; AP Cbtmfs!

Yi Chanttt Z;
/ / ,, , ,
Y«ht Esvat1ans; Atomics - - --✓,,· / / ~ 4

. JatctvflflPbc IQd auantuml, Qec;trgn mnfiluration

1
• The most PfOrnlnent Hne In the
383.8 and 518.4 nm. spectrum of magnesium Is 285.2 nm. Other lines are found at

A In what ~ n of the electromaanetlc spectrum are these lines found? V1'

8
· Which Js the most energetJc? G'71..-v-tVVlo\ c:. f R 7.', ~ /e,,., / ,-
7
k J- . ·

C. What is the energy of one photon of the least .e erg~ light? / ?2U / t? - /
,,r<; lf xI 0-1-M s,, ~ it x , o.~ i \IV' ;::. s, ~-, x
e ~ b. ~ 7.- b '</()-)'f • ), Ox/()t> I~

2. Calculate the wavele111th associated with a rifle bullet (mass • 1.50&) and a velocity of 7.00 x 102
mph. · . \ __ h,
(o -i, ~)( J -1 't[,"; 1 • U _ ---Ti'
. /\~ (i,Sb';JC:r (7 rlf/ .-:;-L 1/x/o l •

3. The energy emitted when an electron moves from a t_,(gher energy state to a lo~r energy state
will emit electromagnetic radiation.

Which involves emission of less energy, an electron moving from n-4 to n=2 or an electron · £
A.
movh11 from n=3 to n=2? Explain. ~ - ;,- , :;:;:-f j 7 &? ; I e-f ~ i:-· c._ V
,f-t;
7
B. Calculate the wavelength of light emitted when an electron changes from n=4 to ,<=3 in tjle J \ )
H atom. What region of the electroma1netk spectrum Is this radiation found? - 2f'xl
5
~ 'r( -t0
C. You are ar) engineer designing a switch that works by the photoelectric effect. The metal _ 1 -.- ,.@2~
you wish f:O use in your device requires removal of. an electron from energy level, n=3. / ~ : .,,., f>.
I) How f!l~nergy is required to ionize this metal? tr-- o ~ e.- · ;!--iJ.
't °I (J )( 1{.o
ii) Will the switch wort if the light striklni the metal surface has a wavelength of 540 or ( _ - - nm
greater? Why or why not?
4. A. When n-4, 1=2, ml=-1, to what orbital tv,,pe does this refer? (.Give the orbital label, such as ls) L{-"J
How many . orbitals can occur at n=S? ~ , i. -, 1, '1
s. dv ~;i-... 1~Lf-
c. How ~any electrons can had have the designation of n=4, ml = +1? Ge- _ ··
o. How manv:electrons can had have the designation of n=6, I = 1, ml +1? = u
E. How many electrons can had have the desiination of n=3, I =2, ml == 0, ms =+1/2? (G

s. Explain briefly why each of the foHowlng is not a possible set of quantum num~rs for an
electron in an 'atom. ~ / ✓W
19
A. n- 2, I =2, ml= 0 . //' )J, ~ ,,:)___,.
a. n= 3, I -o, ml =-2 ') , /'() : ~ 1 l-d\ "
c. n,, 6, I =O, ml= 1 ~,It, ,') .( tAo ,r )
6. Write.the quantum numbers fur the 3 vale"":flectrons ohlu.;lnwn.
, ~ ,..
15, 7- (' 'l,/fy
CY )
7. kientJfy the followlna: f,'= O ,,;--t
~
f~ D
I .... I
'v\~I
A. 1s2ij2p'3s23p14s23d1° yvl. ~ ,.,, J ",_ I 2,
a. [KrJ ~ 24d~Sp1 ·
C. 1s2~2p'3 s23p14S23dJ04Ji'ss24d10Sp'6s24f"-5d'
D. ls22s~p'3s23p14s1 l

I
i
 AP Chemistry wlat· Lio Ea . .
•taations and Electron Confagurations
• Show ALL w,0 rk
on a separate sheet of paper. Watch sig figs and units.
Givm:
• Speed oflight = 3.00 x 10 1 mis
• Planck's constant= 6.626 x 10 ·34 J· s
• Rydberg constant= 2.178 x 10·18 J
MC:
l. Ener~y is absorbed in which of the following electronic transitions in hydrogen?
I. movmg an electron from n=l ➔ n=3
Il. moving an electron from n=3 ➔ n=l
III. moving an electron from a:, ➔ n=l

9 B) uonly C) DI only D) I .... " E) II and m

2 The Bohr model can be used to explain which of the following phenomena:
the line spectrum of hydrogen
the wave-particle duality of electrons
C. the hybridization of atomic orbitals
~ lectron density of s,p,d orbitals
P ,~ g of d electrons from nucleus

3. Which of the following could be the quantum numbers for the valence electron in a potassium
atom in its ground state?
A. 3,0,0, + ½
B. 3,1,1, + ½
~ 4,0,0, + ½
~ 4,1,1, + ½
E. 4,2,1, + ½

4. What is the maximwn number of electrons that can have the quantum numbers
n=4, ml= +l? ~
A. 2 B. 32 C. 8 D. 4 ~

s. Which of the following is an impossible set of quantwn numbers?

A 4,0,0, + ½
4,0, l, + ½
4,1,0, + ½
D. 4,1,1, + ½
.tt2/4,2,1,
.1y· . +½
 the same set o f
' in an atom can .haVC
no two eJec trons
that
W hich o f th e foJJowing rules states
6.
bers?
four quantum num
A. Hund's Rule ciple
e Hei se nb erg Uncertantity prin
B inciple
Pauli Exclusion pr
pothesis
The de Broglie hy
E. The Bohr mod
el l>it to '° 7
......j 9'n from n=_2 ,or , )
1,
7. How m uc h :i e rg y ts
. d to move an e ~
. require
, 1 r~ o
1 (-::10-
1 .---.. .
., tr -:: 1" - J.
A. 4.31 x 10· 11
x 1 0 ·"
11
1
- 1- ,

)
r ;
,I \
v
990x 10·
X 10 ·1 6 J
X ,o -1 9 J
2 1

e following element: {Ar} 4s 3d

8. Identify th E. Br
D. Sr
B. Cr (f )) = o
A. Ru equencies.
diations in order o ftlege,t,sil,f fr
tic ra
wing electromagne
9. Arrange the follo aves, x-rays
waves , JR, G ~ n . Blue, Microw
Radio
recn>Microwaves
Bl ue >x-ra ys > R. adio waves>IR>G
A. Jue>x-rays
aves > M icro waves> IR> Green> B
B. Radio w
es >Green>Blue
rays >IR > M icro waves>.Radio wav
C. x- -rays
es>I R >G recn>B lue>Microwaves>x
~ a d io wav > Radio waves
s >B lue >G reen >IR >Microwaves
(0ray

for the phosphide ion

tron configuration
10. Which is the elec
3
A. Js22s 2p6:Js23p
2

1
B. ls22s22p6Js
C. l s2is2ip6:3s23
p64s 1

1b./2 6
s22s22p 3s23p
2 2 6
6

( { , s 2s 2p
 FR:

1 enc yof 1.141 x 1014 Hzto reach

· An excited hydrog~ atom emits light with a hqu I?~ -i P
begin?
energy level n=4. Iri what energy level did the electron ,~ -/__0-' 7, tit tl
,.1 .
f :: G,b /, (;, y I is-. 7 , l ,I '! I ',/ I O h,
_, Cf t-/ '-
I ' I )
- __.,_
, "7-o ,,.,, ~ " I 7 x Ltl ./ l '1.,, ~

1 . Ci Grrfl ,, _,, /

; :; 0 ·

are n~ ed to ~IJ!ll the energy present in one

2. A) How many photons ofl.O mm wavelength light -6?- ,
- ..,;
photon oflight with a wavelength of 500. nm? - ~
,,- ~t. --6.:xl~ ~ J ·s .. J.~tnrl ,,... r
e /~ --s/-- - - -7 1""""' -- /
e ·/ 'e; o., x{ O
.- J r 7,,
q.oo ;L ( C> V"1 / 7/ f</><I [}
/

valence electron from phosphorous. What is the

B) It takes J060 kJ/mol of energy to remove the first ~, -/? ,,- ""-, V
phosphorous?
lowest frequency oflightthat can be used to ionize
1 /,JGVlt? ~· .;-7 I. 7( y/?J .,,
/ i ·-- •
/ (') 1< - (.~
I' ~ ,:-
tl -;7d
~ , v-· , I ~ I
 3. Silicon is a nonmetal with four valence electrons.
A) Write the ground state electron configuration for silicon.

D) Wrile the ,._ hand eJootrop configuration fouilicon . J ~ 7 ~

UV(1/ ~ f
C) Write the values for the quantum numbers that represent the four valence e
r lectronS below

m, m,
II I

7 0 Cl t- 1/7
,,
'3 e () Y-z
.-- / f 1/2
~ 1
7 { 6 r Y.1
?

4. Microwave ovens emit microwave radiation that is absorbed by water. The absorbed
radiation energy is all converted to heat that is transferred to other components of the food.
Suppose that a microwave radiation has a wavelength of 11.2 cm. How many photons are
required to heat 200.0 mL of coffee from 23 °C to 60 °C ? ( Asswne the density of coffee is
the
same as that of water (lg/ml )and specific heat of coffee is the same as water (4.184 J/g C))

~ ~ . t, I- 6 Y( c{lJ_ ("?- oo x I o i~0 ) - I, 77 "/ c; X l[)' Y-

E - -~ o " r(""l--' v-v'\ --

.,,,..-----

~ --:::,@
7
ic .1'l"J.)C11·c) <{
 Give:,
:
• ShowALLwo...,
.
AP c•-•m
PnctfceWorksbeet
1.11. on a separate sheet of paper.

• Speed of light= 3.00x10 1 mis

• Planck's constant= 6.626 x 10·34 J • s
• Ryberg constant= 2.18 x 10 ·11 J
• 2.204 lb ~ 1 kg

Part I: Quantum Namben and e- Conflguntion

1. Which of the following quantum numbers are not allowed? For each of the incorrect
sets, state the reason why it is incorrect. ·

L n=l, l=O, :.m, = I ;Vci v---

1
/ f
b. n=2, 1=2, ;ID/= I V'v 0
c. n=s, 1=3, :I D/= 2 f Ye
d. n=6, I= -2, m, = 2 /V ~
e. n=6, I= 2, ID/= -2 ye5
2. What is the max # of e- in a n atom with the following quantum numbers?
✓

a. n = 3 J <?c---i,. t -
b. n =2, J=O
c. n=2, I =2 v'\-t? · _
d n= 2, l=O, .m, = o, m, = + 1/2 !e
~
3. Write the full electron configuration for the roqoq elements 1'1 1
() '7 ;
• . J '1-). -1 "J.r~1/·7r(:,tt/.,1~! '- s
-1,vt ~'&f;, GGs""Lf f SJ Gr ....; J.r "l

L
b•
~ ~ ~ -i~<"
,,
t &')~1 ' r1 '1,5
- I .. "
~ J 1r
,,..
<;
.,
. i
Gi>IIALWe

U'oq- , ~s 1 "II
r
1
c. chlorine ,14 1,? 1:}v'7s
d. silver / 7 . . ., 1-.,,, 1s li'' '-ft..., 1

4. Write the short hand (noble g~) configuration for the following.
. tr
a. tungst~ [ x~] ~~ ~1 z-t/:~ J
b. tin LI\ (J 7c, ~{J 1) 1f
"l

c. boron [ r/0 i~"' ~r

5. Write the orbital notation for the following

L sulfur
b. strontium
c. manganese
d. krypton