Chemistry

Marks:30 Subject:12th-Che Date:

Chapter:13 Amines Time:01 Hour
1
[A] Choose correct answer from the given alternatives and write it. [Each carries 1 Mark]
1) [15]
1. What is obtained on acetylation of aniline ?
X
(A) p-amino acetophenone (B) o-amino acetophenone
2 This is demo
(C) N-acetyl ans.
aminobenzene (D) Paracetamol
2. Which of the following is not a sandmeyer reagent ?
(A) Cu2I2 + KI (B) Cu2(CN)2 + KCN (C) Cu2Br2 + HBr (D) Cu2Cl2 + HCl
3. Which of the following substance does not react with C6H5SO2Cl ?
(A) (C2H5)3N (B) (CH3)2NH (C) CH3NH2 (D) C2H5NH2
4. Which of the following pair is used as reagent in carbyl amine reaction ?
(A) CHCl3 and Alcoholic KOH (B) KOH and HNO2
(C) KI and CHI3 (D) CHCl3 and NaNO2
5. What is the name of red azo dye ?
(A) p-hydroxy azobenzene (B) p-amino azobenzene
(C) b-napthyl azobenzene (D) p-N,N-dimethyl amino azobenzene
6. Which oxidised product is obtained when benzene diazonium chloride reacts with ethanol.
(A) Phenol (B) Benzene (C) Benzaldehyde (D) Acetaldehyde
7. Which is the main functional group in Acrolein ?
(A) Aldehyde (B) Alkene (C) Nitrile (D) Ester
8. Which of the following cannot form Hydrogen bond with water ?
(A) Phenol (B) Alcohol (C) Carboxylic acid (D) Tertiary amine
[Cu O] CHCl +
What is C in the following reaction ? Chloro benzene + 2NH3 ¾¾¾¾
2 ® B ¾¾¾¾ 3 ¾
® C
9. 473 K 3 KOH
60 bar D
(A) Phenyl cyanide (B) Benzene nitrile (C) Phenyl isocyanide (D) Nitro benzene
Br2 + 4NaOH
10. CH3CH2CONH2¾¾¾¾¾¾¾ ® Principal Organic Product (X) then what will be X ?
D
(A) CH3CH2NH2 (B) CH3CH2CH2NH2 (C) CH3CH2COOH (D) CH3NH2
11. The correct IUPAC name for CH2 = CHCH2NHCH3 is :
(A) Allylmethylamine (B) 2-amino-4-pentene
(C) 4-aminopent-1-ene (D) N-methylprop-2-en-1-amine
12. The source of nitrogen in Gabriel synthesis of amines is ...........
(A) Sodium azide, NaN3 (B) Sodium nitrite, NaNO2
– +
(C) Potassium cyanide, KCN (D) Potassium phthalimide, C6H4(CO)2 NK
13. The correct increasing order of basic strength for the following compounds is ..............

NH2 NH2 NH2

NO2 CH3
(I) (II) (III)

(A) II < III < I (B) III < I < II (C) III < II < I (D) II < I < III
14. Acid anhydrides on reaction with primary amines give ...........
(A) amide (B) imide (C) secondary amine (D) imine

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15. Cu/HCl ArCl + N + CuCl is named as ...........
The reaction ArN+2Cl– ¾¾¾¾¾ ® 2
(A) Sandmeyer reaction (B) Gattermann reaction
(C) Claisen reaction (D) Carbylamine reaction

[B] Answer the following Questions. [Each carries 1 mark] [01]

(i)HBF4
1. Complete the following reactions : C6H5N2Cl ¾¾¾¾¾¾¾¾
11.7) (ii) NaNO2 /Cu,D
®

[C] Answer the following Questions. [Each carries 2 marks] [10]

2. Match the reactions given in Column-I with the statements given in Column-II.
Column-I Column-II
(i) Ammonolysis (a) Amine with lesser number
of carbon atoms
(ii) Gabriel phthalimide (b) Detection test for
synthesis primary amines.
(iii) Hoffmann Bromamide (c) Reaction of
reaction phthalimide with KOH
and R – X
(iv) Carbylamine reaction (d) Reaction of alkyl-halides
with NH3

O
Cl
3. Identify A and B in the following reaction. KCN A H2/Pd B

NH2 NO2

4. How will you carry out the following conversion ?

Br
2.4)
5. Give one chemical test to distinguish between the following pairs of compounds : Aniline and
benzylamine
7.7)
6. Write short notes on the following : Gabriel phthalimide synthesis.

[D] Answer the following Questions. [Each carries 4 marks] [04]

7. A hydrocarbon ‘A’ (C4H8) on reaction with HCl gives a compound ‘B’, (C4H9Cl), which on reaction
with 1 mol of NH3 gives compound ‘C’, (C4H11N). On reacting with NaNO2 and HCl followed by
treatment with water, compound ‘C’ yields an optically active alcohol, ‘D’. Ozonolysis of ‘A’ gives
2 mols of acetaldehyde. Identify compounds ‘A’ to ‘D’. Explain the reactions involved.

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 Answer Key
Marks:30 Subject:12th-Che Date:
Chapter:13 Amines Time:01 Hour

Section [ A ] : 1 Mark MCQ

No Ans Chap Sec Que PageNo BookType

1 C Chap 13 (Part2) E-D 1 Kumar

RA
2 A Chap 13 (Part2) E-D 3 Kumar
3 A Chap 13 (Part2) E-D 6 Kumar
4 A Chap 13 (Part2) E-D 7 Kumar

ND
5 C Chap 13 (Part2) E-D 11 Kumar
6 D Chap 13 (Part2) E-D 17 Kumar

KE
7 A Chap 13 (Part2) E-D 21 Kumar
8 D Chap 13 (Part2) E-D 30 Kumar
9 C Chap 13 (Part2) E-D 37 Kumar

N
10 A Chap 13 (Part2) E-D HA 42 Kumar
11 D Chap 13 (Part2) D-A 2 Kumar
12 D Chap 13 (Part2) D-A 8 Kumar
13 D Chap 13 (Part2) D-A 13 Kumar
AS

14 A Chap 13 (Part2) D-A 19 Kumar

15 A Chap 13 (Part2) D-A 20 Kumar
AK

Section [ B ] : 1 Marks Questions

No Ans Chap Sec Que PageNo BookType

PR

1 - Chap 13 (Part2) C 11.7 Kumar

Section [ C ] : 2 Marks Questions

AR

No Ans Chap Sec Que PageNo BookType

1 - Chap 13 (Part2) D-C 66 Kumar
2 - Chap 13 (Part2) D-B 58 Kumar
M

3 - Chap 13 (Part2) D-B 64 Kumar

KU

4 - Chap 13 (Part2) C 2.4 Kumar

5 - Chap 13 (Part2) C 7.7 Kumar

Section [ D ] : 4 Marks Questions

No Ans Chap Sec Que PageNo BookType

1 - Chap 13 (Part2) D-E 75 Kumar

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