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Introduction
The emissions of greenhouse gas (GHG) has noticed a steadfast upsurge since the outset of industrial revolution with an annual
increase over the last decade reported to be by an average of 2.7% (Cuellar-Franca and Azapagic, 2015). In order to avert
catastrophic aftermath, two major global gatherings took place in Kyoto (1997) and the other one in Paris (2015). The scientific
suggestion that came from the two meetings was that average global temperature increase as a result of climate change should be
limited to no more than 21C (Voll et al., 2012). For this target to be achieved, worldwide GHG emissions must be reduced by at
least 50% of their current values by 2050 according to IPCC (2013). Carbon dioxide (CO2) is the most popular and well-known
among various other gases that act as GHGs. It is characterized by high anthropogenic emission which acts as one of the major
contribution factor to global warming, caused mainly by fossil fuel combustion (Ustadi et al., 2017). The harmful nature and
impact of climate change and of fossil fuels are well established (McDonagh et al., 2019).
From pre-industrial level to present, concentration of CO2 was reported to have increased from 280 parts per million by
volume (ppmv) to 395 ppmv and it is estimated to reach a level of 570 ppmv by the end of this century (Goel et al., 2015). The
current atmospheric concentration of CO2 is estimated to be about 750 Giga tonnes which was projected to be on the increase for
the next 100 years to come (Fig. 1). This in turn caused the ocean to become acidic and more dangerously creating an imbalance in
the manner by which solar ultra-violet rays are trapped in the atmosphere thereby influencing how water is utilized by plants.
Upsurge in global temperature is therefore directly related to continuous CO2 emission (Fig. 2). Another issue considered by
environmental agencies that need to be drastically addressed is anthropogenic climate change (IPCC, 2005). Carbon capture and
storage is one of the many options that are gaining interest. It is a technology with the prospect of abating the anthropogenic
emissions of CO2 emissions and to achieve the target of holding the increase in the global average temperature at or below the
critical 21C threshold (Thomas et al., 2016; Wang and Qie, 2018). CCS from fossil-fired and bioenergy-fired plants was reported by
IPCC (2014) mutually contribute in reducing CO2 emissions by up to 25% till the year 2100 (Pachauri et al., 2014). Decoupling
energy use as well as CO2 release is a very vital long-term way of halting greenhouse gas emissions with the assumption that energy
use will continue to grow (Herzog, 2001). This can be achieved by utilizing renewable energy sources such as hydro, nuclear, wind,
solar, geothermal and tidal energy. However, these sources cannot fully replace fossil fuels, particularly given the numerous ways
in which such fuels are used and the current global framework for energy. The consequence is that fossil-fuel-based energy
infrastructure is currently been planned that will remain for decades, continuing to increase atmospheric CO2 concentration. This
article reports an overview of the CCS technology, its relevance as a multi-functional climate change mitigation option for oil and
gas companies and the associated challenges of its implementation.
Despite the controversy in the effects of carbon dioxide in the atmosphere, the average temperature of the Earth is rising, especially
when measured at the poles. Fig. 2 show good correlation between the average Earth surface temperature correlates with the amount
of CO2 in the atmosphere (i.e., upsurge in the atmospheric CO2 levels is directly proportional to the increase in surface temperature).
(3) 2RNH3 HCO3 -2RNH2 þ 2H2 O þ 2CO2 [Amines regeneration and carbon dioxide release for transportation to appropriate
geological storage unit]. Alternatively, the process can obey the following mechanism
The flow diagram of the main process is depicted in Fig. 3. Gas flow G1 gets entry from the bottom of the absorption column
with the liquid flow L1 coming in from the top. The rich liquid amine stream L2 enters to a heat exchanger to raise its temperature
and then pass to the stripper where it carries out amine regeneration. For the sake of verifying the mass balance of the whole
process, the regenerated liquid flow is mixed with MEA solution at 30% weight L5. Stream L6 is re-circulated to the absorption
column. The stability of the stream L5 was clue to know the iteration number in the simulator (Chavez and Guadarrama, 2008).
Post-combustion capture has an edge over other capture technologies, having the advantage of being compatible with existing
coal-fired power plant infrastructure as well as being retrofitted without requiring tangible change in basic combustion technology.
It has the highest priority when it comes to gas-fired power plants. Neither the oxy-combustion nor the pre-combustion
approaches are well suited for gas plants.
Another advantage it offers is flexibility as the power plant can still operate even if the capture plant is off but the other two
capture options are highly integrated with the power plant: So if capture fails, the entire plant must shut down. It also proffers
utilities which allow for increased capacity by temporarily restraining the capture process during periods of peak power demand.
Pre-combustion/syngas method is appropriate to integrated coal gasification combined cycle (ICGCC) plants, where by syn-
thetic H2 and CO2 rich gas is produced from the fuel (Heafeli et al., 2004). It first involved the gasification of coal to generate the
synthetic gas comprising of CO and H2 followed by “water-gas shift reaction” of the CO to produce CO2 for capture and H2 to a
turbine to generate electricity. This clean coal technology has good potential for future generation and is currently practised in few
existing facilities in the US and Europe.
Oxy-combustion process involves burning the fossil fuel in pure or enriched oxygen to produce a flue gas consisting mostly of CO2
and H2O vapour. The CO2 can be piped directly to storage unit after being compressed. Cooled flue gases are circulated with the sole
purpose of limiting the resulting flame temperatures to levels common during typical combustion and injected into the combustion
chamber. The constituents of flue gas are mainly carbon dioxide and water vapour, the latter of which is condensed through cooling.
The result is an almost pure carbon dioxide stream that can be transported to the sequestration site and stored. Power plant processes
that relies on oxyfuel combustion are also referred to as “zero emission” cycles, because the CO2 stored is not a fraction removed from
the flue gas stream (as in the cases of pre- and post-combustion capture) but the flue gas stream itself. It is also worth noting that no
matter how small a fraction of CO2 generated during combustion, it will inevitably end up in the condensed water. Thus the water
would have to be treated or be disposed fittingly to merit the label “zero emission”. The technique is encouraging though the initial air
separation step demands a lot of energy. This process is still at the Research and Development (R & D) phase. The main stages of the
above-mentioned three carbon capture methods are summarized in Fig. 4 (Agralı et al., 2018).
Chemical looping combustion (CLC) is an alternate method though under development. It is a method based on utilization of a
metal oxide as solid oxygen carrier. Metal oxide particles usually produces solid metal particles with a mixture of carbon dioxide and
water vapour when reacted with solid, liquid or gaseous fuel in a fluidized bed combustor, condensing the water vapour thereby
leaving the pure carbon dioxide ready for sequestration. The solid metal particles are circulated to another fluidized bed where they
react with air, producing heat and regenerating metal oxide particles that are recirculated to the fluidized bed combustor.
Eradicating CO2 from the atmosphere is a form of geoengineering by greenhouse gas remediation. Widespread media coverage
was given to techniques of this type due to their upper hand in offering the promise of a comprehensive solution to global
warming if they can be coupled with efficient carbon sequestration technologies. It is more common for such techniques to be
proposed for air capture, than for flue gas treatment. Carbon dioxide capture and storage (CCS) is more commonly proposed on
plants burning coal in oxygen extracted from the air, which means the CO2 is highly concentrated and no scrubbing process is
necessary. A hierarchical and multiscale framework was presented by Hasan et al. (2015) to design CCS and CCU supply chain
networks with less investment, operating and material costs by taking into consideration the selection of source plants, capture
processes, capture materials, CO2 pipelines, locations of utilization (for enhanced oil recovery) and sequestration sites, and
Fig. 3 Flow sheet diagram for post-combustion capture. Source: Chavez, R., Guadarrama, J.J., 2008. Optimized process for post-combustion CO2
capture in thermoelectric power plant using structured packing. Available at: http://www.aidic.it/pres11/webpapers/291Chavez.pdf.
4 Carbon Capture and Storage (CCS) Technology: Challenges to Implementation
Fig. 4 Basic principles of carbon capture. Reproduced from Agralı, S., Üçtug, F.G., Türkmen, B.A., 2018. An optimization model for carbon
capture & storage/utilization vs. carbon trading: A case study of fossil-fired power plants in Turkey. J. Environ. Manag. 215, 305–315.
amounts of CO2 storage. A profit of $9.23 per ton of CO2 was achieved by their optimized network. An optimal solution to the
problem of choosing between CCS and carbon trading was founded by Üçtug et al. (2014) for a hypothetical methanol production
facility. A non-linear optimization approach was employed with the objective of maximizing the net returns from pursuing an
optimal mix of CCS and carbon trading. The results are sensitive to carbon credit prices and the discount rate, which determines
the choices with respect to the future and present. Three alternative CCS configurations to the benchmark process which is
absorption by using monoethanolamine, (MEA) as solvent was compared by Schach et al. (2010). They concluded that “the
process with the highest energy savings is not the lowest cost of CO2-avoided, and the influence of rising investment costs of more
complex configurations cannot be ignored.” A coal-fired power plant was also studied by Cristobal et al. (2012a) for which they
considered installing four control devices in series. They assumed that bypassing one or more of these devices before the CO2
discharge point would be possible. They develop a mixed-integer nonlinear programming (MINLP) model that determines which
devices to use and the operating condition of each device. MINLP was also developed by Cristobal et al. (2012b) for a similar
problem where a set of pollution control retrofitting alternatives are considered to be installed in a cap and trade framework.
Ocean storage
Oceans can accommodate CO2 due to its being appreciably soluble in water. Upon its capture, CO2 could potentially be injected
directly into deep oceans and most of it would remain there for millions of years (IPCC, 2005). It was reported by Herzog (2001)
that the ocean embodies the largest storage option for the gas. Already 40,000 Giga tonnes of CO2 were reported to be confined in
the oceans in relation to the atmospheric concentration of only 750 Giga tonnes. Thus, quantities of CO2 that would double its
atmospheric concentration would only change the ocean’s concentration by 2% (Herzog, 2001). As such the countries with better
chance of storing large volume of the gas are those that are closed to the oceans. Below are among the various concepts proposed
for the ocean storage:
Carbon Capture and Storage (CCS) Technology: Challenges to Implementation 5
• Injecting CO2 by ship or pipeline into the water column at depths of 1000 m or more, and the CO2 subsequently dissolves.
• Depositing CO2 directly onto the sea floor at depths greater than 3000 m, where CO2 is denser than water and is expected to
form a ‘lake’ that would delay dissolution of CO2 into the environment.
• Converting the CO2 to biocarbonates (using limestone).
• Storing the CO2 in solid clathrate hydrate already existing on the ocean floor, or growing more solid clathrate.
Negative environmental effects of oceanic storage are usually reported though poorly understood. Living organisms in the
ocean are usually killed by high concentration of CO2 and also the ocean storage is not permanent too as the dissolved CO2 would
eventually equilibrate with the atmosphere. Also, the CO2 reacts with the water to form carbonic acid, H2CO3, hence increasing the
acidity of the ocean water.
CO2 þ H2 O-H2 CO3
About 1600 years was the order of time estimated to take water in the deeper oceans to circulate to the surface. The retention of
CO2 in the ocean would be enhanced by the bicarbonate approach which reduce the pH effects, but other environmental effects
and cost will also increase.
The inevitability of the effects of making the ocean more acidic are absolute as illustrated by Fig. 5, which are easy to predict
due to reliance on simple chemistry, not on complex computer models of climate. The ocean already holds 400 Billion tons of
fossil fuel CO2. Consequently, the ocean is already 0.1 pH units more acid than before industrial CO2 emissions. This means
nutrients for plankton in the North Sea, and all shallow ocean waters, are changing rapidly. This is the base of the food chain for
invertebrates, shells and, eventually, economic fishing. By 2050 the ocean will be five times more acid than at any time since
glaciation (change pH 8.4 to pH 7.8).
Mineral storage
Another form of carbon sequestration involve the reaction of naturally occurring Mg and Ca containing minerals with CO2 to
produce carbonates as can be seen from the following reactions.
2Mg þ O2 -2MgO; MgO þ CO2 -MgCO3
Geological storage
Several factors such as geological setting, integrity of the hydrocarbon column height (cap rock), quality of the reservoir and
possibility of unexpected events like earthquake need to be considered in order to strike a balance between permanent storage and
risks of leakage with regards to the geological storage options. Geological storage options involve depleted oil and gas reservoirs,
offshore and onshore deep saline formations, use of CO2 in enhanced hydrocarbon (oil or gas) recovery and in enhanced coal bed
methane recovery (Galadima and Garba, 2008). In 2001 according to Herzog and Golomb (2005), about 200 million cubic
Fig. 6 Application of CCS for EOR and enhanced methane recovery from coal seams.
meters of the gas were believed to be injected into more than 30 different oil and gas fields of Alberta and Columbia. The gas could
also be utilized in improving the recovery of coal bed methane especially with the fact that the surface structure of coal has good
adsorption affinity for CO2. With the possibility of achieving return on investment in short time, EOR becomes an economic
option with special interest to many oil and gas companies leading to the availability of more than 80 CO2-EOR projects world-
wide in the last 9 years, producing 200,772 bbls of oil per day (Herzog and Golomb, 2005). In general, the cheapest and most
environmentally friendly storage option is the geological storage.
In addition to all these, the captured CO2 can be applied for various other household and industrial applications which include
production of carbonated drinks and soda water, electric fire extinguishers, polymers and plastics, industrial welding urea or as a
promising solvent for organochlorine in the removal of caffeine from coffee, lipophilic organic compounds as well as an industrial
gas laser (CO2-laser). These therefore give a chance to various oil and gas companies to diversify their investments by establishing
related industries
Technology
Shifting towards low-carbon energy sources (more importantly biofuels) has special interest in many countries; most projections
show that the current environmentally undesirable fossil fuels will in the medium term continue to play a crucial role. For example
coal demand alone in developing countries will likely increase from 4215 to 5647 million tonnes from 2015 to 2030. In ensuring the
successful capture of CO2 that will be emitted in line with the combustion of these fuels, an effective technology is very vital. For
successful “Clean Coal Technology” alone, a range of modern technologies that are currently not available in developing countries
are certainly required. These technologies will cover the preparation of coal (washing and briquetting), combustion for example by
fluidised bed boilers and gasification, and clean-up of undesirable gases by processes like flue gas desulphurisation and deni-
trification before the ultimate carbon capture and storage. In fact the whole CCS process involved series of advance technologies, few
of which are under early stages of practise in some industrialised countries like United Kingdom and U.S.A. This clearly indicates that
inefficient technology will lead to a serious setback in implementing CCS in many regions and most developing countries, who do
not have enough technology to provide their citizens with basic amenities (Galadima and Garba, 2008).
Implementation time
Sufficient time and planning is also very crucial when it comes to the implementation of CCS system that can capture desired
quantities of greenhouse gases. In order to promote the efficient isolation and capture of CO2, Each oil and/or gas formation as
8 Carbon Capture and Storage (CCS) Technology: Challenges to Implementation
well as power generation facility (medium or large) requires unique method innovations (Galadima and Garba, 2008). There is
the need for appropriate technology and equipments to be put in place for the transportation of the gas either by pipelines or ships
and also the number of capture facilities fully implemented upon the effective capture costs and cost-sharing agreement finalised
between companies and appropriate authorities assigned by the government. Other reasons that can lead to the shift of project to a
longer period in many countries in addition to lack of efficient technology suitable for CCS include poor planning and imple-
mentation policies, potential cost inconsistencies, serious corruption problems and unmitigated insecurity in the oil industry.
Early compliance by oil and gas companies being the major emitters is another indicator of how shortly and successfully the
implementation will be. However, for CCS project to be successfully executed in the short term, those problems need to be
adequately addressed, which will yield positive results though very difficult (Galadima and Garba, 2008).
Conclusion
Carbon Capture and Storage (CCS) is a carbon emissions reduction process receiving special attention globally today. The
technology provides a good solution against the global climate change. It also provide low-carbon approach to use non-
renewable fuels like coal or natural gas to ensure security of power supply and is a good opportunity for Enhanced Oil Recovery
(EOR) from low producing or partly depleted petroleum formations. In this article, an evaluation of CO2 capture, transpor-
tation and storage potential was given, which include storage site screening, storage mechanism analysis, and storage capacity
evaluations. Though the current economic situation does not consider the process as financially viable, CCS will play a
significant role in mitigating future emissions especially from developing countries. However, careful approach is required to
avoid more problems than benefits. Successful implementation of the technology must be planned ahead of time, effective
future agreement is required from the sides of both government and oil companies, policies and strategies shall be base on
research findings by environmental, geological and policy analysts couple with lessons from prior developed and developing
countries. With correct policies, government and financial support, CCS will undoubtedly play more and more important role
on sustainable development.
References
Agralı, S., Üçtug, F.G., Türkmen, B.A., 2018. An optimization model for carbon capture & storage/utilization vs. carbon trading: A case study of fossil-fired power plants in
Turkey. J. Environ. Manag. 215, 305–315.
Anderson S., Newell R., 2003. Prospect for Carbon Capture and Storage Technology: Resources for the Future. Discussion Paper 02- 68, Washington, DC.
Chavez R., Guadarrama J.J., 2008. Optimized process for post-combustion CO2 capture in thermoelectric power plant using structured packing. Available at: http://www.aidic.it/
pres11/webpapers/291Chavez.pdf.
Cristobal, J., Guillen-Gosalbez, G., Jimenez, L., Irabien, A., 2012a. Optimization of global and local pollution control in electricity production from coal burning. Appl. Energy
92, 369–378.
Cristobal, J., Guillen-Gosalbez, G., Jimenez, L., Irabien, A., 2012b. Multi-objective optimization of coal-fired electricity production with CO2 capture. Appl. Energy 98, 266–272.
Cuellar-Franca, R.M., Azapagic, A., 2015. Carbon capture, storage and utilisation technologies: A critical analysis and comparison of their life cycle environmental impacts. J.
CO2 Util. 9, 82–102.
FAO, 2009. Food and Agricultural Organisation of United States Publication. 6. Food and Agricultural Organisation of United States publication. pp. 117–124.
Galadima, A., Garba, Z.N., 2008. Carbon capture and storage in Nigeria: Fundamental science and potential implementation risks. Sci. World J. 3, 95–99.
Galadima A., Kabiru A., Garba Z.N., Abubakar A., 2009. Carbon capture and storage (CCS): A future challenge to Nigeria. A Paper Presented During the 7th CHEMCLASS
Conference, A,B.U. Zaria-Nigeria.
Goel, C., Bhunia, H., Bajpai, P.K., 2015. Development of nitrogen enriched nanostructured carbon adsorbents for CO2 capture. J. Environ. Manag. 162, 20–29.
Heafeli, S., Bosi, M., Philibert, C., 2004. Carbon Dioxide Capture and Storage Issues – Accounting and Baselines under the United Nations Framework Convention on Climate
Change (UNFCCC). IEA Information Paper, Paris May 2004.
Hasan, M.F., First, E.L., Boukouvala, F., Floudas, C.A., 2015. A multi-scale framework for CO2 capture, utilization, and sequestration: CCUs and CCU. Comput. Chem. Eng. 81,
2–21.
Hendriks, C.A., Wildenborg, A.F.B., Blok, K., Floris, F., Vanwees, J.D., 2000. Cost of carbon removal by underground storage. Paper presented at the 5th International
Conference on Greenhouse Gases Control Technology (GHGT-5), Cairns, Australia, August, 13-16.
Herzog, H.J., 2001. What future for carbon capture and sequestration? Environ. Sci. Technol. 35, 148A–153A.
Herzog, H., Golomb, D., 2005. Carbon Capture and Storage From Fossil Fuels Use. Cambridge, Massachusetts: Massachusetts Institute of Technology, (Article Number: NRGY:
00422).
IPCC, 2013. Climate Change 2013: The Physical Science Basis. Technical Report. Intergovernmental Panel on Climate Change.
IPCC, 2014. Report on Climate Change: the Physical Science Basis. Technical Report.
IPCC, 2005. Facts on CO2 capture and storage. A summary of special report by the Intergovernmental Panel on Climate Change. Available from: http://www.greenfacts.org/en/
CO2-capture-storage/.
Markewitz, P., Kuckshinrichs, W., Leitner, W., et al., 2012. Worldwide innovations in the development of carbon capture technologies and the utilization of CO2. Energy Environ.
Sci. 5, 7281–7305.
McDonagh, S., Wall, D.M., Deane, P., Murphy, J.D., 2019. The effect of electricity markets, and renewable electricity penetration, on the levelised cost of energy of an
advanced electro-fuel system incorporating carbon capture and utilisation. Renew. Energy 131, 364–371.
MGA, 2009. Carbon capture and storage and enhanced oil recovery, fact sheet. Available from: http://www.midwesterngovernors.org.
Pachauri, R.K., Meyer, L.Y., IPCC, 2014. Climate Change 2014: Synthesis report. Contribution of working groups I, II and III to the fifth assessment report of the
intergovernmental panel on climate change.
Schach, M.O., Schneider, R., Schramm, H., Repke, J.U., 2010. Techno-economic analysis of postcombustion processes for the capture of carbon dioxide from power plant flue
gas. Ind. Eng. Chem. Res. 49, 2363–2370.
Carbon Capture and Storage (CCS) Technology: Challenges to Implementation 9
Thomas, B., Henriette, N., Barbara, O.K., 2016. Separating the debate on CO2 utilisation from carbon capture and storage. Environ. Sci. Policy 60.
Üçtug, F.G., Agrali, S., Arikan, Y., Avcioglu, E., 2014. Deciding between carbon trading and carbon capture and sequestration: An optimisation-based case study for methanol
synthesis from syngas. J. Environ. Manag. 132, 1–8.
Ustadi, I., Mezher, T., Abu-Zahra, M.R.M., 2017. The effect of the Carbon Capture and Storage (CCS) technology deployment on the natural gas market in the United Arab
Emirates. Energy Proced. 114, 6366–6376.
Voll, D., Wauschkuhn, A., Hartel, R., Genoese, M., Fichtner, W., 2012. Cost estimation of fossil power plants with carbon dioxide capture and storage. Energy Proced. 23,
333–342.
Wang, X., Qie, S., 2018. When to invest in carbon capture and storage: A perspective of supply chain. Comput. Ind. Eng. 123, 26–32.
Williams T., 2006. Carbon capture and storage technology, capacity and limitations, Canada Library of Parliament publication, PRB 05-89E, Available from: http://www.parl.gc.
ca/information/library/PRBpubs/prb0598-e.pdf.