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INTRODUCTION
238 + 24
234
92U 90Th
(1) The phenomenon of radioactivity was (Parent) (Daughter)
discovered by Henry Becquerel in uranium
salts. (1896) 90Th
234 91Pa234 + -1
0 +
(Parent) (Daughter) (Antinentrino)
(2) After the discovery of radioactivity in uranium,
Piere curie & Madame curie discovered a (11) In this phenomenon, particles and -rays
new radioactive element called ‘radium’. It is are emitted. For a given nuclei at a particular
106 times more radioactive than uranium. time emission of either or takes place,
Radium was extracted from pitch blende never both at time.
(a kind of coal tar) for which curies were
honoured by nobel prize in 1903. (12) rays are emitted in when an excited nuclei
makes transition to any lower or ground
(3) Definition : -The self, spontaneous, energy state the form of photon.
disintegration (i.e. decay) of unstable 238 * Th234 + 24
92U 90
radioactive nuclei’s is known as radioactivity
& the nucleils exhibiting this phenomenon
are known as radioactive nuclelis.
dt
dN N0
Ni
N = – ti N
n n NNi
f
– t t if
t N0/2
N0/4
Nf
n N = – [tf – ti]
i
57
N
Sum of lives of all nuclei' s
(ii) = Total no. of nuclei present =
0 t dN (vii) Fraction of active nuclei left = N
0
N0 (probability of survival)
(viii) Fraction of decayed nuclei
(iii) The average time taken in decaying by the
nuclei of an element is defined as its mean N N0 N
life . = 1 – N = N
0 0
1 (Probability of decay)
(iv) =
(ix) When decay process is too slow
N then N = N0 [e–t]
(v) n N = – t
0 N = N0 [1– t]
N = [– N0] t + N0
On comparingy = m x + c
N
The magnitude of inverse of slope of n N & t
0
(vi) In N = N0 e t
1
If t =
(x) Half life, mean life & decay constant for a
then N = N0 e–1
particular nuclei always remains constant.
N0 N0 (xi) Decay constant () :
= = 2 . 718 = 0.3676 N0 0.37 N0
e
( ) dN
1 N0 (i) = dt
Therefore if = t = then N = 0.37 N0
e N
Mean life of a radio active nuclei is equal to that Rate of decay at a given instant
1 = No. of active nuclei at that instant
time is which no of nuclei left becomes either
e
times the original nuclei or approximately 37% of
dN
the original nuclei.
(ii) = N
or, Number of decayed nuclei in mean life dt
N0 = Probability of decay in unit time.
= N0 – N = N 0 –
e N0
(iii) If = t–1 then N = = 0.3676
e
1
= N0 1 0.63 N0 N0 0.37 N0
e
Decay constant is equal to inverage of that
Mean life is equal to that time in which no. of time in which no. of active nuclei left becomes
e 1 1
decayed nuclei becomes either times either
e
times or approx 37% original
e
nuclei.
original nuclei or apporoximately 63% of original
(iv) N = N0–t
nuclei.
can be written in the form of mass as below
m = m 0e–t
58
When m = mass of radio active nuclei at 4. PAIR PRODUCTION & PAIR-ANNIHILATION
time t & m 0 = mass of radioactive nuclei at
time t = 0 Collision of -ray photon by a nucleus &
production of electron positron pair is known as
m 1
pair production.
m0 = 2t / T
(v) Decay constant is equal to inverse of the
time in which 63% of initial atoms (N 0) is
being decayed.
(vi) Unit :- (second)–1 or (minute)–1 or (year)–1
3. ACTIVITY (A or R)
The rest mass of each of the electron & the
(1) Activity of any element shows instability of
positron is 9.1 x 10–31 kg. so, the rest mass
the element at any time (t).
energy of each of them is
(2) Activity is defined as rate of decay at given
E0 = m 0c2= (9.1 × 10–31) (3 × 108)2
instant.
= 8.2 × 10 –14 Joule
dN = 0.51 MeV
A = – = N
dt Hence for pair-production, it is essential that the
energy of -photon must be at least 2 × 0.51
= 1.02 MeV.
A N
A N 1
= = e t =
A0 N0 ( 2) t / T
59
(3) Neutron :It was discovered by Chadwick in 1932. (iii) Neutral pi-meson : This particle has no
It carries no charge. Its mass is 1839 times the charge. Its mass is nearly 264 times the
electronic mass (1.675 x 10–27 kg). In free state electronic mass. Its mean life is of the order of
the neutron is unable (its mean life is about 10–15 second. Its symbol is 0. On disintegration,
17 minutes), but it constitutes a stable nucleus it forms two -photons:0 .
along with proton. Its symbol is n or 0n1.
(9) Photon :These are the bundles of
(4) Positron :It was also discovered in 1932 by electromagnetic energy and travel with the speed
Anderson. Its charge and mass are same as of light. If the frequency of waves be , then the
those of electron, the only difference being that energy of a photon is h and momentum is h/ c.
is positively-charged whereas the electron is Its symbol is .
negatively-charged. Its symbol is e+ (or +1 0).
Mass
Name of (in comparision Average life
(5) Antiproton :It was discovered in 1955. Its particle
Symbol Antiparticle
to mass of (in second)
charged and mass are same as those of proton, electron)
the only difference being that it is negatively
Photon ( ) 0 Stable
charged. Its symbol is p¯.
Electron e-1 e+1 1 Stable
Proton p+ p– 1836 Stable
(6) Antineutron : It was discovered in 1956. It has
Neutron n n– 1839 1010
no charge and its mass is equal to the mass of Neutrino
neutron. The only difference between neutron and Charged v v– 0 Stable
antineutron is that if they spin in the same pi-meson
direction, their magnetic moment will be in Uncharged + – 274 2.6 × 10–8
opposite directions. The symbol for antineutron pi-meson 0 ( 0) 264 0.9 × 10–16
is n¯.
6. CHARACTERISTICS OF RADIOACTIVE
(7) Neutrino and Anti-neutrino : The existence of RADIATIONS
these particles was predicted in 1930 by Pauli
6.1 Characteristics of - decay
while explaining the emission of -particles from
radio-active nuclei, but they were observed (1) - particle are two times ionised Helium
experimentally in 1956. Their rest-mass and atoms.
charge are both zero but they have energy and (2) - particle carry 2- proton and 2 neutrons.
2He (Nucleus) = -particle
momentum. Both neutrino and anti-neutrino are (3) 4
stable particles. The only difference between them (4) In general - decay is given by
is that their spins are in opposite directions.
Their symbols are v and v respectively.. ZX
A
decay
Z-2Y
A-4 + 2He4 + (Energy),
(-particle)
(8) Pi-mesons :The existence of these particles was
atomic number decreases by 2 & mass no.
predicted by Yukawa in 1935 as originator of
decreases by 4.
exchange-forces between the nucleons, but they
were actually discovered in 1947 in cosmic rays. (5) Mass of - particle = (2p + 2n)
Pi-mesons are of three types. = 6.68 × 10 -27 kg
(i) Positive pi-meson : It is a positively charged Charge of - particle = + 2e
particle whose charge is equal to the electronic = 2 × 1.6 × 10-19 coulomb, (+) Ve.
charge and whose mass is 274 times the (6) In - particle emission an element goes two
electronic mass. It is an unstable particle. Its column backward in periodic table.
mean life is of the order of 10 –8 second. Its (7) Energy in - particle emission
symbol is +.
= (Mx– My – M 2 He 4 ) C2
(ii) Negative pi-meson : It is a negatively
charged particle whose charge is equal to the Energy in - particle emission varies from
electronic charge and whose mass is 274 time 4.5 MeV to 11 MeV. Through calculation
the electronic mass. It mean life is also of the - Particle has to crop potential barrier of
order of 10–8 second. Its symbol is ¯. 21 MeV for their emission. Hence -particle
emission can not be explained on the basis
of classical theory.
60
(8) Emission of -particle can be explained on (8) To explain energy conservation, linear
the basis of quantum mechanics (Tunnel momentum conservation and angular
effect). momentum conservation, a hypothetical
(9) Energy spectrum of - particle is line neutrino was considered
spectrum. (9) Neutrino was first given Pauli.
(10) Energy spectrum of -particle also has micro (10) According to neutrino hypothesis, some
details particle also emits with -emission, which is
(11) Energy spectrum of -particle shows that a called neutrino.
nucleus also has energy levels like atoms (11) Rest mass and charge of neutrino are both
have. zero and angular or spin momentum of
(12) Energy of -particle emitted from a single neutrino is ± ½ (h /2). It travel with speed
nucleus are not same. These emit in various of light and it's spin value is ± ½.
energy groups. (12) So by neutrino hypothesis , emission of
(13) Range of - particle (velocity)3 particle reaction
R v3 0n 1p1 + -1e0 + (Anti-Neutrino)
1
or 0n1 1p1 + -1e0 ( -) (4) These are high energy rays (of photons)
61
(5) When or particle emission takes place, (3) Uranium series (4n + 2 series ) :-
nucleus come in excited state and during
92U
238 Irregular
82Pb
206 (stable)
coming back to normal state radiation , decay
emission takes place
(4) Actinium series (4n+3 series) :-
27Co
60 28Ni
60(exicited state) + -1e0
235 Irregular
207
60 60 92U , decay 82Pb
28Ni (exicited state) 28N (ground state)
+ Q (gama rays) Last element of radio active series is stable
and decay constant of that element has value
(6) In -decay atomic no. and mass no does not equal to zero.
changes.
8. RADIOACTIVE EQUILIBRIUM
(7) Energy spectrum of -rays is line spectrum.
NA A = NB B = ...........
(8) This spectrum verifies that same energy levels
NA NB
are found in nucleus as that of in atom or =
outside the nucelus. TA TB = ..............
93Np
237
Irregular
83Bi209 (stable)
, decay
62
10. POINTS OF REMEMBER (14) Size of nucleus decreases by -emission.
(15) Cloud chamber is used for detecting
(1) Radioactive decay is a nuclear process. radioactive radiations and for determining their
(2) The decay constant of the end product of a paths, range and energy.
radioactive series is zero. (16) Geiger-Muller counter is used for detecting
(3) Radioactivity is not an atomic process. -and -particles and measuring half life.
(4) - rays are never emitted directly by the (17) Coefficient of absorption depends on the
nuclei. wavelength of -rays and the nature of
(5) The time taken by any radioactive material to absorbing material.
decay completely is infinity irrespective of its (18) The mass number and the charge number
mass and decay constant. remain unchanged by -decay
(6) Radioactivity is not associated with the (19) When a -particle is emitted by a nucleus
electron configuration in atom. then its mass number remains unchanged
(7) The spectrum of -rays is a discrete line where as the charge number increases or
spectrum. decreases.
(8) The charge on neutrino is zero. (20) When an -particle is emitted by a nucleus
(9) Activity depends on the quantity & nature of then its atomic number decreases by 2 and
that material. mass number decreases by 4.
(10) Radioactivity remains unaffected due to the (21) There are five types of radioactive
physical and chemical changes of the disintegration.
material. (22) Radiation dose is measured in sieverts (Sv).
(11) 1 curie = 3.7 x 1010 disintegration/sec. (23) The interaction responsible for beta decay is
(12) 1 Rutherford = 106 disintegrations/sec. called weak interaction.
(13) decay is explained on the basis of tunnel
effect.
63
SOLVED EXAMPLES
Ex.1 The half life of polonium is 140 days. In what n n
time will 15 gm of polonium be disintegrated N0 1 1 1
= N0 , =
out of its initial mass of 16 gm ? 4
2 4 2
(A) 500 days (B) 480 days n 2
(C) 560 days (D) 280 days 1 1
= n = 2
Sol. Suppose the initial mass of a radio active 2 2
element is N0. The mass of the element left time of disintegration = half life x number of
n
1 half lives = 1600 × 2 = 32 00 years
after n half-lives is given by N = N 0
2 Ex.4 Find the half-life period of a radio-active
n
material if its activity drops to 1/16 th of its
N 1 initial value in 30 years.
N =
0 2 (A) 15 yr. (B) 7.5 yr.
N0 = 16 gm. The mass of the disintegrated (C) 22.5 yr. (D) 120 yr.
element is 15 gm So, the mass of the Sol. If the initial mass of some radio-active
element left is N = 16 – 15 = 1 gm. Thus element be N0, then the mass of the element
remaining after n half-lives is given by
n
1 1
= n = 4 1
n
16 2 N = N0
2
The half life of polonium is 140 days. Hence,
n n
the time taken in the disintegration of N 1 1 1
150 gm polonium = half-life × no. of half lives N = =
0 2 16 2
= 140 × 4 = 560 days
Ex. 2 The half life of radium is 1600 years. In how n 4
1 1
15 = n = 4
much time will its fraction disintegrate ? 2 2
16
(A) 6400 years (B) 3200 years Half life of the substance
(C) 1600 years (D) 8000 years
time of disintegra tion 30
= = = 7.5 years.
T log(N0 / N) number of half lives 4
Sol. Ist time of Decay t = log 2 Ex.5 If a radio active material contains 0.1 mg of
Th234, how much of it will remain unchanged
16 after 120 days ? Its half life is 24 days.
1600 log 4 1600 log 2
t = 1 = , (A) 0.0312 gm (B) 0.0312 mg
log 2 log 2 (C) .00312 mg (D) .00312 gm
Sol. T = 24 days, t = 120 days
t = 6400 years
Ex. 3 The half-life of radium is 1600 years. After M0 t N0
= = 2120/24 = 25 = 32, N = ,
how many years 25% of radium block m 2T 32
remains undecayed?
Original mass 0 .1
(A) 3200 years (B) 4800 years Mass left = =
32 32
(C) 7200 years (D) 9600 years
Sol. Suppose the initial quantity of radium is N 0. = .003125 mg
Then the quantity left after n half-lives will be Ex.6 The half life of a radioactive material is 12.7 hr.
n What fraction of the original active material
1
N = N0 would become inactive in 63.5 hr ?
2 (A) 1/32 (B) 1/23
N0 (C) 31/32 (D) 23/32
Here, N = 25 % of N0 = Sol. t = 63.5 Hr, T = 12.7 Hr.
4
64
N 1 1 1 T log2 4 log 2
N0 = 2 t / T = 2( 63.5 / 12.7) = 25 8 = 8 = 4T log 2
log 2
N 1 T = 2sec
N =
0 32 N0 1600
N = = N = 200 counts/s
Inactive fraction 2 t/T
26 / 2
N 1 31 Ex.10 1 milligram radium has 2.68 × 1018 atoms.
= 1 – N = 1 – = Its half-life is 1620 years. How many radium
0 32 32
atoms will disintegrate from 1 milligram of
Ex.7 The activity of a radioactive sample drops of pure radium in 3240 years ?
1/32 of its initial value in 7.5 h. Find the half (A) 2.01 × 1018
life ? (B) 0.75 × 1018
(A) 7.5 Hr. (B) 5 Hr. (C) cannot be predicted
(C) 1.5 Hr. (D) None (D) None
R 1 Sol. If the initial quantity of a radio-active element
Sol. Given, R = , t = 7.5 h be N0, then the quantity left after n half-lives
0 32
n
1
R 1
t/T is given by N = N0
2
R0 = 2
The half life of radium is 1620 years. The
7 .5 / T 5 7 .5 / T number of half-lives in 3240 years is
1 1 1 1
= = , 3240
32 2 2 2 n = = 2
1620
7 .5
5 = 7.5/T T = = 1.5 hours 1
2
5
N = 1 ×
Ex.8 A radio active sample contains 10 6 2
radioactive nucleus. It's half life is 20 sec. ( N0 = 1mg), N = 1/4 = 0.25 m
Number of remaining nucleus after mass of disintegrated radium
10 seconds.
= 1– 0.25 = 0.75 m
(A) 7.09 (B) 7.09 × 105
Number of atoms in it = 0.75 × (2.86 × 10 18)
(C) 79 (D) 709
= 2.01 × 1018
1
t/T Ex.11 The mean lives of a radioactive material for
Sol. N = 106 and radiations are 1620 and 520 years
2
respectively. The material decays
10 / 20
simultaneously for and radiations. The
1 time after which one fourth of the material
N = 106 N = 106/ 2 = 106/1.41
2 remains undecayed is-
N = 7.9 × 105 (A) 540 years (B) 324 years
Ex.9 The count rate of a radio active source at (C) 720 years (D) 840 years
t = 0 was 1600 count/s and at t = 8 sec, it
was 100 counts/s. The count rate (in counts) 1620 520
Sol. =
at t = 6 sec will be- = 1620 520 = 394 years
(A) 150 (B) 200
(C) 300 (D) 400 N0
Time of decay t = 2.303 log10
N
N0 1600 t = 394 × 2.303 log104
T log T log T log16
Sol. t = N 8 = 100 = t = 394 × 2.303 × 0.602
log 2 log 2 log 2
t = 546 years
65
Ex.12 When 90Th228 gets converted into 83Bi212, Ex.15 In 420 days, the activity of a sample of
then the number of -and -particles emitted polonium, Po fell to one lights of its initial
will respectively be- value. Nuclear reaction is following
(A) 4 , 7 (B) 4 , 1 a
Po dc 206
Pb ef Half life of
(C) 8 , 7 (D) 4 , 4 b 82
228 = 212 + x ( He4) + y(-1e0) polonium & value of a,b, c, d, e, f will be-
Sol. 90 Th 83 Bi 2
(A) 140, 210, 84, 4, 2, 0, 0
According to law of conservation of charge
(B) 420, 208, 83, 2, 1, 0,0
90 = 83 + 2x – y
(C) 420, 210, 84, 2, 4, 0, 0
2x – y = 7
(D) 140, 210, 84, 2, 4, 0, 0
According to law of conservation of mass
number 228 = 212 + 4x N0
Sol. = 2t/T, 8 = 2t/T 23 = 2t/T
4x = 16, x = 4, 2 × 4 – y = 7, y = 1 N
Hence 4 and 1 will be emitted. 3 = t/T T = t/3 = 420/3 = 140 days
Ex.13 A radioactive Nucleus decays as follows: Reaction will be,
A
A2
A1
A4
A3 210
84 Po 42 206
82 Pb 00
If the mass number and charge number of A Ex.16 A freshly prepared radioactive sample, with
are 180 and 72 respectively, then for A4 these half-life 2 hours, emits radiations whose
values will respectively be- intensity is 64 times higher than its safe
(A) 172, 69 (B) 108, 252 level. The minimum time after which it will be
(C) 108, 72 (D) None safe to work with the sample will be-
Sol. 180 4 176 (A) 42 hr (B) 6 hr
72A = 2He + 70A1
A 176 = e0 + 176 (C) 128 hr (D) 12 hr
70 1 -1 71A2
t/T t/2
71A2
176 = 2He4 + 69A3172 , 69 A 172 N 1 1 1 1
3
Sol. =
N0 = 2 =
64 64 2
= + 69 A 172
4
6 t/T
Ex.14 If the activity of radioactive sample drops to 1 1
1/32 of its initial value in 7.5 Hr. Half life will =
2 2
be-
(A) 3 Hr (B) 4.5 Hr t = 6T = 12 hr.
(C) 7.5 Hr (D) 1.5 Hr.
Sol. A = A0/32, t = 7.5 Hr, T = ?
A0
= 2t/T
A
32 = 2t/T 25 = 2t/T 5 = t/T
T = t/5 T = 7.5/5 = 1.5 Hr.
66