagnetism is shown by lanthanoid ions. Comment.
(b) Compare the basic strength of Ln(OH)3, Ca(OH)2 and Al(OH)3.
(c) Lanthanoids do not form complex.

Chapter Practice
Very Short Answer Type Questions |1 Mark|
1. Fill in the Blanks
(i) The general outermost electronic configuration for d-block elements is …….. .
(ii) The d-block element, which is liquid at room temperature is ……… .
(iii) The maximum oxidation state, exhibit by the element of 3d-series member is ……. .
(iv) Between lanthanoids and actinoids, more number of oxidation-states is shown by.
2. Objective Type Questions
(i) Zinc does not show variable valency like d-block elements because
(a) it is low melting
(b) its d-orbital is complete
(c) it is a soft metal
(d) two electrons are present in the outermost orbit
(ii) Among of the following outermost configurations of transition metals, which shows the
highest oxidation state?
(a) 3d5 4s1 (b) 3d34s2 (c) 3d54s2 (d) 3d6 4s2
(iii) The highest magnetic moment is shown by the transition metal ion with the outer
electronic configuration.
(a) 3d2 (b) 3d7 (c) 3d5 (d) 3d9
(iv) Amongst TiF 2−¿
6
¿
, CoF 3−¿¿
6 , Cu2Cl2 and NiCl 2−¿¿
4 , the colourless species are (atomic
number Ti = 22, Co = 27, Cu = 29, Ni = 28)

(a) CoF 3−¿¿

6 and NiCl 2−¿¿
4 (b) TiF 2−¿
6
¿
and CoF 2−¿
6
¿

(c) Cu2Cl2 and NiCl 2−¿¿

4 (d) TiF 2−¿
6
¿
and Cu2Cl2

3. Match Column I with Column II and choose the correct option using the codes given
below
Column I Column II
(Element) (Atomic number)
A. V (Vanadium) i. 93
B. Zr (Zirconium) ii. 40
C. Ce (Cerium) iii. 23
D. Np (Neptunium) iv. 58

Codes
A B C D A B C D
(a) (i) (ii) (iii) (iv) (b) (iv) (iii) (ii) (i)
(c) (ii) (iii) (i) (iv) (d) (iii) (ii) (iv) (i)
4. Why does the transition element scandium (Z = 21) not exhibit variable oxidation states ?
5. Explain the large difference in melting point of Cr (1920ºC) and Zn (420ºC).
6. Calculate the ‘spin only’ magnetic moment of M2+(aq) ion. (Z = 27).
7. Why does copper metal not replace hydrogen from acid?
8. Why are the Eº values of Mn, Zn more negative than expected?
9. The atomic size of Fe, Co and Ni are nearly same. Explain with reason.
10. Why Zn2+ salts are white while Ni2+ salts are blue?
11. Out of [Sc(H2O)6]3+ and [Ti(H2O)6]3+ ions, which is coloured and why? Give reason.
12. What factors led to the appearance of colour in the transition elements?
13. Draw the structures of manganate ion and permanganate ion.
14. Write the formula of compound in which transition metal is in +6 oxidation state.
15. In chromic acid, (CrO3), Cr has dº configuration but it is bright orange coloured solid,
why?
Short Answer Type I Questions |2 Marks|
16. Reactivity of transition elements decreases almost regularly from Sc to Cu. Why?
17. Why there is striking similarities (horizontal and vertical) among successive members of
the transition series?
18. (i) Why Cu+ salts are colourless, while Cu2+ salts are coloured?
(ii) The elements of d-series exhibit a larger number of oxidation states than the elements of
f-series. Explain.
19. Chromium is a typical hard metal while mercury is a liquid. Why?
20. What happens, when
(i) KMnO4 is heated? (ii) K2Cr2O7 is heated?
21. Why fluorine is stabilises in low oxidation states of transition metals?
22. Complete the following equations :
−¿ ¿
(i) 2MnO4 + 5S2- + 16H+ →

(ii) Cr2O 2−¿¿

7 + 20H- →

23. Write the oxidation reaction of iodide to iodate ion by potassium permanganate.

24. Explain why Cr2O2−¿¿

7 ion is a powerful oxidant in acidic medium but weak oxidant in
basic medium?
25. (i) In the titration of Fe2+ ions with KMnO4 in acidic medium, dil. H2SO4 is used but not
the dil. HCl. Why?
(ii) Arrange the following oxides of Mn in the order of their decreasing acidic nature. MnO,
Mn2O3, Mn3O4, MnO2, Mn2O7.
26. What happens when
(i) H2S reacts with acidified K2Cr2O7 solution ?
(ii) ethanol is oxidised with acidified K2Cr2O7 solution?

Short Answer Type II Questions |3 Marks|

27. How would you account for the following?
(i) Copper (I) is diamagnetic, whereas copper (II) is paramagnetic.
(ii) What is common oxidation state of Cu, Ag, Au?
(iii) The d1-configuration is very unstable in ions.
28. Give examples and suggest reasons for the following features of the transition metal
chemistry.
(i) The lowest oxide of transition metal is basic; the highest is amphoteric/acidic.
(ii) A transition metal exhibits highest oxidation state in oxides and fluorides.
(iii) The highest oxidation state is exhibited in oxoanions of a metal.
29. Although Cu+ does not exist in solution state, but CuCl (s) is formed in the presence of Cl-
ions in aqueous solution of Cu(s) and Cu2+. Explain.
30. Explain the following:
(i) The paramagnetic character in 3d transition series increases upto Cr and then decreases.
(ii) Transition metals are very good catalyst.
(iii) Transition metals form a large number of interstitial compounds.
31. The Eº value with respect of electrodes of chromium (Z = 24), manganese (Z = 25) and
iron (Z = 26) are
Cr3+ / Cr2+ = - 0.4 V; Mn3+ = 1.5 V
Fe3+ / Fe2+ = + 0.8 V
On the basis of the above information, compare the feasibilities of further oxidation of their
+2 oxidation state.

32. Which oxoanion (among VO 3−¿¿

4 , CrO 2−¿¿
4 , MnO 2−¿¿
4 or FeO 2−¿¿
4 ) is strongest oxidant and
which is weak oxidant?
33. Write the chemical equations for the following reactions:
−¿ ¿
(i) Oxidation of nitrite ion by MnO4 in acidic medium.
(ii) Acidification of potassium chromate solution.
(iii) Disproportination of Mn(VI) in acidic solution.
34. Write the chemical equations for the following reactions :
(i) Di proportionation of Mn2+ in acidic medium.

(ii) Disproportionation of MnO 2−¿¿

4 in alkaline medium.

(iii) Disproportionation of MnO2−¿¿

4 in acidic medium.

35. (i) How KMnO4 can be obtained from MnO2 , KOH and KNO3?
(ii) K2PtCl6 is a well known compound whereas corresponding Ni compound is not known.
State the reason for it.
36. Chromium is used extensively in steel alloys. It is extracted from its ore chromite
(FeCr2O4), which contains chromium in +3 oxidation state.
(i) Give the electronic configuration of the elements iron and chromium.
(ii) What is the oxidation state of iron in chromite?
37. Complete the following reactions :

(i) MnO4-(aq) + S2O32-(aq) + H2O (l) →

(ii) Cr2O72-(aq) + H2S (g) + H+ (aq) →

(iii) MnO4-(aq) + Fe2+(aq) + H+ (aq) →

38. Describe the factors on which the stability of an oxidation state of lanthanoid elements
depends.
39. The first few members of the series are quite reactive. They usually form oxides and
hydroxides. Complete the following reactions of lanthanoids.

(i) Ln Heated→with N (ii) LnWith halogens

→
(iii) Ln Burns∈O 2
→

40. (i) NbF4 is paramagnetic while NbX4 (X = Cl, Br, I) are diamagnetic, why?
(ii) Out of La(OH)3 and Lu(OH)3, which is more basic and why?

Long Answer Type Questions |5 marks|

41. (i) Write the steps involved in the preparation of
(a) K2Cr2O7 from Na2CrO4 (b) KMnO4 from K2MnO4
(ii) What is the effect of lanthanoid contraction on the chemistry of the lanthanoids?
42. (i) A blackish brown coloured solid A which is an oxide of manganese, when fused with
alkali metal hydroxide and an oxidising agent like KNO3, produces a dark green coloured
compound C. Identify A, B and C and write the reaction involved when compound C is
heated to 513 K.

(ii) (a) E M ¿
3+ ¿/M ¿
¿ values for the first series of transition elements are given below :

Eº(V) Ti V Cr Mn Fe Co
2+ ¿¿

M 3+¿/ M ¿
-0.37 -0.26 0.41 +1.57 +0.77 +1.97
Identify the two strongest oxidising agents in the aqueous solution from the above data.
(b) Copper (I) ion is not known in aqueous solution. Explain.
(c) In this series the highest oxidation state of a metal is exhibited in its oxide. Identify the
metal.